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By Masakazu Daté

Moisture effect has been studied for the CO oxidation over Au/TiO2, Au/Al2O3 and Au/SiO2, in the range of H2O concentration over four orders of magnitude. It has been found that the catalytic activity is generally enhanced by moisture in the reactant gas. The enhancement is as large as two orders of magnitude. Response to the moisture concentration, however, depends on the support oxide, indicating different contributions of the support to the reaction steps. The moisture effect is reversible and the activity is mainly determined by the amount of moisture absorbed by the catalyst. The apparent activation energies are not significantly influenced by moisture for Au/TiO2 and Au/Al2O3. On the contrary, non-uniform conversion curves versus temperature observed for Au/SiO2 are drastically changed, which indicates that the reaction over Au/SiO2 does not take place at low temperatures without moisture. The moisture effect may be probably attributed to the decomposition of carbonate species accumulated during the reaction, while the ?OH group might directly participate in the reaction pathways as a promoter.

Oct 1, 2003

By Candido Bariáin

A new vapochromic material of formula [Au2Ag2(C6F5)4(bipy)2]n (bipy = 2,2´ bipyridine) has been developed and used for the detection of some volatile organic compounds as acetone either in vapour or in water solution. The material is presented in the form of powders which colour changes with acetone vapours turning from bright yellow in the absence of vapour to white in the presence of vapour. By using the sol-gel technique, the powder ? dispersed in tetraethyl orthosilicate- was easily deposited on optical fibres. In order to study experimentally the behaviour of this material for construction practical optical fibre sensors, a sol-gel material doped with the vapochromic material is deposited onto an extreme of a monomode fibre connected to a coupler. The behaviour of the material was studied for different wavelengths and concentrations of acetone vapours and acetone/water solutions. Changes up to 4dB in the reflected optical power were detected. Optical fibre sensors have many advantages over conventional ones, such as electromagnetic interference immunity, passivity behaviour, possibility of using multiplexation techniques, low weigh and little size, etc. Actually, there is an increasing interest in developing optical fibre sensor for vapour detection in the chemical industry and in fact many sensor had been developed [1]. Some are based on the deposition of a sol-gel-based material either over the core of an optical fibre [1] or onto the thinner zone of a biconically tapered optical fibre [2]. Others are based on Fabry-Perot interferometers [3]. Also there are sensors based on the reflection of the light on films, on the fluorescence of dye-doped polymer cladding in fibre, on colorimetric reagents in the core of a silica fibre or on surface plasmon [4]. The possible materials for the construction of such sensor should be colorimetric reagents able to change the colour or refractive index in the presence of same organic vapours. There are not many metallic complexes with these properties, although same interesting examples have been reported in the chemistry of palladium and platinum as [Pt(p-R-C6H4NC)4][Pd(CN)4] described by Nagel [5] and Mann [6], which reported the construction of some LEDs. We recently reported the preparation of a novel vapochromic material (Fig 1) [7] which can be used for the construction of optical fibre tapered environmental sensors [8,9] of vapour organic compounds (VOC´s). Also we reported other nickel and palladium derivatives which present this type of behaviour [10]

Oct 1, 2003

By Michele L. Kimble

A fast-flow reactor mass spectrometer has been utilized to investigate the reactions of gas-phase gold cluster anions with CO and oxygen. Addition of CO to Aun - produces species of the form Au(CO)m -, where m = 2-5. However, CO does not bind to Au2 - or Au3 -. With oxygen addition in the cluster source, gold oxide species with both molecular and atomized oxygen are produced. The addition of carbon monoxide to these preoxidized gold cluster anions reveals that select species with 1, 2, and 3 gold atoms participate in the oxidation reaction to produce CO2. Bimolecular rate constants for the reactions between these species and CO are also discussed.

Oct 1, 2003

By S. Ivanova

The results presented in this paper show that the gold solution dilution is a key parameter to control the dispersion of gold on ?-Al2O3 the selected support. The variation of concentration leads to changes in pH which modify the nature of gold complexes from HAuCl4 formed in the solution. These complexes are presented. Some of them (AuCl3(OH)- and AuCl2(OH)2 -) react with the surface of alumina and give interesting interaction. AuCl2(OH)2 complex has been considered as an ideal complex because of the strong anchorage of a bidentate species on the alumina. This complex is formed mainly in a solution of gold with a concentration of 10-4 M giving a pH of 3.5-4.5. The nature of the anchorage and the amount of chlorine, has an influence upon the formation of Au-Cl bridges which modify the dispersion of the gold on alumina of the final catalyst as shown by TEM.

Oct 1, 2003

By John A. Rumball, Martin R. Houchin

Data from autogenous and semi-autogenous tests in a 1.67m diameter mill have been analysed in terms of a new model for rock abrasion. This model defines specific rate as the rate of production of fines (material less than 13mm) per unit mass of rock, where the term “rock” is applied to all ore pieces of ore coarser than the grate size. In most cases, an allowance for preliminary rounding and cleavage was made. A method has been developed to analyse steady-state data, using piecewise fitting to the cumulative size distributions. The model was compared to the well-established models, which are based on the population balance method. The specific rate increased for all rock sizes as the volume of 100mm balls in the mill was increased. Tests using a coarser feed and smaller balls provided further evidence that once rocks are rounded, abrasion is due to localised surface damage, caused by impacts, rather than rotational shear. An allowance for rapid rounding of jagged rocks, followed by less rapid abrasion of rounded pebbles was also tested, but the analysis was not conclusive. The average specific rate is a useful measure of the capacity of a primary mill. The effect of power intensity (kW/t of ore) was also investigated as a means of extrapolating the pilot-plant data to large production mills.

Sep 29, 2003

By Ron H. Derammelaere

"The paper point out of the copper slurry pipelines in South America, providing key statistics, such as throughput, diameter, length, etc. In addition, it will present technical aspects of pipeline design that are unique tomountainous terrain, specifically: choke stations for the control of slack flow, batch hydraulics, automation and training.The pipelines listed in this paper operate successfully at availabilities in excess of 98%. Breaks and plugs can occur due to operator error, but are extremely rare. A review of cross-country slurry pipeline operations worldwide over the last 30 years shows that such a major event occurs, on average, once every five years. Under such a worstcase condition, the downtime rarely exceeds five days. Some pipelines have already been in operation over 30 years, the life span being a function of how well corrosion is kept in check."

Jul 31, 2003

By Marc Leduc

Since co-disposal technology promises to replace conventional tailings disposal methods at sites with high strip ratios or plentiful old dumps. While the mine waste needs to be relatively strong and low in fine material, and chemical compatibility must be assured, when these parameters are satisfied there are no other significant hurdles to its implementation. In this sense, the paper describe the resulting benefits range from substantial reduction in capital and operating costs to reduction or essential elimination of the short- and long-term liabilities associated with tailings dams are impoundments.Since tailings dam failures are arguably the greatest environmental liability and public relations problem in the industry, reducing the quantity of tailings managed behind dams is a worthy goal.

Jul 31, 2003

By Samuel Canchaya Moya

Si bien en las últimas décadas se aplicó el estudio de la geoestadística en la minería, el uso de la técnica no ha logrado una mayor difusión. En ese sentido, el presente texto señala la aplicación de los paquetes de software en la minería a través de los módulos de geoestadística. En este punto, la optimización del muestreo, se convierte en un problema tanto en la etapa de exploración como de producción. Por ello, es necesario conocer y comprender los conceptos y métodos geoestadísticos que se apliquen a la medida de muestreo de la veta, ver distancia y ubicación de taladros, costos de campaña de exploración, entre otras medidas, etc.

Jul 31, 2003

By Oswaldo Ortiz Sánchez

El presente trabajo describe la alternativa de uso del mortero de resina en la fijación de pernos de anclaje de las excavaciones mineras, consolidación y disipación de vibraciones en los cimientos de plataformas para la instalación de molinos, winches, tolvas, etc. Esta opción surge en respuesta al problema de reforzamiento con pernos de anclaje en ambientes con aguas corrosivas o en proceso de deformación acelerada en las excavaciones mineras, así como ante obstáculos de subsidencia de cimentación en plataformas, donde se encuentran instalados equipos de gran tonelaje, y que producen fuertes vibraciones durante su funcionamiento.

Jul 31, 2003

By William R. Adamson

"The paper point out how mechanistic blast outcome models can be employed to explore the likely extent of achievable benefits associated with application of different explosive products, of quantifiably known characteristics.maximizing the advantages of the use of this modeling approach requires the use of field based measurements as model inputs, as has been done in this particular study. Inevitably, enhanced confidence in the routine application of the approach will be obtained through the collection, analysis and interpretation of field performance verification data such as fragmentation size distribution data. "

Jul 31, 2003

By George Shou

"The paper point out about economics of thickened tailings transportation. In this sense, the optimal concentration is determined based on the balance between the incremental costs of thickening and transportation and theincremental environmental benefits. A detailed feasibility study is essential for financial success of a tailings project. Hydraulics modeling is the key to estimate the transportation cost curve. "

Jul 31, 2003

By Alexander Seyfarth

X-ray systems for elemental and phase determination have become more expensive and easier to use. In this sense, although the new systems offer more functions in the software for matrix correction, preconfigured optimized measurement parameters as well as wizards for method development, they will not perform for the applications if not used with the right sample preparation technique. Experience in this sector is not widely shared since it is a more empirical trial and error approach unique to the sample preparation equipment used. This paper outlined 3 case studies, where the sample preparation was crucial in the adaptation of the X-ray technique and it also illustrated that an analytical solution is not complete without the sample preparation, which ultimately governs the accuracy of reference materials and unknowns used. Comparing the necessary sample for XRF with the one used for ICP analysis clearly shows the time and cost savings.

Jul 31, 2003

By Francisco J. Sotillo

"The paper point out the fundamentals of surface chemistry used on the design of this organic polymer, and its effect on the rheology of clayishphosphatic slurries in comparison with other available dispersants. Reducingthe viscosity of clayish slurries increases phosphate particles settling rates, and decreases value losses during desliming using gravitational forces. Also presented the improvement of desliming using centrifugal forces by achieving better separation of the ore from the slimes during cycloning."

Jul 31, 2003

By Edmundo Alfaro

"The paper point out about on the use of ion exchange resins for adsorption of gold from ammoniacal thiosulfate solutions. In this sense, the gold can be recovered from ammonium thiosulfate solutions with strong base resins. The amount of gold loaded onto the resin in a batch process is a function of gold concentration in solution, amount of resin, volume of solution, copper and competing ions concentration in solution. Thiosulfate concentration in leaching solution has influence on gold loadings onto resins; in contrast, ammonia concentration in solutions has no influence on gold loadings. Gold seems to be loaded onto the resin preferentially over copper - thiosulfatecomplexes and also over thiosulfate ions. Polythionate ions strongly compete with gold and copper thiosulfate complexes for resin sites. This causes reduction on gold and copper recoveries from the leaching solutions. Even more, polythionates are produced in leaching solutions when thiosulfate is oxidized by the action of both copper and oxygen. "

Jul 31, 2003

By Juan Antonio Huamán Fernández

De acuerdo al estudio que realizó la Dirección General de Minería del Ministerio de Energía y Minas en el Perú, las estadísticas de accidentes fatales reportadas a escala nacional en el 2002 indican que la mayoría de accidentes fatales ocurridos en mina subterránea corresponden al 40% de desprendimientos de roca. Por lo cual, las empresas mineras preveen un programa basado en el desarrollo de la técnica de Gestión de Riesgos, que les permita un control en la seguridad del proceso. En este sentido, el presente texto desarrolla una técnica que identifica los diferentes factores que intervienen en los riesgos principales a través de los riesgos asociados; es decir, cuáles son esos riesgos asociados que influyen negativamente en cada una de las tareas que puedan causar accidentes.

Jul 31, 2003

By Patrick P. M. Afenya

"The paper point out the mineralogical aspects about metals processing volcano-related gold, silver and copper ores. The copper group of metals comprises gold, cooper and silver. These metals have been considered together here because of similarities in their chemical properties. Consequently, these metals commonly form minerals with the same elements or group of elements. It is realized that the formation of minerals and final physicaland chemical states of any mineral may depend on many factors such as temperature, pressure, activity of species and pH of the fluid, mode of formation, paragenesis, geological age and post crystallization events. For the purpose of this discussion, attention will be focused on temperature as the principal factor influencing mineral formation."

Jul 31, 2003

By Andrzej Hebda

The paper point out the method to meet the formal requirements for carrying out occupational risk assessment in companies imposed by various regulations and practical needs of modern safety management in company. The method presented allows also utilizing the assessment of economic effects of work accidents to assess the economic value of the risk resulting from the possibility of harm to health occurring to mine staff. A risk assessment example included in the paper and the calculations made permit positive assessment of the usability of the event-tree method for assessing the risk under conditions of limited availability of statistical information on the frequency of harm occurring. The method presented has also this advantage that it is not based on accident ratios that for many reasons do not always conform to reality and always show past safety level, not anticipating accidents but only recording them.

Jul 31, 2003

By Pedro Fuertes Velazco

El presente trabajo describe el desarrollo de la compañía minera de Caravelí (Arequipa) como mina modelo -en tanto genere alta productividad en las vetas, genere su propia tecnología, así como su responsabililidad con el ambiente y las comunidades involucradas.

Jul 31, 2003

By Reinhold A. Errath

"The paper describes the problem related with contradiction to the development of sag mills, which one are becoming bigger in size almost every year. In this sense, the concentrator plants are being built more and more in remote areas where the power supply and network conditions are not necessarily covering the needs for the operation of such plants. It also illustrates the permissible tolerances in terms of commutation of the powerelectronics, based on already realized installations. Finally the paper gave an overview about the technical impact of a strong versus weak networks."

Jul 31, 2003

By Scott Elfen

The degree of saturation in leach facilities and waste dumps can be determined by means of this simple test equipment. A design flow rate is applied to the sample, which is equivalent to irrigation and/or the design storm event. In this sense, the paper point out that the tests were carried out on two different ore sizes from the Pierina Gold mine in Peru. The samples were remolded by using three different densities, simulating different depths within the heap. The ore was subjected to a predefined flow rate, which was equivalent to the design irrigation rate. The flow rate was increased to consider the additional effect of the design storm event during irrigation. In the future, further tests will be performed using different ores samples from operating mines and varying different parameters to help built a database and develop other useful applications from this test, such as general guidelines for maximum irrigation rates for leach facilities.

Jul 31, 2003