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By R. E. Fanning

"IntroductionThe Aluminum industry is one of many materials industries which strive to make their material the preferred choice for large volume products. In some applications one material has a natural advantage over others, but more frequently several materials compete with one another, each providing one or more advantages and some trade-offs. Customers may design their product with several objectives such as minimum system cost, maximum customer appeal or maximum manufacturing flexibility, choosing materials which best combine cost and performance. In such markets it may become necessary for a material supplier to enhance the attractive features of the particular material to outweigh its disadvantages.It is difficult, if not impossible, to predict how various materials will evolve. Technological breakthrough, government regulations, material availability or sociological issues may redefine the balance between competing materials. In spite of some uncertainty regarding the competitive position of competing materials, there is little doubt that unrelenting pursuit of product quality improvement and cost reduction are essential to future viability of the aluminum industry. It is the intent of this paper to identify some areas where technological improvement would be beneficial. Thus this paper is a collection of briefly described problems that will hopefully stimulate the thoughts and research required for knowledge based solutions. Rolling ProcessA particular example is the beverage can industry where aluminum, steel, glass and plastics vie for a share of the m.arket. The high cost of aluminum relative to steel or glass requires minimizing the amount of metal per can. The high intrinsic value of aluminum has led to extensive recycling of cans although net metal cost is still higher than that of the competing materials. Intensive engineering of the beverage can led to improved design and better understanding of material requirements. These improvements permitted substantial reduction in sheet thickness over the past decade. The downward trend in metal thickness for beverage can sheet is shown in Figure 1."

Jan 1, 1988

By William E. Souder

The behavioral accident simulator (BAS) is a computer program that can be used to simulate accident situations. It demonstrates how the potential to have an accident grows or diminishes as a result of changes in various environmental, organizational, and behavioral factors. It calculates the number of fatalities that may result from various conditions and graphically displays these data. The BAS is useful for studying systems of accident causes, for demonstrating the various ways to diminish fatalities, and for training employees. This Bureau of Mines report provides the detailed instructions needed to use the BAS.

Jan 1, 1988

By Omar A. Muhtadi

6.1 INTRODUCTION The three most critical factors in successful heap leaching operations are: • The methods employed to pretreat ore (i.e, crushing and agglomeration); • Placement of ore on the leach pad (heap building techniques); and • Wetting of the ore with cyanide (solution application techniques). Improper execution of any of these initial steps may result in a substantial sacrifice of total metal extraction or, in the worst case, in project failure. Ore preparation in terms of crushing and agglomeration was discussed in Chapter 5; this chapter therefore focuses on commonly employed techniques for heap construction and solution application. The main objective of heap construction is to obtain the most homogeneous heap possible. "Channeling" of leachate in heaps with preferential seepage paths leads to preferential leachate distribution and uneven/incomplete extraction. The two main contributing causes of channeling are inadequate attention to heap construction and uneven solution application. These pitfall s can best be avoided through a knowledge of the various techniques available and the applicability and success of these techniques with various ore types and site conditions. The remainder of this chapter provides a discussion on these two subjects. 6.2 HEAP BUILDING TECHNIQUES Successful heap building techniques vary with the type of ore and, since no two orebodies are exactly alike, some slight modifications are usually necessary for each specific project. However, it is possible to generalize in terms of the appropriate techniques to be used with ores having similar characteristics. This section discusses the three most commonly used methods of heap construction and provides some guidelines with regard to ore types, construction constraints, and lift height parameters for each of the three. 6.2.1 Run-of-Mine Dumping and Dozing The run-of-mine method of heap building can only be used with ore of a highly silicious nature (i.e., ore which will not generate a large amount of

Jan 1, 1988

By RV. Ramanl, KV. K. Prasad, M. Swaminathan

The objective of the research in this project is to develop a knowledge based expert system for aiding the planning of mine ventilation systems. This system focuses on mine ventilation system design from a coal mine dust control standpoint. It is recognized that mine ventilation system design is an engineering problem involving not only rote numerical calculations to solve the pressure quantity problem but also substantial judgement and expertise to analyze a problem situation and Interpret the results of an algorithmic program. The thrust of this project is to i) extract this knowledge from public domain sources and recognized experts in industry, government and academia, 11) represent this knowledge in the form of IF ... TI-IEN rules in an expert system (ES) and 111) interface the developed expert system with a mine ventilation network analysis program vis. PSUMVS (Pensylvania State University Mine Ventilation Simulator). By providing the numerical computing and qualitative reasoning aspects of mine ventilation system design in a single Integrated system, better quality decision support will be made available to apprentice users.

Jan 1, 1988

By Gopalakrishna M. Rao

"Several industrial and government laboratories are of the opinion that solar--cell technology will grow into a billion-dollar industry by the year 2000, especially if oil prices rise again. Of the variety of materials that have been investigated as the major component of photovoltaic systems, silicon appears to have an outstanding advantage. The cost factor is the primary importance in photovoltaic development, since the technology to make silicon cells of acceptable efficiency and life time has existed since the early stage of the space program. Electrometallurgy is one of the low--cost processes for the production of silicon, since it allows direct, single-stage production from some abundant, inexpensive source materials such as silica and fluorosilicates. Among several systems, two are given particular attention, using inorganic baths with Si0 2 or K2SiF6 as the source of silicon respectively. They appear capable of development to commercial production. Conceptual designs of a commercial--scale cell for silicon production at temperatures above its melting point, and of a pilot' plant for plating silicon from an all-fluoride bath are presented. Energy ProspectsThe major changes in the world energy since the first energy crisis in 1970 have impacted on our community. When oil was $40 a barrel in the mid-1970s, we became obsessed with the energy conservation and a search for alternate energies. Even though the crude oil fell below $15 a barrel during the last several years, our energy security fears continue to haunt us. This time it is not the scarcity, but the abundance of foreign oil and the decline in the domestic production.The prospects of energy depends on the demand and supply of energy. These, in turn, depend on future energy prices, which are linked to economic factors, political events, and unforeseen circumstances. Although no one can predict the future with certainty, three energy consumption patterns used by the Ford Foundation are as shown in Fig. 1."

Jan 1, 1988

By R. H. Church

As part of the research effort of investigating the effects of microwave energy upon the chemical and physical properties of different minerals and ores, the Bureau of Mines has conducted basic research into identifying those properties of minerals that are affected by microwave energy, namely, the dielectric constant and loss tangent. These properties were determined utilizing the theory of microwave propagation in a coaxial waveguide filled with a dielectric material and measuring the input impedance with an RF impedance analyzer that operates from 1 MHz to 1 GHz. By knowing the microwave frequency and filling the waveguide with a powdered mineral, the dielectric properties of the mineral sample were determined. From these dielectric properties, theoretical microwave heating characteristics of each mineral could be calculated. These same mineral samples were then irradiated by a 915 MHz 30 kW variable power microwave oven and dielectric heating studies were performed. A comparison of the theoretical heating characteristics and the results from actual dielectric heating studies was conducted to evaluate the dielectric property measurements on each mineral. This report presents the results of the Bureau's research in identifying the dielectric properties of low-loss minerals according to the mineralogical classification scheme along with their irradiation studies. Though far from complete, this study represents some of the more frequently encountered low-loss minerals.

Jan 1, 1988

By G. J. Grott

Direct Production Costs for Solar Sa 1t approximate the trucking cost for 160 Km. Operations near markets appear unusually attractive at first look. However, many desert operations have been plagued by dust storms yielding salt too high in insolubles for most uses. This paper relates the history of a successful operation in a dust storm area. Saturated brine from the solution mining of LPG storage caverns is evaporated in solar ponds yielding 99.95% sodium chloride (dry basis). Purchased energy is one-eighth that of vacuum pan operations. Production scale tests have proved it works at another desert location using a more complex brine. A new approach for refining soluble salts at ambient temperatures is demonstrated by bench scale and pilot work. Again, savings in purchased energy exceed 80%, even when temperatures are raised to reduce refining time.

Jan 1, 1988

A Feasibility Study to determine the future of ZC Mines was completed in mid 1987. Early in this study, which lasted two years, it was identified that significant reductions in treatment costs would result if the Zinc Corporation Concentrator was closed. All of the production from the existing two mines, The Zinc Corporation Limited (ZC) and New Broken Hill Consolidated Limited (NBHC), would then be treated in the concentrator at NBHC.After a partial upgrade of the NBHC concentrator, the ZC concentrator was finally closed and all of the equipment disposed of. This closure highlighted the need to concentrate all ore haulage in one shaft to further reduce operating costs and remove the cost of surface transport of ZC production to the improved NBHC concentrator. This paper outlines the changes that were made to improve the haulage system for ZC Mines. After a number of options were investigated, it was finally decided that the upgrade of the existing NBHC haulage shaft was the best option even though some production would be lost while the upgrade was in progress.

Jan 1, 1988

The results from three quick methods for the determination of W03 in scheelite ore samples, mill products and concentrates were compared with gravimetric results and tested with standard samples to establish which was the most reliable. Summaries of the methods, two X-Ray fluorescence and one colorimetric, are given. The best method was X-Ray fluorescence, with samples cast as glass discs.

Jan 1, 1988

By William J. Pardee, Michael A. Shaff

"Deeper materials science knowledge from mathematical models and in situ material property sensors will be exploited in next generation factory process controllers to improve productivity and quality. These intelligent control systems will accelerate productivity growth and materials science application through the ease with which they can be modified to accept new materials knowledge and sensors. Carbonization of resin matrix carbon fiber composites, specifically, is a violent solid state chemical reaction with large stresses due to gas pressure, matrix shrinkage, and differences in thermal expansion. The matrix strength falls sharply, then rises again during the process. At least two competing reaction paths are important; the first cleaves methylene bonds, reduces toughness, density and stiffness; the second reforms those bonds, ultimately resulting in aromatic ring condensation that increases density, strength, and modulus. Since these reactions have different temperature dependencies, one can expect to shift the process towards the second path by changing the heating rate, but that change must be accomplished without producing macroscopic interlaminar crack growth. To accomplish this, we employ gas sensors to infer matrix chemical state and acoustic emission to identify microstructural changes and to recognize brittle fracture. The latter does not prevent delamination, but is important in testing models for the causes of delamination and in improving the processing cycle. This paper describes a control strategy to accelerate the process while still lowering the risk of failure.IntroductionDeeper materials science knowledge from mathematical models and in situ material property sensors will be exploited in next generation factory process controllers to improve productivity and quality. These intelligent control systems will be more easily modified to accept new materials knowledge and sensors, thus accelerating productivity growth. Such a control strategy for carbonization control is described below.Carbon-carbon composites are time consuming and costly to manufacture. Processing methods have been developed empirically and are usually very conservative because the process often fails when any change is made. Apparently minor changes in materials or geometry can produce failures that are difficult to diagnose and correct. We will describe below several essentially unavoidable sources of variability. These are best dealt with by applying materials science to adapt (i.e., closed loop control on materials properties) the process in real time to reduce the effect of unavoidable model idealizations, material variability and environmental noise. The most critical issue in control of the carbonization process control is avoiding catastrophic delamination. The strategy developed below makes use of a priori materials knowledge and real time sensors to accelerate the now very slow process without destroying the material, and without requiring unreasonable resources to determine the statistical properties of the material."

Jan 1, 1988

By E. S. Geskin

"This paper is concerned with the construction of a formal technique for the selection of a metallurgical technology. Exergy consumption is used as the criterion of process efficiency. Different items of the exergy balance are considered and techniques for the reduction of exergy consumption are determined. The selected techniques of exergy saving enable us to identify processes which should be used at different stages of steelmaking. The combination of the selected processes enables us to suggest a technology for conversion of iron ore into steel products. The selection of this technology narrows the range of further search of metallurgical processes. The paper shows that qualitative thermodynamic analysis can be used as the first step in the design of metallurgical processes. IntroductionThe existing processes for making, shaping and treating of steel enable us to convert the available iron bearing ores into marketable steel products. However, the energy cost of metal production is much higher than thermodynamically required, while the metal properties are much lower than thermodynamically available. Increasing cost and declining availability of energy and raw meterials make the creation of new steelmaking technologies imperative. In recent years, the number of novel processes for the making, refining, and shaping of steel have been suggested and tested. Some found a practical application. However, the tested technologies make up a small portion of the physically available routes for the conversion of iron ore into a marketable product. It is also not evident that the optimal routes have been tested and that the selected technologies are the best among those tested.Although the development of new metallurgical technologies must be based on the experimental and practical information, the number of the alternative routes for the making, shaping and treating of steel, as well as the cost of examining each single route, make necessary the use of analytical techniques for the evaluation of the possible ways of process development."

Jan 1, 1988

By Ian F. Hughes

"Concepts of an integrated steel plant for sheet products to be built and operating in the year 2000 will be described. The design and operating methodology of this market driven facility will integrate process uniqueness, standardization, manufacturing automation, artificial intelligence and information flow.An integrated steel plant for the year 2000 is defined for this article as one that will be built on a greenfield site and ""started up"" in the year 2000 with a capacity of three million tons per year of flat rolled products ranging from cold rolled and electrical steels to high strength formable steels and a full range of coated products.It may seem that the 21st century and the steel plant we're discussing are far into the future. The startling truth, however, is quite the opposite. As shown in Figure 1, even with accelerated development, a new process on which laboratory development work is begun today might just barely pass through the laboratory phase, pilot plant, and commercial feasibility stages such that it can be considered viable for construction and start up in the year 2000.On that basis, it is very unlikely that this 21st century steel plant will utilize any technology that isn't at least under investigation in the laboratory in 1988. As a result, we recognize that planning and selecting the facilities for this plant is, in fact, a pragmatic rather than futuristic process, and that its main value is in providing a bridge to longer-term predictions."

Jan 1, 1988

In this paper, the plastic increment theory was applied in a 2-D finite element model, and a generalized Von Mises yielding criterion adopted to simulate the progressive failure of coal pillars. Extensive underground monitoring was conducted and the data compared with the computer model, yielding promising results. Three different longwall entry layouts, including a stable (s-s) pillar system, a yield-stable-yield (y-s-y) pillar system and a yield (y-y) pillar system, were investigated using the model developed. The yield-stable-yield system was considered to be the best of the designs studied in the case. A comprehensive parametric analysis was also performed. The triaxial factor and Poisson's ratio were found to be the most important material parameters affecting pillar yielding.

Jan 1, 1988

By A. G. Pronk, D. M. Burton

"A regional till sampling program in the Upsalquitch Forks-Tetagouche Lakes area, centred some 70km west of the city of Bathurst, has proven an effective method for gold exploration in the heavily glaciated interior of northern New Brunswick. Prospecting activities within this area over the past three years, have led to the discovery of several gold occurences associated with quartz-carbonate alteration in a variety of intrusive rock types emplaced along major fault zonesQuaternary mapping shows that the glacial history is complex. However, the displacement of material is uniform in distance and direction, and the till is generally thin (0.5 m to 2.0 m) and locally derived, making the interpretation of till geochemical patterns relatively simple for the explorationist. Previous studies have shown the the fin e-grained gold is best detected in the -250 mesh (-0.063 mm) till fraction (clay plus silt) and that the C-horizon is the preferred medium for analyses.Samples were collected on a 2 km grid and analyzed f or Cu, Pb, Zn, Au, Ag, As, Sb, Mn, Fe, Ni, Co, and Cd. Results indicate that concentrations of 10 to 20 ppb Au can effectively delineate areas of anomalous gold in bedrock associated with fault structures, and that a good potential for discoveries exists to the west of the known occurrences, where up to 678 ppb A u has been detected in tills. IntroductionThis paper reports on the result s of surficial geological investigations conducted over the past two field seasons in north-central New Brunswick. The stud y area is located in the Upsalquitch Forks-Tetagouche Lakes map area s (N.T.S. 21 0 19 and 21 0 (10) 70 km west of the city of Bathurst (Fig. I). The area is situated on the margin of the New Brunswick Highlands and has a maximum elevation of 640 m (for a detailed description of the physiography, see Rampton et al. 1984).Historically, exploration in northern New Brunswick has concentrated on base metals within the Cambro-Ordovician Tetagouche Group, resulting in the discovery of man y significant massive sulphide deposits (Brunswick No.6 and No. 12, Heath Steele, Caribou, Armstrong Brook, Orvan Brook, McMaster, Murray Brook, and Restigouche). Auriferous base metal occurrences along the Rocky Brook-Millstream Fault have also been previously investigated."

Jan 1, 1988

By R. Hogg, T. F. Dumm

"Abstract - With increasing interest in the physical cleaning of fine coal, there is a need for extension of the sink float analysis procedure to finer sizes. Problems arise, however, in ensuring complete dispersion of the particles in the heavy liquids. A procedure has been developed in which surfactants are used as dispersing agents, and solids concentration is minimized (using a simple formula to estimate the minimum weight needed for statistical reliability). Using centrifuges to increase separation rates and subsieve particle size analysis of the specific gravity fractions, a complete size specific gravity distribution can be obtained. Analyses have been performed on coal samples as fine as -10 µm.IntroductionTraditional gravity separation techniques such as jigging, heavy media and water-only cyclones, shaking tables, etc., have been used to remove impurities from coal ranging in size from about 15.cm (6 ln.) to about 150 µm (100 mesh). The coal washabilty or float-and sink technique ls a well-established procedure for determining the optimum extent to which a coal can be cleaned by such physical separation methods. Because of the desire to recover even finer coal fractions by gravity separation techniques, there is a need to extend the coal washabillty analysis into the ultrafine range. The purpose of this paper ls to describe some of the significant factors that influence fine particle specific gravity separation. Washability analyses have been performed on three ultrafine ( <10 µm) coal samples representing three general mining districts in Pennsylvania. Results of these analyses indicate that the washabillty technique can be successfully applied to ultrafine particles when proper care ls taken."

Jan 1, 1988

By K. Hajmrle

The production of nickel coated mica composite powder by hydrogen reduction of a nickel ammine sulphate solution, followed by the production of molded plastic samples containing Ni/Mica is described. Sample preparation by injection or compression molding is outlined and the better results in compression molding are explained by the combination of better particle-to-particle contact, less particle breakage during processing, and more random particle distribution in the plastic. Three volume resistivity measurement techniques are described and compared. Two of them (conductive paint and silver-rubber electrodes) are found reliable and are used throughout the work. The influence of nickel content and particle size of Ni/Mica on volume resistivity is evaluated and the optimum product defined. One of the most important assets of Ni/Mica, its ease of injection molding, is demonstrated by the good electrical properties obtained with little optimization of the injection molding process. Surface roughness of molded plastics with and without Ni/Mica is briefly discussed. Shielding effectiveness of Ni/Mica in four plastics (PP, ABS, PBT and PC) is presented and correlated to volume resistivity data for the same materials. The addition of 15 to 50 weight % Ni/Mica (3 to 16 volume %) to plastics and subsequent injection or compression molding produces composite materials having low volume resistivities (0.03 to 1 ohm.cm) and high shielding effectiveness (40 to 70 dB).

Jan 1, 1988

By Cameron A

In recent years there have been significant developments in the tech- nology available for blast monitoring, analysis and simulation. Progress in these areas has been achieved through research conducted by explo- sives manufacturers and independent research groups from universities and mining companies. Miners are increasingly keen to exploit this tech- nology to help them design blasts which make optimum use of explo- sives to produce easily excavated muckpiles for the minimum possible cost. The art of blast design in the future will increasingly depend on an adequate understanding of the nature of the rock mass, the perfor- mance of explosives and the characteristics required of the muckpile to suit the chosen excavation machinery. Despite recent advances in blast simulation and the prediction of blasting performance, the best way to determine how a particular explosive will function relative to other explosives is to conduct properly designed and monitored field trials. This paper discusses recent work at Mount Thorley Colliery which demonstrates that field blasting trials can be monitored and analysed to provide quantitative data on the relative performance of bulk explosives. Techniques used in the trials included the sampling and analysis of explo- sives, insitu measurement of VOD, monitoring of near and far field vibra- tions, high speed and still photography and survey measurement of muckpiles. These techniques provided data for the analysis of throw, swell, fragmentation and burden movement together with data on the consistency and robustness of different explosive products. The blasting trials allowed both the shock and heave energy of various explosives to be observed in the field and led to the derivation of design rules for the use of differ- ent explosives at the mine.

Jan 1, 1988

By Russell J. Foster

In this Bureau of Mines report a selection process has identified 14 nonstockpiled materials (cesium, gallium, hafnium, indium, osmium, rhenium, rhodium, rubidium, ruthenium, scandium, selenium, tellurium, thallium, and zirconium) that are linked to the continuing evolution of high-technology fields such as electronics, catalysis, and energy, and that have limiting factors associated with domestic availability. A qualitative assessment of the "potential criticality" of these materials was made through a consideration of end uses, demand trends and forecasts, production, mineral reserves, byproduct status, alternative supply sources, substitution and conservation options, and recyclability.

Jan 1, 1988

By L. Crocker

The Bureau of Mines investigated processes for recovering a marketable lithium product from the montmorillonite-type clays of the McDermitt caldera. The clay deposit, located on the Nevada-Oregon border, is estimated to contain over 3 million short tons of lithium. Limestone-gypsum roasting and selective chlorination proved most successful for extracting lithium from the clays; 80-pct Li recovery was achieved using either technique. With both processes, lithium silicate in the clay was converted to a water-soluble compound-either lithium sulfate or lithium chloride. The lithium was then recovered as a carbonate by water leaching the calcine, concentrating the leach solution by evaporation, and precipitating the lithium with soda ash. The operating costs for the limestone-gypsum roast process were estimated at $2.02/lb Li2C03; selective chlorination operating costs were estimated at $3.85/1b Li2C03. The current selling price of Li2C03 is about $1.50/lb. A detailed flowsheet, material balance, and process evaluation are presented for the limestone-gypsum roast process. In addition, lithium reserves and resources are discussed and the McDermitt clays are described.

Jan 1, 1988

By M. Sider, D. L. Piron

"The cost of energy is a growing factor in the cost of zinc production. Electrowinning from sulphate solutions with periodical reverse current or from acidic chloride or alkaline solutions could be the way to lower costs. A comparison of the energy consumption for electrolysis shows that the alkaline solution may be considered the most promising alternative. IntroductionZinc electrowinning from sulphate solutions is a very energy intensive process (typical specific energy usage : around 3.1 kWh / kg zinc). This energy consumption represents 35% of the total cost of electrolysis and is the most important cost component.In order to lower costs, the energy efficiency of the sulphate process should be improved or alternative processes should be developed. In this laboratory, that objective has resulted in research on electro winning in sulphate solutions with the use of periodical reverse current (PRC) and in acidic chloride and alkaline solutions.Some of the results obtained in this laboratory and already published and new experimental results reported in this paper make it possible to present a more critical comparison of the energy consumption of the three processes mentioned.ExperimentalThe experiments at constant current were carried out as described previously. Specific conditions are indicated in Table I. Current efficiencies were obtained by weighing deposits.ResultsThe best energy consumptions for electrolysis obtained in this laboratory for the three media are presented in Table I. More detailed results can be found in the papers already mentioned."

Jan 1, 1988