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By M. Yamine, R. J. Ring, D. J. Waters

"An experimental program has been carried out by the Australian Atomic Energy Commission to compare the effectiveness of Caro's acid as an alternative oxidant to pyrolusite in the leaching of uranium ores from the Alligator Rivers region of northern Australia. Batch leaching tests on Ranger, Nabarlek, Koongarra and Jabiluka ores showed that uranium extraction was unaffected by choice of oxidant, but that Caro's acid reduced acid requirements by 15 - 25%. Lime requirements for neutralization of tailings liquors were reduced by 20 - 30%.The batch studies were extended to a four-stage continuous leaching circuit with a capacity of 400 gore h-I. Comparative leaching tests confirmed the reagent savings obtained in the batch tests. Following these encouraging laboratory results, lnterox Chemicals Pty Ltd carried out plant trials using Caro's acid. Reagent savings in the mill were similar to, or better than, those obtained in laboratory test work. The trials also established that Caro's acid has a number of operational advantages over pyrolusite.IntroductionUranium is most commonly extracted from its ores by leaching in sulphuric acid. Simple hexavalent uranium oxides and compounds are readily soluble but uranium in the tetravalent form is insoluble and must be oxidized for dissolution to occur. The most commonly used oxidants have been sodium chlorate and manganese dioxide. They act indirectly by maintaining iron as the ferric ion which oxidizes uranium by a surface electro- chemical reaction. An Fe3+ concentration of about 1 - 2 g L-I is usually considered adequate for the effective dissolution of uraninite(1)."

Jan 1, 1984

By Lloyd W. Trevoy

Syncrude Canada Limited is presently studying commercial production of heavy minerals from plant tailings of the openpit A lhabasca tar sands operation. When tar sands are processed and upgraded to synthetic crude oil, heavy minerals can be removed f rom the extraction circuit and beneficiated to provide concentrates of zircon and titanium minerals. Calculated recovery rates indicate that crude oil production capabilities of 105,000 barrels per day would provide 26,000 tonnes of zircon and 114,000 tonnes of titanium minerals annually. The titanium minerals concentrate is a mixture of ilmenite, leucoxene and rutile; it could be used as recovered or upgraded to synthetic rutile. With the consrruction of further synthetic crude oil plants in Western Canada, a large reserve of heavy minerals will become available.

Jan 1, 1984

By PETER O. SANDVIK

The Cargill deposit, located 32 km south west of Kapuskasing, Ontario, was discovered by International Minerals and Chemical Corporation in 1975 and has been evaluated through an extensive program of drilling, chemical analyses, metallurgical tests and engineering and economic studies. The Cargill alkalic complex, comprising mainly carbonatite and pyroxenite-amphibolite rocks, was intruded into the rift system of the Kapuskasing magnetic-gravity high. Weathering and leaching under assumed temperate to cool climatic conditions plus faulting, shearing and/ or initial petrographic variations within the carbonatite developed a small, locally confined karst system. This resulted in a thick enriched leached carbonatite zone capped by troughs and sinks, and filled with a residuum of apatite, goethite, clay and other minerals. Residuum thickness ranges from nonexistent on ridges to 170 m in troughs and sinks. Apatite values are 5 to 15% in fresh carbonatite, 20 to 40% in leached carbonatite and 20 to 98% in residuum. A tentative open-pit mine designed for preliminary feasibility studies is estimated to contain 62.5 million tonnes averaging 19.6% P20 5.

Jan 1, 1984

By Paul Guliov

Potash dominates the industrial mineral scene in Saskatchewan accounting for 44% of total provincial mineral production in 1981. More than 7 million tonnes of potash have been produced annualy in recent years; ten underground mines are presently (1983) active. Sodium sulphate and cement are also important mineral products. Construction aggregates, clay products, bentonite, salt, peat moss and sulphur complete the list of industrial mineral products.

Jan 1, 1984

By A. T. GRIFFIS, R. J. GRIFFIS

A large magnesite-talc body is locared in Delora Township, 11 km sourh-southeasr of Timmins, Onrario. The deposit occurs in part of an Archean greensrone belt dominated by volcanic and sedimenrary rocks and large bodies of ultramafic intrusions. The magnesite-talc zane is abour 1800 m long, has a maximum width of 300 m and has been drilled ro 120 m below surface. Chemical analyses of rhe main carbonate zane average 20 ro 28% soluble MgO (magnesia), 5 ro 6% rota/ iron oxide and less rhan 0.1 % CaO (lime). Mineralogically, the zane consists of approximately 54% magnesite, 28% rate, /5% quartz and 3% hematire. Perrographic srudies suggest that rhe various assemblages of magnesite, rate, quartz and serpentine were derived from a parenr serpenrinire (after dunire). An early carbonitization stage, which produced a high-magnesite, low-talc assemblage, preceded a farer decarbonitizarion stage, which formed rhe main magnesite-talc assemblage. Despite a favourably low calcium oxide content of rhe magnesite-talc rock, considerable iron in the magnesire /at rice has limited the quality of the beneficiared product: rhe besr flotation concentrate to dare yields 92 to 94% dead-burned MgO. Experimen- I L t r i i c:~:.•-4- -------- ? -_;> ,•----1---- ta/ work continues on finding a process whereby high-purity magnesia can be produced on a commercial scale.

Jan 1, 1984

By R. Bruce Graham

The formation, evolution and classification of peat bogs is discussed. Factors resulting in the internal and external morphological changes in a bog are described. The fibrous, absorptive and sterile properties of peat moss account for its widespread use in horticulture and related fields. These properties also account for its usefulness as a binder in pelletizing, as an insulating material in bat tons and in panel construction. Peat, the humijied product of peat moss is used in market gardening and sod growing. It is utilized in Europe as fuel. It is a source of activated carbon and gas. Potentially peat can be used to produce waxes, resins, tannins, cellulose, hemicellu/ ose, humic acids, lignin and hymatomelanic acid. At present other cheaper sources are available.

Jan 1, 1984

By BARRY BANNATYNE

Non-swelling bentonite has been quarried in Manitoba by Pembina Mountain Clays Limited since 1941. It occurs in several thin layers near the base of the Pembina Member of the Upper Cretaceous Vermilion River Formation, and is quarried from the narrow outcrop belt along the slope of the Manitoba Escarpment. It is marketed both as natural and activated bentonite for a variety of specialized uses. Percolation of acidic water through bentonite has produced a naturally activated bentonite with good absorbent properties; these properties are enhanced by treatment with sulphuric acid to produce an activated bentonitefor decolourizing petroleum and vegetable oil.

Jan 1, 1984

By DALE MacGREGOR, VERA TUREK

The Blue Mountain nepheline syenite deposit has been the subject of several detailed studies. It has been variously referred to as an intrusive stock, a metasomatic deposit, an intrusive sill and a metamorphic-metasomatic body. The body is divided into six mineralogical zones, the first five being based on the characterizing accessory mineral; muscovite, muscovitemagnetite, biotite-muscovite, biotite, hornblende and pink syenite. Mining currently takes place only in the biotite zone. Foliation is particularly prominent in the central (hornblende) zone and near the margins of the nepheline syenite. Majic bodies within the nepheline syenite may represent basic rocks that have been less altered by metasomatism, metamorphosed basic dykes or sloped blocks of metasediments. The most prominent structural features are the northeast-trending folds that have been modified by later north west-trending folds.

Jan 1, 1984

By JOHN H. HUDSON

Ceramic clays of the Prairie Provinces range in age from Lower Cretaceous to Pleistocene and Recent. Two significant ceramic clay horizons are the Paleocene Willo wbunch Member of the Ravenscrag Formation in Southern Saskatchewan and the Upper Cretaceous Whitemud Formation, which is found in Saskatchewan and Alberta. The Willowbunch Member is worked at one locale in Saskatchewan; the Whitemud Formation is worked at several locales in Saskatchewan and Alberta. Bentonite operations are found at Morden in Manitoba, Rosalind and Onoway in Alberta, and Wilcox in Saskatchewan.

Jan 1, 1984

By PAUL L. DEAN

Industrial mineral deposits are widespread in Newfoundland and Labrador and a variety of commodities are produced. The province has the only pyrophyllite mine in Canada and also produces asbestos, gypsum, silica, barite, limestone, gemstones, cement and other structural materials. Large reserves of these and other industrial minerals are known and several deposits are likely future producers. Most producers are wellestablished and have large tonnages of ore reserves.

Jan 1, 1984

By DONALD E. BARNETT

Since the days of early settlement ew Brunswick has produced a variety of industrial minerals but it is perhaps only the recent discoveries of significant reserves of potash that have elevated the meaning of industrial minerals in their contribution to the provincial economy. With potash production commencing in July 1983, the role of industrial minerals will increase significantly to the value of mineral production in the province.

Jan 1, 1984

By John H. Fowler

Nova Scotia has been mining and exporting industrial minerals for over two hundred years. As an industrial mineral producer, this province continues to rank as the number one gypsum mining and exporting region in North America. Mining of many other commodities is ongoing, supplying many local and export markets. In all, excluding aggregate producers, there are nineteen industrial mineral producers operating at thirty sites producing nine commodities including anhydrite, barite, clay and shale, dolomite, gypsum, limestone, salt, silica sand and stone (Fig. I). Numerous aggregate producing operations supply all the province's aggregate requirements and export some of these materials to other regions of Atlantic Canada and as far away as Bermuda (Fig. 2) . Production value of industrial mineral commodities in Nova Scotia for 1982 was $105 million , representing 39% of the total value for all mineral production for the year. Because of the general improvement in the economy, indications are that the 1983 value of production will be higher.

Jan 1, 1984

By J. R. CAMERON

Gypsum is mined in all Atlantic Provinces except Prince Edward Island. It is generally thought to have been derived from the hydration of anhydrite in areas of minimal drainage. Late Devonian downwarping and crustal oscillation east of the Appalachian fold belt allowed the Windsor Sea to advance and retreat in a depositional trough and deposit about 1,000 m of sediments in Mississippian time, much of which were evaporites. The best areas for further gypsum development are lowland basins such as the Cape Breton Lowlands, the Hillsborough area of New Brunswick and the St. George's Lowlands in Newfoundland, all of which are already sites of gypsum quarries. Nova Scotia's gypsum is mined from the Lower Windsor Group, which is divided into subzones 'A' and 'B'; 'B' provides most of the province's gypsum production. The Atlantic Provinces gypsum industry has markets from the St. Lawrence waterway to the mouth of the Mississippi River.

Jan 1, 1984

By D. R. BUDINSKI

Clinton Creek Mine in west-central Yukon produced 0.94 million tonnes of fibre from 15 million tonnes of asbestos ore between 1968 and 1978. The mine closed in 1978. The deposit lies along the margin of a medium sized ultramafic pluton that intrudes schistose and gneissic rocks of the Yukon Metamorphic Complex. Country rocks are metamorphic equivalents of a mixed sedimentary and volcanic assemblage deposited during Precambrian or early Paleozaic time. Movement along the north west-trending Tintina Fault System probably caused the fairly high meromorphic grade that altered the original rocks to schists and gneisses. The ultramafic pluton hosting Clinton Creek Mine is one of several bodies that were emplaced along a deep seated imbricate fault system parallel to the Tintina Trench. Most of rhe intrusions were hydrothermally altered to serpentinite, bur apparently only the one at Clinton Creek contains commercial quantities of asbestos. The Clinton Creek pluton was probably injecred slowly at relatively low temperatures into the crustal rocks as a "mush" that cooled gradually, allowing sufficient time for serpentinization and chrysotile fibre crystallizarion.

Jan 1, 1984

By MAX VOS

Lithium is the lightest and electrochemically most reactive of all metals. Renewed interest in lithium coincides with research in lithium batteries and power generation by atomic fusion. Ontario lithium resources are contained in spodumene pegmatites that can form where medium- to high-grade metamorphic volcanic-sedimentary formations are intruded by pegmatite and porphyritic granitic rocks. Spodumene pegmatites occur in at least twelve locales throughout northern Ontario, all of which are in the Superior Province of the Precambrian Shield. Tantalum, cesium, rubidium, beryllium, niobium and tin also were noted with lithium in spodumene pegmatites. Considerable potential remains for discovery of additional lithium and rare-element pegmatites in northern Ontario.

Jan 1, 1984

By D. F. VanDine

The phases of a typical exploration program for sand and gravel resources include: (1) collection and assessment of existing information; (2) air photo interpretation and remote sensing; (3) ground investigation and mapping; (4) sampling and testing; and (5) data storage, retrieval, analysis and presentation. Depending on the purpose, time frame and funding available for the study, these phases, and the various techniques used within each phase, will vary. Once a sand and gravel deposit has been located, defined in size and quality, and found to be suitable for a given purpose, it can then be classified as a granular resource.

Jan 1, 1984

By Victor F. Hollister

Although none of the deposits discovered to date are of commercial interest, significant Frasch or sedimentary sulphur deposits occur in Nova Scotia in Upper Mississippian Windsor Group evaporites. The evaporite sequence contains anyhdrite and is overlain by impervious shales. It also is •mderlain by locally petrolijerous formations that are potential hydrocarbon sources for reaction with anhydrite to produce sulphur. As well, stratigraphic and structural traps are known to exist in the Mississippian beds. Thus, all requisites for sedimentary sulphur genesis are present. Available hydrocarbon sources are numerous but small; resultant sulphur deposits therefore are probably also small. Evidence suggests, however, that sulphur deposition is not yet complete.

Jan 1, 1984

By ANNE FUZESY

Soluble potassium salts in bedded underground salt deposits supply most of The world demand for potassium f or agricultural and industrial use. The potassium salts, sylvite and carnallite, were f irs, noted in drillcores in southern Saskatchewan during The search for oil and gas in ihe early /940s. Problems in shafi sinking beset pioneering potash companies, however, and cominuous production did no, begin uniil 1962. Powsh deposits in southern Saskatchewan occur within ihe uppermost 60 111 of the Middle Devonian Prairie Evaporite a, depths in excess of 900 m. Four groups of po/ash-bearing haliie beds have been distinguished: the Esierha-::,y, White Bear, Belle Plaine and Paiience Lake members. Powsh deposiis extend a jell' kilomeires into Manitoba and south imo orth Dakoia and non heasiern Moniana. Individual potash-rich beds are extensive and consistent in grade and Th ickness. Local th ickening occurs where carnallite is the dominani poiash mineral. Th e preferred ore, sy lviniie, is a clean mixiure of sylvite and haliie. Carnalliie and insolubles are avoided wherever possible because of Their detrimenwl effects on mine stability, grade and refining. Sy lvin ite is exTracted by underground mining or brought TO swjace as brine in solution mining. Poiash is separaiedfrom halite byfloiation or sequential crystallization. The refined produci, potassium chloride, is employed as a fertilizer ingredient as well as in chemical and other industrial capaciiies. The ten poiash mines of Wesiern Canada all are in Saskatchewan and account for aboui 25 per cem of world production. Faciliiies are being expanded, and a new mine and refinery was planned for ihe Breden bury area. Deposiis in Manitoba also were being evaluaied.

Jan 1, 1984

By R. M. BUCHANAN

The segment of Canadian industry based on smelting of alum in um and manufacture of consumer products is based entirely on imported alumina and bauxite. In the absence of Canadian bauxite deposits, consideration of anorthosite, a less desirable aluminous rock, is being undertaken as one alternative in maintaining assurance of supply. Anorthosites in Canada cover many thousands of square kilometres of the Precambrian Shield. Although compositions vary widely among Canadian anorthosites, many appear to exceed the specified minimum of 25% A I 20 3 in bodies containing more than the required JOO million tonnes. A lthough most Canadian anorthosites are of Precambrian age, one located in British Columbia has been identified as being Middle _Cretaceous.

Jan 1, 1984

By D. Racicot, T. Hanel, E. H. Chown

Over thirty plutons in the Chibougamau-Desmaraisville belt were examined briefly in the field and sampled, in addition to the few masses that have been studied in detail. The survey indicates that the intrusions may be conveniently grouped in four main categories, based on their time of intrusion. These are; remobilized basement domes, pre-kinematic intrusions, syn-kinematic intrusions and postkinematic intrusions. Basement domes, as exemplified by the Lappa rent Massif, are composed of migmatized tonalite-diorite gneiss that has undergone at least two periods of mafic dyke intrusion and at least three major deformational periods. The rise of the basement domes was accompanied by extensive mylonitization and the intrusion of syn-tectonic plutons. Pre-kinematic plutons, such the Chibougamau pluton, are diori te-tonalite in composition, and were intruded into the supracrustal pile and partly eroded before the main deformation of the belt. Syn-kinematic plutons occur principally as marginal intrusions bordering the belt (Barlow), or as discrete intrusions along structural highs (La Dauversiere), and are either hornblende monzodiorite or tonalite in composition. Post-kinematic plutons, such as Muscocho, are principally granodiorite and often porphyritic intrusions locally deforming the enclosing rocks. The close relationship between mineralization and high-level intrusions such as the pre-kinematic and some of the post-kinematic plutons is discussed.

Jan 1, 1984