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By H. S. Price, F. N. Kissell, R. C. McCulloch, J. C. Edwards

"The methane em1ss10n from deep coalbeds which are actively mined is a serious problem facing the mining industry today. Pinpointing the source of methane and predicting the emission of this gas from these coalbeds is necessary if preventive techniques are to be effectively used to control methane emission. In general, because most coalbeds have water associated with them, the system to be studied may be either single-phase (methane gas) or two-phase (methane and water). Because coal mine geometry is complex and the fluids have variable properties as functions of pressure and methane concentration, the differential equations describing the flow of methane and water are not amenable to analytic solution, but must be solved numerically using high-speed computers. This paper presents the development of such a complex mathematical model along with some preliminary applications of the model to methane emission from one- and two-dimensional coalbeds with and without water present."

Jan 1, 1973

By Smith F. A, Both R. A

The application of biogeochemical methods in mineral exploration in the semi-arid to and environment of Western Australia was investiga- ted in an area near Norseman. The reliability of these methods was evaluated by comparing trace element characteristics of rock, soil and plants in the vicinity of the Pioneer BB pros- pect. The prospect is located in the south- western part of the Pioneer Dome, where granite gneiss core is surrounded by a 'greenstone' sequence of ultrabasic, basic and sedimentary rocks. Nickel-iron sulphide mineralization occurs discontinuously along one of the basic- ultrabasic contacts. Analyses of unweathered and partly weath- ered rock from diamond drill cores show the ultrabasic rock to be highly variable with re- spect to nickel, copper, cobalt, zinc and manga- nese. Samples of weathered bedrock and over- lying soil were analysed both for total trace element contents and for the trace elements associated with secondary iron and manganese oxides. Approximately 30 per cent of the total nickel content of the weathered basic rock is associated with secondary iron and manganese oxides, compared to approximately 15 per cent in the weathered ultrabasic rock. The soil is partly transported but has a residual component sufficient to provide a reli- able indication of the underlying rock chemistry, although the trace element content of the soil is less variable than that of the rock. Total

Jan 1, 1973

By P. J. Finnis

This paper describes the use of wire rope on open-pit mining equipment, giving specifications and examples of the performance achieved. Installation methods are also discussed, making the paper of considerable practical use to mine operators.

Jan 1, 1973

By Zabetakis M. G.

This Bureau of Mines report presents a brief summary of the explosion trends in United States coal mines for the past 160 years. These trends show that in spite of the overall improvements in mine safety, the number of fatalities from ignitions of methane has actually increased in recent years. Suggestions are made of procedures that can be utilized to reverse this trend.

Jan 1, 1973

By J. M. Whiting

"North America has entered a period when greatly increased attention must be given to energy .supply and demand by government, industry and individuals. Such increasing concern about energy will be a long-term phenomenon, accompanied by continuing examination of future resource development and utilization. Those engaged in or associated with mining, a major energy consumer, are likely to experience a variety of problems which are associated with the end of an era of low-cost, virtually unlimited energy supply. Their efforts, furthermore, may be subjected to escalating public and government scrutiny, involvement and control. However, ever-growing recognition of the real and urgent necessity to systematically develop new energy supplies within Canada and the United States will provide unusual challenges and opportunities for those companies and individuals with mining expertise. The vast deposits of coal, tar sands and oil shale provide a relative certainty of supply which only stands to gain in attractive ness with time. In order to benefit from this aspect of certain supply, nevertheless, synthetic fuels will have to be produced at a tolerable cost. This will always require excellent process design and engineering. As synfuels development expands to any significant production level, however, and Jess than ideal reserves are scheduled, the usual geologic-productivity complexities encountered in making ore out of low-value rock will tend to become of prime concern. It is for this reason that the services of experienced mining personnel will be in growing demand in energy production."

Jan 1, 1973

By Carl R. Christiansen

Underground sites have great potential for industrial plants, for warehouses, and for other purposes where above-surface locations are now employed. Subsurface locations have generally been over- looked by industrial planners even though they may offer many features of superiority over the conventional sites. There are many opportunities for industries or warehouses to go underground. New space can be excavated expressly for this purpose or openings in existing mines may be converted to useful space. Another possibility is the pre-planned mine-industrial site, in which a mineral product is mined and marketed as a commercial venture while utilizing a mining plan which will permit rapid conversion of the openings created into active industrial areas while mining continues in the adjacent ground. An underground plant located in chambers created by excavating space in solid rock has many advantages, including low construction costs, low heating-cooling costs, freedom from storm damage or other surface weather conditions, absence of traffic noise and vibration, fireproof construction, low insurance costs, excellent working conditions, easily controlled temperature and humidity, almost unlimited bearing capacity of floors, low maintenance costs, no effect upon surface.

Jan 1, 1973

By J. H. Parliament

"The 15,000-tpd Similkameen open-pit copper mine, 10 miles south of Princeton, B.C., started production during 1972. The two main ore zones are separated by the deep canyon of the Similkameen River, with the Ingerbelle or western deposit being mined first. The location, design and construction of the plant were complicated by the steep terrain and the situation of the orebodies. Mining, utilizing 10-cu.yd electric shovels and 100-ton electric-wheel trucks, is conventional. Closely integrated with the preproduction mining was the construction of a 4-mile section of main highway to bypass the Ingerbelle pit. This entailed a very large fill, placed with mine equipment. Ore is crushed to minus 9 inches, stockpiled and reclaimed for direct delivery to three 32-ft-diameter by 14• ft single-stage autogenous grinding mills, each driven by two 4000-hp motors. Because of the friable ore in the upper part of the mine, 4-inch balls are added, with higher than design throughput attained. Classification is by 91>-inch spiral classifiers and cyclones. The flotation section comprises three parallel lines of ten 400-cu.ft rougher- scavenger cells and a single line of 100-cu.ft cleaner and recleaner cells. Concentrate is transported in end dump, closed trucks to Vancouver for dockside storage prior to shipment to the smelter. Tailings are piped across the canyon on a suspension bridge and through a tunnel to an empoundment area. Water is reclaimed and returned to the concentrator, forming a closed system. Dams are raised with cycloned ands, with the downstream section compacted."

Jan 1, 1973

By J. R. Ross

The extraction and recovery of nitrate from waste solutions generated in the production of titanium were investigated using solvent extraction techniques. Laboratory studies and continuous tests in a small solvent-extraction system showed that up to 98 percent of the nitrate can be selectively extracted by a solution of tributyl phosphate in kerosine. The extracted nitrate can be recovered as nitric acid, at concentrations suitable for reuse, by stripping the loaded organic with water.

Jan 1, 1973

By R. C. Wang

Solid-liquid flow in different pipe geometries was investigated. This investigation was conducted by measuring delivered solids concentration and head loss. The delivered solids concentration was measured to study the effect of pipe geometry on the minimum carrying velocity above which solids do not lag behind the fluid. Head loss was measured to study the effect of pipe geometry on the friction loss. A mathematical formula was developed for determination of the minimum carrying velocity. Darcy-Weisbach's equation and Durand's equation were used for comparison of head losses of pipe shapes. Of the different pipe shapes studied, each having the same interior cross-sectional area, the rectangular pipe with the wide side oriented as the base yielded the lowest minimum carrying velocity at high solids concentrations. The minimum head loss at low velocity and high solids concentration also was attained with this pipe. Although the circular section is known to be the best for transporting liquid only, the present study suggested that pipe geometry is a factor in lowering the operating velocity and reducing head loss in solid-liquid flow.

Jan 1, 1973

By R. R. Schehl

The Bureau of Mines has developed a quantitative Analysis for pyrite in coal by X-ray diffraction that can be accomplished in little more than 1 hour. To minimize the sample analysis time, data processing has been completely computerized with pertinent output information displayed on a VR12 cathode-ray tube display. Use of this computerized system is not only advantageous during the experimental stages of the pyrite analysis project but would also be essential if the X-ray diffraction procedure is accepted as a standard method of analysis.

Jan 1, 1973

By Theodore H. Eyde

The porphyry copper province of the southwestern United States and northern Mexico, is the largest copper producing region in the world. Most of the deposits occur in Arizona which now produces over 54% of the newly mined copper in the United" States. As the many recent discoveries are brought into production, Arizona's share of the nation's copper production will increase. The term "porphyry copper" as used in this paper includes all deposits of generally low grade disseminated copper mineralization amenable to bulk mining techniques. Therefore, copper deposits such as Pima-Mission, Twin Buttes, and Vekol where the copper mineralization occurs principally in the intruded rocks will be considered as "porphyry copper" deposits. Most of the deposits have been discovered since World War II, consequently, the southwest, and particularly southern Arizona is perhaps the most intensively explored area for copper deposits on earth. Most of the major natural resource companies in the United States and Canada maintain exploration offices in southern Arizona. To illustrate the success of exploration efforts, the location of porphyry copper deposits either known or producing prior to World War II are shown on figure 1 and the deposits discovered since World War II which are either in production or in the exploration and development stage are shown on figure 2.

Jan 1, 1973

By Donald E. Redmon

This Bureau of Mines report examines the injury experience in the quarrying industry for the years 1968-69. Twenty-eight tables for each year are presented in which disabling work injuries are summarized by department, source of injury, extent of disability, part of body injured, and nature of injury. Correlative information on employment, worktime, and operating activity is also presented.

Jan 1, 1973

By Thomas F. Joyce

N L Industries, Inc., MacIntyre Development produces ilmenite and magnetite concentrates from its own open pit operation at Tahawus in New York's Adirondack Mountain region. The ilmenite concentrate is used within the company for the production of titanium dioxide pigments and the magnetite concentrate is sold to heavy media processors. Current production is from South Extension mine, loading by by six-yard Marion electric shovels into 85 ton Lectra Haul trucks. Bench heights are 44' and are drilled with a Robbins Rotary 9 7/8" diameter hole on 25' spacing for a yearly production of 3.4 million total tons of rock. The ore deposit occurs in veins dipping on the average at 40 degrees to the west. The ore body, which is divided into three zones, outcrops at surface and continues to depths of 800'. Zone 1 is a high grade band of thickness 150-200' with an Fe/Tio2 ratio of 2. Below this band is Zone 2, a low grade band of thickness 50-100' with an Fe/Tio2 ratio of 2 and beneath that seperated by a band of anorthosite is Zone 3, a high grade band of irregular thickness 50-450' with an Fe/Tio2 ratio of 1.6.

Jan 1, 1973

By Charles C. Boley

Using bench-and pilot-scale coking facilities, the Bureau of Mines produced experimental coke from blends of char with Sunnyside coal (high-volatile A bituminous) from Carbon County, Utah. At bench scale, additions of char made from lignite improved resultant cokes when concentrations of up to 60 pct were used in the blends. At pilot scale (500-pound movable-wall oven), four chars made by entrained-bed carbonization techniques from the parent Sunnyside coal and from a North Dakota lignite were used in two-component blends with the Sunnsyide coal. Chars from Sunnyside coal had volatile matter contents of 5.8, 9.8, and 16.0 pct, moisture-free basis; the char from the lignite had 16.6 pct. In twenty-five 500-pound tests, improvement in coke quality was observed from all blends at char concentrations to 17.5 pct. The best coke, produced from a concentration of 12.5 to 15 pct of S.8-pct volatile char, exhibited physical properties approaching those of an industrial coke produced from Sunnyside coal blended with three higher rank blending coals. Studies were also made of the effects on coke quality of char source, of particle size, of comparative use of char and of a blending coal, and of prolonged coal storage.

Jan 1, 1973

By G. M. Ritcey

The recovery of copper from low-grade solutions res ulting from dump leaching is well known, whereas the recovery from highly concentrated copper solutions has not been practiced. This paper discusses the use of Ashland Chemical's Kelex 100, a substituted quinoline, for the recovery of copper from solutions resulting from leaching copper-nickel concentrates. A flow sheet is described, and an economic comparison shows Kelex 100 to be superior to either the LIX 64N or LIX 70 reagents of General Mills for the recovery of copper.

Jan 1, 1973

By H. W. Smith, N. Ichiyen

A convenient method for the calculation of metallurgical balances, based on statistical treatment of all available data, is presented. An error analysis is included. Examples show the advantages of the method, and also that such balances are less precise than might be supposed.

Jan 1, 1973

By John H. Bassarear

The never ending search for lower unit costs led Pima Mining Company's management to study various alternatives shortly after Expansion III was completed. It soon became apparent that a considerable amount of ore assaying 0.35% copper had to be moved in order to maintain mill feed at the desired 0.54% copper content, which is the overall grade of the ore reserves. Detailed investigations revealed that for a period of 8 - 10 years, about 14,000 tons per day of 0.30 - 0.40% copper ore would pass by the crusher en-route to the low grade stockpile. This ore is very hard, very clean and has to be mined at a relatively uniform rate. A six month pilot plant run testing autogenous and semi-autogenous grinding gave very encouraging results. Since no mining costs need to be charged to the extra tonnage (it had to be mined anyway) the only major costs would be against milling. The decision to proceed was made in August 1970 and Fluor-Utah was retained as the prime design construction contractor. Ore was first put through the new mill on December 29, 1971. By March of 1972 design tonnage of 14,000 TPD had been attained. The first three expansions at Pima Mining Company, 20 miles south of Tucson, increased mill capacity from 3,000 TPD to 36,000 TPD. These expansions included a separate, conventional, three stage crushing plant plus additions to the existing concentrator that primarily duplicated the then current flowsheet. Expansion IV, however, consisted of an entirely new and separate primary crusher and a completely new mill building located about 2,000 feet southeast of the 01 d concentrator. The new mill, using semi-autogenous grinding, produces scavenger and rougher flotation concentrates that are pumped to the old mill for regrinding, cleaning, thickening and filtration.

Jan 1, 1973

By Green R. E.

The removal of silica from commercial iron oxide concentrates by dissolution with sodium hydroxide was investigated by the Bureau of Mines as a means for producing supergrade concentrates. The effects of strength of solution, temperature, and digestion time on the extraction of silica were evaluated using eight iron oxide concentrates. Silica extraction from the eight concentrates was enhanced by autoclave leaching in the temperature range of 150° to 250° C and varied from 70 to 95 pct depending on the concentrate used. Superconcentrates containing less than 2 pct Si02 and more than 69 pct Fe were made only when magnetite concentrates were leached in the autoclave. The investigation showed that it is not difficult to obtain a supergrade product if the gangue is mainly quartz.

Jan 1, 1973

By J H. Dressel, J. E. Williams

This paper presents a brief review of what coal gasification is, procedures that are available today and processes that may be available in the future. Examples are given as to how the process might be used in power plant applications, the effect on pollution level and power costs, and some thoughts on the added burden that might be placed on mining and coal preparation.

Jan 1, 1973

By Yung Sam Kim

The study of ultrasonic-wave propagation in substances has been remarkably advanced in recent years in most engineering and science fields. The main object in studying the velocity of ultrasonic-wave propagation in solids, is to determine dynamic properties of these materials. The present paper, however, presents some other possible applications of ultrasonic-wave propagation in the study of rock mechanics as follows: Investigation of the mechanism of microseismic activites of geologic materials, (a) at initial or low stress level, (b) at final or fracture stress level, and (c) under fatigue loading condition. Also, correlations among stress level, density, and the velocity of ultrasonic-wave propagation in rocks are discussed in this paper.

Jan 1, 1973