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By Ana E. Bohé, Georgina De Micco, Juan P. Gaviría, FEDERICO J. POMIRO, Gastón G. Fouga

Chlorination and carbochlorination processes have industrial applications in metallurgical activity for extraction and purification of uncommon metals such as rare earth elements (REE). This study reviews the chlorination and carbochlorination reactions of light REE (LREE) oxides with chlorine considering the thermodynamic, stoichiometric, and kinetic aspects of the reactions. Lanthanides between lanthanum to gadolinium were considered as LREE, in agreement with previous literature, and the results were detailed in this review. LREE were analyzed taking into account their oxidation states and were divided into three groups accordingly. The results presented show that, although the LREE are chemically similar, their behaviors during the reactions with Cl2 and Cl2–C, and the different LREE-O–Cl compounds formed, have particularities. It was observed that gadolinium, in both thermodynamic calculations and experimental results, presents some differences, and it can be considered intermediate between light and heavy REE; i.e., reactions between LREE2O3 and Cl2(g) begin at approximately 250 °C, except for Gd2O3 that begins at 327 °C. The present work will contribute to a better understanding of the chemistry of LREE oxides and Cl2 under different conditions and the products obtained in the LREE–O––Cl2(g) and LREE–O–C–Cl2(g) systems.

Oct 15, 2021

By Xuezhong Wang, Hao Guo, Tao Tu, Qingsheng Liu

The scheelite concentrate was leached with a mixture of sulfuric and oxalic acids. Chemical compositions, mineral phases, and morphology were characterized by XRF, XRD, and SEM–EDS. Based on the results of the single-factor experiments, the response surface methodology (RSM) was chosen to optimize the leaching parameters: temperature, time, and concentrations of sulfuric and oxalic acids. The RSM results indicate that the optimum values for those parameters are as follows: temperature 72 ℃, sulfuric acid concentration 1.48 mol/L, oxalic acid concentration 0.96 mol/L, and reaction time 2 h. Under the optimal leaching conditions, the model predicts a maximum leaching yield of 99.5%, compared to the value of 99.1% obtained experimentally, that is, a discrepancy of only 0.04%. This good correlation shows that the quadratic polynomial equation obtained by the RSM optimization is reliable. The importance on leaching parameters of scheelite is, in decreasing order, temperature, time, sulfuric acid concentration, and oxalic acid concentration.

Oct 11, 2021

By Huiqin Yao, Dongmei Liu

The study investigated the potential use of low activity circulating fluidized bed combustion (CFBC) ash and phosphate tailings for the production of a filling material based on the cement. The phosphate tailings were used as aggregate and consolidated by cement and CFBC ash. The results showed that the bleeding rate and fluidity of all mixtures decreased with the increasing the amount of CFBC ash. The fluidity of filling slurry is highly related to the experimental factors such as the content of sulfur solid ash, B/A ratio, and mass concentration. The replacement of CFBC ash ranging from 20 to 40% led to a significant decrease in setting time and an obvious increase in compressive strength, but the above effect was obviously weakened when reducing the mass concentration and B/A ratio. The hydrated calcium silicate gel and ettringite generated from the hydration of cement and CFBC ash were the main sources of strength for the filling materials. When the recommended proportion was 1/6 binder/phosphorus tailings ratio, 76% solid content, and 40% CFBC ash replacement, the filling material still met demands on working and mechanical properties; at the same time, the utilization of CFBC ash and phosphorus tailings was maximized.

Oct 11, 2021

By Atta Ur Rehman, Kwame Awuah‑Offei

This paper evaluates the effectiveness of similitude theory in predicting the draft of a rubber tire loader’s bucket during initial penetration. The work uses 1:16 and 1:8 scale models of an 18-t capacity load haul dump, scaled with the Buckingham Pi Theorem, to evaluate the prediction of draft and penetration under different operating and different dynamic conditions. The authors hypothesize that the observed relationships between draft and longitudinal penetration and the operating and dynamic conditions will hold true for an upscaled model. Similarly, the authors hypothesized that the results of experiments conducted with the smaller scaled model should predict the draft on an upscaled model. The results show that the relationships between draft and longitudinal penetration and operating and dynamic parameters are similar for both scaled models. Similarly, the draft on the upscaled model, predicted by using the experimental results of the small model, is similar to the measured draft on the upscaled model. The mean difference between the two is 1.71 N with 95% confidence interval of [-3.51, 6.93], which is very good given the average draft is approximately 330 N. Thus, the work indicates that both hypotheses are true for draft. However, the work shows that scaling muck pile particle sizes using the Buckingham Pi Theorem is not adequate to ensure good predictions of penetration. This work provides insights that will help design engineers to acquire useful data on scaled models and use it for various analyses on heavy machinery.

Oct 6, 2021

By D. Sethuram, P. G. Koppad, S. Iyengar, R. Shobha

TiB2 and CeO2 particle-reinforced Al6061 hybrid composites were manufactured using stir casting and hot rolling techniques. The base alloy and composites were hot-rolled at 500ºC and a 50% reduction was achieved through 12 passes. The effect of varying TiB2 and CeO2 particle additions on the microstructure and mechanical properties of the Al6061 matrix was studied. Scanning electron microscopy showed uniform dispersion of both the reinforcements, with good interfacial bonding. Microhardness and tensile properties like yield and tensile strength were found to be higher for hybrid composite with 2.5% TiB2 and 2.5% CeO2 compared to Al6061 alloy and other hybrid composites. The increased tensile strength is attributed to good dispersion and interfacial bonding between the particles and Al6061 matrix. Fracture analysis using a scanning electron microscope revealed ductile fracture for the Al6061 alloy and mixed characteristics of ductile-brittle fracture for hybrid composites

Oct 1, 2021

By K. A. du Preez, P. J. van Staden, M. van Rooyen

Mine-impacted water, including acid mine drainage (AMD), is a global problem. While precipitation of dissolved metals and neutralization of acidity from mine-impacted water is accomplished relatively easily with lime addition, removal of sulphate to permissible discharge limits is challenging. This paper presents a high-level comparison of four sulphate removal technologies, namely reverse osmosis, ettringite precipitation, barium carbonate addition, and biological sulphate reduction. Primarily operating costs, based on reagent and utility consumptions, are compared. Each process is shown to be subject to a unique set of constraints which might favour one over another for a specific combination of location and AMD composition. Access to and cost of reagents would be a key cost component to any of the processes studied. The total cost calculated for each process also depends on the type of effluents that are allowed to be discharged.

Oct 1, 2021

By Gerald Verbeek, Erick Baziw

Cone penetration testing (CPT) is a popular and cost effective tool for geotechnical site characterization. CPT consists of pushing at a constant rate an electronic penetrometer into penetrable soils and recording cone bearing (qm), sleeve friction (fs) and dynamic pore pressure (u) with depth. The measured qm, fs and u values are utilized to estimate soil type and associated properties based predominantly on empirical correlations. The cone bearing measurements are highly susceptible to additive measurement noise for sandy, silty and gravelly soils. This measurement noise results in high peaks due to interbedded gravels and stones and low peaks due to softer materials or local pore pressure build-up. To date there has been little progress in filtering this additive noise aside from ad hoc techniques, which include discarding qm measurements and smoothing/averaging qm measurements. This paper outlines a qm filtering technique which attempts to put structure into the estimation problem. In this case, the dynamics of the cone bearing measurements are modelled within a state-space mathematical formulation and a Kalman filter (KF) is then utilized to obtain optimal estimates of qm. The mathematical details of the qm KF algorithm are outlined in this paper along with the results from a challenging test bed simulation.

Oct 1, 2021

By MATT RENAUD, Mustafa Kumral

As high-quality mineral deposits are thoroughly exploited, mines of the future will have to move towards more remote and lower quality projects. With these projects comes an increased business risk to the operator. Even now, mining companies often turn to foreign countries for new deposits to produce, introducing the concept of country risk into their portfolio. Furthermore, feasibility studies often fail to accurately quantify the risks associated with various projects, and as such, this study proposes a technique of risk quantification which can both aid mining companies to evaluate the viability of investment and assist in risk disclosure to public investors for the mining industry of the future. This paper aims to quantify the effects of country risk on the valuation of potential mining projects, using a combination of modular and risk-weighting techniques to evaluate the country risk premium (CRP) required to obtain capital for operation of risky foreign mining projects. The techniques proposed in this paper are demonstrated using fictional examples and then evaluated for accuracy against a recently developed debt-funded precious metal project in a country in the Americas.

Sep 30, 2021

By P. Samanta, Mohammed N. Azad, Gustad F. Taraporewalla, A. K. Mukherjee, Abhay S. Patra, D. Sachinraj

Beneficiation of coal is a water intensive process, and the water is recovered in downstream operations in the high rate thickener (HRT) and vacuum belt filtration (VBF). Clean coal particles entering the HRT have an inherent tendency to enter the overflow because they are extremely fine and hydrophobic. Hence, flocculants (polymers) are used to floc the ultrafine particles so that they settle and enter the underflow. Ultrafine coal particles (−37 μ), which are highly hydrophobic, if present in the stream, will not be efficiently captured by using flocculants alone. This is observed in the normal plant operation at one of the beneficiation plants in the Jharia region, Jharkhand, India. Approximately 6–7% of the feed to the HRT enters the over flow (supernatant water). Hence, this amount of clean coal particles is not recovered and account for production losses. A comprehensive settling and dewatering test work was conducted with clean coal slurry using several commercially available reagents. Studies were also done on different combinations of reagents, including coagulants and surfactants along with flocculants, to improve the settling behavior of the coal particles. The reagents were assessed based on their performance with respect to settling rates, overflow water clarity, and compaction of the underflow solids. Emphasis was given to the ability of the reagents in compacting thickener underflow to higher densities so that maximum water could be recovered from the thickener. Pretreatment of highly hydrophobic coal slurry with a combination of coagulant and surfactant followed by flocculation showed very good settling characteristics with clear overflow.

Sep 30, 2021

By Yanxu Shen, Cheng Liu, Zhijie Chen, Hao Chen, Huimin Gao, Zijie Ren

Fluorite, a kind of critical non-metallic minerals, is the primary source of industrial fluorine. Sodium oleate (SO) is commonly used as the collector of fluorite ores. However, because of its some features (such as the low solubility, high solidifying point, and poor dispersion of SO) at low temperatures, it profoundly inhibits its collecting ability as well as the flotation performance. Herein, we have developed a low-temperature-resistant collector for the efficient flotation separation of fluorite from quartz. The advantages and disadvantages of the SO and sodium petroleum sulfonate (SPS) were analyzed by comparing the performance under different temperature conditions. The results of flotation tests suggest that SPS exhibited much better collecting performance than SO under low temperature. The flotation mechanism of the two collecting agents were further analyzed by contact angle measurements, zeta potential measurements, Fourier-transform infrared spectroscopy (FT-IR), and flotation kinetics. The results indicated that both collectors can selectively undergo electrostatic and chemical adsorption with fluorite, with no adsorption on quartz surface. The sulfonic acid group in SPS is a hydrophilic functional group, which has a relatively higher solubility in water. Therefore, the water solubility of SPS is better at low temperatures.

Sep 30, 2021

By A. Halim, A. Martikainen, S. GYAMFI

This paper outlines a unique case of the development of strategies to reduce ventilation and heating costs in Konsuln iron ore mine in northern Sweden. The mine, located just south of Luossavaara-Kiirunavaara Aktiebolag’s Kiruna iron ore mine, was developed as a test mine from 2018-2020 for the Sustainable Underground Mining (SUM) project. Besides functioning as a test mine, Konsuln also contributes to ore production. The existing mine ventilation system was designed for the current production rate of 0.8 million tons per annum (Mtpa). There is a plan to increase this rate to between 1.8 and 2.0 Mtpa.

Sep 30, 2021

By S. Rukhaiyar, M. Ramulu, G. Pradeep, P. K. Singh, P. B. Choudhury

The drill and blast method is the most prominent rock excavation method used in mining and civil engineering projects. The ground vibration is the most undesirable effect of the blasting and needs to be controlled. The blasts are designed so that ground vibration at nearby structures must remain under the prescribed limit. Various empirical blast vibration attenuation models have been presented to estimate the ground vibration for designing purposes. These models assume ground vibration as a function of distance and maximum charge per delay. United States Bureau of Mines (USBM) model is most commonly used for the blast design. However, the uncertainty associated with these models is seldom characterized, thus diminishing its reliability. The probabilistic Bayesian approach associated with the Monte Carlo method can easily quantify uncertainties associated with the model and its parameters. Thirty-three blast vibration observation data from a granite quarry in Kerala, India, is used to estimate the probability distribution of model parameters. Markov Chain Monte Carlo (MCMC) approach is used for sampling 12,000 samples for obtaining the posterior distribution of parameters. The uncertainty associated with model parameters is quantified from the posterior distribution, and this is further used to estimate the credible and prediction limits of the model. The point estimate of the most optimum value of the parameter is estimated using maximum-aposteriori or MAP estimate. The model parameters are also obtained using the commonly used least-square error method, which is a maximum likelihood estimation or MLE approach. It has been observed that the accuracy of the model obtained using both MAP and MLE approach is almost equal. However, the MAP estimate as per Bayesian probabilistic analysis has the added advantage that it can estimate the uncertainty of parameters as well as the model, which is not possible using the MLE approach.

Sep 27, 2021

By JESSICA W. A. AZURE, Samuel Frimpong, AZUPURI G. A. KABA, FORSYTH A. KADINGDI, PROSPER E. A. AYAWAH

This study developed machine learning (ML) models for predicting rock formation reactive forces experienced by a hydraulic shovel bucket during excavation. To do this, rock formation in the form of muckpile was modeled as granular ball elements in three-dimensional particle flow code (PFC) using linear bonding logic. A typical field-size hydraulic shovel bucket modelled in AutoCAD was used to excavate the rock formation and the three-dimensional shovel bucket resistive forces required to cut through the rock formation were measured and recorded. The experiments involved different muckpile height, bulk densities, repose angles, and average fragment size. Six ML algorithms, artificial neural network (ANN), K-nearest neighbor (KNN), linear, random forest (RF), regression tree (RT), and support vector machine (SVM), were evaluated on their ability to predict the shovel bucket resistive forces. The input variables used for the prediction of the resistive forces were the muckpile bulk density, angle of repose, height, and fragment size. The results showed that the ML techniques are useful and reliable methods of predicting rock formation resistive forces based on the rock formation properties. This research is a preliminary step towards developing reliable models for accurate prediction of excavation forces/torques which could potentially enhance hydraulic shovel process automation.

Sep 27, 2021

By Yinan Zhang, Y. Luo

Most of the reported coal spontaneous combustion events occur in surface and underground mines where low rank coals (i.e., subbituminous and lower for this particular studies) are extracted indicating their high propensities for spontaneous combustion. Low rank coals have high moisture content (15 to 45%) and are capable of absorbing more moisture in dried condition. However, it is hard to induce the initial stage of self-heating process for the low rank coal using the current laboratory R70 testing method — a method widely used in the coal industry. Like a sponge, dry low rank coals can absorb water vapor in the air while the heat contained in the moist air is transferred to coal and served as the required activation energy to initiate the coal self-heating process. In order to prove this theorem and quantify the effects, the R70 adiabatic oxidation testing method has been improved to introduce a controlled moist flow into the coal reaction vessel. Tests using the new method and its setup on low rank coals showed that the initial self-heating process of coal sample can be greatly accelerated by the added water vapor — impossible with the regular R70 method. Once the self-heating is sustained, the removal of air moisture can further accelerate the process.

Sep 17, 2021

By Paul R. Lear

Sustainability continues to be an important aspect of remediation and infrastructure projects. Deep soil mixing (DSM), a common construction and remedial technology, can easily incorporate the following sustainability best management practices (BMPs), including Minimizing Total Energy Use and Maximizing Use of Renewable Energy; Minimizing Air Pollutants and Greenhouse Gas (GHG) Emissions and Maximizing Use of Machinery Equipped with Advanced Emission; Minimizing Water Use and Impacts to Water Resources; Beneficial Reuse of Materials/Reduction of Materials and Waste Reduction; Use of Local Labor and Supplies. This paper focuses on the sustainability of DSM treatment and provide carbon footprint calculations at least one completed DSM project which used these sustainability BMPs to demonstrate the environmental impact of the sustainability.

Sep 8, 2021

By Eric P. Bregman, Justin Zarrella, Ryan M. Coulson, Connor Johnson

Within a prominent Boston, MA suburb are a pair of historic stone and mortar structures built in the late 1800’s. Both the Main House and Carriage House have been maintained and occupied throughout their rich history, but renovations were needed to address structural concerns and building code compliance issues. The focus of this paper is to detail an innovative underpinning design that addressed ongoing settlement issues at the Carriage House. GZA GeoEnvironmental, Inc. (GZA) partnered with Phoenix Foundation Company, Inc. (Phoenix) to design foundation wall support systems for Consigli Construction Company (Consigli) that would effectively underpin the historic field stone foundations. Originally, conventional concrete pit underpinning and jet grouting were contemplated as methods for support. However, due to the age and condition of the existing foundations, worker safety concerns, and the risk of additional structural damage, GZA/Phoenix elected to pursue a less traditional approach. The alternate design consisted of micropiles used for combined temporary and permanent foundation support. The load transfer system included steel headers with needle beams cored through the field stone foundation walls and reinforced concrete grade beams/pile caps. To validate design performance and ensure worker safety, GZA installed a fully automated survey monitoring system to record lateral and vertical building deformations. This included real-time email alert notifications to inform the Project Team of any threshold exceedances. From the start of micropile drilling through full load transfer to the temporary support and permanent foundation systems, the underpinning performed as designed resulting in less than 3/16-inch of vertical and horizontal deformations observed. This magnitude of movement is less than half of what is generally accepted deformation tolerances for masonry structures and considered exceptional performance. The focus of this paper is to provide additional details on the unique design, sequencing, installation, and performance of the underpinning systems.

Sep 8, 2021

By Seth Robertson, Daniel Belardo, Travis Coleman

Thermal Integrity Profiling (TIP) is a non-destructive method used to evaluate drilled deep foundation integrity. This integrity testing method is specified more frequently, and is becoming an industry standard in the transportation and private construction sectors. This testing method utilizes heat generated during the concrete/grout curing process to assess deep foundation integrity over the evaluated length. With compilation of the measured temperature versus time and installation records, a model of the Effective Average Radius versus measurement depth is generated. The generated effective shaft model is highly dependent on specific construction details, subjective modeling parameters, and proper interpretation of concrete/soil heat dissipation characteristics. Key components of the TIP analysis include both qualitative and quantitative assessments. Qualitatively, variations or sharp reductions in temperature profiles may indicate potential anomalous regions. Quantitatively, a correlation is established between measured temperatures and estimated Effective Radii for subsequent integrity evaluation. Best practices in processing the TIP measurements are presented, including selecting the optimal time for analysis, normalizing the thermal profile, and proper interpretation of potential anomalous regions. Recommendations for implementing mitigation efforts and interpretation of the TIP results are presented.

Sep 8, 2021

By Gerald Verbeek, Erick Baziw

Cone penetration testing (CPT) is a popular and cost effective tool for geotechnical site characterization. CPT consists of pushing at a constant rate an electronic penetrometer into penetrable soils and recording cone bearing (qm), sleeve friction (fs) and dynamic pore pressure (u) with depth. The measured qm, fs and u values are utilized to estimate soil type and associated properties based predominantly on empirical correlations. The cone bearing measurements are highly susceptible to additive measurement noise for sandy, silty and gravelly soils. This measurement noise results in high peaks due to interbedded gravels and stones and low peaks due to softer materials or local pore pressure build-up. To date there has been little progress in filtering this additive noise aside from ad hoc techniques, which include discarding qm measurements and smoothing/averaging qm measurements. This paper outlines a qm filtering technique which attempts to put structure into the estimation problem. In this case, the dynamics of the cone bearing measurements are modelled within a state-space mathematical formulation and a Kalman filter (KF) is then utilized to obtain optimal estimates of qm. The mathematical details of the qm KF algorithm are outlined in this paper along with the results from a challenging test bed simulation.

Sep 8, 2021

By Murad Y. Abu-Farsakh, Md Habibur Rahman

The properties of all natural soil deposits are highly variable, and they are rarely homogeneous. Cone penetration tests (CPT) were used to assess the site variability, which was then incorporated into the Load and Resistance Factor Design (LRFD) of pile foundations. Data from six project sites with multiple CPT tests conducted at various locations were collected for this research. The semi-variogram was used to assess the spatial variability of CPT data (corrected tip resistance, qt) for each location. For each location, the coefficient of variation due to spatial variability (COVR,spatial) was calculated. From COVR,spatial and COVR,method, the total coefficient of variation (COVR,total) for each site was calculated, which was then used to calibrate the resistance factors (ϕspatial, ϕtotal) for use in LRFD pile foundation design. The findings of this study demonstrated the importance of using site variability in LRFD pile design. For sites with lower site variability than the design method (i.e., COVR, spatial < COVR, method), the value of the COVR, total will be decreased, and hence the resistance factors (ϕspatial or ϕtotal) will be increased (credit), and vice versa.

Sep 8, 2021

By Brian J. Olson, Kevin Haiar

Originally constructed between 1939 and 1941 as part of Franklin D. Roosevelt’s New Deal programs, the Bonneville to Hood River 115 kV Transmission Line required an infrastructure upgrade to remain reliable and in-service. The line traverses the rugged landscape of the Columbia River Gorge on the Oregon- Washington border, featuring steep, talus slopes; uneven, rocky terrain; and a variety of environmental sensitivities. This paper details the design and construction of 27 micropile foundations for new, fire- hardening steel poles through a particularly challenging stretch of the alignment. The difficult access and environmental constraints at these sites designated them as helicopter-accessible and precluded the collection of detailed geotechnical information prior to construction. Micropiles provided a viable foundation alternative due to their portability and flexibility during construction. Detail will be provided on the extensive preliminary desktop study performed, as well as the process of developing engineering designs to successfully accommodate for variability and unknowns in complex geological conditions. With an increasing number of electric power projects traversing challenging terrain and facing similar obstacles, this project stands to provide valuable lessons learned to the industry.

Sep 8, 2021