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By Zhang Yongzhu

Sulfoxides are one kind of extractants for precious metals. The structure, the coordination reaction, the extraction behaviour and the precious metals complexes of sulfoxides are summarized. The differences between sulfides, sulfoxides and sulphones are also discussed.

Jan 1, 1992

By H. S. Sichel, Kleingeld

A frequency distribution model plays a fundamental role in ore evaluation, especially for the feasibility study of new deep gold mines. The geological complexity of the reefs being mined at present in the Witwatersrand basin poses some difficulties regarding the modeling of the underlying ore-value distribution. This geological complexity has given rise to a need for more applicable distributional models. This paper places the geology of the Witwatersrand basin in perspective and draws some important conclusions from the genesis of the deposition. In addition to the three-parameter lognormal model, two more-general distributional models are proposed. These are the compound lognormal (CLD) and log-generalized inverse Gaussian (LN-GIG) distributions. A detailed, although preliminary, comparative study of these two more-general models with the three-parameter lognormal model is described, and the efficiencies of the estimates and modeling are analysed. It is found that the broad assumption that gold grades follow a three-parameter lognormal law is not always the case, and the need to test for departures from log normality should be emphasized so as to ensure the use of appropriate models.

Jan 1, 1992

By Serge V. Krasvin

The excavation of large amounts of ferrous and non ferrous metals, coal, shale, and other minerals - requires intensification of blasting techniques. In the late 80s in the USSR, the annual consumption of explosives reached more than 2.7 ml t., the great bulk of which consisted of granulated and powdery explosives. Nevertheless, slurry explosives, due to lower costs and better blasting characteristics, are gaining a stronger position in the explosives market.

Jan 1, 1992

By R. L. Guerguerian

Hydrostatic trunnion bearings were recently provided on large Semi-Autogenous Grinding (SAG) mills driven by wraparound motors assembled on the head to shell flanges. A conventional SAG mill would have a ring gear driven through one or two pinions. The effects of the magnetic air gap forces from this new SAG mill drive arrangement on the performance of the bearing are discussed. A step-by-step systematic analytical de-sign of the hydrostatic trunnion bearing is presented, followed by a discussion of grinding mill erection requirements to conform with the design. A brief comparison with other bearing types and their response to the effects of magnetic air gap forces are also presented.

Jan 1, 1992

By John L. Hostetler

GALFAN, the Zn-5% Al-mischmetal hot-dip galvanizing alloy is coated onto steel sheet, wire, and tube using high-speed continuous galvanizing lines. Factors critical to producing high quality GALFAN are reviewed, The relationship between minimum mischmetal content in the GALFAN alloy and furnace dewpoint will be described. The relationship between peak annealing temperature and furnace dewpoint will also be shown. Typical suategies for operating multi-purpose hot-dip galvanizing lines including GALFAN will be described. A recent development has allowed preparation of steel smp for GALFAN coating using aqueous fluxes rather than high temperature annealing. This allows production of GALFAN-coated smp without over-ageing of the steel, and allows high steel strengths and hardnesses to be obtained. The principles of this process will be described.

Jan 1, 1992

Industry can achieve best results via thorough planning, consultatiion with agencies and local communities and a 'hands on' approach to' environmental problem solvingThe Department of Energy and Minerals, through its Minerals Group, has regulatory responsibility for the mining and extractive industries in Victoria. The role of the group is to facilitate the environmentally responsible development of these industries for the benefit of Victorians. It has a wide range of contacts with other government agencies, local government and community groups.The paper is in three parts; firstly, an overview of the nature and contribution of the mining and extractive industries in Victoria; secondly, the industries' regulatory framework; and thirdly, the environmental issues facing the industries and the management of these issues.

Jan 1, 1992

By F. F. Aplan

Mineral process engineering is a small but important part of the nation's raw material industry. Minerals are usually processed in large plants of high capacity, at low cost, using few engineers and operators, and at an ever-increasing level of plant sophistication. The magnitude of the mining industry is huge, with about 4 Gt (4.5 billion st) of ore, coal and industrial minerals mined annually in the United States. Industries such as construction, manufacturing and power generation rely heavily on a strong US resource base to maintain a competitive edge. Though rooted in classical chemistry, geology, physics and mathematics, a mineral process engineer must be trained in the science and engineering required to process raw materials. A modern mineral processing program still stresses the traditional aspects of the profession. But it also emphasizes particle technology, applied surface chemistry, chemical processing of ores, solid-fluid separations, process and equipment modeling and optimization, materials handling, personnel management, maintenance and environmental and health aspects. In such areas as particle technology and some aspects of applied surface chemistry, mineral processing academic programs have taken a leadership position in supplying specialists to a variety of other industries. The objectives of a mineral processing program are: • to furnish personnel to support the basic raw materials industries (undergraduate programs); • to provide a research and development base for industry (graduate programs); and • to provide expertise in particle technology, applied surface chemistry and environmental programs for other industries (undergraduate and graduate programs). In the United States, mineral process engineering programs have historically been associated with mining and metallurgy departments. The recent movement of metallurgy programs away from primary processing towards materials science has created the need for a new accommodation.

Jan 1, 1992

By C. W. Schultz

The Alabama tar sands of the Hartselle Sandstone formation present a more difficult problem in primary extraction than do the Athabasca tar sands. In contrast to the Athabasca tar sands, the Alabama tar sands are "oil wetted" and the contained tar, or bitumen, is of much higher viscosity. A physical beneficiation scheme was developed in which clean sand from an external source was used as a scrubbing medium. High intensity scrubbing liberated the tars which are readily recovered by froth flotation. Locked cycle tests have shown that, after the use of an initial ration of clean sand, the system produced enough new clean sand to be self sustaining.

Jan 1, 1992

By N. L. Piret

Reprocessing of low zinc-bearing residuals with a zinc content of less than 10%, originating from the iron and steel industry, has been given more and more attention in the last few years, due to the potential landfill liability and the increasing cost of disposal by dumping. Whereas, recycling of hazardous electric arc furnace dust is already being performed commercially on a large scale in the U.S., Japan and Western Europe, almost no reprocessing takes place in the case of these low grade zinc-bearing materials. In blast furnaces and basic oxygen furnaces dusts and / or sludges are generated at a rate of 1 to 2 % of the respective production. The technologies for the retreatment of these types of materials, either commercially available or still being developed are briefly described hereafter. They involve internal recycling, upgrading by physical separation methods, separate hydrometallurgical processing and pyrometallurgical treatment. Their scope and limitations are critically assessed in terms of technological applicability, economic feasibility and environmental compatibility. Since, the possibtlity of achieving economic profitability is unlikely with this type of material, the main criteria for acceptability of the treatment process are: generation of a iron-rich material, suitable for treatment by the iron/steel industry, acceptance of the non--ferrous metal-bearing sub-product by zinc smelters, generation of non-hazardous waste materials.

Jan 1, 1992

The U.S. Environmental Protection Agency (EPA) and the U.S. Congress are presently considering several approaches aimed at reducing the amount of lead in the environment and society's exposure to lead. One approach is to tax domestic primary lead production or consumption. Objective To assist the Congress and the EPA in their decisionmaking, a study was initiated by the U.S. Bureau of Mines, which assesses the minerals related implications of a tax on U.S. primary lead production and primary lead imports. This investigation analyzes the impacts of a primary lead lax on: (1) domestic primary lead production, (2) domestic lead coproduct and byproduct production (including bismuth, cadmium, germanium, indium, silver, and zinc production), (3) domestic secondary lead production, (4) lead imports, (5) domestic lead recycling activity, and (6) the U.S. lead price. Study Findings Domestic Primary Lead and Primary Lead Coproduct and Byproduct Production. A quantitative analysis based on the application of the Bureau's Supply Availability System (SAM) has been conducted to determine the impacts on domestic primary lead and primary lead coproduct and byproduct production from domestic lead source material for a range of taxes.

Jan 1, 1992

By E. H. Ahrens

This paper deals with the responsibilities of an operating geologists and the relationship of operations to exploration. It should be of interest to those soon to enter the profession, those new to pining geology and as a review to more experienced geologists. Subjects discussed include detailed geologic mapping, sampling, core logging, assaying, selection of proper map scale, posting geological and assay data, section preparation, identification of ore controls, delineation of development drill targets and geologic hazards, models and the very important topic of salesmanship. Methods and ideas, proven valid in vein, pyrometasomatic replacement and porphyry copper deposits are presented. Hopefully, these will smooth the path for new members of our profession.

Jan 1, 1992

By Dwight D. Trueblood

The Benthic Impact Experiment (BIE) is designed to address the effects of sediment redeposition prior to the commencement of commercial mining. The experiment is being conducted in collaboration with Russian scientists from the Yuzhmorgeologiya Association aboard the R/V YUZHMORGEOLOGIYA. Sediment resuspension and subsequent redeposition during manganese-nodule mining is predicted to be one of the primary impacts on benthic communities living on the abyssal seafloor. The redeposition thicknesses that will cause significant faunal mortality in the deep sea are unknown. Sediment redeposition could adversely affect abyssal benthic communities through entombment, or through starvation caused by food dilution and obstructed feeding. This spring NOAA conducted the main portion of the BIE experiment, blanketing the experimental area with varying thicknesses of sediment using the Deep Sea Sediment Resuspension System (DSSRS). The DSSRS was conceived by NOAA scientists, designed and built by Williamson and Associates, and is the critical piece of equipment used to generate the controlled sediment redeposition environment on the 4800-m deep abyssal plane. The DSSRS consists of an 1800-kg sled, 4.8 m long, 2.4 m wide, and 2.2 m high. The sled was towed and powered using an 8,000-m, 26-mm single conductor cable having a 3,000 VAC capacity. As the sled was towed across the bottom, mud was ingested through two rear-facing, 45-cm wide intakes using two 7.6-horsepower pumps, and discharged 10 to 20 m above the bottom through two 20-cm diameter riser hoses. Each pump was instrumented with optical backscatter sensors providing real-time information about the discharge concentration.

Jan 1, 1992

By S. Page, R. Bhaskar

The development is described of a real-time tracer gas sensing system for use in fell-scale laboratory studies of air flow behavior around mining machines. A semiconductor sintered tin-dioxide gas sensor is used for gas analyses. A data acquisition and analyses software specific to the sensor characteristics was also developed as part of the system. The system permits the study of transient behavior and assists in obtaining a better understanding of the movement of air around mining machines and in the study of the effect of potential airflow modification devices on the dust exposure of face personnel. It seeks to replace the current method of using a centralized infrared gas analyzer that polls several sampling points using an array of solenoid valves and gas line purgers. The polling results in a significant time lapse between the first and the last set of readings. The system described in this paper has the advantages of real-time sampling and safe operation.

Jan 1, 1992

By R. A. Metz, Willard C. Lacy

Rather than attempting to present a summary of the many and highly varied papers that have been presented at this symposium on sampling and grade control, I will attempt to extract the general philosophy of analysis and approach, and attempt to identify the trend of future developments. First, the term "sampling" is used with its broadest connotations. A sample consists of a representative portion of a larger mass, and must represent the mass not only in the grade of contained metals or minerals, but also in all other respects in terms of mineralogy and mineral quality (1, 5), deleterious materials, recoverability of economic components, physical behavior, geophysical response (1), and even archaeological and environmental aspects (7, 11). The sample must be taken from a locality and in such a manner and quantity that it is representative of the larger rock mass. This calls for complete and accurate geological control and an understanding of the nature and distribution of the contained chemical and physical elements and a record of the effectiveness of the different sampling methods. Second, value of a given mass of ore material is based upon its profitability - the difference between recoverable value and costs to achieve recovery, beneficiation and sale. There is a strong movement in mining geology control toward more complete analysis in determining cutoff grades and in grade control, as illustrated by the kriging of metallurgical recovery factors as well as grade at the Mercur Mine (8). To achieve a "profitability factor" as a guide for economic mining practice requires further integration of: 1) the value of contained metal or mineral, 2) percentage recovery of values, 3) dilution of ore with waste rock, 4) addition to, or loss of value as a consequence of by-product materials or deleterious components, 5) cost of producing a saleable product plus minimum profit to justify the effort (cutoff), and 6) cost of land restoration (7, 11). All these parameters vary with the rock type, rock structure, mineralogy, depth, geometry, mining and metallurgical methods, but they must be sampled and analyzed if sampling and grade control are to reflect profitability. A wide variety of deposits has been presented at this symposium; each deposit with its own problems and special solutions. Deposits containing high unit-value components, e.g. precious metals and diamonds, present special problems in the obtaining of accurate samples and generally require statistical analysis control methods or may disregard or modify occasional high or occasional low values, based upon experience (12). Grade control may be accurate for the long term but may vary for the short term. Bulk sampling is always essential. Deposits containing metals or minerals with low unit value are very sensitive to transport costs, and they are often very sensitive to small amounts of deleterious components or differences in physical or chemical behavior. Problems of sampling and grade control change with the genetic type of deposit, with the stage of deposit development and with the size of the information base. Precious metal epithermal deposits (2, 6, 8), because of rapid vertical zonation and erratic lateral distribution of values, have always been difficult to evaluate and maintain grade control and ore reserves. On the other hand, evaluation and grade control are relatively easy in bulk-lowgrade deposits (4, 13). However, these deposits generally have a low margin of profit and are sensitive to mining and beneficiaton costs, price fluctuations and political costs. Industrial mineral deposits (5) often must be evaluated on the basis of their behavior, rather than by chemical analysis. Environmental impact generally increases with the scale of the operation, but certain elements or minerals have especially high impact effects (7, 11). In the exploration phase there is no production control of sampling procedures and careful geological observations are particularly essential. The greatest number of problems is related to the oxidized outcrop where the chemical environment of the ore body has changed and the contained values may have been enriched, depleted or values left unchanged (2, 6). Present evidence suggests that gold values may be very mobile under certain conditions (2, 6) and stable under others. Everything must be sampled in detail. Principal values and by-product or deleterious elements may vary dependent upon their position within the soil profile. Such factors as geomorphic position, erosion rate, vegetation, climate, etc., may affect the interpretation (1, 3). During the development phase it is equally easy to overtest, to have "paralysis by analysis," as to undertest (3, 6). Bulk samplng and testing are

Jan 1, 1992

By E. K. C. Chanda

The best use of available reserves to give good metal recoveries relies on short term mine production scheduling.-The aim is usually to produce a plan to guide mining in specific areas that will enable mine operations to deliver the budgeted tonnes and grade to the mill and keep within the long range mine plan. Thus, short term production scheduling is an important aspect of the open pit mine planning function. Since the 60's increased attention has been paid to effective production scheduling as a means of improving the economic viability of existing mines. Hence, mine scheduling scheduling systems have been evolving rapidly during the last two decades. These systems include manual techniques, computer based simulation, mathematical programming and more recently Computer Aided Design (CAD). Some general drawbacks of the current scheduling systems are that firstly, the costs of acquiring and using them are not at all insignificant especially for small to medium sized pits. Secondly, there is an inherent trial-and-error aspect in these systems. Thirdly, they tend to be suited for specific orebody geometries, hence lacking the necessary generality. For instance, the use of computer programs for planning open pits to mine stratiform orebodies raises problems which are not usually met when massive orebodies are considered. There for, a need exists to develop simpler but effective short term pit scheduling procedures suitable for stratiform type orebodies, considering their geometry and geology. This paper describes a PC- based model designed to assist the planning engineer in optimizing the short term production schedule in open pit mines with stratiform orebodies. The model is based on a combination of linear goal programming and deterministic mining simulation. The orebody model is made up of ore and waste mining regions where winning and and/or stripping are taking place. These shovel regions form the basic planning elements in the model. This approach does not require the laborious preparation and use of a regular block model. The computer program consists of main modules: (i) Data capture - processes the raw data into the required format for mine planning. (ii) Precedence mining constraints - checks the status of each shovel .region at the beginning of a given scheduling period with regard to geometrical mining constraints such as undercutting. (ii) LP- Optimization - provides an optimal selection of ore shovel regions which do not violet geometrical constraints for mining in the period, the objective, being to maximize the contained metal equivalent in the blended R-O-M ore and at the same time to minimize deviations in grade and tonnage from the call values. (iv) Post LP-Simulation - enables the user to smooth out the LP solution in order to adjust it to a practically executable plan and simulates mining of ore and waste for the period. Shovel allocation to selected ore and waste shovel regions, unit operations and depletion of reserves are executed in this module. Preliminary testing of the model for monthly production scheduling using data from Nchanga OPen Pit on the Zambian Copperbelt indicates that it can be a useful planning tool and gives acceptable results.

Jan 1, 1992

By Y. S. Roditis

A new method for interpolating a block model is proposed, where both the diamond drill holes (DHs) and blast holes (BHs) data are used. Combining these data types poses a geostatistical "class size" problem due to the different statistical properties of the densely populated BHs and the sparsely populated DH data. This paper discusses how linear regression was used to adjust the DH values prior to the interpolation to account for the "class size" problem which is inherent to the procedure. The correlation between the BHs and the DHs is found. The DHs are then corrected based on the regression line. Each block that falls within a certain range of influence of a blast hole is assigned a different code and is interpolated with the combined BH and regressed DH data set. Blocks that fall outside the range of blast hole influence are interpolated using the original DH data set. A comparison against other methods, indicate a 12% improvement over using DHs only and a 2% improvement over using BHs only.

Jan 1, 1992

By G. J. Trezek

The use of polysilicates for treating heavy metals in soils and mining sludges is discussed. Results of the treatment are given for soil contaminated in a metal scrap yard operation and for copper mining processing sludges. The types of metals of concern are arsenic, lead, copper, nickel, cadmium, and zinc. The application of the treatment is predicated on the mixture and relative concentrations of the metals as well as the material matrix. Reductions in soluble concentrations (STLC or TCLP) of one to two orders of magnitude can be achieved with relatively small additions of silicates and cementitious materials.

Jan 1, 1992

By Gary R. Adams

Coating thickness control is typically difficult with touch-up solders for galvanized steel, and corrosion properties and abrasion resistance are sometimes poor. This paper reports on progress in ILZRO-sponsored research to develop an improved touch-up solder. Encouraging results were achieved in torch soldering trials with zinc-tin based alloys. Mouldability and coating thickness control were achieved over a practical working temperature range in which the solders consisted of a viscous mixture of solid primary zinc phase particles in a liquid zinc-tin eutectic matrix The mouldability was dependent on the microstructure of the starting material, and optimum structures could be obtained through control of casting solidification rates and/or by the addition of small amounts of copper. Hardness and preliminary corrosion test results showed potentially good mechanical and corrosion behaviour. The absence of toxic materials ensures environmental friendliness. Comprehensive performance testing is continuing on selected experimental zinc-tin-copper touch-up solders.

Jan 1, 1992

Develop a safer, more effective, and more efficient method to control fires in abandoned coal mines and waste banks. Maintain the costs of this new method at less than or comparable to conventional AMI fire control methods. How It Works Cryogenic extinguishment of subsurface fires is a method of heat transfer. Bureau-designed injection equipment produces a pumpable slurry of liquid nitrogen and solid particles of carbon dioxide. Liquid or gaseous carbon dioxide from a pressurized tank flows to a bell-shaped nozzle where the change in pressure causes the carbon dioxide to form a granular snow. The solid carbon dioxide is mixed with liquid nitrogen. A jet pump is used to move the slurry through the delivery lines and into a simple injection probe. At injection, the nitrogen vaporizes and the carbon dioxide sublimes. This phase change produces a cold gas (-180° C) that, as it expands and moves in all directions, removes heat and also displaces oxygen. This combined process inhibits the combustion process and lowers the temperature below the reignition point. When the liquid nitrogen and solid carbon dioxide are converted to gases, the expanding gas acts like a piston, forcing warm air out of the porous bed, Although smoke and hot gases arc forced from the burning coal, generally there is no significant increase in the odor associated with burning coal.

Jan 1, 1992

By R. A. Metz, Michael M. Easdon, Michael J. Fiannaca

Disseminated epithermal gold metallization occurs within a breccia unit interpreted to be a submarine debris flow. Gold is associated with oxidized pyrite, fluorite, and jasperoidal silica. A minimum of 8 Mt (9 million at) of open-pittable mining reserves will be cyanide heap leached as run-of-mine ore at a rate of 0.9 Mt (1.0 million stpy). Careful evaluation of the combined results of successive sampling projects has established the pit plan, minable reserves, and process metallurgy of the operation. The sampling procedure utilized for a given test depended upon geological interpretation as well as the procedures, successes, and failures of previous tests. This paper summarizes the sampling and testing procedures of the development effort in light of the project goals and attendant problems in achieving them.

Jan 1, 1992