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By M. K. Quinn, N. P. Reddy, A. W. Khair

"An analysis of coal fragmentation due to the action of a continuous miner is presented. Underground coal cutting by a drum-type continuous miner was simulated in the laboratory using a specially designed unique automated rotary coal cutting simulator (ARCCS). The rotary coal cutter provided the versatility of varying the operating and in-situ parameters to provide information on the effects of generating 37 pm (0.0015 in) particles. In these tests, coal blocks with an approximate dimension of 50.8 x 35.6x 20.32 cm (20x 15x 8 in) were first subjected to confining pressures equivalent to in-situ conditions. The blocks were then cut by the rotary cutting head of the ARCCS, thus simulating the action of the continuous miner in underground coal mining. During the tests under a particular set of in-situ and operating parameters a number of other parameters such as (1) penetration of bit into coal, (2) penetration resistance (thrust and cutting pressures), (3) rotating velocity of' cutting head, and (4) acoustic emission activity in the coal block were monitored. During the test, all the cut products were collected for size distribution analysis. After each cutting cycle the fractured surfaces were photographed and a velocity survey was conducted using a sonic technique. At the end of each experiment the cutting paths of the bits in coal were photographed using a camera attached to an optical microscope.The results led to a better understanding of the mechanisms of the fragmentation process during coal cutting and the effect of operating parameters, in-situ conditions and coal type on the size distribution of the cut product:"

Jan 1, 1989

By R. Hogg, S. Chander

"An overview of various physical and interfacial characterization methods for use in mineral processing is presented in this paper. The availability of a large number of characterization techniques and commercial instruments requires that the reliability and limitation of each be carefully examined. The choice of a method may depend upon the manner in which the information is to be used, for example in development of new processes, plant and process design, plant control, problem solving, etc. IntroductionThe behavior of particulate systems, in mineral processing and other applications, is primarily affected by the physical characteristics (size, shape, surface area, pore structure) of the particles and the nature of the different solid-fluid interfaces present. Mineral processing operations in general are either designed to modify and/or control physical and interfacial properties (grinding, classification, agglomeration, etc.) or are strongly influenced by them (flotation, flocculation, solid/liquid separation, etc.). Characterization of physical and interfacial properties should be an integral part of the development of new processes, plant and process design, and routine plant operation.Our purpose in preparing this article has been to present an overview of the current status of characterization, to point out areas of weakness, and to discuss the reliability and limitations of the various techniques, procedures, and instrumentation available. For more detailed discussion of methods, etc., the reader is referred to standard references.Sampling particulate solids.Sampling is a critical factor in any procedure for characterizing particulate materials — the reliability of characterization data is ultimately limited by the extent to which the sample used was truly represen¬tative of the population from which it was taken.Sampling from particulate solids involves two basic problems: (1) the selection of a random', unbiased sample and (2) choice of the appropriate sample size.The problem of sample selection involves the design of a sample collection procedure that ensures that every kind of particle in the population has the proper chance of being included in the sample without bias. Specific procedures such as the well-known cone-and-quarter technique have been developed and are discussed at length in the literature on particle characterization (Allen, 1981: Herdan, 1960: Gy, 1982)."

Jan 1, 1989

By J. P. Dunford

This U.S. Bureau of Mines report describes the development of a yielding steel post for underground mine support. The report covers concept development, laboratory tests, modifications, and field evaluations. The objective of this work was to develop a stiff support member capable both of supporting high loads and yielding when excessive amounts of mine entry closure were present. The 6-to 7-ft steel post was designed to yield nearly 2 ft while maintaining a 45-ton (force) load. The post is a three-piece unit consisting of top and bottom telescoping legs and a separate foot bracket. It develops its load-carrying characteristics when the lower pipe, with an attached interference ring, is forced into the larger top pipe. Laboratory tests were used to determine critical loads and post performance for various post lengths. Field tests showed that the posts could perform in actual mining conditions. The post has the ability to provide support in highly yielding ground and also, because of its slender profile, enhance ventilation and provide more area for travelways and escapeways. The design is simple enough to allow for fabrication at most mine shop facilities.

Jan 1, 1989

By Qing Wang

A longterm overburden removal plan can be realistic and optimum only when the cost and capacity profiles off the equipment assigned to the operation are taken into consideration. Therefore, the planning should involve the proper assignment of equipment capacity by insuring a timely investment and a timely replacement policy throughout the mine life. A dynamic solution algorithm has been developed, by which all possible truck fleet alternatives are evaluated for each year off the operation. Cumulative cost off the operation is carried throughout the analysis. The optimum solution is obtained by selecting the minimum cumulative cost at the last year and tracing backward the best fleet alternative for each year. The solution provides: 1. the optimum amount of overburden to be removed each year; 2. the best fleet to be assigned to the job; and 3. the best equipment replacement policy.

Jan 1, 1989

By Samuel Polinsky, Lawrence W. Bierman, Wayne Perkins

[A column float beneficiation plant using 9, 8.5 foot diameter, cells was constructed by the Simplot Company and the Smoky Canyon Facility in the fall of 1986 and has been in operation since May of 1987. The float beneficiation process was developed jointly by the Simplot Company and the Bureau of Mines (Salt Lake City, Utah) which incorporates the Bureau's bubble generator design and chemistry system based around the reverse float technology, (Albany Bureau of Mines, Application of Carbonate-Silica Flotation Techniques to Western Phosphate Materials, Rule, Dallenbach , Larsen, RI8728, 1982) . This chemistry has been modified by Simplot in both patented and unpatented improvements. The objective of the beneficiation process was to reducethe A1203 content in the overall pipeline concentrate by 0.2 wt z. Therefore, a process stream was identified in the mill circuit which provided an opportunity to isolate and treat 1100 tons per day of poor quality phosphate concentrates The process allows recovery of approximately 15% of the mill concentrates, otherwise unsuitable for fertilizer production. The alternative would have been to waste this ore. Wasting would have resulted in considerable ore loss, increased mining costs and required additional products grinding. ]

Jan 1, 1989

By P. Ventura

Reliability of the liquefaction analysis is based on data plotted as by piezocone, as by deep vibrocompactation monitored tests. The negative porewater pressure, re lated to hydrostatic value, recorded by piezocone, is a good marker of the absen ce of the liquefaction. Systematic measures of the ground settlements, inside the vibroinfixed steel pipe, allow to locate the liquefable strata with loose density. Experimental study of the combined soil improvement by stone columns is carry out in particular in sea bed. The interaxis of the columns for the best efficiency is valued as of the vibrocompactation, as of the drainage effects, especially during earthquake.

Jan 1, 1989

Using normal low pressure filtration methods for the dewatering of fine china clays, the best that can be achieved is cakes with about 30% moisture. In order to get the moisture levels down to acceptable levels the traditional method used is thermal drying, which is both costly and dust creating. It was to improve this process that ECC International embarked upon a programme of development of filtration equipment using high pressure to achieve significantly lower moisture levels. This development work investigated several design philosophies and culminated in the production of two quite different solutions. The High Pressure Plate Press uses round plates / chambers of one metre diameter and a filtration pressure of 70 bar. This press is fully automatic and produces a surface dry cake that has sufficient plasticity for the further processing that is required on specific qualities of china clay. The TUBE PRESS on the other hand uses a unique design configuration and operates at a filtration pressure of 100 or 140 bar, depending upon the model. The TUBE PRESS produces a brittle, surface dry cake that is easy to handle and a filtrate that is usually crystal clear. The TUBE PRESS achieves a much higher degree of separation than is possible with conventional equipment, which is particularly important if the filtrate is the product. Over the past 15 years plants incorporating both HP Plate Presses and TUBE PRESSES have been installed in the china clay operations of ECC International and are giving excellent trouble free service. The TUBE PRESS has also proved to be extremely versatile, effectively dewatering a wide range of fine particled slurries, in a number of diverse industries.

Jan 1, 1989

By A. Ballester, F. Gonzalez, M. L. Blázquez

Pyrometallurgical process are usually used to recover valuable metals from metal sulphide concentrates. However, their use is diminishing as the cost of energy rises and pollution controls become strictes. An alternative method of treatment sulphides could be bacterial leaching due its simplicity and negligible contamination (1-2). This process is presently used commercially to re cover metals such as Cu and U from low grade ore concentrates. In spite of numerous researchs during recent years (3-5) there exists very little kinetic data concerning the speed of bioleaching process. The kinetic analysis of bacterial activity is related with the metabolism and growth of microox ganisms . This fundamental information permits ma- king the best utilization of bacterial oxidation and to suggest techniques which might increase the production of the products desired. However, bio- kinetic models are especially complicated due to the existence of many metabolic routes and parallel reactions which are important for the life of the bacteria. Microbiological oxidation of a mineral substrate is influenced by its own inicial concentration: This influence can be determined by means of a kinetic study. In a medium with sufficient concentration of nutrients (nitrogen, phosphorous and potassium) and an adequate supply of 0, and CO2, as the only & L source of carbon for the biochemical synthesis, the substrate concentration would remain the only limitation in the rate of leaching. In this case the Michaelis-Menten model could be applied (6). The model is based on an association of the enzyme (El with the substrate (S) with consequent decomposition of the latter into enzyme and products [ ] The rate of dissolution is defined by the equation : [ ] Were V is the rate of metal extraction (mg 1-1 1 h-1 ) ; S is the pulp density Mn is the maximum rate for metal extraction (mg 1-1 h-1) and K is the constant of Michaelis (concentration of substrate that yields Vm/2). This method is applicable only when the rate of bacterial growth is similar to the rate of metal extraction. It would therefore be sufficient to control the concentration of metal in the medium over the period of time. In the present work a systematic study of the kinetics of ZnS and CuFeS bioleaching in sphalerite and complex ore concengrates was carried out. The rate of dissolution of the Zn and Cu as function of the pulp density and temperature was determined. However, most oxidations of sulphide dissolution take place with a very slow kinetic; but, this can be accelerated considerably by the addition to the solution of suitable catalytic ions, as was Suggested many years ago by Bjorling (7). Such ions can exercise an important influence on the rate of the oxidation-reduction reactions, both homogenous and heterogenous, which take place during the leaching of sulphides; they also affect the nature of the reaction products. The action of catalytic ions has been fully developed in aqueous systems, but in the absence of bacteria (8 - 11) although the actual machanisms is not totally known. The mechanisms proposed as hypotheses in the literature (8) indicate that, in the case of ZnS, the catalyst ion act through an electrochemical mechanism according to the reactions: [ ]

Jan 1, 1989

By A. Uribe-Salas, J. A. Finch, B. J. Huls

Froth depth or interface level is an important control variable in column flotation which can influence both grade and recovery. A common method of locating the level is based on sensing the hydrostatic pressure at one or more points along the column. The level position is then calculated from these pressure readings using an equation which includes the bulk density in the froth and bubbling zones. The precision with which the level is detected depends on how well these density values represent both zones. The calculation of these bulk densities from theoretical considerations is not possible and, therefore, the practice is to estimate them by calibration. Unfortunately, the calibration parameters often do not report the level with an acceptable accuracy. A portable conductivity probe has been developed to detect the position of the interface from conductance measurements across the interface. The location of the interface corresponds to the position where a large change in conductance is observed, which is primarily a consequence of the difference in gas holdup between the bubbling and froth zones. This probe can be used to detect the position of the interface to an accuracy of± 5 cm. The probe can be used while the column is in operation, which allows the on-line calibration of the level detection system. Results obtained in its application in a pilot-scale column (0.91 min diameter) are described.

Jan 1, 1989

By Margaret Armstrong, Normand Champigny

"In order to define the ore/waste boundaries as finely as possible, mine planners often insist on kriging very small blocks (relative to the spacing of the available sample grades). These kriged estimates for very small blocks are over-smoothed. For several simple sampling patterns the relation between the block size and the variogram range, and the kriging results were studied. Meaningful estimates of individual blocks are obtained when the variogram range is large compared to the block size and the sample spacing. For a variogram range less than half the sample spacing, the kriged block estimates were found to be uncorrelated with the actual grades. The over-smoothed estimates should not be used for calculating recoverable reserves IntroductionNowadays most mining companies know that the geostatistical estimation method, kriging, gives the best estimates of individual block grades. As most mining engineers and geologists are now familiar with the basics of geostatistics, the definitions of the variogram and of kriging will not be repeated here. An appendix containing definitions and mathematical formulae is given at the end of the article for the sake of completeness.Even though it is well known that the kriged estimates for very small blocks are over-smoothed, mine planners who want to define the ore/waste limits as finely as possible (especially for selective underground mines), are often tempted to krige very small blocks. So we ask how small is ""too small""? Clearly ""smallness"" cannot be expressed in yards or metres. It depends on the nature of the orebody under study and this is reflected in the variogram model chosen to describe it.To answer this question, the changes in four key parameters are studied:• the kriging variance,• the variance of the estimated grade,• the slope of the linear regression of the true but unknown grade on its estimated value, and• the coefficient of correlation between the actual grade and the estimate;as a function of the block size and the variogram range. (Definitions of these four parameters are given in the appendix). Ideally the kriging variance should be low while the variance of the estimated grade should be equal to the dispersion variance of the blocks. The slope should be l.0, and so should the correlation coefficient.These four parameters have been calculated for several simple 2-D examples. The effect of using kriged block estimates that are too heavily smoothed are shown, and the dangers of trying to use these estimates for predicting recoverable reserves for small blocks (i.e. selective mining units) are pointed out."

Jan 1, 1989

By N. N. Moelbs

The U.S. Bureau of Mines is conducting research on many topics relating to the hazards of coal mining, increased production, and protection of the environment. One area of research that has received scant attention in recent years is that of water inflows, probably because few fatalities in the United States have been attributed to them. As mining goes deeper, the problem of water in 1ow could increase dramatically because of adjacent or overlying mines in which huge water pools are impounded. Inaccurate mine maps and ineffective barriers can constitute a serious problem for operators both from gradual inflows and sudden inrushes of water. This report describes a wide but ineffective barrier that permitted an average 240-gpm inflow to a developing mine from an adjacent mine. The anomalous geologic structure that facilitated this leakage is described, demonstrating that size, alone, is no assurance against serious leakage. Some recommendations for managing serious water inflow are included.

Jan 1, 1989

By P. G. Claridge, G. P. Holmes, M. A. Redfearn

"IntroductionThe purpose of this chapter is to describe current practices in operation and maintenance of flotation circuits in Canadian mineral processing plants. The chapter consists of five sections covering description of equipment, typical flow diagrams, operating practice, instrumentation and maintenance. The approach to this subject matter is intended to be practical in nature, hence no deeply technical treatment of flotation theory will be included.Flotation is an extremely common method of beneficiation of ores. Reasons are the relatively low cost of flotation compared to many other processes, the wide range of minerals to which flotation may be applied and the high efficiency of separation which can usually be achieved. The flotation process as we know it today has been developed within this century and it has had a major impact on the mining industry. While flotation is commonly considered to be important because it provides a relatively simple method of separating minerals in complex ores, the availability of flotation has also made a multitude of mineral deposits in Canada into economically viable mining operations because it allowed production of a concentrate of valuable minerals from the ore. These concentrates could then be transported from geographically remote locations to centraHzed plants for further processing, although the existence of the remote and perhaps small ore body alone would not have justified installation of metallurgical processing plants on site and the grade of ore would not have justified direct shipment of ore.Some of the more common minerals concentrated by flotation are sulphides of copper, nickel, cobalt, iron, zinc, molybdenum, lead and arsenic, as well as non-sulphides such as sodium chloride, potassium chloride, phosphates, silicates, chromite, fluorite, limestone and coal. Precious metals are also recovered by flotation, generally in association with another sulphide mineral."

Jan 1, 1989

By K. Meyer

"INTRODUCTIONThe David Bell Mine Concentrator started production in April 1985. A staff of twenty-seven people operate and maintain the concentrator. The crew is grouped into the following main areas.16 Operators6 Assaying/Metallurgy/Refining/Clerical4 Maintenance people2 SupervisionOperating highlights of the following unit processes will be discussed in detail:Screening and ThickeningPre-aeration and CyanidationCarbon-In-Pulp Gold AdsorptionCarbon Handling andGold RecoveryFor a complete description of the concentrator, refer to the papers by: (1) C.V. Sibbald, Teck-Corona's Hemlo Mill, October 1984, (2) R.A. Ford, The David Bell Mine at Hemlo, From Exploration to Production, November 1987. For operating details of the grinding circuit and effluent treatment plant refer to papers by: (3) T.G. Smith, SAG Mill Experience at The David Bell Mine, October 1988, ( 4) AN. Veltmeyer, The Effluent Treatment Plant of The David Bell Mine, January 1989.TRASH AND CARBON SCREENSTrash ScreenThe vibrating trash screen is inclined at 5 degrees and is clad with a 28 mesh stainless steel cloth which is changed monthly during the SAG mill liner replacement/inspection shut down. Other screen openings and configurations have been tried and the screen has been by-passed to change the cloth ""on the fly"". These attempts resulted in fibres (usually wood) to report to #1 Carbon-In-Pulp (CIP) tank, where the fibres are trapped in the CIP launder screens, and downstream carbon handling screens causing serious blinding problems. The trash screen in a Carbon-In-Pulp (CIP) or Carbon-In-Leach (CIL) gold mill removes fibres before they:are reground in the ball millsaturate with gold bearing leach solutionplug launder screens in CIP or CIL tanksplug carbon circuit pipe screenstherefore the trash screen is best placed ahead of the thickener."

Jan 1, 1989

By Jaril B. Lavrencic

The unique and irregulator distribution of working places in a mine always poses the two questions: - which and how much production equipment is to be used, - what production can be expected. Since the development of analytical methods would be impractical for such cases, a lot of computer programs has emerged in recent years trying to simulate the productiom process and thus find the best answer. The usege of a simulator has its dark side well felt by the author(s) of such a program: the credibility and the confidence of the customer. Using the simulator means to respect and to incorporate all the restrictions imposed by the narow underground space, methods of production, safety regulations etc., which can turn out to become a major programming effort. If the program is not properly structured, it will be used for a single special' case only, and never again. In this paper the structure and internal mechanism of the simulator is described for which the author believes that can easily be adapted to conditions of various underground and open pit mines. MINSIM tries to reach the following rather ambitious goals: 1) Estimation of the production before opening the mine, or a part of the mine. 2) Training the personnel to make decisions. 3) Making the daily time schedules for the entire fleet of the equipment units.

Jan 1, 1989

By S. A. N. Sheya

The U.S. Bureau of Mines performed batch equilibrium contact experiments to examine the ability of activated coconut-shell carbon to adsorb various metal cyanide complexes. Tests were also conducted to determine the effect these cyanide complex impurities might have on the adsorption of gold by the activated carbon. Metal cyanide species included in the investigation were antimony, arsenic, cadmium, calcium, cobalt, gold, iron, mercury, nickel, silver, thallium, and zinc. Tests were made over a pH range of 6.4 to 12.5. The carbon exhibited a preference for gold adsorption over other metals present in solution. In the absence of gold, the metal cyanide complexes were adsorbed; adsorption generally decreased with increasing pH. However, calcium and thallium adsorptions increased with increasing pH, while arsenic and iron were not adsorbed at any pH.

Jan 1, 1989

By Clark R. Neuharth

To assess the supply status of ultra-high-purity silicon for national defense needs, the U.S. Bureau of Mines conducted a general study of the availability of materials and processing technology for silicon used in the manufacture of infrared (IR) detectors from raw materials to the highly advanced device state. The United States possesses all of the raw materials and processing technology for IR detector-grade silicon production, but does not produce at all of the processing stages on a regular basis. Consequently, the United States continues to rely on foreign sources for some of these critical materials.

Jan 1, 1989

By E. D. Attanasi, M. W. Bultman, J. H. DeYoung

The 1987 recovery in the US mining industry permitted modest increases in exploration expenditures that year (Fig. 1). Favorable market conditions apparently allowed the gains to be sus¬tained in 1988. There was great uncer¬tainty early in the year as to whether world and US economic growth would be a casualty of the October 1987 worldwide stock market crash. By nearly all measures, the performance of the US minerals industry was strong¬. A weak US dollar and the strong growth of worldwide capital spending resulted in in¬creased US exports of con¬sumer and producer durable items as well as strong domes¬tic demand for metals. In fact, 1988 US steel industry exports reached levels not attained since the mid-1970s. It was re¬ported that steel industry labor productivity is now roughly twice the 1981 level. Among metals with signifi¬cant average nominal price increases in 1988 over 1987 levels were copper (43%), alu¬minum (52%0), and zinc (44%). Even though domestic copper production has grown since 1984 by 30% in mining and 24% in refining, em¬ployment in mining and milling is 4% below the 1984 level. Domestic unit costs are reported in the range of $1.10 to $1.33/kg (50 to 60 cents per lb). The US base metals industry is proba¬bly in its best cash position in many years. However, there has not been a large increase in exploration expendi¬tures. This is due mostly to the percep¬tion that worldwide capacity can easily be increased. Industry reports do show that "low cost" copper producers have been buying reserves from weaker com¬panies. The 1987 Society of Economic Ge¬ologists (SEG) survey of exploration activity indicated that 95 cents out of every exploration dollar spent by US and Canadian firms was for base and precious metals (Economic Geology, January 1989). Press reports, though, make it clear that most of that spending was targeted for precious metals. US claim staking data (Fig. 2) rein¬forces this suspicion. The apparent lag in new claim filings in Alaska and phe¬nomenal growth in filings in the lower 48 states suggests that exploration is directed at relatively low risk targets. In the conterminous 48, more than 40% of the new claims were made in Nevada, indicating an emphasis on gold (although even Nevada had some base metals exploration). Even with a price decline during 1988, the difference between the gold price and average global "cash" production cost of $7.30/g ($227 per oz) still leaves room for an attractive return (Northern Miner, 1988). Exploration plans and results Metals Economics Group (Halifax) indicated in its 1988 exploration survey that exploration expenditures by US and South African firms would be at about 1987 levels. It also reported that Canadian and Australian firms were ex¬pected to reduce their exploration spend¬ing significantly. Firms in both coun¬tries were caught in changes in tax laws. In Canada, the Mining Ex¬ploration Depletion Allow¬ance (MEDA) once permitted generous tax write-offs to in¬dividuals investing in miner¬als exploration. It was to be replaced in January 1989 with the Canadian Exploration In¬centives Program (CEIP). Although structured and ad¬ministered differently than MEDA, CEIP can provide an equivalent or possibly greater financial incentive for min¬eral exploration, for junior mining companies. In 1987, it is estimated that junior com¬panies accounted for two¬-thirds of the off-property (or grass roots) exploration ex¬penditures in Canada. Australia will revoke the tax exemption for gold in 1990. Australian operators, therfore, were expected to concentrate efforts on speeding up pro¬duction during 1988 and 1989. In 1988, Chile and Mali announced special efforts to attract gold explora¬tion by foreign companies. The Cana¬dian government continues to express concern about the write-off (and drawdown) of base metal reserves. Falconbridge did announce a new initiative to identify additional base metal reserves in the Sudbury district. Discoveries Gold deposits dominated discoveries

Jan 1, 1989

By T. OnIin, F. F. ApIan

"A study has been made of the surface properties of coals of differing ranks, in their natural state and as modified by the addition of collectors. The evaluation of their surface properties has been done by captive bubble contact angles, water and methylene iodide sessile drop contact angles, zeta potential, point-of-zero charge (PZC) shift, and flotation. .changes in the hydrophobicity of coal is a function of both the rank of the coal and the collecting reagent.INTRODUCTIONThe chemical and physical properties of a raw coal will determine its response to a given beneficiation process. .For such processes as flotation, filtration, flocculation, dispersion, handling, dust supression and agglomeration, however, it is also necessary to consider the surface properties of the coal and mineral matter constitutents of the raw coal. In the case of a specific particle to be floated, it is also necessary to consider the properties of the coal as modified by the addition of some reagent designed to modify (usually increase) the hydrophobicity of the coal surface. General properties of the coal have been well summarized by Van Krevelen (1) and Elliott (2), while the data for the surface properties of coal are much more scattered in the literature (see, e.g.: Parekh and Aplan (3), Gutierrez-Rodrigues et al. (4), Aplan (5), Arnold and Aplan (6), Hogg and Chander (7) and Rosenbaum and Fuerstenau (8)). While a knowledge of the inherent surface properties of a sample are important, of much greater practical significance are the properties of the particle in the presence of a reagent, such as a collector, designed to enhance the hydrophobicity of the particle. This study will focus on the surface properties of coals of various ranks in the presence of a variety of collectors."

Jan 1, 1989

By Diego L. Romero, Joy P. Romero

"IntroductionMinerals may be classed broadly as ferromagnetic (magnetite for example), as paramagnetic (attracts to regions of magnetic field convergence) and as diamagnetic (attracts to regions of magnetic field divergence). High-intensity separators are not necessary to separate ferromagnetic minerals from other classes. Rather, low-intensity units that generate fields below 5000 gauss are adequate for this purpose. However, paramagnetic minerals, such as ilmenite, with high magnetic ""attractability"" require fields of up to 10 000 gauss; those with low attractability may require even higher fields. Table 1 shows approximate ranges of field intensities necessary to separate ferromagnetic and paramagnetic minerals from minerals of lower attractability, along with the force with which they are attracted relative to iron in a standardized magnetic field.Uniform magnetic fields, not useful for separators, are generated between flat parallel surfaces; non-uniform fields, useful for separators, arise when at least one of the surfaces is of irregular shape. The diagrams below show how magnetic lines of force align relative to north and south poles.If a particle is placed in a uniform field, it feels no displacing force unless the particle distorts the applied field assymmetrically. This is not the case in non-uniform fields which are required for magnetic separators.Magnetic fields can be generated by permanent magnets (low intensity), by electromagnets (medium and high intensity) and even by superconducting coils (100 000 gauss fields and higher), although the latter are not as yet useful in production environments .The magnetic force of attraction per unit of mass, that acts on a paramagnetic mineral such as hematite, increases in proportion to the strength of the field . Unfortunately, the highest fields attainable with electromagnets is of the order of 20 000 gauss. Fortunately, the gradient of the fie ld (that is, the degree of convergence of magnetic lines of force) is important, because the attractive force per unit mass is proportional to it also . This can be stated:"

Jan 1, 1989

By P. Bhakta

The U.S. Bureau of Mines developed an alkaline oxidative pretreatment leaching procedure to increase the recovery of gold from arsenopyrite (FeAsS) ores. The best solution compositions for arsenopyrite dissolution were determined using cyclic voltammetry and chronocoulometry. Initial arsenopyrite dissolution occurred at -0.20 V versus standard hydrogen electrode (SHE) in a sodium hydroxide (Na0H) solution. Leaching of a high-grade arsenopyritic ore containing, in percent, 28.2 As, 25.3 Fe, 19.9 total S, and 1.0 Sb and, in troy ounces per short ton, 1.6 Au and 5.5 Ag resulted in >90 pct As extraction at 1000 C, 40 psig O2,4 h, and 2M NaOH solution in a 2-L autoclave. Cyanidation of the leach residues resulted in 90 to 93 pct Au and 60 to 80 pct Ag extractions, compared with only 5 and 15 pct, respectively, without the pretreatment. The procedure was further tested by leaching a low-grade gold ore and a bulk sulfide flotation concentrate prepared from it. Cyanidation of the leach residues resulted in 70 pct Au and 31 pct Ag extraction. The NaOH leachate was partially regenerated by precipitating the arsenate as calcium arsenate [Ca3As04)2] and the sulfate as barium sulfate (BaS04).

Jan 1, 1989