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By Colwell JB, Cronan DS

Manganese nodules cover great areas of deep ocean floor far from land, and have long been considered a major potential resource of nickel, copper, cobalt and perhaps manganese. A decade ago there was a period of intense evaluation of nodule fields, especially those lying between the Clarion and Clipperton Fracture Zones in international waters southeast of Hawaii. There, nodules are abundant and of high grade (average of 2.4% Ni+Cu+Co). The evaluation activity has since declined, but a recent agreement on lease boundaries among all interested parties may lead to a resurgence of work. Indeed, French and Japanese groups have pushed ahead with field and economic assessments.The Southwest Pacific, where there are large nodule fields in the waters of the Cook Islands and Kiribati, has seen considerable assessment of resources in the last ten years, especially through a major field programme of the Japanese Metal Mining Agency. The best prospect appears to be in the South Penrhyn Basin, in Cook Islands waters, where nodules are very abundant but of only moderate grade (1% Ni+Cu+Co). Using a cut-off of 5 kg of wet nodules per m2, Cronan (1989) and Cronan et al. (1989) have estimated the total resource to be a huge 110 million tonnes of Ni+Cu+Co.

Jan 1, 1990

By Dennis Nottingham

Spin-fin pipe piles can develop large loads in tension, thus have evolved as a foundation product of great potential. Currently, over 500 spin-fin piles have been used successfully in dolphins, docks, buildings and bulkheads. Spin-fin piles are pipe piles with plates welded near the tip at a batter-in-screw fashion. Thus, as the pile is driven, the pile screws into position. Tests show this pile type to have highly unusual stress/strain relationships, wherein plunging failure is usually never reached either at normal or large deformations. Tension capacity can approach pile capacity in bearing; thus, large reserves are usually available for tension. Tests have been performed on 8-5/8-inch to 24-inch-diameter piles in silt, sand, and gravelly soil, to provide a broad spectrum of data.

Jan 1, 1990

By D. Castillo

The effectiveness of a flotation column is due principally to the addition of wash water to the froth phase. The wash water flow rate can be significant, especially so for systems yielding a high weight recovery of fine solids, e.g. zinc sulfide flotation. Therefore, it is critical to recognize and assess the impact of the water addition upon upstream separation stages. This paper examines column flotation circuit configurations using data from a portable 2 t/day pilot plant. The objective is to provide an improved basis for column design, either as a retrofit or as part of a new circuit.

Jan 1, 1990

By D. B. Dreisinger

The zinc pressure leach process developed by Sherritt Gordon, Ltd. permits the direct leaching of sulphide concentrates according to the overall reaction, ZnS +H,zS04 +402.+ZnS04+H20 +S0 The kinetics of the leach are affected by three rate controlling steps; ( l) oxygen mass transfer from the gas to the leach solution, (2) homogeneous oxidation of ferric ion to ferric ion by dissolved 011.ygen and (3) ferric ion leaching of zinc sulphide in the presence of a sulphur dispersing detergent (lignin sulphonic acid). Fundamental studies have been conducted to identify the factors that influence the kinetics of each individual rate controlling step. Oxygen mass transfer studies have been directed toward optimization of the agitator configuration for solids mixing and gas pumping from the atmosphere above the leach slurry. The rate of ferrous oxidation by molecular oxygen and the rate of zinc sulphide leaching by ferric ion have been studied over a wide range of temperature and solution compositions. The study of zinc sulphide leaching by ferric ion was supplemented by a series of interfacial tension measurements in the liquid sulphur - zinc sulphate solution system. The various kinetic studies have been summarized in terms of the importance of each rate to the performance of the process.

Jan 1, 1990

By Nabil A. Bibawy

An improved method for preparing gravimetric standard gas mixtures of helium-4 in nitrogen has been developed by the U.S. Bureau of Mines. A single-pan 12-kg analytical balance that has a sensitivity of 3 mg is used to prepare the mixture. The balance will accommodate a cylinder having a volume of approximately 4 L that weighs approximately 5 kg. The method has been improved to a precision of ±O.04 pct by performing four successive dilutions, by improved handling of gases in the manifold, and by using an improved analytical method to select high-purity gases.

Jan 1, 1990

Ventilation 'is currently used in mines to sustain human life, prevent explosions, and provide a more healthful work place. Future automated-mining systems could use ventilation techniques quite. different from today's practices. The Bureau of Mines is anticipating various methodologies for ventilating the automated mining systems which are now beginning to emerge in the mining industry. This paper examines the special ventilation requirements for automated mining systems. Topics include requirements for automated systems, current studies with blowup ventilation tubing, and ventilation of two types of highwall -ripper type mining machines.

Jan 1, 1990

By W. S. Fyfe

The future environment of our planet, with the concept of sustainable development, has moved to centre stage of all future plans for development. This global view is new. It presents great opportunities and challenges for the Earth Sciences. We have the tools to describe our environment on all scales - planetary to molecular levels. We must respond to this great demand by world society.

Jan 1, 1990

By Welby G. Courtney

This publication reviews recent U.S. Bureau of Mines studies of frictional ignition of a methane-air environment by coal mining bits cutting into sandstone and the effectiveness of remedial techniques to reduce the likelihood of frictional ignition. Frictional ignition with a mining bit always involves a worn bit having a wear flat on the tip of the bit. The worn bit forms hot spots on the surface of the sandstone because of frictional abrasion. The hot spots then can ignite the methane-air environment. A small wear flat forms a small hot spot, which does not give ignition, while a large wear flat forms a large hot spot, which gives ignition. The likelihood of frictional ignition can be somewhat reduced by using a mushroom-shaped tungsten-carbide bit tip on the mining bit and by increasing the bit clearance angle; it can be significantly reduced by using a water spray nozzle in back of each bit, which is carefully oriented to direct the water spray onto the sandstone surface directly behind the bit and thereby cool the hot spots formed by the worn bit. A bit replacement schedule must be used to avoid the formation of a dangerously worn bit.

Jan 1, 1990

By J. D. McKay

Flotation columns have been readily accepted for use in most sulfide flotation plants; however, recently columns are being used in many other areas. Recent improvements in design methodologies have overcome many operating problems and led to improvements in metallurgy. In addition, physical improvements in column design have simplified their operation while leading to better control. The Turbo-Air External Bubble Generator has provided a method for bubble size control and variation in air holdup and carrying capacity. These have enabled commercial operations to improve grades and recoveries by optimizing performance.

Jan 1, 1990

By Margaret M. Ragin

In a cooperative effort between the U.S. Bureau of Mines and the Florida Institute of Phosphate Research, with input from the phosphate industry, the conversion of phosphogypsum to sulfur has been investigated. The first step in the conversion scheme involves reduction of phosphogypsum to calcium sulfide. Effects of temperature, catalyst, reaction time, and type of reductant (carbon monoxide and coal) are discussed. It was determined that phosphogypsum could be reduced to calcium sulfide at 850° to 1,000° C using either coal or carbon monoxide as the reductant. The required temperature was lowered to 750° C using ferric oxide or magnetite as a catalyst for the reduction reaction. Results indicate that as the volatiles content of the coal is increased, reaction temperature may be decreased to obtain a given conversion, or if the reaction temperature is maintained constant, the conversion can be increased. Best results were 95- to 100-pct conversion using a high-volatile coal at 800° to 850° C. Addition of a catalyst increased calcium sulfide yield when low- or medium-volatile coals were used as reductants, but had little effect when high-volatile coals were used.

Jan 1, 1990

By William M. McKewan

The U.S. Bureau of Mines has established a wire rope research laboratory to examine the factors that affect the life of wire rope. Ropes of sizes ranging from 3/4 to 2 in. in diameter and from 2 to 35 ft in length were tested to determine their breaking strength, elongation, and torque. This was done to characterize the test equipment on ropes used in mine hoisting systems.

Jan 1, 1990

By R. E. MacDougall

Very few mineral properties spend their entire lifespans from discovery to depletion in the hands of one owner. More likely, properties will have several owners, and partial interests may change quite often. Similarly, mineral companies are bought and sold with frequency, in recent years at what appears to be an accelerating rate. The reasons for selling a property can be manifold -need for additional capital in other parts of the business, need for development capital, realization of a large gain at a perceived high point in the market, pessimistic commodity outlook, retirement of principals, or resolution of estate problems. Regardless of the reasons for a sale, there are specific steps that logically follow. Spruce up the business, package the information, market the property, negotiate the terms, close the sale, and make sure it stays sold. Adherence to certain very basic ground rules in property sales can maximize the profits and minimize the effort.

Jan 1, 1990

By W. R. McDonald

Part of the U.S. Bureau of Mines mission is to supply the U.S. mineral industries with information that is useful in planning to meet the Nation's critical and strategic mineral needs if a national emergency occurs. The Bureau conducted laboratory research including operating a nominal 100 lblh pilot plant to demonstrate the recovery and concentration of chromite by gravity and flotation operations from three northern California mineral deposits. Gravity beneficiation test results show that concentrates contained as much as 52 pet chromic oxide (CrZ03) with recoveries of about 80 pet. Results from the bench-scale unit operations of mineral liberation, tabling, vanning, spiraling, pinch sluice, work index, and thickener area determination tests are presented in this report.

Jan 1, 1990

By R. J. Wesely

The paper describes the various methods which are currently being used or considered to refine gold and silver. These methods are then compared on a technical and economic basis. Conclusions are drawn on the factors which might influence the choice of process for different feed stocks and economic constraints

Jan 1, 1990

By John J. Sammarco

The U.S. Bureau of Mines is conducting research into computer-assisted mining, which requires investigation of new techniques for development and application of computer-based technologies. Today's technology can require significant effort in software development, as has become evident in the early stages of this Bureau research. Technologies for software automation, such as computer-aided software engineering (CASE), are available. This report explores CASE, its general features, and its importance in software development. Information is presented to assist in selection and application of the variety of CASE tools and methods for automating various stages of software development. When evaluating CASE for use, it is important to examine tools that support an organization's existing methods of software development. Support for existing hardware platforms must also be examined. Merely selecting a "good" CASE tool does not insure success. Thorough evaluation of implementing CASE is also critical. Subjects to evaluate for CASE implementation include organization culture, support from management and end users, training resources, and pilot projects. Organizations that benefit the most from CASE evaluate CASE features with respect to their needs and they properly implement CASE.

Jan 1, 1990

By Richard J. Mainiero

The U.S. Bureau of Mines in cooperation with Jim Walter Resources, Inc. (JWR), Brookwood, AL, evaluated the use of sheathed explosive charges in breaking up large stones that can jam the feeder¬breaker or pan conveyor on longwalls and halt operations. Use of the sheathed charge reduced the downtime of the longwall panel to 15 to 30 min as compared with the 1 to 2 h required to drill and shoot the stone. Firing the sheathed charge at the face caused no significant damage to Iongwall equipment. Use of the sheathed charge also represented an improvement in safety by eliminating the exposure of miners to the inherent hazards of the face for extended periods of time. Another benefit, which is difficult to quantify, is the elimination of the temptation to shoot mudcaps or adobes, which is illegal in U.S. underground coal mines.

Jan 1, 1990

By Thomas J. Albin

This U.S. Bureau of Mines report identifies potential causes of slip-and-fall accidents occurring during surface mine equipment maintenance and describes the relative roles of direct worker behavior and machine design. The relative roles of human behavior and machine design in the causation of slip-and-fall accidents were determined through analysis of accident records, observations of maintenance worker behavior, and evaluation of mine machinery. From these data, relative risk ratios were calculated. Behavior had a relative risk ratio of 1.5; machine design, specifically access systems design, had a relative risk ratio of 2.2. Of the access systems, ladders had the highest relative risk ratio, 7.0. This study suggests that accident intervention would be most profitably made in improving the design of systems used to access maintenance worker areas of mining equipment.

Jan 1, 1990

By N. S. Dalal, Xianglin Shi

"Electron spin resonance (ESR) measurements provide direct evidence for the involvement of Cr(V) in the reduction of Cr(VI)· by NAD(P)H. Addition of hydrogen peroxide (H2 O 2) to NAD(P)H-Cr(VI) reaction mixtures suppresses the Cr(V) signal and generates hydroxyl (·OH) radicals (as detected via spin trapping), suggesting that Cr(V) reacts with H2O 2 to generate the ·OH radicals. Reaction between H2O 2 and a Cr(V)·glutathione complex, and between H2O 2 and several Cr(V)-carboxylato complexes also produces ·OH radicals. These results suggest that Cr(V) complexes catalyze the generation of ·OH radicals from H2O 2, and that ·OH radicals might play a significant role in the mechanism of Cr(VI) cytotoxicity. KEY WORDS: ESR. spin trapping, Cr(VI) reduction, Cr(V), hydrogen peroxide, free radicals.INTRODUCTIONThis communication reports an ESR spin trapping detection of hydroxyl ( OH) radicals.in reactions between some Cr(V) complexes containing biologically important ligands and hydrogen peroxide (H2O 2 ). This work was undertaken because while the reduction of Cr(VI) to lower oxidation states has been suggested as a key step in the mechanism of Cr(VI) toxicity, the reaction· mechanism is not yet clear. 1 Mutagencity has been well documented for Cr(VI) via various bacterial assays, while Cr(III) has been shown not to be mutagenic.2 • 3 Since it has been reported that compounds containing Cr(VI) do not react with isolated DNA,4 the reduction of Cr(VI) by other cellular constituents has been thought to be important in the mechanism of Cr(VI) induced DNA alteration.1·4 • 5 For cellular systems earlier studies include those on the reduction of C~(VI) by microsomes,6-8 rat liver DT-diaphorase,9 and aldehyde oxidase. 10 Regarding the reduction mechanism, Jennette used ESR spectroscopy to show that a long-lived Cr(V) complex is formed as an intermediate in the microsomal reduction of Cr(VI) in the presence of NADPH.8 She postulated that Cr(V) is the ""ultimate"" carcinogenic form of chromium compounds. This conclusion has led to many further investigations of the formation of Cr(V) in the reduction of Cr(VI) under biologically relevant conditions.11 - 19 More recently, however, it has been suggested that oxygen-derived radicals generated during the Cr(VI) reduction are the species responsible for the DNA alteration.20.2• To the best of our knowledge, however, no information is available on the generation of such radicals in the reduction of Cr(VI) under biologically relevant conditions, except some preliminary results on the glutathionyl (GS·) radical formation in the reduction of Cr(VI) by glutathione (GSH). 11 - 19 We, therefore, undertook a systematic investigation of the reaction of Cr(VI) with NAD(P)H, GSH, ix-hydroxycarboxylic acids, and H2O 2 • NADPH was chosen as a model reductant because of its ubiquitous existence inside the cells, its critical role in the enzymatic Cr(VI) reduction,1·6-9 its representation of important cellular Cr(VI) reductants, and its ability to reduce other metal ions.22 GSH was chosen as another model Cr(VI) reductant because GSH also exists inside cells, it represents another important category of cellular Cr(VI) reductants, the thiols, and it also plays an important role in the Cr(VI) toxicity .1• 1 ""- 19.i3.i4 For further clarification, we also studied the reaction of Cr(VI) with several '1'.-hydroxycarboxylic acids in the presence of H2O 2 since these acids are definitively known to reduce Cr(VJ) to form stable, isolable Cr(V).25 .2 6 The results obtained indicate that Cr(V) complexes, produced in the reduction of Cr(VJ) by cellular reductants, react with H2 O 2 to generate ·OH radicals, which might be the initiators of primary events in Cr(VI) carcinogenicity."

Jan 1, 1990

By K. E. Harrison

Acid rain legislation as proposed by President Bush [1], if enacted, will immediately refocus current thinking on the economic decision-making as related to coal preparation facilities. Unit operations currently ignored because of their costs, will become mandatory to coal plant designers and operators to ensure maximum energy recovery and sulfur reduction in the entire coal stream. In anticipation of this need, the U.S. Department of Energy, The Ohio Coal Development Office, EPRI and others are sponsoring research in several areas of coal preparation, and coal plant designers are beginning to consider more innovative techniques as they configure their flowsheets for plants of the future. Preparation plants then will have recleaning

Jan 1, 1990

By Joseph Gersic

In 1989-90, the Bureau of Mines appraised selected high resource potential areas containing gold, rare-earth-element, or pegmatite deposits in or near the Black Hills National Forest. Available mineral resource data were used to construct mine and mill models and to compute discounted cash-flow rate-of-return analyses. Using this information, the economic feasibility of possible operations and probability (in the nonmathematical sense) of exploration and development within the next decade were assessed. High exploration and development probabilities are forecast for gold deposits around existing and permitted mine areas near Lead-Deadwood and west of Galena. The area east of Galena has low to moderate exploration and development probability; the Rochford area has low to high exploration probability and low to moderate development probability; the Keystone area has low to moderate exploration probability and low development probability; the Medicine Mountain area has moderate to high exploration and low to moderate development probabilities. Exploration probability in the Bear Lodge Mountains area is high for rare-earth elements and gold; development probability is low. Exploration probability for gold in the Mineral Hill area is low to moderate; development probability is low. The current level of activity associated with pegmatite mining in the Black Hills would probably not change significantly in the next decade; both exploration and development probabilities are low to moderate.

Jan 1, 1990