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By George J. Karcas

"Non-ferrous metals such as copper, nickel, lead, zinc and precious metals are produced via the electrorefining and electrowinning processes. Apart from controlling electro-chemical conditions for the production of these metals, there has always existed the challenge of controlling the corrosive effect of the electrolyte environment which serves as the medium for non-ferrous metal production.The practice of acid containment in electrometallurgical operations has entered the world of high technology with the advent of advanced acid resistant materials such as vinyl ester resin which is either combined with aggregate to form polymer concrete or used to line various acid containment vessels and ·surfaces. ill comparison to some Asian, European, and African copper refineries, the North and South American copper industry has recently embraced quite heavily in the use of polymer concrete electrolytic cells and process vessels, such as electrolyte storage tanks, and in the use of vinyl ester resin for corrosion protective surface sealing 'systems in lieu of epoxy, acrylic and other materials because of its combination of higher corrosion resistance and superior flexibility.Electrolytic cell construction has undergone a transformation from a multiple part configuration to a single piece moulded/cast unit. ·The one piece moulded polymer concrete cell, which has been patented by Corrosion Technology International, with the overflow, decant, inlet, fast fill and segregation systems integrally designed is now the industry standard.. The combination of a wood, steel, or concrete frame with a lining made of lead, asphalt, rubber or plastic has been historically successful in providing limited protection from chemical and mechanical attack in electrolytic cells and electrolyte storage tanks all over the world. These combinations have now become obsolete as materials such as polymer concrete provide exceptional corrosion and mechanical protection with greatly reduced maintenance requirements and improved efficiency and productivity for the tankhouse. ill addition, polymer concrete can be disposed of in a regular land fIll which is much less costly than disposing of contaminated concrete that is normally associated with conventional lined concrete cells."

Jan 1, 1997

By Claude Lorenson

"The Spyrometer™ imaging pyrometer brings new dimension of imaging capabilities to temperature measurement technology by combining a high temperature video camera with scanning optical pyrometry. This gives the operators the ability to observe process conditions while measuring the temperature of virtually any object or region in the field of view. Since the lens tube of the camera can be air or water cooled, it is possible to see inside furnaces giving a very good view of many different types of metallurgical processes. Specific benefits in process knowledge and maintenance tasks for furnaces in different types of metal industries are discussed.1-Principles of Imaging PyrometryLens tube, camera and processorImaging pyrometry is the combination of video imaging and computer-driven pyrometry that measures the temperature of certain zones (selected by the operator) within the image viewed on the monitor screen. To obtain a detailed image of the metallurgical process under observance, it is necessary to place the optical objective of the camera close to the process. The Spyrometer™ (which is Quadtek's tradename for its imaging pyrometer) objective is housed in a lens tube that is cooled and permits insertion inside the vessel of interest. The length of the lens tube is chosen on the basis of making sure that the tip of the tube is just beyond the refractories lining the inside of the furnace. In most pyrometallurgical processes, we have found that the most reliable system set-up uses a water cooled shroud to cool the lens tube optics. A sapphire window provides maximum protection from the environment. Even in the case of the water cooled version, there is an air purge for the lens that keeps the objective clean and protects against hot metal splashes."

Jan 1, 1997

By M. G. Karfakis

Grouting has been used in underground mining for more than twenty years. Chemical grouting is often used as a remedial measure when the implemented ground control program is unable to completely prevent structural failures or when there is a need for preventing a structural member from unraveling. Utilization of the polyurethane grout currently being used is restricted by its limited range of physical and mechanical properties that restrict its utilization. To overcome some of the drawbacks of polyurethane, research has been conducted on a newly developed polyester based grout. The polyester resin, identified by Sandvik as StrataGrip, provides a number of features, including variable gel times and much reduced chemical hazard. Equally important are the mechanical properties of the product. The strength and deformability of any chemical grout must be compatible with the intended purpose of grouting and the expected deformation of the rock that is to be grouted. Assessment of the mechanical properties of polyester grout is the focus of this work. Field experiences and laboratory research have defined the properties of an effective grouting material. Experimental results indicate that the polyester grout meets or exceeds the recommended properties for many injection applications. Furthermore, the results suggest that the ability to adjust mechanical properties via resin formulation has the potential to expand the applicability of chemical grouting in ground control.

Jan 1, 1997

By John E. Tilton

Mining is one of the oldest human activities. It goes back at least to the Bronze Age and possibly even the Stone Age. The Romans mined copper in Spain and tin in England some two thousand years ago. The writings of Agricola in the 16th century show that mining was important in the Middle Ages. Today we mine more mineral commodities in greater tonnages than ever before. This long and fascinating history closely tied with the economic development of the human race is one of the charms of the mining industry. It also, unfortunately, gives rise to some widespread misconceptions.

Jan 1, 1997

By Michel Lefebvre, André Piché

Every organization performing R&D is faced with the challenge of introducing new technologies to its operations. Difficulties must be overcome if companies are to realize the benefits anticipated from such developments. This paper outlines the difficulties encountered in transferring to operations various technologies developed at the Mining and Exploration Division of the Noranda Technology Centre. The approach used in the selection of a privileged partner for the technology transfer, the criteria motivating the choice and the process followed to establish the partnership are presented.

Jan 1, 1997

By S. Dempsey

Since its passage in 1872, the Mining Law has been modified on several occasions to meet the changing needs of America's society and economy. Despite its evolution, the Mining Law continues to be criticized as outdated. This paper briefly traces the major points in the history and evolution of western mining laws, and reflects on the current status of ongoing discussion to reform the 1872 Mining Law.

Jan 1, 1997

By Orlando C. Gaspar

Abstract - The presence of fine-grained mineral intergrowths, the complex distribution of deleterious minor elements, and the variable base-metal contents in some assemblages commonly pose technical problems for the processing of volcanogenic massive sulfide ores. The beneficiation of most massive sulfide ores from the Iberian Pyrite Belt requires extremely fine grinding to liberation sizes of K80 = 15 µm to 25 µm. For several deposits, mapping of the ore types and metal zoning patterns has shown that the different ore types are distributed as ore lenses within the massive sulfides. Mineralogical, textural, and metallogenetic studies have provided an understanding of the distribution of both the vertical and the horizontal metal zonation in the orebodies. Because the efficiency of ore processing is affected by ore textures, and because the same mineral commonly has different textures and varies in chemical composition, a relationship between textures of the feed and the middlings must be established for all ore types defined at the deposit scale. Quantitative mineralogical methods have been developed to provide, on a timely basis, the information needed to optimize the concentration processes for the massive sulfide ores at the Aljustrel and Neves-Corvo deposits, Iberian Pyrite Belt, Portugal.

Jan 1, 1997

By T. V. Ramey

Heap leaching in certain parts of the world, such as Chile's Atacama Desert, brings unique design problems in the form of possible large differential settlements of the foundation soils due to the dissolution of salts in northern Chile the soils often contain very high concentrations of soluble salts (nitrates, potassium, magnesium, and common sodium). When a leak in the liner occurs, the escaping solution dissolves these salts and triggers differential settlement. If the settlement is great enough, the geo-membrane tears, the leakage increases, triggering more differential settlement. The nitrate plants have experienced many occurrences of this phenomenon where a brine pond will undergo a sudden and complete loss of the impounded liquors. The authors present a simplified technique to quantify the differential settlement resulting from dissolution and provide a method which can be used to select a geo-membrane with suitable flexibility under axi-symmetric (multi-axial) load conditions to tolerate the predicted settlement. (This paper was previously published for Randol Gold Forum 1996 [Ref. 6]).

Jan 1, 1997

By David J. Krichten

A method of retrofitting air-fuel burners with oxy-fuel capability overcomes the potential problems associated with oxygen combustion in aluminum melting furnaces. The retrofit burner uses the existing combustion air connection, burner housing, and burner tile and replaces the gas tube with an oxy-gas burner. Maintaining a portion of the air flow to the burner reduces the potential for localized overheating. Proper design of the burner reduces NOx emissions by moderating the flame temperature with furnace gas recirculation. Economic analysis of using oxygen shows the benefits are increased productivity and reduced overall unit cost of melting. In practice, the melt rate in rotary furnaces increases by up to 50% and by up to 35% in reverberatory furnaces. Oxygen utilization reduces total melting cost by 112-314 cents per pound of aluminum melted.

Jan 1, 1997

By Victor Stancovski, Uday Pal, Stephen C. Britten

"An in situ electrochemical technique for measuring the concentrations of easily dissociable oxides in slags at temperatures between 1200-1600°C is being developed. The technique utilizes a partially-stabilized-zirconia solid electrolyte (PSZ), which conducts oxygen ions, to separate a reference-gas compartment from the slag of interest. Three types of measurements are currently under investigation which yield different information concerning the slag phase and hence will be combined into a single amperometric device for monitoring the properties of easily dissociable slags.Type I utilizes an open-circuit-voltage measurement between the reference gas and the slag phase. Type II utilizes a potentiostat to apply a direct current potential step or sweep between the inner and outer compartments of the electrolyte, driving oxygen ions from the slag into a reference gas. With the use of open-circuit-reference electrodes, the resulting current-potential profile reveals the dissociation potential and concentration profile of dissociable oxides such as those of iron, manganese, and chromium. Information on the transport properties of the cations can also be generated from these measurements. Type III utilizes a potentiostat with reference electrodes to carefully electrolyze a known volume of slag by removing large quantities of oxygen ions from the slag to the reference gas. The coulombs of charge removed at different applied potentials can be used as a direct indication of the concentration of each dissociable oxide species present within the slag."

Jan 1, 1997

By Malcolm Scoble, Nick Vagenas, Greg Baiden

Recent advances in underground communications technology have demonstrated the feasibility of teleoperation and automation in underground metal mines. One major challenge lies in the automation of underground mobile machines from surface, with the potential to reduce significantly the need for human involvement in underground operations. This paper reviews the evolution of underground metal mining automation, principally related to the development of teleoperation and automation of mobile mining machines. Examples of prototype systems are given and the associated benefits that have been observed are reviewed.

Jan 1, 1997

By L. Y. Zhang

The current status of metal hydride alloys for NiMH batteries was systematically reviewed. Extensive application-oriented research and development has successfully made the NiMH battery an important part, with growing potential, among rechargeable batteries. The rare earth based metal hydrides (AB5) have been considered the best alloy material for use in the negative electrode in NiMH batteries. However, being in demand for high performance electronic markets, the still young NiMH industry is facing serious technical challenges in developing better products. Among all the efforts to respond to the challenges, advanced AF3, alloys are in great demand: the capacity enhancement race requires new or improved alloys possessing higher volumetric capacity; price competition mandates MH materials with low cost; high performance under severe service environments calls for alloys with high corrosion resistance when subjected to electrochemical cycling; and finally, high power service requires the negative electrode to deliver current at high rates.

Jan 1, 1997

Solid Energy New Zealand Limited has grown significantly since becoming a State Owned Enterprise in 1987. Exports, profit, turnover, output per employee are all trending upwards. The company has identified the management of Health and Safety as a key capability to sustain future growth, and to add value to the business. It has set a target of being the best practice in managing Health and Safety.   This paper examines the company's activities in the Health and Safety area, and how it sees that value can be added by preventing and containing losses through accidents involving people, property, process and the environment. Solid Energy is confident that a Planned approach to managing Health and Safety can achieve this. It will explore historical events, strategic changes, Health and Safety systems, Benchmarking, Performance Measures, initiatives, progress to date and challenges for the future.

Jan 1, 1997

By H. Polat

Relatively large amounts of such hydrocarbons as fuel oils are often needed in flotation of low rank coals. The amount of oil can be decreased considerably by using surfactants as promotors. The reagents which are good candidates as surfactants to promote hydrophobicity can also act as emulsifying and wetting agents. Since the physical and chemical variables influence various sub-processes in different ways, their influence on the performance parameters is complex. The results of laboratory tests are presented to show that the dual role of reagents can be judiciously exploited to increase both the recovery and grade of clean coal. The mode and order of reagent addition is critical in enhancing their efficacy as flotation promotors. The results demonstrate the benefits of proper conditioning of the pulp prior to flotation.

Jan 1, 1997

By Versiane A. Leão

The hydrochloric leaching of chrysotile tailings and soapstone powders) is discussed. This two materials are magnesium compounds associated with carbonates and iron oxides. In this work the chemical and physical characterization of formers is presented and the thermodynamic analyses of leaching is carried out. Magnesium extraction is almost complete for chrysotile tailings while, for soapstone powders, one can be reached 60%. The behavior of iron and calcium impurities is discussed.

Jan 1, 1997

By N. Behnood, W. Pascheto

"Laboratory wear tests are important tools that can be used for the evaluation of materials for wear applications and mitigation of wear problems in the mining industry. However, laboratory test parameters must be fully characterized and test results must be carefully interpreted if a material selection is to be made. Failure to do so may lead to erroneous conclusions. Suitable lab-oratory tests are valid only if they reflect the field conditions to which materials are subjected. Therefore, it is important to know, in detail, the field conditions, as well as the wear test techniques being considered. It is important to recognize the limitations of the various wear tests and the wear test data published in the literature. This work will review present wear testing technology, including the various wear tests avail-able, wear test equipment and test limitations. Several wear test procedures will be related to common equipment used in the mining industry.IntroductionThis paper will concentrate on non-lubricated wear mechanisms, because they are the most costly to the mining industry. Very frequently we are faced with the task of selecting materials for wear applications or improving existing systems that are giving poor performance. There are plenty of examples in the literature of practical wear cases and ranking of materials for wear applications. It is also very common to find materials manufacturers’ data -sheets listing wear tests results by comparing their materials performances against those of competitors. Much of the published wear data lack the description of the type of wear test, test parameters and the type of wear mechanism to which the data should be applied (if any).Before considering wear test data for a specific problem one should ask which type of wear mechanism is involved? What type of test and what test parameters were used to produce the results? Even if the type of wear tests and parameters are known, how accurate and useful are the published wear data? How are the results related to a particular type of wear? It is important to point out that even the standardized wear tests, such as those in ASTM standards, have limitations. Such limitations are recognized and clearly spelled out in the standards themselves. Basically, wear tests may lead to erroneous results if the test is not able to repro-duce the same wear mechanisms encountered in the field. Therefore, the use of published results may be helpful, as a starting point, but may be of little value for a final material selection.This work will discuss the main types of non-lubricated wear mechanisms encountered in the mining industry. In addition, it will discuss the many wear tests available and their correlation with the various types of wear mechanisms. The limitations of several standardized wear tests and the limitation of using published wear data will also be discussed."

Jan 1, 1997

Proposed by outstanding electrochemist and electrometallurgist Prof. Raphael Agladze (191 1- 1989), process of copper and manganese co-electrowinning was enhanced to the pre- electrowinning stages: low,temperature co-leaching of copper and manganese containing materials, and to high-temperature co-roasting of the same materials with consecutive leaching. The report presents results of experimental investigations of the processes mentioned above, as well as results of thermodynamic investigations of co-roasting processes, and co- leaching processes computer modeling.

Jan 1, 1997

By Wayne W. Murdy

Since 1993, Newmont has been actively growing through the development of three major foreign mining operations with a fourth under construction. The first project, Yanacocha in Peru began operating in October 1993 at a time when political and business risk in that country was considered high. In 1995, Newmont began operating the Muruntau Joint Venture in Uzbekistan, the first of its kind in the CIS. In early 1996, Newmont started operating the Minahasa mine in Indonesia. Now, in early 1997, Newmont is undertaking the construction of a $1.9 billion project in Indonesia and is completing a feasibility study with our partner for the development of a gold operation in Mexico. All of these projects have been considered "risky" by most standards, and Newmont has been very successful in all of them through risk mitigation programs including utilizing strong and successful in-country partners, concentrating on developing a strong national workforce with minimal expatriate employees, utilizing World Bank, EBRD and IFC financing and building and maintaining strong ties with host governments. This paper describes in more detail, some of the risk mitigation programs that Newmont has used to successfully grow the company through development of major foreign mining operations.

Jan 1, 1997

By C. M. Clapperton, K. E. Darke, A. J. Boyce, C. M. Rice, S. D. Redwood

"Abstract - The Kori Kollo gold deposit is hosted by a c.15 Ma sericitized dacite stock in the La Joya district on the Bolivian Altiplano. The mineralization is of the Bolivian polymetallic vein (BPV) type, with a significant amount of the gold reserves contained in the oxide cap. Field and microscopic studies, K-Ar dating, ??34S values of pyrite, alunite and jarosite, and ??18O values of alunite and jarosite demonstrate that some of this gold is supergene. Two types of supergene gold are present: minute gold grains, 1 to 10 microns across, of high fineness and associated with jarosite and iron oxy-hydroxides; and ‘invisible’ gold, which is probably sorbed onto minerals such as jarosite and iron oxy-hydroxides.Pyrite ??34S values fall in the limited range -3.5 ± 0.6‰, consistent with a magmatic origin. Sulfate ??34S values are homogeneous and overlap closely with those of pyrite (-1.2 ± 2.1‰), which supports petrographic evidence that sulfates replaced pyrite. By contrast, sulfate ??18O values are inhomogeneous with a large range (alunite +2 to 26‰, jarosite -5 to +18‰). These data are interpreted as reflecting kinetically controlled reactions involving various proportions of atmospheric oxygen and local meteoric water. This is typical of supergene alteration and is due to the seasonally dry climate of the Altiplano.The oxide-zone mineralogy is dominated by sulfates and iron oxy-hydroxide minerals with some phosphates and halides, which indicates that the groundwaters were acidic, oxidizing and relatively saline. Under these conditions the most likely complexes responsible for gold mobilization are halides.Geological data and K-Ar ages indicate that oxidation of the BPV deposits began at least around 11 Ma and possibly up to 15 Ma ago, and that supergene alteration lasted until around 4 Ma. During this period, erosion was minimal. Although supergene processes have been active on the Bolivian Altiplano since the Middle Miocene, in contrast to Northern Chile, enrichment of gold has not occurred."

Jan 1, 1997

By II Browne

After a decade of high copper prices, major mining companies are renewing their interest in purchasing operating properties and/or development of ore bodies. An existing operation carries with it a history that can present unique opportunities, while a greenfield operation allows for the establishment of a defined culture. Capital investments are distinctly different. A comparison of BHP Copper Robinson Operation, a greenfield property, and BHP Copper Tintaya Operation, a government owned Peruvian property, will provide insights into mining, concentrating and cultural differences between North and South American Operations.

Jan 1, 1997