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By E. D. Regad, W. E. Wallace, V. Vallythan, V. Castranova, P. Hathaway, F. H. Y. Green, M. J. Keane

"Abstract—Inhaled particle contact with pulmonary surfactant in the hypophase lining pulmonary alveoli was modelled in vitro by exposing two respirable sized dusts, kaolin and silica quartz, to lecithin, a major component of pulmonary surfactant, emulsified in physiological saline. Lecithin adsorbs to the dusts upon incubation at 3TC and suppresses their cytotoxicity as measured by pulmonary macrophage and erythrocyte assays, suggesting that pulmonary surfactant provides a defence system against prompt cell membrane lysis by inhaled dusts. Subsequent pulmonary macrophage phagocytosis and lysosomal enzyme digestion of the coated dusts was modelled in vitro by incubation with phospholipase A2 for one hour. With increasing lipase activity, silica haemolytic potential was restored to native silica levels. Kaolin was retoxified to levels far in excess of native kaolin haemolytic potential. Elution, thin layer chromatography and phosphate assay of treated dusts indicate that most lecithin on silica is digested to lysolecithin and desorbed, silica retoxification being due to surface and adherent lysolecithin effects. Most lecithin on kaolin is not digested in the same time; that which is. results in adherent lysolecithin which is responsible for the kaolin retoxification. Digestion with phospholipases A2 and C together produces only weakly retoxified kaolin. Results suggest that surface adsorption properties which control the adherence of prophylactic surfactant distinguish the pathogenic potentials of quartz, kaolin and mixed dust.INTRODUCTIONERYTHROCYTE HAEMOLYSIS and pulmonary macrophage enzyme release assays show quantitatively comparable high cytotoxicities for both silica quartz and kaolin respirable sized dusts (BROWN, et al., 1980; DANIEL and LE BOUFFANT, 1980.) This contrasts with the strong potential for respirable quartz dust to induce pulmonary fibrosis and the much more limited potential of kaolin dust to do the same (MORGAN and SEATON, 1975).In an attempt to understand this anomalous situation, assays were performed on quartz and kaolin dusts incubated with dipalmitoyl lecithin emulsified in physiological saline, to simulate the initial contact of a respired dust with the pulmonary alveolar hypophase. The ability of kaolin dust to adsorb dipalmitoyl lecithin from physiological saline has been quantified (WALLACE, et al., 1975). Such lecithin treatment suppresses the cytotoxicity of both silica and kaolin to background levels (WALLACE, et a1.,1984).Surfactant coated detoxified dusts should then be phagocytised by pulmonary macrophages, incorporated into a macrophage secondary lysosome and exposed to hydrolytic lysosomal enzymes. Among these is phospholipase A2, which hydrolyses diacyl lecithin to lysolecithin. This was modelled by incubating lecithin treated dusts with phospholipase A2 in vitro to determine if the enzyme can digest the dust-adsorbed lecithin, and if the retoxification differs between the two dusts in a manner which might distinguish their pathogenicity."

Jan 1, 1988

By Zhao Guangwen, Wu Tan, Qiuzhan Tian, Duan Shuzhen

"A thorough study of lost currents in bipolar cells has been made for the development of the great potential of bipolar cells in energy saving. A proper equivalent circuit for bipolar cells has been found, and mathematic methods for computing lost currents at all kinds of polarization have been developed.At linear polarization, the lost currents can be computed by solving either a tridiagonal matrix or an ordinary differential equation of second order. This kind of values can be used to evaluate the minimal lost currents at given conditions. At other kinds of polarization, the lost currents can be computed by the same methods as above if the necessary experiments of measuring the cell voltages of every electrolytic compartment have been made. This kind of values can be used to design bipolar cells at practical conditions.Extensive experiments have been made to evaluate the effects of electrode polarization, emf of galvanic cell for the formation of electrolyzed substance, gaseous products, geometric dimensions of electrolytic cells, special resistance of electrolyte used, and the total and ordinal number of electrolytic compartments on lost currents. It is the first time to make such a systematic research by experiments in the world. Experiments showed that theoretic models were in good agreement with measured data. Experiments also showed that D.C. energy consumption of 0.45 kwh/kg of Pb for lead electrolysis from molten chlorides could be achieved in a cell with 7 bipolar electrodes.IntroductionIt is very promising to apply bipolar electrolytic cells to electrolysis of aluminum, magnesium, lead, zinc and perchlorinates for their great potential of energy saving for example, bipolar cells had been used in the production of magnesium and saved more than 30% of energy, being one of the three main techniques of energy saving in the production of titanium sponge (1)."

Jan 1, 1988

By K. N. (Mani) Subramanian

A 2.5 meter diameter column has been successfully used in a 100 tph flotation plant at the Harbour Lights Mine in Leonora, Western Australia, to produce a final gold bearing sulfide concentrate from the ore in a single stage. This pioneering application of column flotation cells to rougher stage was pilot tested using a 11 cm column, which demonstrated column's capability in rougher, scavenger and cleaner flotation stages. A hybrid circuit involving columns and mechanically agitated flotation cell s was adopted for the commercial installation. This paper describes pilot plant results, design of the plant flotation circuit, and early results of commercial operation.

Jan 1, 1988

By R. J. Roman

During the refining of primary magnesium metal: a spent flux (sludge) is produced which is considered a dangerous waste by the Washington State Department of Ecology. Four years of research, testing and marketing has identified two beneficial markets for the spent flux: 1) as a fertilizer and soil admendment as a result of the material's high potash and nitrogen content and its high lime equivalence and 2), as a roadway deicing agent to clear roads of ice and snow as a result of both the salt content and the flux containing chemical compounds which exothermically react with water.

Jan 1, 1988

By Ken Bright

This paper is an overview of approaches to assessment of ore grade for gold and the platinum group at the exploration stage of a project. Proper sampling techhniques must be complemented by good assaying. In turn, correct assaying has its roots in thoughtful, systematic sampling and sample preparation procedures. While intricacies of the subject matter could occupy a book, we will comment on acceptable sampling approaches, outline a lab hand- ling scheme, and discuss preferred analytical methods. Pitfalls previously encountered by the mining and exploration industry will be highlighted with emphasis on a perceptive under- standing of the nature of ore occurrence. Lastly, focus will be centered on reliable assay approaches.

Jan 1, 1988

By K. Hanna

This paper describes a method to improve coal mine entry intersection design. The method considers the effect of in situ stresses, local geologic conditions, rock physical properties, and mining sequence. Development of the method is discussed, including the results of field instrumentation studies and numerical modeling investigations. Data required to evaluate the effects of roof span, mining sequence, entry orientation, and bolting patterns on intersection stability are also presented. Ground control studies conducted by the U.S. Bureau of Mines in two underground mines in the Illinois Coal Basin have shown that in situ horizontal stresses and roof geology have a critical effect on intersection stability. Methods to reduce the adverse effects of these parameters are emphasized. Typical failure behavior associated with specific geologic and horizontal stress conditions is' presented to illustrate proposed control methods to alleviate adverse ground conditions.

Jan 1, 1988

By J. D. Christensen

In August 1987, we marked the tenth anniversary of the Surface Mining Control and Reclamation Act. Anniversaries are supposed to be times of celebration, and I truly believe that we have something to celebrate on this anniversary. For, after ten years, there has been much progress in the implementation of the surface mining law.

Jan 1, 1988

Prospecting in arid terrain can produce substantial environmental impacts, comparable to or greater in magnitude than the impacts associated with actual mining or petroleum production. Impacts are likely to be particularly severe where prospecting involves intensive geophysical exploration, especially in areas which have escaped degradation by other land uses such as pastoralism. With appropriate environmental planning and management, however, the environmental impacts of prospecting in arid terrain can be greatly reduced and mitigated, at low cost. In many countries, prospecting licences, exploration leases and associated tenements now carry a range of conditions relating to environmental protection. The assessment, avoidance and mitigation of environmental impacts is therefore an important component of and-zone exploration. My aim here is to give an overview of some of the main aspects of an environmental planning and management (EPM) programme for prospecting in arid terrain (PAT). Detailed operational prescriptions for environmental protection procedures are necessarily specific to particular areas and types of prospecting: see. e.g., Buckley (1982a, 1984, 1985a, 1986a), Klepacki et al. (1985) and Stone (1986). The intention here is to provide a checklist rather than a recipe book: as an aid in incorporating environmental aspects into the overall planning and management of an exploration programme, and in liaison with company environmental staff, consultants and regulatory bodies. I also hope to show that whilst some of the techniques used in particular environmental disciplines certainly require specialist expertise, the overall design of an EPM programme is not in the least esoteric, but simply an exercise in straightforward common sense. Perhaps this paper could be subtitled: "Demystifying environmental Planning".

Jan 1, 1988

By McKendry J. B

Gretley Colliery is situated at Wallsend, a suburb of Newcastle in New South Wales and is owned and operated by the Newcastle Wallsend Coal Ccnpany, a wholly owned subsidiary of Peko Wallsend Limited. The mine has been an efficient bord and pillar producer by industry standards. However, its continued economic viability was threatened because the bulk of remaining reserves lie in more difficult mining conditions and are of poorer quality. Alternatives were examined to improve productivity and allow Gretley to become more competitive in the current difficult market Environment.

Jan 1, 1988

By Tom Burleson

High-speed photography has proven to be an extremely valuable tool for the evaluation of blasting practices in the Warrior Coal Basin. A research project, coordinated by Nelson Brothers Inc. and The University of Alabama's Mineral Engineering Department, has centered on the use of high-speed photography to study and analyze blast performance. A large number of production shots in this region has been filmed and studied. The data obtained from the films have been used to establish graphical relationships between certain blast parameters and overall shot performance. These relationships will be used to develop a computer model that will estimate cast results from a given burden explosive energy combination. This paper describes the methods and procedures used to develop these relationships. The results of the research are discussed along with plans for continuing the research project.

Jan 1, 1988

The mineral sands industry in Australia can contribute much more sig- nificantly to economic development beyond the year 2000 by increased production of constituent minerals such as ilmenite, zircon, rutile, leu- coxene and monazite from existing and new resources, and especially from downstream processing to intermediate and finished products based on these resources. The end-use areas for mineral sand-based products include those products whose demand is tied to general economic growth, such as paints and plastics, and refractory bricks for the steel industry. High techno- logy applications such as zirconia ceramics and super-magnets are indica- tive of new developments in technology which provide considerable scope for expansion at higher rates than overall western world economic growth. An optimistic outlook for the industry is outlined, based upon a brief review of opportunities.

Jan 1, 1988

By Gary F. Meenan

Continuous pi lot scale dewatering tests compared the performance of the vacuum disc filter with that of the screen bowl and the solid bowl centrifuges. The test results allow the a priori prediction of plant product moisture based on the feed particle size. This information is useful for selecting the best dewatering device for a given size material and for optimizing the dewatering performance of existing plant installations. Quantitative information was gathered on the ability of filter aids to improve the filtration rate of fine coal slurries. A polymeric flocculant and oil were added to the disc filter feed material at various dosage levels. Both filter aids increased the disc filter output. For the coal tested, the flocculant filter aid achieved higher filtration rates at a lower cost.

Jan 1, 1988

To provide a flexible, low-maintenance, low-cost continuous mine air monitoring system as an alternative to conventional fixed-point, electronic monitoring systems. Background Continuous monitoring of mine air is highly desirable (and often required) not only to improve miner safety, but also to increase mine productivity. Continuous air monitoring systems can provide earl" warning of developing fires, excessive methane accumulation, reduced oxygen levels, and other developing problems in remote, inaccessible or sealed areas, and in active workings. Fixed-point, electronic systems require one Sensor for every gas to be measured at every defined monitoring location. As the number of monitoring locations increases, so does the cost, along with increases in the time required for routine maintenance and calibration of the sensor System cost also increases when monitoring locations are identified for mine areas requiring permissible electrical equipment.

Jan 1, 1988

By A. R. Przybylek

A fluid bed dryer has been designed for a nonconventional application to upgrade the value of fine anthracite culm and silt recovered from culm banks and anthracite tailings pond beds. This material can be seen as large spoil piles scattered throughout the anthracite coal regions of Eastern Pennsylvania. Engineering of the system commenced in December of 1986 and at this writing start-up is scheduled for late October or early November of 1987. This paper will focus on generalities concerned With system design and operation, and qualify the differences from conventional fluid bed coal drying systems.

Jan 1, 1988

By D. A. Rice

As part of a cooperative effort between the U.S. Bureau of Mines and the Florida Institute of Phosphate Research (FIPR), with input-from the phosphate industry, the conversion of phosphor-gypsum to sulfur is being investigated. The proposed process incorporates a thermal reduction of phosphogypsum to calcium sulfide (CaS) and a hydrometallurgical treatment to convert calcium sulfide to ammonium bisulfide (NH4SH), which is then oxidized using a catalyst to produce elemental sulfur. The paper summarizes the results of continuing laboratory studies using an activated carbon catalyst which was loaded with sulfur through oxidation of ammonium bisulfide solution. The extraction of the sulfur that forms in situ on the catalyst is a key area in the development of the sulfur recovery process. Two approaches for removing the sulfur are being investigated: 1) thermal treatment to volatilize sulfur, and 2) leaching the sulfur using liquid anhydrous ammonia. The research has shown that it is technically feasible to recover over 90% of the sulfur from the carbon by either volatilization or ammonia leaching. Locked-cycle testing has demonstrated that the carbon has the potential to be recycled after ammonia leaching.

Jan 1, 1988

By Andrew F. McKown, Robert A. McClure

This paper will describe a trench blasting case history in close proximity to several adjacent structures, including a bridge abutment, railroad tracks, and utility pipes. Some design considerations involved in close-in blasting will be discussed, including allowable peak particle velocities and prevention of rock block movement. The importance of several trench blast round design factors is pointed out, including choice of explo sive to prevent propagation, maintaining a sufficiently high powder factor, and mucking out for maximum relief after every round. Vibration monitoring and good record keeping are shown to be important in order to evaluate blast problems and make modifications to round designs.

Jan 1, 1988

By Ramani R. V

There are many important physical phenomena in mine ventilation which involve transient mass and heat transfer processes. These processes have been modeled using differential equations often solved with close form solution. Within the last two decades, many numerical schemes have been devised to solve these mass-transfer problems. Much of this effort has focused on variants of the finite element and finite difference methods. In this paper, the solution of mass transfer models in mine ventilation by finite difference technique is discussed. Specifically, the computational effort and the accuracy of the solution are presented.

Jan 1, 1988

By Thomas J. Peters

In 1987, at the request of the U.S. Bureau of Land Management, the Bureau of Mines studied the 350-acre Henry?s Lake Wilderness Study Area (ID-035-077) in order to evaluate its identified mineral resources. The Wilderness Study Area is located in northern Fremont County, ID, approximately 140 air miles north-northeast of Pocatello and 3 miles south of the Montana border. The Wilderness Study Area is near the north shore of Henry's Lake at the foot of the southwest-facing slope of Black Mountain. Archean hornblende gneiss, the main rock type present, crops out northeast of the Madison Range Fault, which trends northwest across the southwest corner of the Wilderness Study Area.

Jan 1, 1988

By J. A. Finch, J. Yiantatos, A. R. Laplante

This paper re-examines the mixing conditions in the collection zone of flotation columns. These have in the past been characterized with a single uniaxial dispersion coefficient, E. The relationship between E and column diameter, Dc, is examined based on residence time distributions (RTDs) in columns of Dc ranging from 5.lcm to 184cm. Results agree with published correlations in chemical engineering, i.e. E a Dc '" , Data explain why pilot columns display significant upgrading between the feed level and the interface, whereas plant columns do not. It also suggests that, for plant columns, the full collection zone (up to the interface) can be considered when calculating the residence time. A mathematical model considering two regions of different mixing was compared to the single E model. Both models adequately fitted measured age distributions inside the column and overall RTDs. Measured and simulated mixing characteristics are compared to those of flotation banks, using a tanks-in-series approach; banks of comparable mixing to columns are identified.

Jan 1, 1988

By Skaviniak M

Some better perspectives applying to the exploitation and dressing of polymetallic ores in the Banskfa. gtiavnica-Hod- rusea Ore District are supposed to be achieved after a suc- cessful investigation and proving there the existence of deep-seated mineralization as well as due to increasing de- mand for non-ferrous metals and consequently to higher mar- ket prices of those recently noticed. With respect to the present situation in mining and to the further technical development as well, a several times higher exploitation may be in this region expected, especially in the deeper .eated parts of the deposit. When solving the tasks of a complex economic exploitation over the whole region, consi- derable attention is paid to regional relations and impact studies (due to expected exploitation and ore dressing but also to very difficult problems of dewatering (drainage pro- blems-). It will be first of all necessary to find there an equilibrium between the consequences resulting from the re- naissance of mining industry and environmental requests un- dispensable for the city of Banska 9tiavnica and the other neighbouring towns in the vicinity of mining plants.

Jan 1, 1988