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By Stuart K. Nicol, Malcolm D. Engel, Neville T. Moxon

Ion flotatir,n of gold is a process being developed to selectively float extremely dilute aurocyanide liquors using a novel surface active complexing agent. The principle of ion flotation is also applicable to a wide range of other metal-containing solutions. The market potential of the gold flotation process would be enhanced by the possible combination of the gold recovery capabilities with both cyanide recovery and metal removal. For example, recovery of copper cyanides from a return liquid strean1 would be a useful means of reducing operating costs and satisfying environmental pressures to treat tailings dams. Experimental work is described where samples of tailings solution from a far north Queensland gold mine were subjected to ion flotation to remove copper cyanide species from a clear recycle solution. The form in which these products was removed was of secondary importance compared to the need to produce a clean solution for use in the plant. Recovery of the anionic copper cyanide species was accomplished using a quaternary ammonium surfactant.

Jan 1, 1991

By J. W. C. Wong, S. D. Miller, J. J. Jeffery

Pre-mining identification of acid forming mine and waste materials is of concern to the mining industry because of the potential for the generation of acid mine drainage, acid rock drainage, and soil acidity problems. Accurate identification of acid forming material is essential for developing appropriate waste management strategies to reduce environmental problems related to acid generation from sulphide containing wastes. The acid-base accounting procedure, in its various forms , is commonly used for pre-mining screening of mine and mine waste materials. The procedure is generally effective when used and applied correctly but is prone to incorrect interpretation of results which can have significant financial and environmental implications. This paper examines the acid-base accounting Procedure and the possibility of misuse of this method with special emphasis on the sampling method, the sulphide forms, the acid neutralization capacity, and the interpretation of results. Data from numerous coal, base metal, and gold mining operations are used to illustrate the application of the acid-base account. The data base indicates that overall, approximately 1/3 of all waste generated by mining and mineral processing is potentially acid forming indicating the need for correct identification and management. Problems associated with simple application of 'absolute' acid-base criteria for classifying acid forming material are highlighted and the need for developing site specific or 'relative' criteria is discussed and illustrated by case study.

Jan 1, 1991

By Victor F. Hollister

Porphyry-type deposits are characterized by mineralization in, as well as adjacent to, an igneous body, usually a porphyritic stock. One deposit style includes both mineral dissemination and mineralized veinlets, and both porphyry copper and porphyry molybdenum deposits are characterized by dissemination and veinlet control of ore minerals. Those gold deposits that occur in stocks, with gold occur- ring in veinlets and disseminations within the stock, clearly are can- didates for consideration as porphyry gold type. Porphyry copper and porphyry molybdenum deposits are also characterized by potassic, phyllic, argillic, orpropyllitic alteration or some combination of these alteration types. Where two or more alteration zones are present, these are arranged in a sequential outcrop pattern. Gold occurring in dissemination and in veinlets in as well as adjacent to stocks, and which also occur in typical pervasive porphyry alteration suits, constitute a clearly defined class of deposit that fits the definition of a porphyry gold type. Porphyry copper deposits may carry appreciable gold. Porphyry copper-gold deposits are known from all porphyry copper provinces. This chapter is intended to cover porphyry gold occurrences that may have little or no copper or molybdenum as economic concentrations.

Jan 1, 1991

By J. C. Zelanko

The U. S. Bureau of Mines conducted a multi-faceted geomechanics research project at a bump-prone longwall coal mine in eastern Kentucky. This mine presented a unique opportunity to study coal mine bumps in that the problem appeared to be confined to areas beneath a sandstone channel of limited areal extent. The Bureau's research plan sought to exploit the uniqueness of the site by monitoring strata behavior and longwall support reactions as the longwall face approached and passed beneath a sandstone channel. The study incorporated static pillar stress and strata deformation measurements, shield support leg pressure measurements, and microseismic monitoring as well as geologic mapping and the collection of observational data. Data collection was underway when a major coal bump occurred on the longwall face at the mine. Pillar behavior (load and deformation), shield loading, and microseismic activity were monitored prior to, during, and after the bump. Observations in the tailgate indicated that these pillars were failing prior to and after the face bump. Shield load data which were evaluated in an effort to identify trends which could be used to forecast coal bumps appear to provide a measure of the effectiveness of destressing operations conducted on the face (e.g. shot firing). Analyses of microseismic data revealed anomalous values associated with microseismic "energy" prior to the face bump. In addition, microseismic source location data and underground observations provided some insight as to the sequence of pillar and face bumps.

Jan 1, 1991

By P. C. van Aswegen

The Bacterial Oxidation (BIOX®) process for the pre-treatment of refractory ores for gold recovery developed by Genmin, the mining division of Gencor, has been operating successfully at the Fairview mine since October 1986. The continuous operation of a pilot plant at Genmin Process Research has resulted in further process developments to improve plant operating efficiencies. These new developments which include a higher solids content of the pulp feed to BIOX®, lower retention times, higher operating temperatures, lower power utilization for oxygen dispersion .and reduced nutrient addition have all been successfully implemented on the Fairview plant.lt has furthermore been confirmed that the arsenic precipitate formed in the neutralization of effluent solutions complies to the United States of America EPA standards. Continuous cyanidation pilot plant work conducted on BIOX® product has indicated that cyanide consumption can be drastically decreased if a continuous flowsheet is implemented in preference to a batch leaching system.

Jan 1, 1991

1. Reviews Extraction metallurgy, by J.D. Gilchrist. 3rd ed. Oxford, Pergamon, 1989. 431 pp. £50.00 (hard cover), £14.95 (soft cover). Reviewer. Prof. M.D. Brayshaw. Reviewer. Prof. M.D. Brayshaw This third edition bears testimony to a work that contains much of value for lecturers, students, and practising metallurgists. Mineral processing in the United Kingdom, edited by P.A. Dowd. London, Institution of Mining and Metallurgy, 1988. 223 pp. £25.00. Reviewer: Prof. M.D. Brayshaw It came as both a pleasure and a challenge for a resident of South Africa (with its volume and diversity of minerals) to review a book focusing on the beneficiation of ores from the sparsely endowed mineral chests of the United Kingdom. 2. Recent issues Rock mechanics. Theory and applications with case histories, by W. Wittke. Translated from German by R. Sykes. Berlin, Springer-Verlag, 1990. 1076pp. DM248. McGregor's quick reference to the JSE. Pretoria, Juta & Co., 1990. R39,95. McGregor's economic alternatives. Pretoria, Juta & Co., 1990. 400 pp. R34,95. 3. New journals Journal of Materials Chemistry, edited by A.R. West and J. Leader, and published two-monthly by The Royal Society of Chemistry (Blackhorse Road, Letchworth, Herts SG6 IHN, OK). £195 per year, starting in 1991. New Materials World, published monthly by Lawrence Cooklin (15 Selvage Lane, Mill Hill, London NW? 3SS, OK). £180 per year. Mendeleev Communications 4. Books from The Institute of Metals The following were published recently, or are to be published soon, by The Institute of Metals, 1 Carlton House Terrace, London SWl Y SOB, OK. Illustrated case histories of marine corrosion. 1990. Modern steelmaking methods, by C. Moore and R.I. Marshall. 2nd ed. 1990. Grain boundary fractures, by S.F. Pugh. 1991. 160 pp.

Jan 1, 1991

Written contribution by J.F. Curtist The paper is an interesting exercise in the application of mathematics to a theoretical situation presumed to oc¬cur underground. However, some of the assumptions on which the calculations are based are unlikely to occur in any actual mining situation. Assumptions made in the paper Objections to these assumptions are noted seriatim. (1) `it is assumed that any loading-rate effect will be small and can be ignored' (p. 3). A loading rate of the order of 50 kN-12 per cent of the maximum load-is customary to prevent the props being dislodged by the blast. (2) `it is unlikely that all the props will be installed with their full stroke available, but for the purpose of this analysis, it is assumed that this is the case' (p. 3). A more reasonable assumption would be that, with the most careful selection of prop length and the most rigid control of stope width, the available stroke length would on average be reduced by the order of 70 mm on installation-20 per cent of full stroke. (3) `each support unit supports a block of 3,3 m2 bound¬ed by vertical fractures with zero cohesion that are parallel and at right-angles to the stope face respec¬tively' (p. 5). Joughin and Jager have shown this to be an unwar¬ranted assumption in respect of the positioning, the direction, and the dip of the fractures present in a stope in rockburst conditions. If, as assumed, there was `zero cohesion' between such blocks, the removal of a hydraulic prop in row 3 supporting such a block would ensure that it fell out before a profile prop could be installed in the same position. (4) `the height of each of these blocks is 3,0 m, the volume of each block is 9,9M3, the mass of each block is 27 225 kg' (p. 5). The concept of individual props being affected by dis¬crete blocks of known and uniform dimensions of relatively low ground velocities (less than or equal to 2,16 m/s) acting in line with the axis of the prop is one that lends itself to neat mathematical calcula¬tions. It does not, however, bear much similarity to the actual conditions that are exposed underground in excavations where rockbursts occur. Ortlepp and co-workers concluded that `the impulse of the shockwave can cause the displacement of the

Jan 1, 1991

By Batric Pesic

The interactions of mineral-pyrite with T. ferrooxidans were studied by using a cyclic voltametry technique. The interactions with bacteria were examined during the entire growth stage of bacteria (fermentation), The pyrite ?surface invariably drastically changed ' its. properties at the second day of fermentation. Beyond two .. days of fermentation, the cyclic voltamograms were insensitive to convective diffusion produced by stirring. The product layer was examined by SEM,. X-ray diffraction and chemical analysis. The SEM study revealed that bacteria populated the pyrite surface at an extremely high density levels. The high density of bacteria, and the solid reaction products formed on the pyrite surface created conditions for pore diffusion which explained why the CVs became .insensitive to convective diffusion in solution (stirring). The x-r:ay diffraction study confirmed jarosite as a product layer. A mechanism of T. ferrooxidans cells serving as nucleation sites for jiarosite formation is proposed.

Jan 1, 1991

1. Books on management The following are available from Knowledge Resources, P.O. Box 3954, Randburg 2125. . Competitive advantage of nations, by Professor Michael Porter from Harvard Business School. This book highlights the importance of industries in contributing towards national competitiveness. It is being regarded as one of the 10 best business books published during 1990. . The borderless world, by Kenichi Ohmae, Managing Director of McKinsey in Japan. This deals with business in the new interlinked economy. . Megatrends 2000, by John Naisbitt and Patricia Aburdene. This book outlines the mega/macro trends that will

Jan 1, 1991

By M. J. Oliver, A. J. Nugent

Hydrogen Peroxide and Caro's Acid (H2so5) were used to treat cyanide containjng effluents. Significant reagent savings were achieved by using Caro's Acid. Weak Acid Dissociable (W.A.D.) cyanides were removed at near stoichiometric levels of Caro's Acid. Hydrogen Peroxide showed poorer efficiency in the presence of W.A.D. cyanide complexes, resulting in higher consumption rates. By using Caro's Acid, reaction catalyst requirements ar(! el.iminatnd, react.ion I.imes significant.I y rnduced and capita] costs for an effluent lreal.ment facility are minimal. The Efflox* Process ut ilisc�s this more efficienl oxidising reagent in a treatment system exhibiting a simple non proprietary control system with minimal peroxygen consumptions.

Jan 1, 1991

By F. W. DeVries

The preoccupation with cyanide as an environmental issue has been described as virtually an obsession for state and federal agencies enacting regulations for environmental protection. This seems likely to continue in legislative planning, as well. This is despite the fact that the only significant group of cyanide-related incidents has been the bird-mortality occurrences, predominantly in arid areas, and these have been greatly reduced by a concerted effort by operators. What follows is a brief list of areas for which the industry may need either additional information or plans for defensive strategies over the next two to five years.

Jan 1, 1991

By Paul F. Ziemkiewicz, John J. Renton, Thomas Rymer

Any viable model or deterministic formula used to make predictions must follow certain criteria. The standard models and procedures used to project acid load from mining activities operate from a number of assumptions, some of which, although logical, are scientifically oversimplified and, hence, invalid. Highly variable field parameters have lead to highly variable acid projections. Kinetic tests are in themselves misnomers in that no parameters associated with chemical reaction kinetics are ever determined. Sampling error coupled with assumptions made as to the distribution mode of pyritic materials in rock units can lead to highly inaccurate conclusions explaining why acid generation often occurs where none is predicted. The fact that probability theory and paradigms governing luck and chance have not been incorporated into the science of acid prediction undermines any credence placed on such projections. To date, with few exceptions, the acid prediction is logically closer to a game of chance than practical science.

Jan 1, 1991

By Lyda W. Hersloff

As decommissioning of various radioactively contaminated facilities begins, the question of appropriate residual surface contamination becomes an issue. Surface contamination can result in exposure to people via inhalation, ingestion, and external radiation exposure, There is therefore the potential of exposure to workers involved in the dismantling of a facility as well as members of the general public acquiring salvageable equipment, tools, and building materials. The levels established as acceptable for unrestricted use by national and international organizations vary by as much as an order of magnitude for certain radioactive materials. The calculated doses associated with some acceptable contamination levels can be significant. The principle of ALARA, as low as reasonably achievable, is therefore a necessary element in establishing surface contamination levels for a specific site. Some components in evaluating site specific surface contamination levels for unrestricted use, especially removable contamination, include evaluations of the historical use of a facility, the mixtures of radioactive materials a&sociated with surface contamination, and resuspension factors for various materials.

Jan 1, 1991

By Myles G. Hyams

A mining project is proposed for the state of Pahang, Malaysia. The proposal involves the mining of a sulphidic ore body and initial processing to form a sulphide concentrate which will be transported to a roaster/acid plant for the production of sulphuric acid. An outline is presented on the potential environmental impacts of the project which have been assessed by superimposing project infrastructure and processes on to the physical, biological and social environment during the early design and planning stage of the project. The potential impacts eliminated by engineering design and the techniques employed are presented. However, there are a number of potential impacts that require careful consideration and planning for long term management. These include surface water drainage, waste rock leachate, tailings disposal and the social environment. Environmental management designed to minimise or alleviate these impacts as a result of project implementation concludes the paper.

Jan 1, 1991

By G. H. Khoe

addressed in a number of studies in the past. In this paper, the stability of a ferrous arsenate compound is evaluated using a solution model and the thermodynamic data which were determined for the system. The environmental stability of the ferrous arsenate precipitate is compared with the literature data for ferric arsenate and arsenate-bearing ferric hydrous oxide.

Jan 1, 1991

The Canadian concept for nuclear fuel waste disposal is being assessed by AECL Research in a series of experiments at its Underground Research Laboratory (URL) near Lac du Bonnet. Manitoba, Canada. As pan of this research, the Mine-by Experiment has been designed to obtain information on rock mass behavior, the development of an excavation-induced damage zone and failure mechanisms around a circular bored tunnel. An iterative design approach was used to effectively reconcile the experiment objectives and construction logistics. This paper discusses the design considerations and construction methodology adopted on the project.

Jan 1, 1991

By Gerald L. Dollinger, Joseph A. Roby, David Krauter, Kenneth Deering

Three high performance TBM's equipped with large diameter (483mm) disc cutters are currently operating in Norway. This paper summarizes the design philosophy, field performance and ongoing technical development of these cutters. Included are discussions of the early problems encountered with their usage and the solutions to these problems that have been developed. Also included are discussions of the penetration rates and cutter usages observed. From this data it is concluded that high performance TBM's with large diameter cutters can produce significant improvements in both overall performance and in cutter costs under hard rock conditions.

Jan 1, 1991

At Pasminco Mining's South concentrator. which was commissioned in 1952. an expansion. modernisation and efficiency improvement program commenced in 1986 with a coarse ore stockpile and grinding circuit expansion. the replacement of small flotation cells and the upgrading of reagent mixing and metering equipment. The program continued with the installation of a TDC 3000 based process control system (1988) and concentrate thickeners (1990). By mid-1991 a further grinding expansion and the installation of zinc flotation feed regrind ball mills and zinc recleaner column cells will be complete. leaving the use of ceramic disc fillers and development of process control strategies as probably the remaining major avenues for improved process efficiency at present.

Jan 1, 1991

In 1987 the control strategies at the then ZC Mines' New Broken Hill Consolidated concentrator were a miscellaneous mixture of computer hardware and technology for ISA, grinding and residue thickener control. Field instrumentation was based on current-to-air technology of approximately the 1960s. Decisions were made to rationalise computer and field instrumentation technologies; the object being to consolidate control loops into one system to enable expansion of the system to include all facets of plant operation. The first stage was to install a DEC Micro PDP 11/23 computer and serial line communication as recommended by AMDEL Ltd, for the ISA system, as discussed by Walsh and Freeman (1988). The second stage was to select and install a distributed control system for the centralisation of the control loops into one system, and to replace field instrumentation with state-of-the-art technology. This paper deals with the second stage of the rationalisation, in an attempt to give an insight into what is required when personnel are faced with such a decision, details of costs involved in keeping a system functioning and utilised; and the requirement to train personnel for acceptance of further control strategies.

Jan 1, 1991

By Rokot M

In a little over three years, Chevron Niugini has built up a team of relatively young, hard working men and women, mostly Papua New Guineans, who spend most of their working days out among people in the Southern Highlands and Gulf Provinces who are directly affected by the Kutubu Petroleum Development Project. These are Land and Community Relations officers, or LACROs. They take on a huge responsibility, not only representing Chevron but also being friend, advisor and negotiator, frequently dispensers of medicines, and agricultural advice and more. When things go well, others get the praise, when things go wrong, LACROs are the martyrs. Just as the geologists who locate the oil, the drillers who find it, the engineers who design the facilities, the construction gangs who build them, the landowners who claim it, and the Government who monitor it, so are the LACROs part of a team.

Jan 1, 1991