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By Zhuang Jianming, Liu Qinxia, Yuan Mingliang, Mei Xiangong, Chen Jin

Up to now, the leaching of manganese carbonate ore is usually performed at high temperature of 363K and the leaching rate is lower than 90%. Although in laboratory test, the leaching rate is only 90%. This paper introduced an improved method for leaching of manganese carbonate ore. Certain ammonium salt was added to the pulp to raise the solubility of Mn2+ and reduce the adsorption quantity of Mn2+ on the ore surface. Experimental results show that a leaching rate over 95% can be obtained at the temperature >273K. The activation energy is calculated to be 7.15 KJ/mol and is lower than that of normal leaching technique. The effects of the parameters, such as particle size, pulp density and initial acid concentration on the process results are investigated. A leaching rate higher than 95% can be obtained under the following conditions: particle size below 0.25mm, leaching time 60 min, stirring speed higher than 960 r.pm. H2SO4:MnCO3>1 .2, pulp density 105-205 g.L-l. A kinetic model was deduced, verifying with actual experiments. It showed that the model can describe the leaching process successfully.

Jan 1, 1995

By Mance G

Today there are many different techniques of soil remediation used in Australia and throughout the world. This paper considers the thermal desorption remediation technique and, in particular, the application of high temperature filtration to the process. The thermal desorption technique involves the treatment of hydrocarbon (oil, petrol, etc) contaminated soil. The process involves heating the soil in a retort or kiln to drive off the volatile organic contaminants. The exit gas stream from the retort is subsequently passed through an after burner to thermally oxidise the hydrocarbons. This technique produces soil and combustion gas streams which are free of hydrocarbons. Due to the heating and agitation of the soil within the retort, soil particles become entrained in the hot gas stream. To avoid the blockage and fouling of the system's interim ductwork and the afterburner, high temperature filtration technology has been applied to remove these soil particulates without cooling the gas Stream.

Jan 1, 1995

By Kirk H. P. E. McDaniel, Mark T. Strever, Keith G. Jr. Wallace

This paper presents the design and installation of an underground ventilation remote monitoring and control system at the Waste Isolation Pilot Plant. This facility is designed to demonstrate safe underground disposal of U.S. defense generated transuranic nuclear waste. To improve the operability of the ventilation system, an underground remote monitoring and control system was designed and installed. The system consists of 15 air velocity sensors and 8 differential pressure sensors strategically located throughout the underground facility providing real-time data regarding the status of the ventilation system. In addition, a control system was installed on the main underground air regulators. The regulator control system gives indication of the regulator position and can be controlled either locally or remotely. The sensor output is displayed locally and at a central surface location through the site-wide Central Monitoring System (CMS). The CMS operator can review all sensor data and can remotely operate the main underground regulators. Furthermore, the Virtual Address Extension (VAX) network allows the ventilation engineer to retrieve real-time ventilation data on his personal computer located in his workstation. This paper describes the types of sensors selected, the installation of the instrumentation, and the initial operation of the remote monitoring system.

Jan 1, 1995

By D. E. Larson

The U. S. Bureau of Mines has developed a image analysis methodology to correlate the energy consumed during the grinding of an ore to the mineral liberation achieved. Energy consumption values are obtained using a laboratory-scale ball mill equipped with a torque sensor, and an automated image analyzer is used to determine the liberation present in ground products. By combining liberation information with energy consumption data an appraisal can be made of the energy required to liberate the mineral(s) of interest. Results of tests performed on a complex sulfide material determined the effects of grind duration on the liberation achieved and the energy efficiency.

Jan 1, 1995

By G. Ferrara

Hydrocyclones and other dynamic separators are normally fed with pulps of water and solid particles. The particles have different sizes, shapes and densities and, except in the special case of mono-characteristic particles, are segregated into size, shape and density. Segregation is magnified by the high values of centrifugal acceleration in the hydrocyclones. This paper develops the theory of the segregation, indicates the major variables involved and reports experimental data of segregation under different operating conditions for mixtures of magnetite and/or ferrosilicon and non-magnetic minerals.

Jan 1, 1995

By George R. St. Pierre

A method for the quantitative description of activity interactions between solutes in a metallic solvent which is consistent with stalistical thermodynamic principles is presented. The chemical potential of a solute in an alloy is derived from the weighted mean of its values in the individual solvent components, µi = S?jµi(i). The weighting factors, ?j, are obtained from the distribution functions. The resulting equation contains far fewer adjustable parameters than the Epsilon Formalism and because of its correct functional form it provides an improved fit to the available data on a variety of alloy systems containing oxygen, carbon, sulfur, nitrogen, and hydrogen. For a binary metallic solvent ( A, B ) containing a solute (i), it is shown that

Jan 1, 1995

By Bobby J. Timmons

A few years ago during a Southeastern Geological Society field trip, a professor from a Florida university and a trip leader commented at one of the stops, "... and for those of you interested in the geology ...." More recently, in the spring of 1992, a geology faculty member at another southeastern university remarked, "Field geology is obsolete." An interviewee for a potential assistant position stated that he had never had a field class. This would-be assistant was to receive his Master's Degree in-Geology within a few days from yet another southeastern university. A regional illness? Certainly not, but symptomatic of the general health of Geology. Capitulation to Environmental Sciences seems to be in vogue with Geology becoming a four-letter word and the mention of mining is verboten regardless of the company. These trends permeate our profession while the demands for earth materials increase, often exponentially. Efficiency, a word lost on government, is routinely expected of business--our business--the industrial minerals geologist and producer. Our stage shrinks but the responsibilities expand. Are we meeting the challenge? Stay tuned!

Jan 1, 1995

By M. Alnot, J. A. Mielczarski, J. J. Ehrhardt, J. M. Cases

The flotation behavior of minerals depends on the balance between hydrophobic and hydrophilic species present at the surface of the minerals. The direct characterization of the interfacial products formed by the interaction of water and an aqueous solution of amyl xanthate with chalcopyrite, tetrahedrite and tennantite (the two former contain antimony and arsenic) were carried out by X-ray Photoelectron Spectroscopy (XPS) and infrared (IR) reflection spectroscopy. The experimental data collected from in-situ (IR ATR) and ex-situ (XPS, IR External Reflection) measurements have let us determine the types of the adsorption products and to propose mechanisms of interaction between the aqueous solution of surfactant and surface of the investigated minerals. It is shown that two major processes take place at the mineral interfaces: (i) the interaction with water and oxygen resulting in the formation of the oxidation products which are mainly hydrophilic (but also a hydrophobic product was found), and (ii) the adsorption of xanthate producing different types of hydrophobic surface products. The results obtained show differences in the composition of the outermost atomic layers of the investigated minerals which obviously will produce differences in the flotation behavior of these minerals. This work forms a good fundamental basis for a better separation between copper minerals containing arsenic and antimony, and chalcopyrite.

Jan 1, 1995

Remotely monitor overburden response to longwall mining using time domain reflectometry (TDR) and a combination of hardware and software, as part of the U.S. Bureau of Mines (USBM) program to characterize subsidence. Background TDR was developed in the 1960's as a method to locate, discontinuities in coaxial transmission cables. In this method, voltage pulses sent along a cable are reflected by cable defects. The pulse reflections are used to determine the type and magnitude of the defects. The TDR concept was extended to material property measurement by embedding cables into particular materials and evaluating the cable's dielectric behavior as material properties were modified. This technique was adapted by the USBM in 1978 for use in monitoring rock movement during underground mining. The same concept is utilized today. A coaxial cable is grouted into a rock mass that is expected to deform. Progressive rock movement causes the cable to deform, as shown in figure 1, and changes to occur in the cable's electrical properties, which then produce changes in TDR reflection signatures. The technology has advanced to the point where it is now possible to distinguish shear deformation from tensile deformation and to quantify rock mass displacements by analyzing the TDR signatures.

Jan 1, 1995

By McBride N

Location The Boddington Gold Mine (BGM) is located approximately 120 km south east of Perth, Western Australia. (Figure 1). Located within the picturesque Darling Ranges, the land was previously used for forestry activities prior to mining commencing in mid-1987. Mineralisation is hosted within deeply weathered felsic and intermediate intrusions and volcanic rocks of the Saddleback Greenstone Belt.

Jan 1, 1995

By Dale J. Sadowski, Richard J. Switalski, Kyle R. Ott

This paper discusses design and construction aspects of shaft construction through rock saturated with petroleum hydrocarbons (crude oil). During the subsurface exploration phase for design of the Hilltop Interceptor project in Cleveland, Ohio natural crude oil was encountered at depths between 6.1 and 61 m below ground surface. The oil-saturated Euclid sandstone contained up to 12,000 mg/kg total petroleum hydrocarbons (TPH), various volatile organics, and had flash points as low as 18.9°C. Interceptor hydraulic design required that construction of access and/or drop shafts penetrate the layer of petroleum hydrocarbon saturated rock. This led to the design of a special lining and some special handling procedures for the excavated material.

Jan 1, 1995

By R. D. Archibald

Currently, around 100 million tons of construction materials and aggregates are shipped annually by rail. And recently, producers are looking much more carefully at rail not only to reduce fixed costs through increased volume, but also to eliminate operating headaches, such as increasing community pressures about trucks on the road, noise and dust. Many producers are uncertain as to how to enter the rail shipping business since railroads have historically been reluctant to ship small quantities short distances. This article provides strategies to help producers examine and pursue moving their rock by rail.

Jan 1, 1995

By Larry Schneider

I n the simplest application of a shock tube initiation system, the tubing acts as a “relay line” which passes a detonation signal from borehole to borehole. When the signal arrives at each borehole, it causes the detonator attached to it to fire. Such a single path constitutes a progressive series where each unit must function properly in order to activate the following units. Any application error, malfunction, or mistake in connecting any surface unit will stop the progression of the detonation signal through the system and result in a “cutoff” or misfire of the following charges.

Jan 1, 1995

By H. Akgun, J. J. K. Daemen

Design of plugs for abandonment of boreholes and shafts may be governed by the bond strength between the plug and host rock. Presented in this paper are the results of push-out tests on two types of expansive cement grout plugs emplaced in rock salt. The average interface shear strengths range from 2 to 12 MPa. Peak shear stresses (assuming an elastic stress distribution along the interface) are up to eight times higher. Dissolution along the interface may be enhanced by clay inclusions in the salt and appears to reduce bond strengths. Application of the results to the design of plugs for larger openings (e.g., shafts, drifts, or boreholes) is discussed.

Jan 1, 1995

By Andrzej Luszczkiewicz, Kazimierz S. Sztaba

Flotation tailing of Polish copper sulfide ores represents more than 90% of the mass of run-of-mine ore. The tailing contains mainly quartz, dolomite, clay minerals, traces of sulfides, and some accessory minerals. Almost all minerals of the tailing are well liberated and, therefore, any further beneficiation process applied to the tailing is expected to be inexpensive. In this work, results of investigations on utilization of flotation tailing using classification and gravity concentration are presented. It is shown that due to classification of flotation tailing in hydrocyclones, the coarse fraction becomes suitable material for gravity separation providing backfill material for underground mines as well as heavy minerals, a source of valuable rare elements. It was also found that heavy minerals separated by gravity methods contain a significant amount of rare elements such as zirconium, titanium, silver, rare earth metals, and uranium. The light fraction of the gravity separation contains well deslimed quartz particles and meets strict requirements for hydraulic filling material ked for structural support in underground mines. Evaluation of the cost of the proposed technology indicated that investment to implement the method would provide a return within 2-4 years.

Jan 1, 1995

By Cheung L. C C, Maconochie A. P

SIROFRAG is a computer-based imaging system that quantifies the post-blast rock fragment size distribution in a muckpile in a mine environment. Improvements in blast performance and blast modelling are being hampered by a lack of a quick and objective method to evaluate the major result of the blast: the fragment size distribution. This is usually done by hand digitising muckpile photographs: a labour intensive and tedious process. SIROFRAG is being developed to quickly, cheaply and objectively provide this information. SIROFRAG is based on active stereo image analysis. It uses a light stripe to illuminate a muckpile and a pair of video cameras to determine the 3D nature of the scanned objects. The imaging system is based on a novel prototype scanning projector that allows images to he captured in full daylight. The Microsoft Windows based software controls the projector and interprets the captured images to provide a size distribution of exposed rock fragments.

Jan 1, 1995

By Houston Kempton, Tim Dyhr, Andy Davis, Mark Bloom, Connie Travers, Dave Atkins, Jeff Deen

INTRODUCTION Historical mining activities in the Robinson Mining District, in the Egan Range of east-central Nevada (White Pine County), resulted in five open pits (Veteran, Tripp, Liberty, Ruth, and Kimbley Pits), several large mine-waste dumps, and numerous underground workings developed for copper, zinc, gold, lead-silver, and manganese (Figure 1). Groundwater percolating downward through the copper sulfide ores produced a blanket-like supergene zone enriched in copper, which has been one of the primary objectives of mining since the early part of this century. To obtain permits for future operation, an EIS was conducted that evaluated future pit- lake chemistry, groundwater quantity and quality issues, transport of water and solutes subjacent to a proposed tailings impoundment, and the potential for waste dump acidification. AREA HYDROGEOLOGY The mine area is on a ridgeline draining to the Steptoe Valley to the east and to the White River Valley to the West. Precipitation in the Robinson Mining District ranges from a low of 15 cm (6 in.) per year in the valley to more than 50 cm (20 in.) per year in the surrounding mountains. Evapotranspiration exceeds precipitation, leading to a net loss of water from the basin as either surface flow or underflow to the north at Currie, Nevada (Eakin et al. 1967). The White River Valley, which lies to the south and west of the mine area, includes approximately 4,200 km2 (1,620 mi2) of the upper part of the Colorado River Basin. This valley is 112 km (70 mi) long, 32-48 km (20-30 mi) wide, and like Steptoe Valley, evaporation and transpiration exceed precipitation (Maxey and Eakin 1949). The local groundwater flow system in the Robinson Mining District and the proposed mine area is dominated by two main components: (1) a groundwater mound or high between the Ruth Pit and Murry Springs, and (2) a shallow groundwater flow divide that follows the ridge crest south of Ruth, which contains the Veteran and Tripp pits. Besides the alluvium, the main hydrostratigraphic units controlling groundwater flow are limestones, shales, and sandstones, along with the intrusive quartz monzonite stocks. Based on the piezometric surface measured in October 1993, three distinct groundwater regions were identified. In the Giroux Wash area, an apparent fault runs between WCC-G1 and WCC-

Jan 1, 1995

By J. B. Hanlon

In order to protect coal mine owners, operators, and lending institutions from potential environmental liabilities, responsible parties must maintain a thorough understanding of the environmental disposition of the property they control, and the ramifications of impending laws and regulations. The best way to accomplish this is to periodically conduct a Phase I Environmental Audit. The systematic approach of an audit will reveal areas of DOD compliance with SMCRA and EPA regulations which the coal owner and/or operator will be able to use to correct deficiencies and prevent the occurrence of conditions which could lead to permit block, fines, and ultimately reduced productivity.

Jan 1, 1995

By G. L. Mowrey, S. D. Maksimovic

An important element of the U.S. Bureau of Mines (USBM) mining research program is the development and evaluation of reliable coal interface detection (CID) systems. Commercially available CID sensors based on natural gamma radiation (NGR) are only applicable if the immediate roof is composed of shaley material. The USBM has made numerous underground and laboratory measurements using several NGR systems approved for installation on mining machines by the Mine Safety and Health Administration. In addition, two small handheld NGR instruments were used to make comparative measurements. Underground NGR measurements in 10 different coal seams, potassium-uranium-thorium radiometric analyses on samples from 16 seams, and chemical analyses of coal and rock for correlation with NGR counts were made. Laboratory test results on the effect of air gap and sample thickness, size, and weight on the NGR measurements, as well as general results of the various NGR systems, are discussed.

Jan 1, 1995

By Christopher Cloete Uys, Luis Manuel Poinha Valentim

The purpose of this workshop is to describe and demonstrate the use of SPEEDWAVE, a high speed data recorder, its VOD enhancements, and the software which binds the system together. The system was designed by TLC Sohware, SOUTH AFRICA. TLC is a company spedalising in the solution of engineering problems, using computertechnology as a base. TLC was founded in 1987, and has since been involved in many different.measurement, control, simulation and modelling projects. Wth respect to the blasting industry, TLC has, in conjunction with AECI South Africa/ICI, developed a tunnel mining design aid, a ring blasting design aid, a multkhannel seismograph and a laser surveying program. In 1989, TLC designed and built the BA800. a microcomputer-based high speed recorder. These recorders are still in use and are producing valuable results. Based on improved technology and with the field experience of the BA800, TLC has designed and developed the data recorder SPEEDWWE.

Jan 1, 1995