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We describe a new method of characterising the effect of dissolved materials on the rate of coalescence of bubbles in aqueous media. Single bubbles were allowed to rise to meet the surface of an aqueous solution, and the time of persistence between arrival and bursting of bubble was measured as a function of solute concentration. A laser beam was placed just above the surface of the liquid, with a detector in the light path, so that any disturbance at the surface could be seen as a break in the beam. The arrival of a bubble at the surface could be detected from the behaviour of the trace on an oscilloscope, and when the bubble broke, another significant change in the signal could easily be seen. The time between disruptions was reported as the persistence time. The effect of a homologous series of n-alcohols (C1 to C8) on the persistence time was measured, in aqueous solution. It was found that with increasing concentration of a particular solute, the persistence time increased up to a point, and then declined. However the magnitude of the persistence time was found to increase with increasing numbers of carbon atoms in the molecule. Bubbles of 1, 2 and 3 mm diameter were used. Persistence time increased with increasing bubble diameter, the maximum values observed being of order 100 secs. For a given solute, the persistence (drainage) time increased with increasing bubble diameter. The concentration Cmax at which the maximum persistence time was observed, was found to be independent of the bubble size. It decreased uniformly as the carbon number increased, and was well correlated by the function y1/2 (dy /dc) -2 I dc)-2 . There was no apparent correlation with the surface excess at maximum persistence time.

Jan 1, 2006

By V. Nenov

The study is based on the so called METASEP process which includes selective sorption of heavy metals by special bonding agents (BA), separation of boding agents from the water by means of microfiltration and/or flotation and regenerating the loaded bonding agents, leading to a metal concentrate for reuse or discharge. The bonding abilities of different bonding agents suitable for application in METASEP process were evaluated. Two groups of BA are studied, namely: chelating ion exchange resins and water soluble oligomers. The group of ion exchange resins studied includes eight organic resins, mostly chelating cation exchangers and representatives of conventional strong and weak cation exchangers. The resins with iminodiacetic and aminomethyl phosphoric acid groups showed highest affinity towards several heavy metals. The study of resin particle size showed that this parameter is a key factor influencing the kinetics of heavy metal sorption. The group of water soluble oligomers (WSO) includes polyvinyl alcohol, carboxyl-methyl-cellulose, polyvinylethylenimin and pectin. The Metal-WSO complexes were separated by Ultra Filtration. The effect of Metal-WSO mole ratio and pH was studied. Depending on the operational conditions the heavy metal retention varies within 68-99%. It was shown that regardless of pH and mole ratio Metal-WSO, separation of certain ion from the metal mixture is not possible.

Jan 1, 2006

By Antonio Karzulovic, Ricardo Sepulveda, Manuel Schellman

Mantoverde Division of Empresa Minera Mantos Blancos S.A., Anglo American Chile, developed an open pit mine to exploit copper oxide ore. Mantoverde mine is located in the Province of Chañaral, Northern Chile, about 1,020 Km far from Santiago. Currently, the East wall of the mine is reaching the condition of final pit. To evaluate the possibility of a pit optimization on this wall a geotechnical study was performed, including slope stability analyses by limit equilibrium and numerical methods. As a result of this geotechnical evaluation, it was decided to allow a probability of failure of 12% for instabilities affecting up to 600,000 tonnes, and use steeper slopes on the East Wall of the mine. This paper describes this geotechnical evaluation and how the results of the stability analyses were used to define a flexible slope design, which allows modification if the observed slope behaviour deviated from the expected one.

Jan 1, 2006

By H. Venkatesh, Balachander R.

This article discusses the method that was adopted for controlling damage to rock mass while excavating an underground powerhouse cavern at Tala Hydroelectric Project. It discusses in detail the near field vibration studies carried out and the safe vibration levels established for that rock mass condition.

Jan 1, 2006

By R. A. L. Drew, F. Jalilian, M. Jahazi

Joining of superalloy Inconel 61 7 with a foil interlayer using transient liquid phase bonding (TLP) technique was studied. Inconel 617 is a solid solution, Ni - Cr - Co- Mo alloy with an exceptional composition of high temperature strength, oxidation, carburization resistance and thermal stability. In this investigation, two bonding temperatures, 1065°C and 1150°C, and two interlayer thicknesses with joining times varying from 5 minutes to 24 hours were employed. Experiments were carried out using nickel base interlayer (A WS BNi-3) with boron as the melting point depressant (MPD) element. Joints were characterized using optical microscopy, SEM, FEG-SEM, EBSD, XRD and microhardness. The results indicated that the rate of elimination of the liquid phase with increasing the bonding temperature, holding time and decreasing the thickness of the interlayer increased. The main precipitates in the diffusion layer had platelike and blocky morphologies for both bonding temperatures and all holding times.

Jan 1, 2006

By William Everett, Jack Eloranta

United Taconite is an iron ore mine operated by Cleveland-Cliffs Inc (Cliffs) located near Eveleth, Minnesota. The mine, originally known as Eveleth Taconite Mines, was purchased in December 2003 by Cliffs (70%) and Laiwu Steel (30%). The mine site, known as the Thunderbird Mine, produces taconite ore for delivery by rail to the company’s Fairlane plant, located approximately 10 miles to the south near Forbes, Minnesota. At the plant, the crude ore is ground, concentrated and processed into pellets for steel industry customers. Total pellet production capacity is about 5.4 million long tons (Ltons) per year.

Jan 1, 2006

By Ahmet Geveci

In this work it is aimed to assess the plant analytical data which appeared during efforts to decrease the effect of carry-over slag (basic oxygen furnace slag) that can not be prevented to leak during tapping of steel in the ladles. While the amount changes, carry-over slag that escaped to ladle, consists of appreciable amount of reducible oxides (?FetO? and MnO) which act as oxygen source for steel bath. By using aluminum dross, containing %30-35 metallic aluminum, which is a non-recoverable process outcome (discard) for most of the aluminum factories, slag reduction behavior will be analyzed together with other parameters such as reaction time, initial amount of total Fe+MnO, amount of reducing agent and reducing effect of soluble aluminum in steel bath while obtaining a slag composition which promotes higher desulphurization capacity and inclusion removal for liquid steel.

Jan 1, 2006

By Wantae Kim

In order to establish the optimized recovery process for heavy minerals from Korean beach sand, we investigated the several physical separation methods such as gravity and magnetic separation followed by mineralogical characterization. There was clear relationship between the particle size and heavy mineral content that heavy minerals were mostly concentrated in the particles below 100mesh. Gravity separation using the spiral and shaking table separators made it possible to concentrate heavy minerals by rejecting the light and coarse particles consist mainly of quartz and other non-valuable minerals. The high-intensity magnetic roll separator and subsequent induced magnetic separator were applied to fractionate magnetic particles according to their magnetic susceptibility. The content of TiO2 of high susceptible ilmenite-rich fraction was 43.98wt.% while those of ZrO2 of non-magnetic and magnetic residue were 6.78wt.% and 3.11wt.%, respectively.

Jan 1, 2006

By Bjöm Böhle

Top-down construction (or cut and cover construction) is providing important advantages when comparing with conventional construction techniques for commercial developments with deep basements, underground car parks or near surface infrastructure and traffic tunnels. Main features are substantially reduced restrictions to surface usage, avoidance of intervention with adjacent property, provision of rigid substructures resulting in minimal deforma­tions and settlements and, last but not least, accelerated construction pro­gramme. The present contribution illustrates the construction method in general and elaborates in detail on the special foundation works for a major urban commercial high rise development requiring a six level basement structure.

Jan 1, 2006

By R. L. Derick

On a regular basis, mine personnel should obtain air samples directly from active underground areas as well as remotely from sealed locations. These samples provide mine officials with data relative to the makeup of the various atmospheres. Should conditions underground change, these results can provide a baseline that can assist officials in determining the extent of change. Relating the concentrations of individual gases to time, applying gases to equations, and examining their change over time are tools that have been successfully used to determine if a heating event exists and, if so, the extent of the emergency. These atmospheric status equations have either been developed for the mining industry or adapted from other industries. They serve as tools to assist personnel in determining the condition of underground mine atmospheres. As long as the problem area continues to be ventilated, certain gases, gas ratios, and equations can be used to determine if a fire exists, what type of material could be burning, and what quantity of coal is burning. Once the mine or the involved section has been temporarily sealed, gases, ratios, and gas-derived equations can assist personnel in determining how conditions within the sealed volume are changing over time. To alleviate potential explosions when fresh air is once again introduced into the sealed volume, equations and a diagram have been developed to predict the likelihood of an explosive atmosphere. Similarly, prior to commencing recovery of a mine or section, equations exist that can assist in determining if the fire will rekindle when air is reintroduced. This paper serves as an overview to remind and/or instruct readers about gas-sampling methodologies and gas analyses to assist in determining the status of underground atmospheres.

Jan 1, 2006

By M. Fafard, M. Dupuis, P. Goulet, J. Bédard

Start-up of a Hall-Heroult cell is a delicate task that can affect pot performance and pot life. Modem practices for high amperage cells involve preheating the lining before the molten electrolyte is poured in. Different preheating methods and heat-up schedules are used throughout the industry, and the optimum between a short start-up and damage minimization to the cell is elusive. Direct electrical coke-bed preheating is one of the most common techniques. This practice typically results in a non-uniform surface temperature distribution and can generate detrimental thermal gradients in the cathode blocks. Numerical modeling is an invaluable tool to study this complex problem and can help improve the preheating procedures. The modeling of the mechanical response of the lining is critical to detect risks of cathode block cracking or the development of gaps where liquids could leak into. Taking into account the baking of ramming paste, the quasi-brittle nature of carbon and the contact interfaces between different materials are examples of key elements to consider. A finite element slice model of a cell was built and simulations of different electrical preheating scenarios were performed using the inhouse code FESh++ to demonstrate what can be learned through thermo-chemomechanical modeling. The potential industrial application of the model is discussed.

Jan 1, 2006

By M Lund

Due to operational and regulatory practicalities, pit lakes will continue to be legacies of many open cut mining lease relinquishments. Unplanned or inappropriate management of these significant geographical features may lead to a short-term liability to all stakeholders during mining operations, or to ongoing liability to the local community and environment following lease relinquishment. However, the potential for pit lakes to provide benefit to companies, communities and the environment is frequently unrecognised and yet may be a vital contribution to the sustainability of the open cut mining industry. Improved remediation technologies are offering more avenues for pit lake end use than ever before, at the same time mining companies, local communities and regulatory authorities are also becoming more aware of the benefit these water resources have to offer. Sustainable pit lake management aims to better minimise short- and long-term pit lake liabilities, and yet also to maximise short- and long-term pit lake opportunities as well.

Jan 1, 2006

By H. Utsunomiya

Most magnesium alloy sheets show low deformability in rolling. Edge cracks and transverse fractures are common difficulties. In addition, rolled sheets show well-developed basal texture <0001>//ND. The texture causes high anisotropy in mechanical properties and low formability in subsequent metal forming. Differential-speed rolling, where the upper and the lower rolls rotate at different speeds, introduces shear deformation through the thickness. Not rolling texture but shear texture evolves in the sheet so that the asymmetric rolling can be a method of texture control. However the primary slip system of the hcp alloy, is basal, the shear texture should be also basal. Differences between the two basal textures, i.e., the rolling texture and the shear texture, have not been understood completely. In this study, conventional (same-speed) rolling and differential-speed rolling have been applied to commercial AZ31B sheets at 623K. Microstructures, textures and mechanical properties of the rolled sheets before/after annealing are compared. It is found that the basal texture is more pronounced by the asymmetric rolling. On the other hand, the asymmetric rolling is effective to decrease the grain size and the planar anisotropy.

Jan 1, 2006

By Kliment Y. Hakobyan

A new technology for treating molybdenum sulfide concentrates has been developed. It includes roasting the concentrate in a special regime with water vapor, cooling and neutralizing exit gas, oxidation roasting of rhenium containing MoO2, and the extraction of rhenium from exit gases. This technology allows economically efficient and environmentally safe processing of molybdenum concentrates: The degree of molybdenum extraction is 98.8%, rhenium-90%, sulphur-98.4%. The technology also ensures high extents of extraction of selenium and tellurium as well as the fixation of sulfur in the form of sodium sulfide or elemental sulfur.

Jan 1, 2006

By Raffaella Granata

The paper deals with the remediation of two areas formerly utilized for the disposal of hazardous wastes in a petrochemical plant. The works, designed on the basis of the criteria of maximum safety and minimum environmental impact, consisted in the confinement of the contaminated soil and groundwater within surface caps and perimetrical cut-off walls embedded in the underlying clay layer. The cut-off wall is 0.8 m thick and has a maximum depth of 33 m: it was designed to guarantee, as a minimum, the level of safety for a landfill for hazardous wastes, in accordance with the applicable National Standards. It was constructed with self-hardening mud and with the installation of an HDPE geomembrane. The HDPE liner of the cut-off wall was then sealed to that of the capping to obtain the complete encapsulation of the contaminated soil. A system of piezometers allows the monitoring of the cut-off efficiency measuring the fluctuations of the groundwater table and testing the chemical contents. Some wells installed within the contaminated areas will contribute to guarantee the full efficiency of the system in case of state of emergency, controlling the water-table level inside the confined areas.

Jan 1, 2006

By E Widijanto, A Srikant

PT Freeport Indonesia operates a copper-gold mine located in the remote highlands of Papua, Indonesia, about 3500 km east of Jakarta. Currently, the district produces about 240 000 tonnes per day (tpd) of which about 45 000 tpd come from the DOZ Block Cave and the rest is mined from the Grasberg Open Pit. Over the next ten years, ore production from large block caves in the area is expected to reach about 200 000 tpd, replacing a large part of the production from the Grasberg Pit. Block cave mining alters the hydrological characteristics of the area being mined and when the cave expresses itself at the surface in the form of subsidence, it increases the entrapment area for surface water. Operating a large block cave mine in a region with an average annual rainfall of 5500 mm in steep mountainous terrain and complex geological and hydrological features presents a challenging scenario for dewatering or depressurisation of the area. The high rainfall infiltration and entrapment in stacked mines operating within an essentially single orebody, coupled with the presence of fine-grained and clayey material within the draw points of the block cave, creates mud rushes or wet muck spills, which can endanger the personnel and interrupt production. This paper outlines the problems caused by high water inflow into the DOZ Block Cave and the efforts undertaken to ensure the safety of the miners and continued achievement of desired production rates from underground mining in the district.

Jan 1, 2006

By Kirk Nobis

Develop a Risk Management Plan for Your Mine ? Why? ? Measuring ? Managing ? Conclusion

Jan 1, 2006

By John O. Marsden

The past fifteen years have seen a number of important developments in copper hydrometallurgy, including the commercial application of biological heap leaching of secondary (chalcocite-dominant) copper ores, the commercial demonstration of chalcopyrite concentrate leaching technology using pressure leaching and biological processes, and the application of novel configurations of solution extraction circuits. Significant emphasis is now being placed on the development of effective stockpile leaching practices for primary ores (chalcopyrite and bornite-dominant mineralization). Some of these developments have been highly successful, and will pave the way for further development and commercialization. Others have been less successful. These developments are reviewed in the context of the metal price cycle and trends for the future are identified.

Jan 1, 2006

By M. E. Reed

Clyde Materials Handling (CMH) and WorleyParsons have developed a concept for a flash furnace feed system using the specialist pneumatic conveying equipment expertise of CMH and the flash furnace process experience of WorleyParsons. CMH has developed a proprietary volumetric feeder (called a Rotofeed) which is extremely accurate and overcomes many of the problems inherent with loss-in-weight screw feeders and drag chain conveyors, previously regarded as state-of-the-art. Initial indications are that the Clyde-WorleyParsons Feed System could deliver the following benefits to Flash Furnace operation: ? Accurate pulse-less delivery of feed material to the head of the burner leading to improved combustion performance and process stability; ? Highly accurate split to the individual quadrants of a conventional burner tube, or provision of a smooth hollow curtain to a burner without guide vanes; ? Decreased pressure pulsation in the furnace due to improved combustion control and performance; ? Decreased temperature fluctuations in the furnace due to improved combustion characteristics and hence reductions in refractory thermal stress and wear; Plant measurements have indicated a correlation between the discharge of concentrate from the drag chain conveyor and high speed pressure fluctuations in the flash furnace settler. Pilot scale test have been conducted to illustrate that the system delivers pulse-less feed to the burner with even feed distribution axially.

Jan 1, 2006

By P J. Fourie, J R. Walklate

Gravity separation techniques have been in use in the mineral sands industry for decades; from the Reichert cone to Wilfley tables, Wright sluices and the Kelsey Jig, all attempting that elusive perfect gravity separation. Just as the gravity separation industry evolved, Richards Bay Minerals also evolved in their use and approach to gravity separation. This paper discusses the history of gravity separation at Richards Bay Minerals and briefly comments on future developments. History Primary Concentration Richards Bay Mineral?s (RBM) first mining concentrator and mineral separation plant commenced operation in 1977 to process ilmenite, rutile and zircon bearing dunal deposits along the northern Natal coast. The orebody contained a greater proportion of non-valuable magnetic heavy mineral in the SG range of 3 to 4 compared to West Australian and Florida USA deposits, making mineral separation more difficult(1). The deposit was mined using two dredges feeding a floating 2000 tph concentrator. Concentrator feed was screened and fed to two four-stage circuits consisting of primary, scavenger, cleaner and recleaner Reichert cones [see Figure 1]. The primary units were fed at a rate of 80 tph and a density of 60% solids by weight.

Jan 1, 2006