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By Kenneth R. Maser

This report describes the development of a system which modifies an existing fly ash-foam remote mine sealing technique to make it capable of impounding water in a fire zone. The modification involves blending equal quantities of fly ash and bentonite to form the bulk of the seal, and blending a thin layer of fly ash and Huron Regulated Set Portland Cement (RSPC) as a coating. The modification replaces the pure fly ash approach, but continues to use a froth foam topping to complete the seal. The modified material system is implemented with minimal complexity by adapting a "Y" connector to the existing delivery system. Each bulk hauler (fly ash and bentonite, or RSPC) will pump into one leg of the 'Y'; and the blending will be controlled by two pinch valves. The development effort has involved an evaluation of potential material systems by using small sample, quarter scale, and full head tests. The small sample tests measured the basic properties of a large number of selected material combinations. Property measurements included capillarity, permeability, shrinkage, and shear strength. As a result of these tests, particular combinations of fly ash-bentonite and fly ash-cement were selected for scale model testing in a 1 /4 scale test facility. These tests simulated, in a scaled manner, the water rise and total head which would be experienced by a seal. The tests indicated that shrinkage in the fly ash-cement combination would always result in leakage; whereas, fly ash-bentonite mixes were impervious to water.

Jan 1, 1974

The panic bars (and associated linkages and electrical circuitry) that are defined in this document are a machine operator-actuated control for the emergency deenergization of the tram motors on self-propelled, electric and diesel face equipment; including haulage equipment such as shuttle cars. There are nine basic types of panic bars (and several variations) that are recommended in this document, but all of the panic bars arc characteristically of the 'fire door" type that is frequently encountered on outside exit doors of many public, and some commercial buildings. It is also the intent of the following panic bar designs that, when emergency brakes arc added to the face equipment machinery for which they arty required, that they be designed and hooked up so that actuation of the panic bar will result in automatic application of the emergency brakes (immediately following the deenergization of the tram motors). The following panic bar design requirements are a restatement of the proposed requirements defined in the Federal Register, requirements cited in "Guidelines for the Design and Installation of Devices for Deenergization of Self-Propelled Electric Face Equipment/Automatic Emergency Brakes" by C. E. Lester and J. D. Greenhalgh of MESA, and Bendix recommendations that were formulated as a result of discussions with personnel at the various machine manufacturers and underground coal mines that we surveyed, discussions with G. I. Judy (our consultant), etc:

Jan 1, 1974

By Leonard Bronitsky

The construction mineral aggregates industry--the largest industry on a tonnage basis--is threatened with large shortages in the near future. Ironically, these common minerals which include sand, gravel, and stone are among the most plentiful in the earth's crust. However, as these minerals are low in value and used in large volumes, they are extremely sensitive to transport cost, e.g., a haul of 20 miles doubled the delivered cost of mineral aggregates. Consequently, these minerals must be located close to points of demand to have economic usefulness. But the development of new deposits is virtually impossible near many urban areas for legal, sociological and economic reasons. The spector of unfinished urban transport systems, curtailed residential construction, and a general deterioration of the physical urban plant, looms as a direct consequent of future mineral aggregate shortages in the U. S. metropolitan areas. The shortages of mineral aggregates in the Greater New York Metropolitan Area (G.N.Y.M.A.) are prototypical of the shortages faced by the U. S. Metropolitan areas. This paper presents an economic analysis of the consequences of not considering the broad aspects of conservation economics as a major component of resource management. The needless annual cost for the G.N.Y.M.A. is shown to be $30 million.

Jan 1, 1974

By Hoke M. Garrett

The domestic cement industry demands about 550 trillion Btu annually, at a time when reduced fuel use has become a necessity due to the energy shortage. In terms of the overall power picture, that 550 trillion Btu, which includes both fossil and electrical energy, means about 0. 870 of all energy consumed in the U. S. The various factors influencing reduction of this energy consumption are the subject of this paper. Nationally, the energy shortage is being tackled on two fronts--increasing supply and reducing demand. Making cement consumes energy; therefore, the industry cannot join the effort to increase the energy supply except indirectly as noted later. Demand can also be attacked on two fronts--by reducing cement consumption or by reducing the amount of energy required to make cement. The following discussions on reducing cement industry energy consumption center briefly on the prospect of reducing cement consumption followed by a broad evaluation of the potentials for improving cement-making thermal efficiency.

Jan 1, 1974

By Bruce H. Mason

The exploration for a commercially acceptable deposit of limestone is consid¬ered by many to be a relatively easy task; however, trying to locate a zone of high calcium limestone of economic thickness within a formation, which outcrops only in a narrow band varying in width from a quarter mile to ten miles, adds considerably to the normal problems experienced during an exploration program. The existence of varying glacial and karst features in the outcrop area intensified the problems encountered and complicated the interpretation of the economic value of the deposit. This paper highlights a recently completed five year exploration program during which approximately 3,900 acres of ground in seven civil townships were evaluated as potential sources of high-calcium limestone. Details are given with respect to the final site chosen and the methods used in determining the suitability of the site. This site exhibited many karat features and several methods were utilized to determine the effect of these features on the gross characteristics of the deposit. Aerial photography for both mapping and interpretation were utilized. Black and white panchromatic photography, black and white infrared and color infrared photography were flown. Resistivity, diamond core drilling and close-interval angering were used to supplement the information obtained from the aerial photography.

Jan 1, 1974

By M. Shabbir

A study was made to determine the optimum conditions for precipitation of uranium from mill solutions using hydrogen peroxide. Precipitation tests were made on both synthetic and actual mill solutions. Parameters studied included amount of hydrogen peroxide, initial pH, reaction pH, time, and temperature. Also investigated was the effect of varied amounts of vanadium, molybdenum, and sulfate in the test solution on uranium precipitation and product quality. The optimum conditions for complete precipitation and high product quality were (1) the use of 150 percent of the stoichiometric requirement of hydrogen peroxide, (2) initial pH of 1.0, (3) reaction pH between 3.4 and 5.0, (4) 4 hours reaction time, and (5) ambient reaction temperature. The excess hydrogen peroxide requirement is partially dependent on the amount of impurities present in the feed solution. The hydrogen peroxide process appeared applicable to treatment of the several mill eluate and strip solutions tested. The experimental studies also indicated that the hydrogen peroxide technique gives substantially better product quality than that produced by ammonia precipitation.

Jan 1, 1974

The Kalgoorlie Golden Mile is proposed as an Archaean volcanogenic-type deposit, modified and redistributed along later-developed structures. Rich pyritctelluride and Green Leader gold mineralization is associated with the end phase of basic volcanism and, in a general sense, is confined to a broad interface zone between the products of marine basic volcanism and later acid volcanism. There is virtualIy no ore associated with the main body of acid volcanics.Green Leader is the local name of a type of ore that occurs at some igneous rock contacts in association with graphitic sediments and layered acidic tuffs. It is characteristicalIy green, of various shades, and commonly yields very high gold assays, the reasons for which are not apparent in hand specimen.Carbonates, carbonaceous shales, tuffites, rich gold ores, and acid and intermediate dykes, alI indicating a common heritage, are features common to the main ore hosts, viz. the Paringa Basalt (Calc Schist) and theGolden Mile Dolerite ("Quartz Dolerite Greenstone").Several probably related fracture systems have reconstituted most, but not all, of the original deposits into a large number of steep tabular lodes.Includes two sets of discussions and comments from later Proceedings volumes.

Jan 1, 1974

By Laurance L. Oden

The Bureau of Mines conducted corrosion tests of 18 commercial alloys in H3 P04 -phosphate rock or A1,03 slurry, in 10 pct HF, and in 25 pct H2 SiF6 to simulate three environments anticipated in a Bureau process to extract fluoride values from phosphate rock. Small alloy coupons were rotated in duplicate tests at 4.4 to 21 fps in the slurry at 170° C to determine rates of erosion-corrosion. At 4.4 fps the lowest rates, in mils penetration per year (mpy), were measured for Hastelloy C-276 (<20), Hastelloy B (30), and Inconel 625 (150);the rates increased at 21 fps to 55 mpy, 45 mpy, and 1,000 mpy, respectively. The corrosion rate for all alloys exceeded 40 mpy in either the equilibrium vapor or liquid phases of aqueous solutions containing 10 pct HF or 25 pct H2SiF6 at 100° C. Uniform corrosion in 10 pct HF at 50° C was observed only for Inconel 625 (22 mpy), Hastelloy C-276 (43 mpy), and Illium 98 (17 mpy). Inconel 625 (0.75 mpy), Hastelloy C-276 (1.3 mpy), Illium 98 (1.7 mpy), and Incoloy 825 (0.45 mpy) were attacked uniformly in 25 pct H2SiF6 at 50° C.

Jan 1, 1974

By Rolland L. Blake

The Bureau of Mines is concerned with extracting minerals from residual geothermal brines after their heat content and some demineralized water have been recovered. This literature study is based on a survey of the literature and discussions with individuals knowledgeable on various aspects of the subject. This report examines the potential of the domestic geothermal mineral resources, considers the technical problems involved, and outlines possible effects on the environment from reservoir fluid withdrawal and reinjection. Geothermal resources in the Western United States were extensively explored during the 1960&apos;s. Limited development operations included exploratory drilling and operating wells producing hot brine, separating steam for experimental electric power generation, and recovering minerals in solar evaporation ponds or in extraction plants. Interest in the recovery of minerals and salts from geothermal fluids waned because of corrosion and scaling problems and low or no market value of the mineral products. Most of these problems can be controlled with existing technology and careful planning of processes and equipment. Extracting geothermal minerals is technically feasible, but the problems of low or no market value for major mineral products, and insufficient amounts of more valuably major products, make mineral recovery uneconomical at present.

Jan 1, 1974

By R. R. Schehl

The Bureau of Mines analyzed the structure of a high-grade metallurgical coke, carbonized at different temperatures in the range 500° to 1,000° C, through X-ray diffraction studies. Growth in the crystallite size with increasing coking temperature was calculated from profile analysis and compared with values obtained from the radial distribution function. The carbonization temperature appeared to have little influence upon the stack height, whereas the layer diameters more than doubled in size between 500° and 1,000° C. These results are comparable to those obtained from other studies of poorer quality cokes.

Jan 1, 1974

By B. W. Madsen

Experimental results obtained from large scale (7 tons), long-term (500 days) leaching of low tenor copper sulfide ores were interpreted by a geometric model involving the movement of a reaction zone through the ore fragments. The postulated leaching mechanism involved mixed kinetics and included diffusion of the reacting species through the host rock and a chemical reaction at the surface of the mineral particles. Ore properties which were considered were ore particle size and shape, grade of ore, and mineral content. Excellent agreement between the mixed kinetic model and the laboratory leaching results was obtained when minus ½ inch ore particles were not included in the leach. Also, a satisfactory prediction of copper recovery from plus ½ inch ore with a different particle size distribution was made; however, it was necessary to modify the shape factor in the model. Predictions of copper recovery from an ore sample which included the minus ½ -inch fine fraction and leaching for 460 days was 56.5 percent, and the recovery from leaching was 47.0 percent. The presence of fines caused channeling and uneven solution distribution and inhibited the leaching rate.

Jan 1, 1974

By R. G. Bottge

To better understand those factors which increase mining costs in Alaska, a Bureau of Mines study was conducted to compare the estimated costs of operating a 100,000-tpd open pit copper mine located on a hypothetical ore body in the Lake Clark area, Alaska, with the costs of mining a similarly sized hypothetical copper ore body near Tucson, Ariz. The information derived should be beneficial to the State and Federal governments in appraising the potential for development of large, low-grade porphyry copper deposits in south-central Alaska. Conventional mining and concentrating methods were assumed, and capital and operating costs were derived using flowsheets and standard costing methods. The total price required for copper mined in Alaska and Arizona was $1.12 and $0.63 per pound, respectively, plus or minus 20 percent. These values were obtained assuming no leaching of low-grade copper, recovery of gold, silver, and molybdenum as byproducts, 100-percent equity financing, and a 12 percent discounted cash flow rate of return. The average domestic and international prices for copper in July 1973 were $0.60 and $0.916 per pound, respectively. The existence of a developed transportation and power system in Alaska would have reduced capital and operating costs subs tantially. The required price for copper would have declined from $1.12 to $1.05 per pound, plus or minus 20 percent.

Jan 1, 1974

By William Detty

An architect representing the Atlanta office of the Brick Institute of America periodically presents a slide lecture to interested groups entitled "The First 10,000 Years of Brick". The title signifies the fact that brick, man&apos;s oldest manufactured building material, has been around for quite some time and will continue to be utilized by architects and builders in the foreseeable future. This is not to say that the brick industry can rest on its laurels and ignore the competition presented by newer more innovative products. The industry will have to be equally inovative and market oriented in order to maintain its market share of the predicted construction boom between now and the year 2000. The implication is made, however, that brick can be produced under rudimentary conditions and that the desire to use the product has been long standing. In addition, history has sham that there has been plentiful clay available to produce the product. This paper is an attempt to assess the climate in which the brick industry will operate during the next 26 years. An analysis of regulatory conditions affecting the manufacture of the product will be followed by an assessment of the materials environment in which the industry will be operating. These factors are then reconciled with a projected demand for the product to determine the ability of the industry to satisfy future demand for brick. From a mineral point of view this paper will address itself generally to the availability of and demand for clay. However, other than a brief overview of the uses of other specific types of clay, it will concentrate on the clays utilized in the production of structural clay products, specifically brick.

Jan 1, 1974

By Roshan B. Bhappu

Stimulated by current $0.80 to $1.20 per pound price tag of copper, considerable interest and activity have been generated in the copper mining camps throughout the world, and especially in the Southwestern United States and Northern Mexico copper belt. Under these economically favorable conditions, many of the marginal oxide-copper deposits, as well as newly discovered prospects, are under scrutiny for possible exploitation. For both the known deposits and new prospects, the big question facing the mine operator is the selection of the best method for processing these economically attractive oxide-copper deposits. Several variations of the hydrometallurgical processes are currently available for treating oxide-copper ores which can be mined by the open-pit method. Basically, these processes involve preparing the ore for application of an acid solution, applying the solution to the ore, and recovery of the metal from the pregnant solution. Dump leaching, heap leaching, vat leaching, agitation leaching and, in more recent times, in situ leaching or solution mining in combination with well established cementation process or the newly developed solvent extraction-electrowinning system have all been employed or have been investigated for the recovery of copper from oxide ores. Of these processes, dump, heap and vat leaching have been successfully practiced for treating oxide-copper ores. Agitation leaching is a relatively newcomer and has been adopted from the experiences of uranium and gold processing. Finally, the inplace leaching technique is the latest process to be suggested for possible treatment of oxide-copper ores.

Jan 1, 1974

By Lulie H. Crump

Salient information on reserves, production, and consumption of fuels and energy by State are summarized in this Bureau of Mines publication. The data are broken down by fossil fuels (coal, petroleum, and natural gas) and hydropower and nuclear for the major consuming sectors: Household-Commercial, Industrial, Transportation, Electric Power and Miscellaneous. In addition, total energy consumption in the Nation in 1972 is compared with consumption in 1971 and 1973 (preliminary data).

Jan 1, 1974

By Daniel T. Hegyan

The employment of continuous rotary vacuum disc filters to filter refuse from the fine coal washing circuits has been increasing as it has become more important to close the water circuits and eliminate sludge holding ponds. This paper will discuss our past experience filtering refuse, effects of solids concentration in the filter feed, use of polymer flocculation aids, effect of flocculation devices, and effects of particle size and ash content on the filtration rate. Detailed tests were performed on existing installations utilizing coal refuse filters to determine optimum flocculant dosage, solids concentration, and disc rotation speed to form a dischargeable cake. Information was also obtained showing effect of flocculant addition on the moisture of the filter cake. Our test work has shown that the continuous filtration dry cake rates for fine coal refuse correlates very well with the data developed and presented by Silverblatt and Dahlstrom1 except that the curves have moved up the scale by use of polymer flocculant additions. These polymers were not available at that writing. Finally, our tests also confirmed the general premise stated by S. K. Mishra2 that controlled additions of polymer flocculants will reduce filter refuse cake moistures somewhat.

Jan 1, 1974

By Peter L. Comanor

At Getchell, Nevada a thousand tons per day mill for extracting gold from an ore containing orpiment and realgar was operated several years until early 1967. A cyanide process with a roaster was used in the processing of the ore. Mill wastes were contained in tailings ponds, in which the concentration of arsenic, currently, is one per cent or higher, Studies were conducted determining the effect of the tailing wastes on the Upper Sonoran vegetation of the area. Grid and line-intercept techniques were employed to obtain botanical informatics of the area surrounding the tailings ponds. Data of the per cent ground cover, species frequency, and plant vitality as a function of distance from the tailings ponds was collected. The data was compared to other botanical data collected from a control site outside the influence of the tailings ponds. In an attempt to isolate naturally occurring factors for varying plant communities from hose induced by factors derived from the close proximity of the tailings, soil cores were taken along the line-intercepts at intervals of 30 meters. The cores were analyzed for several compounds and elements needed for growth, or known to inhibit growth. Specific physical parameters of the soil samples were also taken. The paper describes the impact made by mill wastes containing large amounts of arsenic on the Upper Sonoran vegetation of the Getchell region. Described in detail are the techniques used to make the correlations between the plant communities and the influences of mill wastes.

Jan 1, 1974

By A. Metzer

When paraffinic gases (ethane, propane, butane) are used as the gas phase in flotation systems, the initial rate of flotation and recovery are generally increased as compared with air. The mechanism of the effect of paraffinic gases in flotation was studied and it was shown that they co-adsorb with the collector ions on the mineral-aqueous solution interface. The effect of this co-adsorption was interpreted in terms of apparent increase of the effective chain length of the collector by the co-adsorbed gas. Adsorption densities, contact angles and flotation behaviour were studied on the following systems: a) Quartz - dodecyl ammonium chloride - ethane and propane b) Calcite - sodium oleate - propane and butane. The positive effect of the co-adsorbed gases is a maximum at low collector concentrations or where critical conditions for flotation with air prevail.

Jan 1, 1974

By Armstrong

This is a world of change and has been from the beginning. There are constant efforts on the part of natural forces to wear down the high spots and fill in the low spots. Wind and water over eons of time tunnel through obstacles and build windways and waterways to make movement of air and water easier and more efficient. It is a natural, never ending, ever changing continuing effort. Man in his struggle to survive, and to progress, has had to adapt the terrain of the earth to fit his needs the best he could. First, he used natural caves to protect him from the elements; then he learned how to build earth and rock-moving tools from antlers, bone, rocks, and sticks and adapted his cave to increase his security and provide better protection from heat and cold and from his predatory enemies. As his numbers increased, so did the necessity of further adapting his environment to accommodate his needs. Water was usually not available when and where needed, especially in the desert areas where civilization developed, and long tunnels were drilled to intercept ground waters and lead them to underground caves carved out of soft limestone. Most of the tunnels of early man were to bring water from where it was to where man needed it. Then, as now, as man increased his chances for physical survival, he turned to the quality of life -- and this reflected in the concern for life after death. This lead to the elaborate shafts and tunnels for the protection and prservation of the more affluent noblemen and pharaohs of the early Egyptian civilization. Man used the underground for the stable temperature and for protection and safety.

Jan 1, 1974

By Kenneth G. Knight, Frank L. Lynch

It&apos;s 12:30 A.M. The day before had been a long one with problems ranging from proper application of shotcrete during cold weather and the follow-on precautions for curing, meetings with city officials to avert a job shutdown because traffic wasn&apos;t being maintained properly and finally a briefing before METRO&apos;s General Manager to bring him up to date on projections for meeting the operational date of June 1975. The phone rings and Officer Jones of the Park Police says "Mr. Lynch, this lady in the apartments overlooking the jobsite is complaining of noise and she wants the job shutdown". "Officer Jones, have you called the Project Manager or the Resident Engineer?" "Yes, sir, but there is no answer!" "O.K., Officer, I&apos;ll check it out." In calling the job, I can only get the guard, because the inspector is in the tunnel. After some time, the guard calls back and says he doesn&apos;t know the way down into the tunnel. I have since had a difficult time believing that one. In the interim I finally reached the Resident Engineer and explained the situation. And finally at 1:30 A.M. the inspector called the Resident to say that the Park Police stopped the job at 1:00 A.M. because we didn&apos;t respond promptly. A similar situation had occurred some 2 years previously. With great expectation, noise specifications were developed to correct the earlier situation that had occurred. These newly developed specifications were in force at the time of this most recent shutdown. Common sense would tell you that even though we had developed and implemented, we believe, some of the best and most practical noise specifications in construction practice today, we had not enforced them. What caused the shutdown - a noisy

Jan 1, 1974