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By R. G. Reddy

The effect of solid particles on viscosity behavior of Na2O-O-B2O3-SiO2 melts of composition XSio2/XNa2o =0.5 and in the temperature range of 900- 1150 K was studied. Samples were analyzed by X-ray diffraction and optical microscopy. The results showed that a crystalline phase (NaBO2) was formed and its amount increases with decrease in X,, from 0.50 to 0.25. The experimental viscosity values were compared with the predicted values using our viscosity model developed earlier. At low temperatures, for low content of B2O3 , the experimental values exhibits a large deviation from the predicted values. It was concluded that the deviation was due to the formation of solid particles in the molten slags. The existence of these solid particles increased the viscosity values significantly. A new viscosity model was developed to include the effect of solid particles.

Jan 1, 1993

By Catharine T. Fogg

The U.S. Bureau of Mines investigated the availability of platinum, palladium, and rhodium from 16 deposits in four market economy countries (MEC's). Major recoverable products include 164 Moz of platinum, 80 Moz of palladium, 13 Moz of rhodium, 24 Moz of ruthenium, 4 Moz of Iridium, 2 Moz of Osmium, and 10 Moz of gold. The 12 deposits in the Republic of South Africa are estimated to account for 96.7 pct of total recoverable platinum. The base-case scenario estimates the long-term cost of production including recovery of capital, but provides no return on the investment or O-pct discounted cash-flow rate of return (DCFROR). The total production costs in January 1990 U.S. dollars ranged from $325/oz to $1,288/oz of platinum compared to an average January 1990 price of $492/oz. Approximately 83 pct of total recoverable platinum was economic at a cost level of $4S0/oz or less. At the IS-pct DCFROR, only 26 pct of total recoverable platinum was economic. For platinum-group metals (PGM), attention has been focused on the ratios of the three primary metals: platinum, palladium, and rhodium. Sensitivity analyses were performed to determine the impact long-term rhodium price increases could have on the total cost of production for platinum and palladium.

Jan 1, 1993

By Saurabh Rastogi, Vikram Shishodia, B. Pitchumani

Comminution is a unit operation which consumes major part of energy in mineral processing industries such as fertilizer production. Ball mills are widely used for size reduction of a given ore to the liberation size that is required in further beneficiation processes. In grinding of materials much effort is concentrated on control of top size of the product and this results in production of fines, also creates secondary problems of pollution due to the difficulty in the collection of fine particles. The present work has been carried out to control product size distribution for rock phosphate grinding in an Industrial Ball Mill of 600 TPD. The plant data are taken for a given feed distribution and mill operating conditions. The information at various Ball Size distributions are collected. The comminution functions such as specific rate of breakage and breakage distribution functions are estimated by back calculation technique to solve the mass balance equation. A simulation program is written to study the product size distribution obtained for various ball size distribution.

Jan 1, 1993

By S. C. Suboleski, R. Zhao

A Simulation/Animation Model (SAM) with several unique features has been developed for continuous mining in room-and-pillar production systems. Initial cut data are generated by the program based on a short list of general section parameters, and is graphically displayed on the screen for checking and editing. This portion of the program includes several intelligent features. For example, a different cut sequence will be generated for uni-directional section ventilation than for bi-directional flow. Once the data are accepted, the entire simulation may be viewed in animation. Effectively, much of the data are checked visually by watching the actions of the mining equipment. Following the simulation, results are summarized as bar and pie charts, as well as printed output. In addition to the extensive use of graphics, the program contains several advances in simulation techniques as well.

Jan 1, 1993

By Dal Sun Kim, Michael K. McCarter

"Comminution (crushing and grinding) of rock materials is energy-intensive and expensive. Mucheffort has been directed to improve the efficiency of conventional milling practice, but relatively littleattention has been given to the potential benefits of blast-induced damage on comminution processes. To help assess this effect, research has been conducted at the IRECO Laboratory and the Generic Center for Comminution at the University of Utah. The objective of this research is to investigate the effect of shockinduced “crack-like” damage on rock properties and subsequent breakage efficiency for three petrologically different rock materials under laboratory conditions. In order to evaluate the effect of shockinduced damage, a quantitative measure of rock damage is needed. For this purpose, a scalar variable (0) is proposed."

Jan 1, 1993

By G. Mbuyi Kamba, J. Patigny, E. Jacques

Traverse anemometry is still widely used today. In this paper an investigation of the influence of three factors which are believed to contribute to the resulting error of the method, is reported. They are the shape of the traversing path, the size of the vane anemometers and the air velocity pattern. These factors are experimentally studied on a test facility developed specially for this purpose. Taking into account the results of 576 measurement sessions, as well as published information, some preliminary conclusions are drawn, and additional questions are raised.

Jan 1, 1993

By Baxter D. A

This paper, one of two written about the Queensland Railways Brunswick Street tunnels presented at the VIII Australian Tunnelling Conference, 1993, describes the design and monitoring aspects of the railway tunnels built between Central Station and Brunswick Street Station.The design was mainly influenced by the need to minimise settlement of buildings above the route. The performance of the design details and the monitoring of the tunnels are briefly described.Appendices include extensions to the work of Curtis in the analysis of circular tunnels in a viscoelastic ground.Reference: Asche, H R and Baxter, D A, 1993. Design and ground support monitoring of the Brunwick Street rail tunnels, Brisbane, VIII Australian Tunnelling Conference.

Jan 1, 1993

By Y. Topkaya, R. E. Johnson, B. R. Palmer, R. B. Bhappu, Ronald J. Roman

The hydrodynamics of the leaching solution in leach heaps is known to be one of the important variables in the performance of the heap. The solution hydrodynamics are also important in the decommissioning of a heap where the aim is to flush out the residual dissolved metals and the remaining reagents. Chemical engineers have studied the hydrodynamics of "trickle bed" reactors for 40 years in an attempt to relate the performance of trickle bed reactors to flow conditions. Their work is reviewed with emphases on areas of similarity to heap leaching.

Jan 1, 1993

By C. Bazin

"Discrete transfer functions which use the grinding circuit feed tonnage to predict mass flowrates at reagent addition points in the flotation circuit were calibrated using a dynamic grinding/flotation simulator. Predicted values are multiplied by g/t ratios to calibrate reagent flow. The transfer functions are currently integrated into the distributed control system at Les Mines Selbaie.INTRODUCTIONThe development of adequate tools for the control of flotation processes is a continuous challenge. Since the early 1970's there have been numerous publications dealing with practical applications of flotation process control. A review of that literature shows that basic feedback and feedforward controls are the two preferred strategies for flotation processes. Some advanced control schemes started to emerge (e.g. Zaragoza and Herbst, 1988). Feedforward and feedback aim at reducing the effect of the following flotation process disturbances (e.g. McKee, 1991):0 Changes in throughput;0 Changes in feed grade;0 Changes in particle floatability (size, liberation, surface oxidation ... );0 Deliberate changes of set-point;Feedforward strategy acts on manipulated variables, mainly reagent addition, to attenuate the effect of disturbances such as changes of feed rate and grade. The feedforward strategy is driven by measurements of disturbances. Feedback control acts to compensate unmeasured disturbances, such as ore floatability, and to bring process variables to targeted set-points of concentrate or tails grades. The feedback control action is driven by set-point error, caused by either a deliberate change of set-point or unaccounted disturbances.This paper proposes a way to improve feedforward control schemes by addition of a simple model of solids transportation. The feedforward strategy considered in this paper is of ratio type, i.e. the manipulated variable is changed according to a predefined ratio between this variable and the measured disturbances. A typical example is the ratioed reagent addition to mass flow of ore."

Jan 1, 1993

By Michael S. Wieland

This report discusses the U.S. Bureau of Mines research regarding the desensitization and malfunction of cap-sensitive explosives deployed in underground coal mines. Delay blasting in underground coal generates severe shock waves and rifting forces that fracture and heave coal. These dynamic interactions can damage other charges still remaining in the delay pattern. The debilitating impacts precipitate degrees of reduced charge performance ranging from misfires to weak detonations or out-of-sequence firings. Damaged charges react poorly, perform less useful work, and/or generate atypical fumes with higher toxicity.

Jan 1, 1993

By E. vanHuyssteen

A method of establishing the relationship between the mineralogy of a sinter and its subsequent processing behaviour in a lead blast furnace is demonstrated. It involves: 1) analyzing the Zn-spinels, hardystonite, larsenite, Pb-silicates, Pb-arsenates, Pb-(Ca)-sulphates and other femtes with an electron microprobe; 2) determining the extent of elemental substitutions in various mineral structures; 3) establishing a sequence in which the various phases formed during sintering. In this manner the relationship between the bulk chemistry of a sinter formulation and the speciation of elements into various phases in the sinter can be established. Specifically, the-substitution of Mg for Zn in hardystonite significantly influences sinter production. Mg substitution releases Zn into the surrounding matrix. This Zn reacts with the Pb-silicate to form larsenite thereby reducing the amount of Pb-silicate available for anhydrite digestion. Excessive amounts of residual anhydrite thus result if the sinter formulation is based solely on the CaO/Si& ratio.

Jan 1, 1993

By J. R. B. Lima

The present work emphasizes the selection in the separation of the apatite/calcite by the direct anionic flotation versus the double flotation, with a reverse second stage of the Jacupiranga phosphate ore. The double flotation would allow the obtaining of two concentrated solutions: one of them mainly constituted by a calcium carbonate material (CaCO3) and the other one, phosphatic (apatite). The calcium carbonate concentrated solution is used for the production of cement. The presence of phosphatic material in the calcium solution is not desirable, phosphor being a harmful element to cement. On the other hand, smaller quantities of calcite in the phosphate concentrate would represent a substantial economy in the processes of production of phosphated fertilizers. These processes make use of sulfuric acid to the solubilization of the apatite and the presence of calcium material consumes acid. Also that, when carbonates are solubilized, unwanted products are formed resulting in losses in the process and diminishing the quality of the fertilizer produced. These characteristics are discussed in the paper and are compared to another Brazilian phosphate ore, the reverse route of which can be considered more adequate. The results are discussed according to recent discoveries, and special emphasis is given to the use of corn starch and its crucial role in promoting the selection in the direct flotation process.

Jan 1, 1993

By Onal G, Celik MS, Dogan MZ

Chromite tailings assaying 21.2 per cent Cr2O3 was upgraded to 48.7 per cent Cr2O3 at a recovery of 72.0 per cent using column flotation with a mixture of anionic collectors at pH 11. Electrokinetic methods were used to elucidate the mechanism of collector adsorption and correlate the findings with the optimum flotation conditions. Multivalent constituent ions such as Cr3+, A13+, Fe2+ and Mg2+ were found to adsorb on chromite surface and shift the zpc of chromite in the direction of oxide form of the mineral. The anionic collectors also imparted a negative charge to chromite in the entire pH region. The higher zeta potentials obtained upon adding the anionic collectors is ascribed to the adsorption of anionic surfactant onto the positively charged chromite surface. The positive sites are generated through formation of significant amount of hydroxy complexes of magnesium at pH 11. Complementary infrared data reveal the absence of a shift in the spectra indicating the possibility of physical adsorption in the system.

Jan 1, 1993

The South Junction deposit of St Barbara Mines Limited was discovered in 1989 by the geologists of Ross Atkins Mining.The deposit occurs in the lower part of the Gabanintha Formation of the Lukes Creek Group in the Mt Magnet -Meekatharra greenstone belt. Country rock is predominantly talc-chlorite schist. Gold mineralisation is associated with north-south shear zones, quartz-carbonate-fuchsite alteration of the ultramafic rocks and in particular close to deeply weathered quartz-albite porphyry. For a detailed description of the geology of the South Junction Deposit see Fiala (1992).

Jan 1, 1993

By Warren M

Many Australian tunnelling and mining companies regularly investigate different methods or equipment in an attempt to keep ahead of their competition. Sometimes the result is a new approach or process which wins a tender or provides an advanced solution to a problem.The Australian Government has a policy of encouraging forward thinking among Australian companies and provides a range of incentives. One of these incentives is currently available retrospectively to 1985 - 86, and the registration process is relatively simple with only one form to be completed. Companies who investigate methods of raising productivity could be reimbursed for the costs of the investigation.

Jan 1, 1993

By R. S. Farinato

Thionocarbamate flotation reagents have enjoyed a niche position in the recovery of copper sulfides and activated sphalerites since their introduction in the mid 1950's (Harris, 1954). Thionocarbamates containing an allyl group (-CH2- CH=CH2), introduced recently Lewellyn, 1985; Nagaraj, 1988; Avotins, 1991), are used commercially as collectors for copper sulfides and activated sphalerite. Laboratory flotation tests and plant usage have demonstrated that allyl-containing thionocarbamate collectors exhibit certain unique properties that distinguish them from the corresponding dialkyl thionocarbamates. Spectroscopic (FTIR, XPS) and wettability studies of N-allyl iso-butyl thionocarbamate (AIBTC) and its saturated analog N-propyl iso-butyl thionocarbamate (NPIBTC) adsorbed on copper at pH 9 were performed in order to investigate whether there were any fundamental reasons for these differences. Flotation tests were carried out on chalcocite, copper ore and an activated sphalerite.

Jan 1, 1993

By Finch W, Dunne R

Understanding how liberated and unliberated minerals behave in comminution and classification circuits is of vital importance to ensure that maximum liberation occurs without unnecessary and costly overgrinding. This paper presents the results of a study carried out by the Julius Kruttschnitt Mineral Research Centre and Newcrest Mining of the liberation performance of Newcrest Mining's New Celebration grinding circuit. Using data from surveys of the circuit, together with QEM*SEM analyses of individual streams, a detailed picture of the liberation and classification of gold-associated pyrite is presented. In addition the relationship between the QEM*SEM analyses and results from laboratory leach tests are also discussed. Using the survey and QEM*SEM data, mathematical models were constructed of the performance of the ball mill and cyclones, and simulations carried out to investigate ways of improving the performance of the circuit. The results from the more promising scenarios are Reviewed.

Jan 1, 1993

By Jankowski P

The Bannockburn gold deposit is located 67 km north-west of Leonora in a poorly exposed part of the Norseman-Wiluna belt of Western Australia. The deposit consists of narrow, complexly shaped orebodies which have presented a challenge to find successful grade control and mining methods. The deposit also presents an opportunity to examine in detail the geology of this part of the Norseman-Wiluna belt.This paper discusses the geology and structure of the Bannockburn gold deposit as well as the grade control and mining systems developed to define the ore and extract it with minimum dilution. We discuss the different techniques employed for grade control in the past and their shortcomings, and the evolution of the present system of doing grade control in cross section from blast hole assays.

Jan 1, 1993

By J. R. Goode

The first part of this paper comprises a general discussion on refractory gold ores and their mineralogy processing methods now in use are reviewed and test procedures for the important methods are discussed. Factors determining the selection of a process are outlined. The paper includes a survey of production plants using pressure oxidation, roasting and biological oxidation to process refractory ore. The status of processes under development is briefly reviewed.

Jan 1, 1993

By Robert L. Brooks

This paper is intended for companies at all levels of the Explosive Industry and in particular, those that do not have a risk manager. It is strictly informational in nature and no reference is made, or intended towards any existing insurance company or agency.

Jan 1, 1993