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By H. O. Lien

Among the known iron deposits in Canada, many are of low grade and require beneficiation to produce an acceptable blast-furnace feed. Some of the deposits have never been considered for commercial exploitation due to the lack of a suitable concentrating process. A number of deposits of this type are located in Northern Ontario. The problem in upgrading these deposits is three fold. Firstly, the iron occurs as a mixture of magnetite and hematite. Secondly, the grain size of the material can be fine to very fine. Thirdly, the complex mixture of gangue minerals, which consists invariably of silica, flaky silicates and carbonates, slimes excessively on fine grinding. Algoma's efforts to concentrate these iron-bearing materials culminated in the development of a "Selective Flocculation and Desliming Process" employing slimes removal as the sole beneficiation technique. The process was applied successfully in the laboratory using two stages of grinding and a total of seven deslimings. Prior to the removal of slimes, the iron-bearing fines were selectively flocculated from a thoroughly dispersed pulp using a modified starch as flocculant, Sodium silicate was employed as dispersant. An attempt was made to optimize some of the process variables using material from one specific iron formation near the town of Geraldton in Northern Ontario. The preparation of the starch proved most critical. This matter, and the method used to evaluate the degree of breakdown of the starch molecule, are therefore discussed in some detail.

Jan 1, 1978

By Ven Mercade

The flotation of calcite has been studied by many investigators, especially in terms of type of collector; pH; and metal ions that activate and, more importantly, depress the flotation of calcite (1)(2). Research was extended to the investigation of the effect of polyvalent metal salts and sodium silicate using these materials added separately or in mixtures (3)(4)(5)(6). Flotation of calcite was also studied with respect to its function as a carrier in the beneficiation of kaolin clays by Ultraflotation (7) (8) (9). The carrier used in Engelhard Minerals & Chemicals Corporation's industrial Ultraflotation operation is calcite. This fact, coupled with the continuing interest in Ultraflotation phenomena, led to a study to determine the effect of polyvalent metal-silicate hydrosols on the flotation of calcite.

Jan 1, 1978

By R. Tipman, T. C. Burnett

"A general computer program has been written to calculate material balances using multiple regression techniques. The program can handle metal assays or size distribution data obtained in multiple surveys of the flotation circuit. The ""best fit"" weight split is calculated between the input and product streams by minimizing the sum of squares of the residual errors using all of the available data. The program includes an assay adjustment feature in which each assay is recalculated to fit the ""best fit"" mass balance. Thus assay or sampling errors can be easily identified. Also the assays can be statistically weighted so the most precise measurements are given the most influence on the material balance. The computer output reports the mass balance, the actual and corrected assays, the percent metal recoveries and the significance and confidence levels for the weight splits.The program enables a rapid and accurate evaluation of mass balances from large masses of data obtained in multiple surveys around a flotation circuit. The effects of changing process variables can be quickly evaluated with statistical confidence."

Jan 1, 1978

By W. R. Cowan

The availability of mineral aggregates for construction purposes is rapidly declining through inadequate resource planning. restrictive zoning and legislation , and competing land uses. The Geological Branch of the Ontario Ministry of Natural Resources has undertaken to provide aggregate inventory reports for all townships designated under The Pits and Quarries Control Act, 1971, and eventually for all towns hips in heavily populated areas. The reports contain maps and recommendations for extractive zoning by municipalities; of necessity only the largest deposits are given priority recommendations. It is intended that these reports should improve the resource planning in areas underlain by large aggregate deposits. The inventory is only possible because a concentrated effort has been made to map the Quaternary geology of populated areas over the last ten years. Future needs require that we develop methods to determine the extent of poorly defined and buried aggregates and that we look for natural alternatives.

Jan 1, 1978

By Jr. Garnar

Heavy mineral mining has been a relatively small but important Florida industry for over sixty years. Geology of the Florida heavy mineral deposits is similar. Each formed along active coastlines after which the titanium minerals were upgraded in TiO2 by post depositional oxidation and leaching of the iron. There are four heavy mineral plants currently Operating in Florida. Ore is mined by dredges and the heavy minerals concentrated by gravity separation. The heavy mineral concentrates are further processed with high tension and electromagnetic separators to Produce titanium mineral concentrates for TiO2 pigment manufacturing plants. Zircon sand is produced as a co-product at all of the Florida plants. Staurolite is produced by Du Pont and Titanium Enterprises. Du Pont also markets a kyanite-sillimanite product. (Monazite is produced by Humphreys and Titanium Enterprises). Reclamation of mined-out land is an important part of heavy mineral mining. At the Du Pont plants soil is removed ahead of the dredge and placed over the quartz sand tailings. Grass is planted after fertilizing. A year later the land is fertilized again and pine trees planted. Most of the heavy mineral deposits now being mined will be nearly exhausted by the end of the century. New deposits to be mined in the 21st century will probably be smaller and lower grade than those now being mined. Advances in mineral processing technology will have to be made to allow these lower grade deposits to be mined economically.

Jan 1, 1978

By J. E. Matta

The methane gas emitted from coal samples collected from the conveyor belts dumping into silos was measured by the Bureau of Mines. Approximately 50 pct of the total gas desorbed into a sealed can within 1 week was released during the first 24 hours. No simple correlation between the gassiness of the coal stored and the methane concentration in the silo open space above the coal was found. This was probably because the gassier coals were stored in open-top Silos, which were better ventilated. Although the methane concentration in the open space above the coal pile was less than 1 pct for all 34 silos investigated, a methane measurement in the coal pile showed that high methane concentrations can exist. The methane released in the pile appears to accumulate and not liberate freely into the open space above the coal pile. Probably this gas is released during reclaiming operations, but further research is required to substantiate this claim.

Jan 1, 1978

By E. Allen Hendt

It is a pleasure to be invited to speak before a gathering of executives representing America's leading mineral companies, I welcome this opportunity, particularly because it comes at an important period in the development of U.S. commodity policy. This morning, I discussed our general commodity policy primarily in the. Context of the north-south dialogue between developed and developing countries. This afternoon, I would like to focus more specifically on potential cartel activity and U.S. mineral import dependence.

Jan 1, 1978

By M. L. Joy

The heat pipe is a self-contained, passive structure that uses a liquid-vapour fluid cycle to provide high thermal conductance . Through the proper selection of working fluids and container materials, heat pipes have been operated at temperatures ranging from less than -300°F to more than 3,000 °F. The passive nature, high efficiency and configuration flexibility of the heat pipe are presented. The application of McDonnell Douglas Astronautics Company Cryo-Anchor® heat pipes for foundation and support stabilization in permafrost regions is discussed. Using the proven Cryo-Anchor technology base. a proposed application of heat pipes in a cold -region mine ventilation system heat recovery heat exchanger is presented. Information obtained from the development of an air-cooled heat pipe steam condenser provides the technical basis for large -scale heat pipe applications.

Jan 1, 1978

By V. S. Tadsen

Today, man is able to probe space because of technological advancements including the ability to control certain combustion reactions very precisely. The recent adjustment of the attitude of Skylab by radio command from earth is an excellent example of such control. It is strange, and indeed unfortunate, that very little is known about the mechanism of combustion of pulverized coal, the primary fuel for rotary kilns. The selection of a coal for direct pulverized firing of a rotary lime kiln may be determined by trial and error, persistence of sales personnel, proximate analyses, grindability, or apparent BTU cost. Occasionally, the only question asked is, "How much lime will it make?" To study the behavior of a particle of coal in the combustion stream of a rotary kiln is most difficult. We must, therefore, discuss the general mechanism of combustion of pulverized coal, and relate this mechanism to the selection of a proper coal for a rotary kiln. The classic three T's -time, temperature, turbulence -must be enlarged upon for a better understanding of the problem. Pulverized coal occupies only 0.01 per cent of the volume of air required for its combustion. This mixture behaves like a gas and the general laws governing the movement of solid particles in gasses are in effect. The differential velocity between air and coal particles depends on forced and natural convection, diffusion, and the length of time each particle is in the combustion space. As a particle of coal absorbs heat from its surroundings, it begins to give off volatiles". These gasses ignite as their kindling temperature is reached, and burn readily because of the excess oxygen immediately available. Combustion proceeds at this stage by the outward diffusion of gas from the coal particle into the surrounding oxygen-rich envelope. We could say combustion at this stage represents a small coal particle surrounded by an envelope of volatiles burning at their point of contact with sufficient oxygen. This release or expulsion of gasses from the coal may result in exfoliation or disintegration of the coal particle. If this occurs, and it is desirable that it should, it will accelerate the final stages of combustion. The escape of volatile material from the particle of coal and its subsequent combustion will cause increased turbulence around that individual particle. Ignition is maintained by radiation from gasses and solids in the combustion system, and most importantly, re-radiation from the kiln refractories and the process load.

Jan 1, 1978

By Robert W. Curtis

Kaiser Aluminum & Chemical Corporation's (KACC) entrance into the alumina market began in 1946 with the purchase of a small plant in Baton Rouge. Louisiana. Since that time KACC has been involved with the design, construct; on, and operation of many alumina plants around the world. One of these plants is located in Gramercy, Louisiana. The Gramercy Works is a multiplant installation consisting of an alumina plant, a caustic-chlorine plant, a petroleum coke calciner and a fluorochemicals plant. Each of these plants require their own specific environmental control programs to abate pollution. Kaiser has made significant progress through the years on their own initiative in pollution control. But many new challenges have been and continue to be created with the enactment of environmental laws. The 1970 Clean Air Act Amendments, the resurrection of the old "Refuse Act" in 1970 and finally the 1972 Federal Water Pollution Control Act Amendments prompted the formulation of our current philosophy towards the abatement of pollution. Since the formulation of these complicated pieces of legislation, others equally complicated, have come to being. The Federal Insecticide, Fungicide and Rodenticide Act as amended by the Federal Environmental Pesticide Control Act of October, 1972, the Toxic Substances Control Act of 1976, the Solid Waste Disposal and Resource Recovery Act of 1976 and the Safe Drinking Water Act sighed in December of 1974 have all contributed to the challenge for an alumina plant to meet regulatory constraints. However, this paper will only discuss the alumina plant?s environmental programs designed to meet compliance with air and water pollution legislation. At the Gramercy Alumina Plant, over $25 million has been spent for pollution control since 1969. The Gramercy Plant is a prime example of KACC's commitment to meeting the environmental challenge.

Jan 1, 1978

By Mason L. Dicks

For many years The Hanna Mining Company has been investigating the flotation of the non-magnetic iron ores located in the Western Mesabi Range of Minnesota.1 During the 1950's a number of anionic iron procedures were evaluated and in the late 1950's and early 1960's the anionic silica floats and the cationic silica floats were tested with improved results.2 The cationic float became more attractive and effective by the use of the improved ether amines. About 1962 a desliming process by selective flocculation was developed by the U.S. Bureau of Hines at Minneapolis', Minnesota.3, 4, 5 This is a very efficient method of desliming and was first tried with the anionic silica float and then the more practical cationic silica float. In the mid 1960's The Hanna Research Laboratory began studies to optimize the selective flocculation process for our ores. This was followed by studies to optimize the cationic silica float after desliming by selective flocculation. This testwork was done on large, 500 to 1000 tonne bulk samples of oxidized taconite which were later successfully piloted at .68t/h (1500 Lbs. /hr.). A program was then begun to test the oxidized portions of numerous taconite drill holes to outline the ore bodies and develop mining plans. This paper will discuss our optimization results of both the selective flocculation and the cationic silica float as applied to our various ores. In addition the pilot plant studies and drill core testwork will be discussed.

Jan 1, 1978

By D. M. Hausen

A quantitative x-ray diffraction method has been developed for the analysis of alteration minerals in wallrock. Alteration data are plotted and contoured (analogous to geochemical data). Alteration trends outlined by this technique correlate closely with geochemical anomalies, and in some cases attend well beyond the perimeter of anomalous base metal values. "Monomineralic contouring," applied originally to porphyry-type mineralization, has been extended to other types of mineralization, including volcanogenic massive sulfide deposits. Equipment and techniques used in the quantitative measurement of alteration mineralogy are discussed.

Jan 1, 1978

By Alan Bauer

New developments in drilling, blasting and explosives in both open-pit and underground mining operations are discussed, as well as novel surface blasting techniques such as are used in tar sand mining.

Jan 1, 1978

By D. C. Myntti

An open pit mining equipment maintenance program, in order to be successful, must have many active segments covering the full range of equipment selection, trained personnel, repair facilities, preventive maintenance programs, warehousing, interdepartmental cooperation, paperwork and effective communications. The mine maintenance program is required to protect company assets Which are units of equipment generating revenue. The program should result in reduced unscheduled equipment downtime, increased equipment productivity rates, and decreased unit operating costs. Current maintenance problems; maintenance effectiveness and future projections on equipment maintenance are discussed. Equipment maintenance is big business and the maintenance department is a full-time partner in the mining venture.

Jan 1, 1978

By V. A. Preto

The Rexspar uranium deposit is located approximately 5 kilometres south of Birch Island, B.C. Three separate zones of commercial-grade uranium mineralization mineable by open pit have been outlined. Uranium and fluorite-celestite mineralization occur in a trachytic member of alkali-feldspar porphyry, lithic tuff, tuff breccias and pyritic schist conformably interlayered with a succession of strongly deformed greenschists and fragmental rocks that are, in large part at least, of volcanic origin. The age of these strata is not precisely known, but they are considered as part of the possibly Mississippian Eagle Bay Formation. Commercial-grade uranium mineralization is always associated with fluorphlogopite-pyrite replacement of the trachytic unit and is contiguous to, but separate from , a zone of ore-grade fluorite mineralization. In all zones, ore occurs in lenses of variable thickness and lateral extent, which lie parallel to the schistosity of the trachytic rocks and surrounding greenschists. The principal radioactive minerals at Rexspar have been identified by other workers as uraninite, uranothorite, bastnaesite, torbernite and metatorbernite. Considerable amounts of thorium oxide and widespread rare earths have been reported from all three radioactive zones. The geology of the deposit suggests that the trachytic rocks represent a highly differentiated intrusive-extrusive system in which fluorphlogopite, pyrite, fluorite and uranium-bearing minerals were deposited late in the evolution of the system by deuteric, volatile-rich fluids. The considerable amounts of thorium and widespread rare earths associated with the uranium tend to support the thesis that this element is of primary origin rather than secondary.

Jan 1, 1978

By Georges E. Vaillant

Air pollution control in primary aluminum smelter . Various processes are known for air pollution in electrolysis plants. Mainly two systems have to be taken into consideration: -Treatment of concentrated gases collected directly from hooded pots. This is normally achieved by either dry or wet process. This is not the object of this paper as these processes have been already described. -Treatment of low concentrated fumes. A certain amount of gaseous and solid fluoride (35 % of total fluor pollution) goes out of the hooded pot. Gases commonly called secondary fumes are generally treated by wet process. The object of 'this paper is to describe two plants with specific treatment for secondary fumes. 1/ A plant in operation in Vlissingen (Netherlands) for PECHINEY. 2/ Presentation of tests carried out by a specialized Company. The results of such tests have been used for the design of the scrubbers presently under construction for ALUMINIO ESPANOL San Ciprian (Spain).

Jan 1, 1978

By William H. Lane

After a number of years of engineering and operating assignments and through many types of evaluations, the need for a simple analytical method of evaluating mine haulage alternatives became obvious. Haulage, like 50 many other facets of mining, is generally a sequence of interconnected events that change, often drastically from mine to mine. Often the operator or the mine engineer has neither the time, manpower, facilities, or information needed to prepare a detailed evaluation. For many studies or for routine variance analysis, that detail may not be necessary. The intent of this article is to present an approach for analyzing mobile mine haulage that is simple and straight-forward. These methods are not designed to replace more formal and detailed procedures that have been developed previously and are available in our technical libraries. They are offered as a tool to be applied to preliminary designs, feasibility studies, and variance analyses where more complete detail is not warranted. These methods will eliminate combinations that are not economical or appropriate before more intensive and complete evaluations are undertaken. These methods may also be used to evaluate ongoing operations and to plan changes in those operations. This presentation describes a series of steps that have evolved for the handling of haulage evaluations. It concentrates on the factors having major impact on the results. Because the approach is a sequence of distinct steps, a case study was chosen as the best method of presentation. This case is a composite of several actual situations that have been encountered within the last few years.

Jan 1, 1978

By Irvine G. Reilly

Results of a preliminary study of the ammoniacal leaching of covellite (CuS) in an aqueous oxidizing system in the presence of a non-miscible organic sulfur solvent are described. Up to 60% of the sulfur can be recovered from the solvent as elemental sulfur 1 while achieving high degrees of solubilization of the mineral. The effects of temperature, particle size, oxygen pressure, ammonia concentration and ammonium ion concentration on the degree of sulfur recovery were investigated. Maximum recoveries were achieved at moderate temperatures and in well-buffered systems, with a large excess ammonia concentration. Oxygen pressure and particle size were found to have little effect on fractional recovery of sulfur. A simple empirical model based on electrochemical theory correlating the effects of some of the parameters cont-rolling the degree of sulfur recovery is presented. The results of this work also confirm that in any proposed reaction mechanism for the oxidative ammoniacal leaching of copper sulfides, the primary oxidation product of the sulfide ion in elemental sulfur.

Jan 1, 1978

By Carl R. Peterson

Development of reliable, portable, low headroom, hard rock crushers would improve the efficiency of most currently operated conveyor systems and make it possible to bring conveyor haulage closer to the face, thus eliminating expensive rock rehandling procedures. A crusher that could be easily moved would permit the more widespread use of lower cost haulage systems, such as conveyors, to transport the ore out of the mine. Such crushers would be installed close to the working areas, resulting in an optium haul from the face to the dump location. A recent contract study by Rapidex, Inc., "Application Study of Portable Underground Hard Pock Crusher" (USBM Contract No. J0265006) provides a survey of industry needs in portable underground crushing, together with conclusions and concepts as to specifications and type of crusher required to serve the greatest number of operations. To fill this need a three phase program has been undertaken by the Bureau of Mines: Phase I - Design: Phase II - Construction and Testing, and Phase III - Production Underground Test. This report covers Phase I only, and includes the complete engineering design and specifications of the Rapidex Rotary Jaw Crusher conceived in the earlier "Applications Study". Also included are the design, construction, and testing of a quarter-scale functional model, utilizing three different types of rock and two different crusher feeder systems.

Jan 1, 1978

By Donald N. Rosenblatt

I would like to commend the author on his description of Pinto Valley's plant, and its interesting innovations. The author's discussion of 18 ft in diameter by 21 ft long primary ball mills (the largest wet ball mills made to date) is of considerable importance to those who have been engaged in the field of studying ball mill liner wear as it relates to various grinding installations. While it is stated that the mills have operated on a fixed tonnage and therefore it has been difficult to determine the best liner pattern, calculations from the data in the paper indicates that for mills 1, 2, 5, and 6, the tonnage per hour varies from a low of 223 for mill No. 1, up to a high of 314, for mill No. 2, while mills 5 and 6 calculate 285 and 246, respectively. Analysis of the wear patterns for the single wave liners used in mill No. 1 as compared to the double wave liners in mill No. 2, suggests that the author's data may tell more than he suspects about liner wear to be expected and thus what should be a best pattern selection from what may appear to be only limited hours of operation. [Fig. A] is a reproduction of author's [Fig. 10], to which wear forecast patterns [F-1 and F-2] have been added. Forecasts are based on many previous studies of large diameter ball mill operations over many years of field service. Calculations from the first-wear pattern provide an initial wear rate of only 13 lb of liner per 100 sq ft of shell liner surface per day, or 0.031 lb per to: ground. However, the second wear pattern is ac-

Jan 1, 1978