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By J. W. Lyman

Nickel-metal hydride (Ni-MH) battery electrodes have been developed as a substitute for cadmium-containing negative electrodes. Use of Ni-MH electrodes offers enhanced electrochemical properties in many instances as well as reduced environmental toxicity. Rechargeable batteries using Ni-MH electrodes are also strong candidates for electric vehicles. During the production and secondary reclamation of these battery types, recycling procedures will be needed to prevent environmental impact caused by these wastes as well as to recover the value inherent in the scrap. The U.S. Bureau of Mines (USBM) is investigating hydrometallurgical technology that separates and recovers purified metallic components from Ni-MH battery scrap of two types, AB, and AB,. An investigation of acid dissolution and metal recovery techniques has determined several processing alternatives that may be used to promote the successful recycling of much of the battery fabrication scrap and eventual secondary scrap. Although recovery techniques have been identified in principal, their applicability to mixed battery waste stream and economic attractiveness remain to be demonstrated.

Jan 1, 1995

By Jinrong (Patrick) Mang

Three of the most challenging problems in phosphate beneficiation are discussed: flotation efficiency, resource conservation and environmental impact. Some new flotation machines offer the opportunity of reducing power and reagent consumption significantly, while increasing specific capacity many fold. Efficiency might also be improved dramatically by replacing the "double float" process with a single-collector scheme. Model based software control is a powerful tool for improving overall plant efficiency. Recovery of phosphate values from the phosphatic clays could extend phosphorus reserve life significantly. phosphate recovery from the slimes might be achieved by sizing-flotation, selective flocculation and bioleaching. Reducing the volume of phosphatic clays produced is another key stop to minimizing phoephate logs. Such a reduction may be realized by floating at finer cut size. Although an ideal' dolomite separation process is yet to be developed, a cationic flotation process may prove to 'be economically feasible. Loss of phosphate in the desliming stage is the major problem with most of the flotation schemes for removing dolomite.

Jan 1, 1995

By D. A. Rhys, M. Sieb, M. A. Prefontaine, C. L. Swanson, S. R. Frostad, H. Q. Smit

"Gold-silver mineralization at Red Mountain (1992 resource of 2.5 million tonnes grading 12.8 g/t Au and 38.1 g/t Ag) occurs within several discrete zones within a folded sequence of Middle to Late Triassic Triassic sedimentary rocks, Early Jurassic volcaniclastic and pyroclastic rocks, and Early Jurassic intrusions. Three phases of Early Jurassic sills and stocks collectively comprise the Golds/ide intrusions: (1) irregular bodies of medium-grained hornblende monzodiorite (Hillside porphyry); (2) hornblende-biotite + quartz porphyritic monzodiorite to quartz monzodiorite (Golds/ide porphyry; U-Pb zircon ages of 197.1 + 1.9 Ma); and (3) biotite porphyritic hornblende monzodiorite sills (Biotite porphyry). Contact breccias and igneous breccia dikes are common features of the Golds/ide intrusions. Chemical similarities and equivalent ages of volcanic rocks and intrusions, and the presence of intrusive clasts in volcanic rocks suggest that the intrusions are feeders to overlying volcanic units.Hydrothermal alteration affects all pre-Tertiary rocks on Red Mountain, including all phases of the Golds/ide intrusions. Several shallow-dipping alteration zones are developed sequentially above a propylitic quartz stockwork/molybdenum zone. These include: (1) sericite-quartz-pyrite alteration (pyrite-dominant alteration); (2) chlorite-K-feldspar-sericite-titanite alteration with disseminated and vein pyrrhotite (pyrrhotite-dominant alteration); and (3) brown to black tourmaline veins and K-feldspar-pyrite-titanite-actinolite alteration. Anomalous gold(> 0.3 g/t) mineralization is developed at the transition from the pyrite to the pyrrhotite dominant alteration over a > 1 km2 area. Within this anomalous zone, high-grade (3 g/t to 20 g/t Au) gold-silver mineralization occurs in 5 m to 29 m thick, semi-tabular pyrite + pyrrhotite stockworks with intense sericitic alteration and surrounding disseminated sphalerite + pyrrhotite.Stratigraphic, spatial and geochronologic relations and alteration zoning indicate that mineralization formed in a subvolcanic environment at the top of the Golds/ide intrusions and at the base of the Early Jurassic volcanic pile. The Golds/ide porphyry is interpreted to be the mineralizing intrusion. The alteration zoning, molybdenum-copper mineralized quartz stockworks, extensive Ksilicate and tourmaline alteration, and the relationship with a hypabyssal porphyritic intrusion show similarities to many porphyry systems."

Jan 1, 1995

By Marco Olper

After two years of extensive research a new and innovative modification to the CX-EW process has been exploited. This process, called CX-EWS, avoids completely all the critical aspects of the previous process which affected the cost of the energy, of the chemicals and of The maintenance of the insoluble anodes. All these benefits reflect a saving of about 30% of The operating costs compared to the present traditional production and allow for a total operating costs of less than 6.5 cts/lb. lead (net of raw material cost). With this new technology it is allowed for the first time the treatment in the same plant facilities of both primary lead sulphide concentrate and spent batteries. The paper describes the technical and economical aspect of the new process with a feasibility study for 150,000 t/y spent battery facility throughput.

Jan 1, 1995

By Carlie JC

Many low sulphidation epizonal gold and zinc-lead vein deposits within magmatic arcs are situated on basement highs, and post-date both the main volcanic episode and porphyry copper (gold) mineralization. These features are best explained by emplacement of a flat batholith a few kilometres beneath each mineral district, as recently demonstrated by geophysical data in the Baia Mare district of Romania. The batholith provides heat for the hydrothermal system, and results in extensional faulting both through up-doming of the overlying rocks, and in some arcs through incipient collapse of the thermally weakened crust under regional extensional stress. More water-rich magmas emplaced at greater depths could explain some deep epizonal and mesothermal gold deposits situated outside magmatic arcs.

Jan 1, 1995

By P E. H Gregg, D Horne, R B. Stewart, N Bolan

The Tui mine site is situated on the NW flank of Mt. Te Aroha, at approximately 400 m altitude. During underground mining operations two lead-copper-zinc ore bodies were exploited and processed on site. The legacy of the mining operation is a barren dam containing over 100 000 mm of sulphide-rich tailings. The Tui mine site is arguably the worst case of environmental degradation resulting from past mining activity inNew Zealand. Although the impacted area (approximately 4 ha) is extremely small by international standards, acid mine drainage (AMD) emanating from the abandoned tailings dam and mine adits has severely contaminated local streams and prevented natural plant recolonisation of the site for more than 20 years.   The suitability of the tailings as a potential plant growth medium was assessed with the end view of revegetating the tailings dam and alleviating AMD. This paper outlines characterisation work conducted on the tailings and summarises preliminary results from plant growth trials. The tailings contain up to 5% Fe, 1.15 % Pb, and 0.45% Cu in the form of sulphide minerals. The distribution of heavy metals, sulphate and total sulphur with depth indicates that the top 200 - 300 mm of the tailings have been extensively weathered since their deposition. The oxidation of sulphide minerals, particularly pyrite (FeS2 ) has reduced the pH of the tailings to nearly 2 in places. Below 300 mm the sulphide minerals are largely unweathered and the theoretical acid generating potential of the tailings exceeds 170 Mg CaCO3/1000 Mg tailings at certain depths. Plant growth trials were conducted to study the effects of lime and organic matter addition on the establishment of vegetation on the Tui mine tailings. Several plant species were assessed including some cultivars bred for their tolerance of heavy metals.

Jan 1, 1995

By R. Kuhns

The western coast of South Africa hosts a significant diamond resource within gravels associated with paleo-shorelines, channels and transgressive lag deposits. Diamonds were transported from the Kaapvaal Craton to the coast largely during the late Cretaceous via the paleo-Orange river systems. On shore and near shore environments are underlain by Proterozoic metamorphic and granitic rocks which provide gully and pot hole-type traps associated with paleo-channels, basins, bays and beaches. Inner and mid-shelf environments are covered by diamondiferous, poorly lithified upper Cretaceous and Tertiary sediments. The upper Cretaceous gravels were reworked along the sediment-starved coast during much of the Tertiary. Reworking was mainly achieved during marine flooding events which produced lag gravels along the paleo-shorelines. This process reworked the diamonds from low-grade Cretaceous gravels and concentrated them in higher-grade Tertiary gravels.

Jan 1, 1995

By Gil Espejo, Denise Duncan

"In Alberta, several initiatives are under way to form partnerships between educators and industry to work together in preparing a skilled and technically competent workforce for the future. One successful initiative is the Teachers in Business program which provides high school teachers one month paid internships in Alberta businesses. Initiated by the Science Alberta Foundation in 1992, this program has offered participating teachers a variety of work experiences and job shadowing tours in industry.A Growing Need of Education and Industry PartnershipsIn our ever evolving world, industry is in a tight race to keep up to date with new technology and to remain competitive. Industry is relying on the education system to provide them with the core base for their future workforce. To accomplish this, the education system needs the support of industry to develop the right focus to prepare its students for the race. What skills will our future workforce need? How can we best prepare our students for these needs?Teaching the latest in technology, especially at the high school level, is a major challenge. It is difficult for educators to keep abreast of the rapid changes in technology. High school graduates need exposure to the latest advancements. And so do their teachers. Students must be prepared to adapt to the challenges of the future, Le. global competition, rapid technological change and an expanding knowledge base."

Jan 1, 1995

By Marion Dattilo

The search for an improved anode for the electrowinning of lead from fluosi1icic acid medium has led the U.S. Bureau of Mines to investigate composites. Polymer bonded metal oxide powders which may contain catalyst additions were prepared by pressing. These composites display an improved activity toward the oxygen evolution reaction over electrodeposited lead dioxide on titanium, carbon, and nickel substrates. These composite electrodes contain 5 to 10 wt. " binding polymer, with the balance being metal oxides. Lowered anodic potentials achieved using the compnsite anodes resulted in lower levels of lead dioxide deposition during electrowinning.

Jan 1, 1995

By J. R. Koehler

Yield pillar-based gate road designs oftentimes fail to provide mine operators with adequate ground control because of the unknowing misemployment of "critically" sized pillars. A "critical" pillar is one that is too large to either yield nonviolently or yield before the roof and floor sustain permanent damage, but is too small to support full abutment loads. To demonstrate the critical pillar concept, a field study of a tapering gate road was conducted by the U.S. Bureau of Mines at the Sunnyside Coal Mines, Sunnyside, UT. Extreme pillar stresses and associated coal bumps characterize the response to first panel mining of a 16.8-m wide critical design. Significantly lower pillar stresses, early yielding of the pillar and adjacent panel rib, and an absence of coal bumps suggest that a narrower 12.2-m-wide design more closely approaches proper yield pillar dimensions. Probehole drilling of several 1 O.6-m-wide pillars revealed low stress levels and substantial pillar and panel rib yielding prior to abutment onset, indicating a properly functioning yield pillar design.

Jan 1, 1995

By P. L. Sibrell

The U.S. Bureau of Mines has tested cyanide leaching for recovery of palladium (Pd) from spent petroleum processing catalysts. Three different catalyst samples were supplied by a spent-catalyst processor. These catalysts consisted of a zeolite base and contained 0.4 to 0.7 pct Pd. During alkaline cyanide leaching, the catalysts exhibited ion-exchange properties due to their zeolite matrices. Hydrogen ions were released from the zeolite in exchange for sodium ions in solution, resulting in a significant decrease in solution pH. This could present a safety hazard because of the potential for release of toxic hydrogen cyanide gas. A pretreatment .step where the catalysts were contacted with a 1.0M sodium hydroxide solution was found to prevent the pH shift from occurring. Following the sodium hydroxide pretreatment, two stages of leaching at 160 °C with solution containing 1 pct sodium cyanide and 0.1M sodium hydroxide gave at least 75 and up to 95 pct Pd recovery. The Pd was quantitatively recovered from the leach solution by thermal decomposition in an autoclave at 250 °C for 1 h. The Pd content of the precipitate was over 50 pct. Thermal decomposition also decreased the total cyanide content of the barren solution to less than 0.2 mg/L. The catalyst leach residues passed the Federal Toxicity Characteristic Leaching Procedure and the California Waste Extraction Test, indicating that landfill disposal of the leach residues would be acceptable.

Jan 1, 1995

By J. N. Hryn

This paper describes some of the work done in Phase 1 of a multi-year, five-phase program aimed at demonstrating the economic feasibility of producing commercial-scale quantities of commodity materials derived from salt cake residue-oxide. The amount of salt cake generated annually in the U. S. is estimated to be 510,000 tons, including 340,000 tons of residue-oxide. Used beverage can (UBC) processing accounts for the majority of residue-oxiae that could be made available for further processing into commercial products. To characterize the composition of residue-oxide. eight residue-oxide samples from various secondary processors were obtained and analyzed. Surprisingly, the composition of residue-oxide was found to be independent of source or alloy family being processed, with? the exception of slightly elevated silicon levels in 3XXand UBC residue-oxide samples. Major phases detected in the residue- oxide were? alumina, spinel, and aluminum hydroxides. Preliminary economic analyses indicated that the refractory market appears to be the best choice for high value-added products produced from residue-oxide with minimum processing. Bench-scale tests indicated that low silicon containing residue-oxide is ready to enter this market, but the elevated silicon content of UBC and 3XX residue-oxide preclude this possibility. A separation technology should 'be developed to remove silicon-containing . species from the alumina and spinel values Present in residue-oxide. This technology would then allow UBC and 3XX residue-oxides to be converted to significantly higher value-added products.

Jan 1, 1995

By A. D. Zunkel

The zinc in electric arc furnace dust (EAFD) arises from the fuming and oxidation of the zinc present, mainly as galvanizing, in automotive scrap. The dust is collected from the electric furnace offgases in bag filters and is classified by the EPA as a hazardous waste (K061). As more zinc is used in galvanized sheet on automobiles and more automobile scrap is recycled via the EAF, the more zinc will be available for recovery and recycling. EAFD will become a more prevalent and important source of zinc compared to the traditional zinc sulfide concentrates ifit can be cost effectively processed.

Jan 1, 1995

By Guocheng Pan

Geostatistics has been widely accepted as a standard tool for reserve estimation and mine planning. Kriging has been adopted as the best estimator of grade. Although many discussions have been conducted in the use of kriging in the mining industry, insufficient attention has been given to solutions for over-smoothing. This effect has been frequently encountered in many mines. The so-called over-smearing refers to two facts: (1) over-reduction of grade variabilities and (2) over-estimation of low-grade ore tonnages. This study attempts to link over-smoothing effects with several other practical aspects in kriging. These include the weight independence of data values, variogram modeling, and search strategy used in estimation. All solutions recommended here are suited for precious metal deposits (e.g. gold) in open-pit mining.

Jan 1, 1995

By N. Dahmen

The Robbins Mobile miner has been in development for more than ten years. Two machines have been trialed in mining environments. While day to day performance to date has fallen short of the levels anticipated, instantaneous performance has been impressive for given rock conditions and continues to encourage further development. The Pasminco mobile miner has been committed for a 1.8km main decline extension at Broken Hill. M.I.M. Holdings, parent company of Mount Isa Mines, owner of the first mobile miner, are considering a new machine for McArthur River. Robbins, Pasminco, and The Centre for Mining Technology and Construction have, joined forces to accelerate development of .mechanical rock cutting techniques in general, and of the Mobile Miner in particular.

Jan 1, 1995

The Golden Cross mine is a Joint Venture between Coeur Gold New Zealand Limited, as Manager, and Viking Mining Limited. The mine is targeting Zero Lost Time Accidents as a goal.   The Golden Cross operation produces gold and silver from both underground and open pit. The mine is based on an epithermal gold-silver deposit. Treatment of ore is on a campaign basis for each ore type (i.e. underground or open pit). Milling is conventional SAG Mill and Ball Mill grinding circuit followed by carbon in pulp recovery of gold and silver. All tailing materials are treated through the Cyanisorb process to reduce cyanide levels prior to being discharged into the tailings dam.

Jan 1, 1995

By H. M. . van der Donk

In this work an overview is given about the techniques available for the removal of metallic impurities from molten aluminium. The overview is focused on the removal of iron. Also, some experimental results are given about the creation of iron-rich intermetallic compounds in an aluminium system, which are subsequently removed by gravity segregation and filtration techniques. This work is part of an ongoing research project of three major European aluminium companies who are co-operating on the subject of recycling of aluminium packaging materials recovered from household waste by means of Eddy-Current techniques. Using this technique the pick-up of some contaminating metals, particularly iron, is almost unavoidable.

Jan 1, 1995

By H. Dho

Two aromatic-type chelating agents, 1,10 phenanthroline (phen) and 8-quinolinol (quin), were tested as specific depressants for magnetite in the cationic silica flotation of magnetic taconite concentrates. Micro and batch flotation tests, along with zeta potential and adsorption measurements were used. In the presence of a cationic collector, dodecylammonium chloride (DAC), the Fe/phen surface chelate electro-statically repelled DAC, and magnetite was depressed. The negatively charged Fe(quin)2(OH)2-on the magnetite surface attracted the cationic collector and made magnetite floatable.

Jan 1, 1995

By Y. C. Kim

Using an exhaustive data set of Walker Lake, four different kriging techniques plus the inverse distance squared weighting were compared with regards to each one's performance in accurately estimating the block grades. The North-West quadrant of the Walker Lake data area was used because of its extreme variability of values and its distinct contour of the values. There were 1900 exhaustive data points in the selected area from which a total of 121 samples were drawn following the sampling strategy given in Isaaks and Srivastava (1989). The average of 5 x 5 exhaustive data points was treated as the true, known block grade. A total of 780 blocks, each block corresponding to the average of 5x5 exhaustive data points, were then estimated using the 121 sample points. The resulting estimates were then compared with the true known values to determine each technique's prediction performance. For this particular portion of the Walker Lake and for the given sampling strategies used, the obtained results for the global estimation are mixed. For the variable U which is much more variable, the rankings are; 1) Jackknife Kriging (JK), 2) Indicator Kriging (IK), 3) Inverse Distance Square weighting (IDS), 4) Ordinary Kriging (OK), and 5) Log-Jackknife Kriging (LJK). For the variable V, the results are; 1) OK, 2) IK, 3) JK, 4) LJK, and 5) IDS. When we apply several cutoff grades to the estimates to determine the conditional mean grades and tonnage, the above rankings generally get shifted around. Two exceptions to these cases are; a) UK for U and b) IDS for V. These two consistently ranked at the bottom.

Jan 1, 1995

By Bryce Clark

Cobalts history from the 14th Century is outlined, with a look at its various sources over that period. The present sources and quantities are given, when in 1994 it is an equal co-product of copper in Africa and nickel elsewhere (Canada, Australia, Russia). Future trends in this scene are also examined. The final section deals with cobalts uses in superalloys, magnets, colours, electronics, chemicals, and examines trends in its markets. Supply and demand in co-product cobalt are shown, based on the latest production figures.

Jan 1, 1995