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By Li Shibo, C. Halls

The compositions of olivine, pyroxene and chromite from the Proterozoic ultramafic complex are analagous to those of cumulate ultramafic rocks of tholeiitic origin, suggesting that the parent magma may have been tholeiitic rather than komatiitic. The complex contains economically significant Ni-Cu sulphide mineralisation. The high sulphide/silicate ratio is best explained in terms of the segregation of sulphides from a large volume of magma, of which all but the ultramafic cumulate fraction has since been eroded. Platinum-group minerals that have been identified include sperrylite, moncheite, native platinum, froodite, merenskyite, michenerite and Pd-rich pentlandite lamellae exsolved from pyrrhotite. They are characteristically found in close association with chalcopyrite, either along the contacts between hydrosilicate and sulphide grains or in cracks within pentlandite and chalcopyrite, which may also be intergrown with galena. Crystallisation from a Cu-rich residual magmatic liquid also enriched in Pt, Pd, As, Sb, Bi, Te, Zn and Pb is postulated.

Jan 12, 1993

By G. H. Blackwell

Sequences in open pit mining must be planned and regularly revised to incorporate changes in the variables which affect profitability. Interactive computer planning with colour graphic facilities is an effective tool for this purpose in the short and medium term. An interactive computer planning system for medium-size, low grade porphyry copper-molybdenum open pits is described. The planning system proved especially valuable during the critical stages of pushback mining when deep, inner pit ore was nearly depleted and the erratic grades of the next pushback provided ore and marginal material at a time of depressed metal prices.

Jan 8, 1993

By P. Rama Krishna, B. Narasimha Rao, P. Ali i Peera

Induced polarisation (IP) surveys are commonly used in uranium exploration programmes in India. The IP method is effective in detecting the disseminated metallic sulphides that are often associated with uranium minerals. However, conductive and polarisable host rock or overburden often introduces inductive or electromagnetic (EM) coupling into time domain IP measurements. This makes it difficult to distinguish between responses due to such coupling and those that might indicate economic mineralisation. Attempts must be made to remove the EM effects before the IP technique is used in drilling programmes. Transient decay curves which were recorded during field surveys at Pisnari were factorised using the Marquardt algorithm. Dispersion plots of the amplitudes and relaxation times of the composite exponential function enable a clear distinction to be made between the effects of EM coupling and those of mineralisation.

Jan 4, 1993

By R. Trueman, D. B. Tyler

Numerical modelling was used to determine the magnitude and direction of stresses around drives both adjacent to and distant from open stopes in the South Crofty tin mine. Modelling predicted that drives near the stopes are situated in a stress-relaxed zone. The peripheries of drives that are sited in solid rock away from the influence of stoping are in compression. Key-block modelling was used to determine the typical geometries of critical blocks and distinct element modelling was used to determine block stability. The conclusions derived from modelling fitted the observational data. This indicated that key-block theory is a valid tool for analysing the stability of roadways in the South Crofty mine. The support requirements for drives located next to stoped-out areas were formulated using a risk analysis approach to key-block formation. The results were compared with support guidelines derived using empirical design methods. Good agreement was obtained for the roofs of the drives but not for the sidewalls. The concept of a critical excavation width was formulated: once an excavation is larger than the critical size the length of rockbolts need not be increased as the excavtion dimensions increase. This may be the case in all rock mases.

Jan 4, 1993

By Tuncel M. Yegulalp, Selamet G. Ergelebi

A description is given of a method of analysing modern mining systems in terms of reliability and their effects on productivity. Non-exponential distributions, such as the Weibull and lognormal distributions, for failure and equipment repair times are also considered. The resulting non-homogeneous Markov process is solved by the method of stages. A longwall mining system is analysed as an example.

Jan 4, 1993

By T. J. White, R. A. Farnfield

Early computerised blast monitoring equipment consisted of a digital version of the existing analogue machines with, perhaps, a few enhancements. Many additional facilities have since been developed to enable the efficient collection of high quality data. These developments are examined with reference to digital sampling, triggering systems, the storage of complete recordings and signal processing. Recent advances have been made in the use of blast monitoring systems that comprise multiple blast monitoring locations with centralised control and data collection. Software has been developed to help record blast parameters and assess environmental effects. Computer databases have many advantages over their paper counterparts. Data can be easily retrieved and processed. The scaled distances used in the prediction and control of peak particle velocities can be calculated rapidly when the data are obtained directly from a database. Since the whole vibration signal can now be recorded, signal processing can be used to provide information such as signal length, dominant frequency and response spectra.

Jan 4, 1993

By T. T. Chen, J. E. Dutrizac, C. Canoo

The calcine consists principally of ZnO and ZnFe2O4, which occur as banded and porous grains, together with lesser amounts of Zn2SiO4, Zn-Fe-Pb silicate, sphalerite, quartz, PbSO4 and Fe2O3. Al is present in solid solution in most of the Fe-bearing phases and also as residual aluminosilicate minerals from the original concentrate. Si occurs mostly as Zn2SiO4, Zn-Fe-Pb silicate and as residual silicate minerals. As is commonly found in the ZnFe2O4, Fe2O3 and Zn-Fe-Pb silicate phases. The major As carrier may be calcium arsenate particles less than 1 micrometre in size which are dispersed throughout the calcine. The neutral leach residue consists mainly of ZnFe2O4 and precipitated masses of iron gel-silica gel. Lesser amounts of ZnO, Zn2SiO4, Zn-Fe-Pb silicate, PbSO4, sphalerite, Pb-K-jarosite and basic zinc sulphate are also present. Al occurs in minor concentrations in most of the Fe-bearing phases and in the Zn-Fe-Pb silicate. The residual aluminosilicates are also an important Al carrier. The major As carrier is the precipitated iron gel-silica gel phase, but some As is also present in the Zn-Fe-Pb silicate, ZnFe2O4 and Fe2O3 phases. Silicon is divided about equally between the iron gel-silica gel, Zn2SiO4, Zn-Fe-Pb silicate and residual silicate minerals. The weak acid leach residue is generally similar to the neutral leach residue except for its reduced content of ZnO and basic zinc sulphate.

Jan 4, 1993

By L. Wade, R. Wang, M. A. Horton

Laboratory methods to find the mechanical properties of rock are inherently biased towards stronger strata, which best survive the sample preparation process. Geophysical techniques are not subject to such bias and may be used to predict mechanical properties rapidly and cheaply. Samples (151) were obtained from a borehole that had been comprehensively geophysically logged. The mechanical properties of the samples were established in the laboratory and correlated with the geophysical responses of the strata from which they came. The results indicate that, for homogeneous strata at least, it is possible to predict the unconfined compressive strength reasonably well from sonic travel time measurements made in the field. Predictions of static Young's modulus may also be made from this data source, but with a lesser degree of confidence. A multivariate regression equation is presented which relates down-hole sonic travel time to unconfined compressive strength, depth and the frequency of fractures in the rock mass. This equation may offer potential for the prediction of the mechanical rock properties of fractured and layered strata.

Jan 4, 1993

By Thomas J. Keefe, O&apos

Results of metal electrodeposition experiments conducted at the University of Brussels and University of Missouri-Rolla over the past few years are reviewed in terms of the relationship and impact on industrial processes. Examples are cited from common electrowinning, electrorefining, or electroplating operations for copper, zinc, nickel, cobalt and silver. The following topics are considered : metallographic structure, crystallographic texture, surface morphology, nucleation and growth, additive monitoring and effects, high current density, substrate related properties including adhesion. The studies were conducted on a variety of scales from laboratory beaker tests to full sized pilot and industrial operating plants.

Jan 1, 1993

By H. Soto

As a follow-up to a laboratory study, a pilot scale column for the flotation of coarse particles was designed and then tested in two different applications. In the first test, the concentration of a coarse phosphate ore (normally beneficiated by skin flotation in spirals) was carried out in a flotation plant in Florida. In the second pilot test, the column was used as a scavenger cell in the coarse flotation section of a potash beneficiation plant in Saskatchewan, Canada. Particle size of the phosphate feed was of the order of 0.6-1.0 mm and the potash feed 1-3 mm. The column was 1 feet diameter and was fed at rates between 0.5 to 1.4 tph. The effect of operating variables such as air and water flow rates, bubble size, frother concentration, residence time, sparger, etc were evaluated. The most important factors in column performance were found to be bubble size, air flow rate and the thickness of the froth bed. Best results were obtained in the absence of a froth bed, with low air flow rates and with small bubbles. The paper presents comparative performance and discusses details of the column design. Phosphate recoveries in the column were better than 90% whereas the conventional skin flotation circuit normally yields about 60% recovery for a comparable concentrate grade. Potash recovery from the tailings of the conventional flotation circuit was as high as 42% recovery. Particle size distribution of the potash concentrate was coarse enough to meet requirements for potash fertilizer.

Jan 1, 1993

By S. G. Kumar

The performance of nickel based high temperature materials is directly related to their microstructure, which is controlled by the various processing steps. Nickel base alloys are melted and refined by a variety of processes that include Vacuum Induction Melting (VIM), Vacuum Arc Remelting (VAR) and Electroslag Remelting (ESR). The limitation of VIM is that the metallrefractory reactions lead to the disintegration of the crucible and hence contamination of the product due to macrosegregation. This macrosegregation is alleviated to some extent by controlling the solidification in VAR. The main attraction of ESR is its ability to produce a clean product by controlling the deleterious inclusions. In recent years Electron Beam Melting (EBM) is emerging as an alternative to the VIM, VAR and ESR. This paper reviews the current status of these processes and outlines the scope for further improvements in the processing technology.

Jan 1, 1993

By Terry J. Close

At the request of the Idaho Congressional Delegation, the U.S. Bureau of Mines Western Field Operations Center investigated the mineral resources of the 140,000-acre Red Mountain roadless area, located northeast of Lowman, in central Idaho. The area includes U.S. Forest Service Red Mountain RARE II area (4-063). The highly mineralized road less area is underlain mainly by granitic rocks which are transected by a northeast-trending fault system. Associated with the granitic rocks and fault system are gold and black sand mineral resources. At least 1,395 ounces of gold and 858 ounces of silver have been recovered from six lode and placer mines within the roadless area. A total of 525 tons of columbium-tantalum, 2,049 tons of euxenite, 83.5 tons of columbite, and 54,862 tons of ilmenite concentrates have been produced from a nearby black sand mineral placer. Mine workings and facilities in the roadless area consist of two dismantled mills, 15 open and caved underground excavations totaling about 2,900 ft of workings, seven large pits and quarries, over 166 smaller dozer-and hand-dug prospect pits and trenches, and in excess of 66 drill holes. The mineralized sites in the roadless area are covered by about 690 current (1992) mining claims. About 130 individuals are holding the claims. Also within the roadless area are four patented lode mining claims. Twenty-five of the 54 mineralized sites identified during the study of the roadless area have, or likely have, mineral resources. One has gold and three have black sand mineral resources that are marginal or subeconomic. There also are two hot springs with thermal water resources, some veins that could be sources of decorative quartz, and dimension stone which was quarried in the past and could be again.

Jan 1, 1993

By Frank A. Stephens

The process of converting iron ore (principally Fe,03 or Fe30,) into iron carbide (Fe,C) to be used as feedstock for steel-making yields complex mixtures of several Fe-containing compounds as a function of processing conditions. In addition to the above compounds (hematite, magnetite and cementite), the mixtures typically contain wustite (FeO) and metallic iron(Fe). Mossbauer spectroscopy has been developed into aquantitative analytical method for monitoring the degree of conversion to carbide from samples periodically extracted from a fluidized bed reactor type of pilot plant. Calibration of absolute quantities of the above five compounds is based on standards prepared from known mixtures of the high purity individual phases. The PC-based spectrometer allows fitting of the well-known spectral components of each of the five phases, the resulting spectral areas then being compared with the calibration curves via PC software to yield the weight fraction of each. Emphasis has been placed on standardizing and simplifying the analysis procedure for routine use in an industrial environment.

Jan 1, 1993

By R. M. Graves, C. B. McKenzie, D. Barbour, D. W. Desnoyers

"Abstract -The prospective Tulks volcanic belt hosts five significant massive sulfide deposits, Tulks Prospect, Tulks East, Jack's Pond, Daniel's Pond and Victoria Mine, as well as numerous showings and indications throughout its 70 km outcrop length. Regionally, the 498 Ma sequence consists dominantly of felsic pyroclastic rocks and flows with interbedded mafic volcanic units and fine­ grained sediments, commonly graphitic. Contemporaneous granitoid rocks occur in the south half of the belt. Rocks usually display a strong NE-SW, steeply dipping, penetrative foliation and other shear-related high-strain fabrics. Facing directions are normally northwest, although there is local evidence of folding. Sulfide bodies and their alteration systems are deformed and shape-modified in the style of ambient strain.The Tulks, Tulks East and Jack's Pond prospects appear to occupy a similar stratigraphic level, on or near the contact between a thick felsic pile and an overlying broad, conductive package of graphitic sedimentary rocks. AU are pyritic deposits with well-developed footwall alteration systems. The Tulks prospect comprises four polymetallic lenses totalling 750 000 t. Three lenses constituting more than 6 000 000 t of sulfide mineralization are indicated at Tulks East but only the 210 000 t ""B"" lens contains significant base metals. Jack's Pond consists of a very extensive, zoned alteration complex in which four lenses of massive to semi-rnassive pyrite + chalcopyrite are known.The central part of the system, characterized by Mg chlorite and carbonate, is enveloped by pervasive sericitization and capped by intensely silicified and pyritized volcanics. The sulfide lenses are interpreted as part of the footwall zone and are beneath that part of the system most likely to host polymetallic massive sulfides.Daniel's Pond differs from the other prospects in such fundamental ways as metal content, associated alteration and structural setting. The deposit comprises strongly tectonized, Ag-rich, Zn-Pb mineralization distinguished by a pronounced Ba-As-Sb signature. Mineralization is confined to a narrow, north-south high-strain zone which separates unstrained mafic volcanic rocks to the east from well-foliated felsic rocks. The deposit Jacks an extensive alteration halo and at its north end is associated with a lens of barren, undeformed massive pyrite.The Victoria Mine deposit, the most cupriferous of the five, is related to a moderately dipping structure that separates well-foliated Tulks volcanic rocks from an overlying, Jess deformed volcanic­ sedimentary sequence that may be as young as 462 Ma. The structure is also the locus of black chlorite, dolomite and quartz alteration. Structurally remobilized precursor sulfide mineralization is one possible source for the deposit."

Jan 1, 1993

By Nieves Iglesias

The removal of the refractoriness of a gold bearing pyrite- arsenopyrite ore is studied. Flotation concentrates were prepared and leached with a dilute acidic ferric sulfate solution. The elemental sulfur film which forms on arsenopyrite in the oxidation process is not responsible for the low rate of the arsenic dissolution observed. A positive effect on the leaching rate is observed when Ag' is added. This pretreatment eliminates the refractory nature of concentrates.

Jan 1, 1993

By Valois R. Shea-Albin

Ground control problems are an important factor affecting safety, production, and efficiency in underground coal mines. A major portion of ground control problems encountered in underground coal mines can be attributed to geologic features in the strata surrounding the extracted coal seam. The U.S. Bureau of Mines has compiled information from numerous sources on the geological features that contribute to ground control problems in underground coal mines. The compilation includes (1) sedimentary features such as paleochannels, crevasse splays, clastic dikes, mold-and-cast structures, concretions, and lithologic factors, and (2) structural features such as folds, fractures, joints, cleat, and faults. The compiled information will aid in identifying the features, predicting their occurrence in advance of mining, and controlling or minimizing roof failure when these features are encountered in an underground coal mine.

Jan 1, 1993

By Nakahiro Y, Wakamatsu T

In the present study, from experimental results, a new concept of possibility of flotation separation of quartz from feldspar is presented. The effect of the nonionic surfactant Brij 58 on the flotation behaviour of quartz and feldspar has been investigated. The effect of the surfactant adsorption at the solid-liquid interface was also studied. The results demonstrate that maximum flotability of quartz occurred at low concentration of surfactant. Feldspar is not collected by this surfactant. Flotation tests with feldspar that had previously been subjected to leaching by hydrochloric acid yielded similar flotation response as that of quartz. The effect of removal of alkali cations from feldspar surface on its flotability was investigated. The effects of inorganic and organic additives on the flotation recovery of quartz are discussed in terms of the slating-out or salting-in properties of these additives. KEYWORDS: Alkyl polyoxyethylene; feldspar; flotation; nonionic surfactant; quartz; salting-in; salting-out; separation; silanol groups.

Jan 1, 1993

By S. K. Sharma

The Bureau of Mines has investigated the fundamentals of the flocculation process. The objective of this study was to determine the effects of various physico-chemical parameters such as shear rate, polymer dosage, and polymer concentration on floc growth and to determine the applicability of a model in predicting polymer flocculation behavior. A rapid in-line particle size analyzer was used to follow the progress of both the floc growth and the breakage as a function of time. A genetic algorithm (GA) was used to determine the unknown parameters in the model and to fit a curve to the experimental data. Results show that the model, using GA as a tool to determine the unknown parameters, reproduces the experimental data with only reasonable accuracy and was relatively insensitive to the parameters. Results of the flocculation study showed that increases in polymer dosage had greater effect on the time required to reach the maximum floc size than on the floc size itself. It was also determined that, given all the aforementioned parameters, the degree of slurry mixing during the flocculation process had the greatest bearing on the floc growth.

Jan 1, 1993

By M. Tapper

If one considers that prehistoric man's first house may have been a limestone cave, calcium carbonate may be the most timeless of all building materials. Fanciful history aside, CaCO3 has been used for countless applications in human habitats. After all, tine marble block and tiles have always been the hallmark of eloquents and style. Mortars and cements derived from limestone have held together the very blocks of our civilization. In modem times, synthetic polymers are blended with ground limestone to produce everything from pipe, floor tile, cultured marble and house siding. All of these miracles of our technology contain CacO3 of various sizes and in varying amounts. This paper will discuss some of the critical attributes of CaCO3 which make it suitable for the new building products that have helped increase our standard of living. The vehicle of discussion will be a residential, single family house.

Jan 1, 1993

By J. W. Matousek

Cobalt behavior in pyrometallurgical processes is traditionally analyzed using slaglmatte distribution coefficients as functions of matte grades or matte iron contents. L(s/m) = (%Co) I [%Co] = f [%CuNi] or f [%Fe] The method is inconvenient to use in predictive mass balance work because of the interdependence of assays and mass quantities. An alternative procedure is proposed based on cobaltliron ratios for slags and mattes: Js = (%Co) / (%Fe), Jm = [%Co] / [%Fe], and J, = b + m [Jm]

Jan 1, 1993