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By S. K. Kawatra

Many mineral oxide and multi-component oxide (basalt) specimens break down into powders upon expo-sure to sodium vapor at elevated temperatures for extended times. This paper examines several possible mechanisms of oxide breakage by sodium vapor, both experimentally and from a thermodynamic viewpoint. The oxides for which reduction by sodium was thermo-dynamically favorable all exhibited some degree of fragmentation. The oxides which were not favorable for reduction by sodium did not exhibit fragmentation, with the exception of rutile, a titanium oxide. The rutile fragmentation was caused by the reduction of iron that was in solid solution in the rutile crystal structure.

Jan 1, 1995

By Fred N. Kissell

This U.S. Bureau of Mines report is a guide for the control of air contaminants during tunnel construction. Topics discussed are calculating air quantity requirements, types of ventilation systems, planning ventilation systems, control of methane gas, control of dust, control of diesel emission, ventilation to remove blasting fumes, measuring airflow, and measuring gases. This report does not provide detailed design information, but seeks to answer practical questions on air contamination issues.

Jan 1, 1995

By E. Burgos Cruz

The behaviour of S, N and P during refining of Fe-18 wt%Cr-10 wt%Ni with calcium carbide was investigated. The effects of the initial contents of C and N in the metal phase, as well as the supply method of calcium carbide to the melt on the removal degrees of S and P were evaluated. Heats were carried out at 1873K, in MgO crucibles, using a laboratory induction furnace. It was observed that simultaneously with S and P, N and O have also participated in the reactions. It seems that, in fact, O governs the behaviour of the other elements dissolved in the melt and that N is had to the removal of P with calcium carbide. It was also noticed that high C content in the metal phase have not altered the dephosphorization and desuffirization degrees, but that the supply of calcium carbide done by injection led to a lower dephosphorization degree than the one obtained by dumping it.

Jan 1, 1995

By A. Benchekroun

The phosphate mining industry is confronted everywhere in the world with financial difficulties and low prices which prohibit further investments and development of new mines even in regions with a comparative cost advantage (North America/ North Africa/ and Middle East). But old mines are being progressively exhausted/ and if no replacement mines come on stream in the near future/ we may soon find ourselves (around the year 2000) with a global annual production capacity of 160 million tonnes of marketable phosphate rock instead of the capacity of 200 million tonnes existing today. Unless prices improve/ phosphate rock/ a non-renewable resource and a vital commodity to world agriculture/ may turn to be in short supply to world fertilizer industry. Whatever the extent of recovery of fertilizer demand/ the expected decline of the production capacity during the 1990 I s is bound to cause the disappearance by the year 2000 of the important surplus characterizing today the supply/demand balance.

Jan 1, 1995

By Richard N. Snyder

In this system for connecting blasting caps to the initiation source, the need for a redundant design structure provides more reliable method of explosive initiation. This is accomplished by using a complete system starting at the blasting control, through the initiation line structure through the initiation line and connecting blocks to the blasting cap. The connecting structure between the initiation device and the blasting caps may be connecting blocks or other means.

Jan 1, 1995

By Eugene R. Palowitch

From the late 1880s to the present, the Appalachian region continues to be a dominant supplier of premium-quality coals. The region contains an estimated 93.4 Gt (102.7 billion st) of demonstrated reserves in Alabama, eastern Kentucky, Maryland, Ohio, Pennsylvania, Tennessee, Virginia and West Virginia. Therefore, Appalachia will remain a source of quality coals for the metallurgical, export and utility markets. Figure 1 shows the annual production of coal in Appalachia and nationally from 1970 through 1993 (Energy Information Administration, 1994). During that 23-year period, annual domestic coal production almost doubled. Coal production from Appalachia increased at an average annual rate of only 0.7%. Coal production remained essentially constant at about 409 Mt/a (450 million stpy). Thus, Appalachia's market share decreased from 69.8% in 1970 to 47.2% in 1993 - a drop of almost one-third (Energy Information Administration, 1994).

Jan 1, 1995

By E. R. Bauer

The ground control aspects and occupational safety concerns of extended depth-of-cut mining are presented in this U.S. Bureau of Mines (USBM) report. The scope of extended cut use and typical face operations while extracting extended cuts is reported. A comparative review of roof fall fatalities and a statistical analysis of accidents and injuries for both extended and nonextended cut mining is included. The views and opinions on extended cutting from a series of interviews with mine workers in five states are summarized. In addition, some of the problems and safety concerns of this extraction system are mentioned.

Jan 1, 1995

By M A. Etheridge

The evolution of economic precious metal and copper-gold deposits in high-level igneous terranes is dependent on very efficient fluid focussing. This is most readily achieved by contemporaneous deformation, igneous intrusion and hydrothermal activity. Mineralisation in these environments generally occurs in fault and fault-vein arrays developed in the cover sedimentary and volcanics sequences above older regional scale fault systems. Such reactivated fault systems are particularly prone to developing tile complex fracture arrays, extreme local dilation and dramatic increases in permeability that are necessary to efficiently focus hydrothermal fluid and produce large mineral deposits. The arc systems of tilePacific rim are typically structurally and tectonically complex. At any given period in the evolution of an arc system, it may be dominated by extensional, compressional or strike-slip deformation. Indeed, it is common for the tectonic environment to change repeatedly through the development of a single arc segment. As a result, structures formed in one tectonic environment are commonly complexly reactivated in quite different environments later in arc evolution. These complexly reactivated structures have greater potential to localise extreme fracturing, dilation and fluid flux than primary structures. Application of this knowledge to practical exploration requires an understanding of the primary geometry of the controlling fault systems, the fault movements during reactivation, intrusion and mineralisation, and the consequent location and geometry of dilational sites. Simple 2D lineament analysis and targeting on lineament intersections does not suffice. Chemical processes that results from structurally focussed fluid flow may also contribute to permeability enhancement and further enhance fluid flux. Two main types of chemical feedback are important. The first involves selective dissolution of minerals during alteration and tile consequent production of increased porosity and permeability. The second occurs where alteration changes the mechanical properties of tile rock mass, especially where it leads to a greater propensity for fracture (eg by silification). In near-surface environments (< ~1 km), geomorphic processes complement fault systems in focussing fluid flow to develop sub-horizontal bodies of mineralisation, such as the giant Ladolam gold deposit (>42 million ounces of gold).   Along with classification schemes which stress crustal level, host rocks and alteration assemblages, the styles of high level 'epithermal' and reated deposits must also be considered in respect of their controlling co-active fault structures. Such structural understanding, combined with understanding of tile chemical processes involved (eg host rock reactivity), provides a major tool for exploration particularly in terrains obscured by deep weathering. Geological interpretation based on integration of field mapping with magnetic, radiometric and other remotely sensed imagery provides a powerful complementary tool to the traditional geochemical and geophysical targeting techniques. Timely and effective geological input is capable of reducing exploration risk and providing a more cost-effective basis for drilling and development. Examples of deposits associated with fault reactivation in extensional, compressional and strike-slip settings within arc systems are discussed in this context.

Jan 1, 1995

By Guiseppe Bonifazi

This work applies the definition of "separation function" already introduced in the paper presented at the XVIII IMPC. This 'function" (defined for a certain size distribution after comminution of an ore) refers to the recovery distribution of a mineralogical species in a product made up of all the particles having at least a given content of that species. Many tests would be required to determine the liberation function for each mineralogical species, particularly for complex ores. Several stages of comminution would need to be examined and the mineralogical composition of the particles of each grain size class would need to be analyzed for each process step. A quick and dirty method is shown for obtaining the "separation function". It is based on the processing of data from topological maps of polished and/or thin representative sections of ore. By superimposing grids of different sizes over these maps and with appropriate combinations of mesh sizes, it is possible to simulate the grain size distributions linked to different stages of comminution and then evaluate the mineralogical composition of each grain. The procedure is carried out full automatically and can simulate a complete treatment circuit, imposing cut-off grades for the products at each separation phase. It is also possible to predict the results of treatment processes that involve grinding phases. The procedure has been successfully applied to complex ores containing several useful components.

Jan 1, 1995

By A. I. Kogut

Impurity minerals in fluorspar ores and concentrates from a deposit in Southern Africa have been studied by reflected light, transmitted light, and cathodoluminescence microscopy. The principal impurities are quartz, calcite, aegirine, apatite, ankerite, magnetite, goethite, and synchysite [Ca(La,Ce,Nd)(CO3)2F]. Cathodoluminescence microscopy was found to be very useful in studying the character of the fluorite and especially for recognizing the presence of apatite and calcite impurities. Fluorite exhibits blue, calcite shows yellow, and apatite has white, light purple, and pink cathodoluminescence. The cathodoluminescent character of apatite varies with its geological environment and position in the orebody. The results of this microscopic study show that phosphorus present in fluorite concentrates occurs principally in binary locked apatite-fluorite particles. Successive fluorite cleaner concentrates contain progressively smaller amounts of locked apatite-fluorite particles. Free apatite has been effectively partitioned to the final tailings.

Jan 1, 1995

By Y. C. Guan

The cementation of gold on to copper and zinc in ammoniacal solutions has been studied using rotating disc electrodes. The cathodic reduction of aurous ammine was studied on a gold rotating disc electrode and the anodic dissolution of copper and zinc was studied in the absence of aurous ammine. The cementation rate was found to be a first order with respect to the concentration of aurous ammine and to be proportional to the square root of the disc rotating speed. Based on the results obtained, it was concluded that the cementation reaction was controlled by mass transfer of aurous ammine to the reaction surface under the experimental conditions.

Jan 1, 1995

By Denby B

The ever increasing demand on land use has led to large areas of land being considered for development, which because of past mining activities are covered by substantial depths of fill materials. This paper examines the problem faced with the development of land infilled with open cast mining backfill, in predicting the behaviour of the fill upon development. To be able to design foundations suitable to withstand the movements that occur within open cast backfills or design a backfilling operation that produces land suitable for a proposed after development, a means of predicting backfill settlement is required. Factors critical to this prediction are the timing of backfilling operations, the compactive state of the backfill and the inundation of the backfill. The analysis of a considerable quantity of data collected from the monitoring of backfilling operations and backfill movement at a range of open cast coal sites located within the UK has given the authors a better understanding of how open cast backfills behave in terms of long-term creep settlement, collapse settlement and how these are effected by backfill scheduling. This knowledge has been encoded into a program running under Microsoft Windows that enables a user to make settlement predictions for a point, a given section or area or for the whole site. Differential settlements, critical to any development design, can also be determined between any two points taking into consideration the heterogeneous nature of open cast backfills. The program was tested with data from an open cast coal site in the UK. Compaction monitoring during the placement of the backfill material enabled a model of the backfill to be constructed taking into account backfill properties and scheduling. This model, taken as input into the program, enabled future backfill settlement predictions to be made. A comparison is given between these results and actual settlements obtained from a short-term settlement monitoring scheme.

Jan 1, 1995

By P. C. O. Chukabarah

Many aerodynamic and thermodynamic properties (such as temperature, pressure, velocity and density) vary widely, and in random spatial and temporal manner for a given underground mine environment. Such variabilities are seldom evaluated statistically, even though the relevant theories and principles are both available and feasible. The main purpose of this paper is to introduce the methodology for applying aerostatistics to the analysis of multiple fan systems in mine aerology/ventilation. Pertinent data were obtained from a small multi-level European coal mine. Results confirmed that aerostatistical methodologies are computationally more efficient. Being grounded in solid engineering statistical theories, they can be used to analyze networked parameters in mine environmental engineering.

Jan 1, 1995

By Richard Hogg, Heechan Cho

Investigations of long-time grinding of fine quartz (to about 80% passing 0.35 pm) in a 0.6 liter stirred-media mill are described. Breakage rates and primary breakage distributions have been determined based on extensive characterization of the ground products by laser scattering/diffraction and gas adsorption. The results indicate that, while there is qualitative similarity between the breakage parameters for ultrafine and conventional (coarse) grinding, there are important, quantitative differences. In particular, it is found that primary breakage distributions become significantly narrower in the submicron sizes. The trend can be described using double-truncated log-normal distributions in which both a maximum (breaking) size and a grind limit are specified. The breakage distributions become progressively narrower as the size being broken becomes finer. Breakage rates follow a typical, consistent pattern in which the rate decreases with size according to a simple power law. Further decrease in the rates seems to occur after very long grinding times when the entire mill contents become finer than about 1µm. The effect is explained as a result of changes in the rate/size relationship in the submicron range.

Jan 1, 1995

By E. L. Gillenwater

Coal mine planning has three distinct decision levels: (1) decisions made at the upper level of management that determine production requirements for specific mines, (2) decisions made at the middle management level, the mine level, that determine how the mine satisfies its production requirements, and (3) decisions made at the operating level of management, the sectional level, that determine the sequencing of machine movements at the face. In this paper, the underground production scheduling problem is formulated in multi-stages using the Hierarchical Production Planning (HPP) approach. Two linear programming HPP models for accomplishing decisions at the first two levels are developed. Both models address the aggregate production planning process. The Mine Production Scheduling (MPS) model permits determination of monthly production and inventory levels. The Section Production Scheduling (SPS) model incorporates a quality blending requirement into the determination of weekly sectional production and inventory levels.

Jan 1, 1995

By R. J. Kriek, J. J. Cruywagen, W. J. Engelbrecht

Selective photo reduction, using the semiconductor TiO2 under UV irradiation, has been investigated as a possible recovery and/or separation method for the PGM's rhodium, palladium and platinum. The effect of pH value and concentration of the sacrificial reducing agent (ethanol) on the rate of reduction of Rh (III), Pd (II) and Pt(IV) ions have been determined separately for these ions as well as for some mixtures. Conditions favourable for the reduction and adsorption (or precipitation) on TiO2 have been established. It has been found that already deposited Pt or Pd metal promotes reduction of Rh (III) ions at a pH value where it would not otherwise be reduced. A method for the separation of a mixture comprising Rh (III), Pd(II) and Pt (IV), based on photo reduction and adsorption on the TiO2, is proposed.

Jan 1, 1995

By D. R. Boyle

"The Murray Brook precious metal (Au, Ag) gossan deposit is one of nine supergene mineral deposits that have developed over polymetallic massive sulfide deposits in the Bathurst Camp of New Brunswick. Reserves consist of 1.9 Mt of gossan containing 1.53 g/t Au and 65.9 g/t Ag. The supergene zone at Murray Brook consists of six distinct units: a) altered massive sulfide, b) pyrite-quartz sand, c) massive sulfide gossan, d) disseminated sulfide gossan, e) ferruginized wallrock, and f) leached bedrock. The massive sulfide gossan constitutes the main body of economic mineralization and consists of goethite, primary quartz, secondary amorphous silica, K-Fe-Pb-As- Sb-Ag hydrated sulfate and oxide minerals (beudantite, plumbojarosite, jarosite, bindheimite, scorodite), trace cinnabar, and cassiterite of primary origin. The order of stability of sulfide minerals during oxidation was pyrite _ arsenopyrite _ galena _ Bi-Sb sulfosalts _ chalcopyrite _ tetrahedrite group _ sphalerite.Two mass balance techniques (isovolumetric and conservative element) indicate elemental depletion in gossan relative to primary ore in the order: S>Cd=Zn>Cu=Mn>Na=Ca>Fe=Al=V> Mg= K=Se=Hg>Pb>Ti>Ag>Mo=P>Ba; and enrichment in the order Au>As>Sb>Si>Bi. Tin, as cassiterite, is conservative.Mineralogic and paleomagnetic data suggest that the gossan deposit formed under a warm temperate climate throughout the Pliocene. The rate of oxidation and the compositional nature of the ore was significantly influenced by: a) the position of the primary sulfide zone in a downward moving hydrological system, b) primary sulfide composition and zonation that promoted the development of a strong electrochemical oxidation system, and c) pronounced intercalation of carbonate and sphalerite mineralization in sulfide zones, which promoted rapid development of secondary porosity, permeability and downward flow of oxygenated groundwater.During progressive oxidation and physico-chemical erosion of the gossan zone, Au was transported downward in groundwaters, probably as a Auo colloid complex, to be concentrated in the lower horizons of the gossan profile. The precipitation of Au was greatly increased in the pyrite/arsenopyrite zones. Gold concentration was multi-cyclic with continual dissolution and nucleation of the metal until final concentration in the void structures of the gossan. Leaching experiments and microprobe analyses indicate that Au is present in the gossan as submicron composite sols of Au-Ag-silica."

Jan 1, 1995

By G. A. Weisenfluh

The successful application of factors limiting the? availability of coal in eastern Kentucky depends on ac-curate assessment of the original resources. Examination of several previous coal-resource estimates for the region reveals significant differences among the outcomes. These differences relate to methods of analysis, biases in data and their utilization, and the problem of defining the lateral continuity of mineable beds. Improvements in the methods of estimating the original resources would greatly enhance the reliability of the results of the Coal Availability Program.

Jan 1, 1995

This paper reviews an analytical model that defines the relationship of weight-weighted or volume-weighted average haulage distance with bench height and other related parameters; presents the optimum bench heights under various conditions in terms of minimising the weighted average haulage distance of ore/waste during the full lifetime of an open pit mine, and discusses the truck-haulage economics of mining open pits by high bench, specifically by 15 m, 18 m and 20 m bench through marginal analysis. The observations from these analyses disprove the previous conflicting assertions that the overall weighted average haulage distance either increases or decreases monotonically with bench height. It is concluded that: (i) an increase of bench height to 15 m from 12 m is likely to be viable under the general conditions of large-scale deep open-pit mines; (ii) the reduction of haulage cost is limited with the case of increasing bench height to 18 m from 15 m; and (iii) the feasibility of mining open pits by 20 m benches is generally questionable. These conclusions may serve as a useful guide for those who advocate open pit mining by high benches.

Jan 1, 1995

By L. D. Snyder, J. K. Russell

"The Lower Jurassic Iron Mask batholith intrudes Upper Triassic Nicola Group volcanic rocks in the Quesnellia terrane of southcentral British Columbia and hosts Cu-Au mineralization. The batholith comprises three mappable intrusive phases, including: Pothook gabbro to diorite, Cherry Creek monzodiorite to monzonite and Sugarloaf diorite. The Iron Mask hybrid forms a fourth mappable unit that makes up to 45% of the areal exposure in the batholith. It is highly variable in texture and composition and subdivided into three types; Type I and II have abundant (partially digested) xenoliths, many of which are derived from the Nicola Group, whereas Type III is xenolith-poor and shows extreme outcrop-scale textural diversity.Pothook and Cherry Creek rocks are similar in texture, mineralogy, whole rock and mineral composition and style of alteration. Contacts between the two can be intrusive or gradational. Rocks collected from these two suites have compositions that are permissive of a single magma batch, although simple crystal fractionation does not explain all chemical variations within and between the two suites. The Sugarloaf unit comprises a diverse group of amphibole-phyric rock types and is texturally and mineralogically distinct from Pothook and Cherry Creek suites.The Iron Mask hybrid represents progressive stages of physical and chemical interaction between Nicola Group country rocks and Pothook magma. Magmatic assimilation (selective or partial) is supparted on the basis of field relationships, petrographic observations, and REB compositional data. Thermal dehydration and partial assimilation of Nicola Group rocks by Pothook magma is shown to be a valid means of promoting early and extensive volatile saturation in the Iron Mask batholith."

Jan 1, 1995