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Physical and chemical methods were investigated to tower thorium levels in Eneabba Ilmenite from the natural levels of 180-500 ppm to give Becher Process synthetic rutile with less than 100 ppm thorium. Chemlcal treatments, but not physical separations were successful. A pilot plant trial of a sodium hydroxide leach (25M NaOH at 75°C and 40 wt% solids for Ih) followed by a sulphuric acid leach (3M H2S04 at 90°C and 60 wt% solids for 211) confirmed that thorium could be removed to below 100 ppm. However, the activity of the ilmenite was not lowered to the same extent

Jan 1, 1996

By G. Laird, N. B. Gray, N. Lawson

"Photographic, video, laser, hot film and conductivity methods are used in the experimental study of gas-liquid flows. A discussion of their capabilities and limitations are given in this paper illustrating the wide range of phenomena that can be studied. Most of these methods are limited to physical models at room temperature with transparent fluids, although they can be extended for use with opaque and hot fluids. A number of these techniques have been used by the GKW CRC in studies on industrial plants and their usage is increasing although a number of technical difficulties still need to be overcome. An in-depth discussion of the laser doppler anemometry (LDA) and particle image velocimetry (PIV) methods is given with experimental results on the flow field of an air plume in water based on advanced development of the techniques and studies carried out at the GKW CRC. The LDA method provides high resolution data on the velocity profiles, while the PIV method provides an overall view of the complex flow structure occurring at the gas-liquid regions. These two methods complement each other in providing experimental data for validating numerical models and exploring the complexities of multi phase flows.IntroductionThe injection of gases into melts is an important operation in the metallurgical industry. It is used in converters, anode furnaces, blast furnaces, ladles, bath smelters, zinc fumers and many other smelting processes. In many of these processes, the gas is injected into a molten bath resulting in the formation of bubbles that promote reaction, mixing, alloying and heat transfer. The study of gas-liquid systems presents enormous challenges to the researcher due to the complexity of the mathematical and physical modelling which require innovative numerical and experimental skills."

Jan 1, 1996

By J Taylor, L Richards, M McKenzie

When a collapse in its services shaft caused rapid gas build up and its premature closure in. 1951, the Blackwater Mine at Wiauta was in full production with significant ore reserves yet to be mined. A total of nearly 23 tonnes of gold was produced from the mine during its 44 year life. It was New ZealandÆs deepest underground mine, producing gold from an extensive sub-vertical mineralised quartz reef that averaged 0.6 m in width. Mining was by stoping between adits and short shafts, latterly with the main mine access through the 840 m deep Prohibition shaft. Macraes Mining Company Ltd are presently investigating the possibility of reopening the mine. This paper outlines a preliminary assessment of the main geotechnical factors for achieving the reopening, using recent exploration and old mine information. The greywacke host rock mass in the vicinity of the quartz reef has been evaluated using both these sources, and the paper discusses how the geological structure, intact and rock mass strengths, the rock mass defects, in situ stresses, and groundwater inflows may effect the reopening and support of the prohibition shaft, the excavation methods and support for a new supplementary shaft, and the likely excavation and support requirements for working adits and stopes in the rejuvenated mine.

Jan 1, 1996

The kinetics of adsorption of gold di-cyanide onto activated carbon has been investigated extensively over the past two decades. These studies have demonstrated that both film and intra-particle mass transfer affect the kinetics. The dominant mechanism of intra-particle mass transfer has not yet been identified. In the work described, surface diffusion and pore diffusion are considered as possible rate-determining mechanisms of intra-particle mass transfer. Mathematical models are described that incorporate film mass transfer and the respective intra-particle mass transfer mechanism with equilibrium described by a Freundlich isotherm. Rate constants of film mass transfer and pore or surface diffusivities were estimated by the fitting of the respective models to experimental carbon adsorption data. The estimated pore diffusivities, after they had been corrected for the porosity and tortuosity of the carbon, were found in most instances to be higher than the molecular diffusivity of dilute gold di-cyanide in aqueous solution. This situation is not physically viable. The surface diffusion mechanism acting in parallel with the pore-diffusion mechanism is thus responsible for the intra-particle transportation of most of the gold.

Jan 1, 1996

By J. Cassells, N. Chrisman, R. Arnold, P. Rusin, L. Quintana

Toxic substances in On solutions can retard biological leaching of sulfide dump ores. On solutions were ana1yzed for metals, organics and chloride and showed inhibitory concentrations of aluminum, manganese and chloride. Inhibition of bacterial activity by the solid fraction of On solution with and without the organic constituents, was evaluated. Bacterial toxicity was evaluated by monitoring bacterial numbers, pH, Eh, and rates of iron oxidation. The On solution solids were toxic at 50% to 60% of their field concentration. Most of the toxicity of the On solution was due to the organic fraction. Different solvent extraction (SX) reagents show varying degrees of inhibition of T. ferrooxidans. Bacterial inhibitory effects of carriers and lixiviants used in the SX plant should be determined so that entrained SX reagents do not retard biological dump leach systems. The reagents used should be the most cost-effective and the least toxic.

Jan 1, 1996

By S. Vongpaisal, T. R. Yu

"A set of new blast damage criteria has been developed, with special reference to blasthole mining operations, for assessing damage by incorporating the vibration level, rock properties, site characteristics and the effects of ground support systems. The main objective of this work was to provide a database with reasonable accuracy for use in optimizing blast design, numerical analysis and ground control expert system module development.The new damage criteria allow one to estimate the degree of damage to rock structures in terms of a dimensionless parameter defined as Blast Damage Index (BDI). This allows for the description of blast damage in a unified form, and facilitates the development of codes for numerical modelling to express the degree of blast damage universally. A number of field investigations from several stope production and slot opening blasts at a large underground base metal mine were carried out to verify the developed index. The results show a good correlation between the observed damage and the type of damage predicted from the BDI values.Practical measures are also provided for minimizing blast damage in large underground blasthole mining operations"

Jan 1, 1996

By P. W. Finck

Detailed mapping, using a large diameter diamond-drill in conjunction with high resolution reflection seismics, has increased known resources of kaolin clay and glass-grade silica sand from scattered deposits generally < 1 km2 to large areas of Cretaceous valley fill up to 130 m thick. Detailed chemical and physical analysis of drill core is presently underway. Silica sand deposits intersected in this study are up to 99.4 % SiO2 without beneficiation. Light grey to white kaolin clays identified by XRD and DT A have concentrations values (without beneficiation) up to 47.28% SiO2, 37.44% Al2O3, 0.45% Fe2O3, 0.49% K2O, 0.07% Nap, 0.07% CaO and 0.39% MgO.

Jan 1, 1996

By M. E. Poad, M. M. McDonald, J. C. Johnson, W. G. Pariseau

A U.S. Bureau of Mines case study of pillar recovery in high-grade ore near the Ross shaft at the Homestake Mine, Lead, SD, has demonstrated the usefulness of the finite-element method for evaluating shaft pillar mining plans and shaft stability. In this study, borehole extensometers and other instruments were installed to provide data for model verification and to monitor shaft displacement. Results of a recalibrated two-dimensional model (UTAH2)confirmed the premining stability evaluation. However, after mining began, concern developed because of cracks and other signs of ground motion that appeared at considerable distances from the area of active pillar mining. An intense three-dimensional modeling effort using the computer modeling program UTAH3 was initiated. The results again showed the observed effects were within expectations and that the shaft would remain safe. Three-dimensional analyses of alternate pillar mining scenarios indicated that more of the shaft pillar ore reserve could be recovered than previously thought on the basis of two-dimensional analyses. This report focuses on startup and implementation of the three-dimensional model, calibration of the three-dimensional model, and application of the model to shaft pillar mining.

Jan 1, 1996

By Rolf R. Schillinger

Subject of the paper are blasting vibrations as sources of environmental molestations including acceptance level,complaint level and damage level as well. Besides, the subject shows a comparison of international regulations and their problematical aspects. In consideration of blast induced immissions the subject shows that human annoyance has become an important place in blasting works. It provides a solution proposal how to minimize environmental effects of blasting works.

Jan 1, 1996

By S. Narasimha Rao

Bored cast in situ piles are highly susceptible to construction defects like necking, discontinuity in concreting, poor compaction of concrete, improper end bearing condition due to inadequate cleaning of bore hole, exposure of reinforcement, segregation of concrete etc. There is a necessity to understand the behavior of piles so as to design effective foundation system. In this paper investigations of two field cases were discussed to bring out the effect of defective piles. In one case improper end bearing has been discussed for a concrete pile of length of 45m and diameter equal to 1.2 m and is reinforced with 32 no&apos;s of 28mm diameter steel bars and in another case necking of the pile has been discussed. Further model piles with preformed defects have been tested in laboratory to bring out the influence of defective piles.

Jan 1, 1996

By Kunihisa Katsuyama, Yuji Ogata, Yuji Wada

The one free surface blasting of a concrete block was simulated by Discontinuous Deformation Analysis(DDA) method. Comparing the simulated results with the concrete block blasting experiment, the crack growth and the free surface displacement which were simulated by DDA were observed with a high speed camera.

Jan 1, 1996

By K. Y. Haramy, B. T. Brady

A scale-invariant theory of the strength and deformability, of rock masses in static equilibrium and at incipient failure is proposed The theory provides a rationale, for designing structures in rock. This paper presents results of experiments conducted by the US Bureau of Mines and presents theoretical methods to determine and interpret the in situ strength of rock masses using the borehole shear tester.

Jan 1, 1996

By E. Kaya

Investigations of fine grinding of bituminous coal in a laboratory-scale pulverizer are described. The results indicate essentially "normal" breakage behavior at relatively coarse sizes (greater than about 20 µm) but show clear evidence for re-agglomeration in the fine size range (less than about 10 µm). A simplified population balance model for simultaneous growth and breakage has been formulated. Breakage rates and breakage distributions are assumed to follow the patterns typically observed in simple grinding systems. It is recognized, however, that solid particles and agglomerates may exhibit different breakage behavior. Agglomeration rates are assumed to be determined by contact probability, i.e. by the relative numbers of interacting particles. Based on comparisons of model simulations and experimental data, it appears that agglomerate re-breakage rates and fragment size distributions are quite different from those for solid particles. The result is that product size passes through a minimum and then increases with time as agglomeration begins to dominate.

Jan 1, 1996

By C. R. Edwards, D. G. Feasby

"Over the last 50 years disposal of uranium mill tailings has evolved from dumping untreated tailings into the nearest depression to depositing chemically-stabilized tailings into highly engineered management facilities. This paper describes the evolution of disposal methods and the criteria which have determined the development path followed. Remediation techniques to bring older and now unacceptable tailings deposits into satisfactory compliance with today's· regulations are reviewed.With the closure of the uranium mines in Elliot Lake, Ontario, considerable effort is being made on decommissioning the tailings areas by developing long term maintenance of water covers. The innovative methods being used to develop these water covers are detailed. Methods now under development in Saskatchewan for subaqueous deposition of high density or paste tailings for permanent disposal in mined out open pits are described.SummaryThe technology for uranium mill tailings disposal in Canada has evolved considerably over the past 51 years. This evolution has been driven by an improving understanding of how best to safely and permanently store tailings, in conjunction with stricter environmental protection regulations. Old sites are being decommissioned in situ, but may require long term care and maintenance. The use of water covers is an important technique in eastern Canada to prevent intrusion, radon evolution and, for the Elliot Lake tailings, acid generation. The major drawback of water covers in any above ground disposal method is the requirement that a long term maintenance and monitoring plan be put into effect for each site.New higher grade mines in Saskatchewan will increasingly use disposal in mined-out pits using the pervious surround method and/or paste tailings technology as a method to permanently dispose of these wastes and to permit “walkaway” after a few years of monitoring."

Jan 1, 1996

By Dave Bigby

Hatworth Colliery, operated by RJB Mining (UK) Ltd, is successfully mining the Deep Soft Seam at a depth of 1000m using single face retreat longwalling. The seam is characterised by a weak roof generally comprising 4 to 6m of well bedded carbonaceous mudstones overlain by weak siltstones. The paper describes the layout and support design strategies which have enabled the colliery to adopt sole support by rock reinforcement techniques for its longwall gateroads. To achieve this success the colliery layout has had to be radically modified to take account of the in-situ horizontal stress field. The layout is also closely controlled by environmental considerations, the seam being one of the gassiest in the UK Economic support by strata reinforcement has been achieved using a combination of rockbolting of the roof and sides installed at the face of the heading, and systematic double birdcage cable bolting installed on drivage and supplemented ahead of the retreating panel. The layout and support strategies have been developed through a combination of detailed underground measurement of support and stress parameters backed up by numerical modelling using FLAC. The FLAC modelling has paid particular attention to careful representation of bedding properties and validation through underground stress measurement.

Jan 1, 1996

By J. Pérez

A lead smelter slag with high copper, lead, arsenic and silver contents was treated at laboratory scale for arsenic removal. The slag was first leached at atmospberic pressure with sulfuric acid and oxygen. According to arsenic contents leaching of most of the arsenic was achieved in either one or two stages, producing a lead-silver rich residue and a solution high in copper and arsenic concentrations. Alternative routes were considered to treat the resulting solution. Firstly, solvent extraction of arsenic with a mixture of TBP and 2-etbyl-bexanol was tested and extractions of over 95 percent of arsenic were achieved. Secondly, a copper arsenate precipitation treatment was done to eliminate arsenic and copper from solution.

Jan 1, 1996

By KNona C. Liddell

"Many metal recovery processes involve heterogeneous reactions in porous media accompanied by fluid flow and mass transfer. Modeling such systems is difficult because of the number of rate processes involved and is complicated even further by effects due to the structure of the porous medium. Data on even bulk properties of the medium are often severely limited or unavailable. For many such systems, a cell model may provide an attractive alternative to models based on transport mechanisms in a differential volume. A cell model requires less input data and is computationally efficient. Identical residence time distributions can be obtained with models of both types, and both allow conversion and concentration profiles and histories to be calculated. The formulation and properties of cell models for metals recovery are described in detail.INTRODUCTIONSubsurface mineral leaching, metal ion recovery and environmental remediation are significant modeling challenges. They involve one-, two-, or three-dimensional reactive flow in multi reaction open systems. Dissolution, adsorption, and ion exchange occur at reactive mineral surfaces, and these heterogeneous reactions are accompanied by acid-base, complexation, and redox reactions in the solution phase.Two approaches have been taken to reactive flow problems in geologic media: mixing cell and transport models. Mixing cell models, the subject of this review, are based on a network of connected cells, each with a specified number of input and output streams. Mixing cells are assumed to have no internal solute concentration gradients, that is, each cell behaves like a well-stirred tank. Gradients are represented by step changes between connected cells; this results in a model that is spatially discretized at the outset. Different methods of discretizing the model equations are considered more fully below. Although this is not strictly necessary, it has usually been assumed in subsurface flow applications that all cells in the network have the same volume and identical initial properties."

Jan 1, 1996

By J. D. McAteer

It is widely agreed throughout the mining community that federal mine safety and health legislation administered by the Mine Safety and Health Administration (MSHA) deserves significant credit for the past quarter-century&apos;s remarkable improvements in miner safety and health. Recently, however, it has been suggested that the mining industry in the United States has now evolved to a point that current mine safety and health law may be obsolete. This proposition deserves attention. Today, I propose to give it the close logical scrutiny that is its due. I conclude that the obsolescence of current mine safety and health law is not supported by the evidence. The existing mine safety and health law continues to serve as a critically important supplement to mine operators&apos; safety programs at a modest cost to the taxpayer. At the same time, trends in a changing industry do call for responsive adaptations in the Federal mine safety and health program. I will argue that timely and appropriate responses to changing needs can be accomplished within the framework of existing legislation, provided federal officials avail themselves of the flexibility provided by existing law.

Jan 1, 1996

By Dougal R. McCreath, Dwayne D. Tannant, Peter K. Kaiser

The Geomechanics Research Centre at Laurentian University in Sudbury, Canada, has undertaken a five-year research program into the design of support appropriate for control-ling damage caused by rockbursts. Rockburst damage mechanisms in Canadian hardrock mines are reviewed and a support design approach is presented. Each element in a sup-port system performs a reinforcing, holding, or retaining function. The desirable load-displacement characteristics for elements in burst-resistant support systems are described, and recommended support systems are presented for a spectrum of rockburst conditions ranging from minor to severe. A support system can be designed to (a) prevent the triggering of aground fall or a rockburst; (b) deform to accommodate the large imposed deformations arising from a rockburst; or (c) absorb the kinetic energy contained in ejected blocks of rock.

Jan 1, 1996

By Rainer Schmid-Fetzer

"Isothermal solidification can be used to form strong bonds at low temperature which remain solid at much higher temperatures. The exploitation of this principally known technique for new high temperature processing steps and applications in electronic assemblies is the aim of this study. Three basically different variants of this bonding process are given. A comprehensive metallurgical screening is performed and the feasibility of binary material systems is given on a quantitative scale. Very attractive systems are spotted that have never been studied before. Detailed examples for the realization of bonding with complex ternary and multilayer systems are given. A highly innovative example is the chip stack or wafer to wafer bonding of unmetallized Si or SiC at 250°C. The proposed bond remains stable above the melting point of Si and enables entirely new semiconductor manufacturing steps. An improved die bonding process was proposed and verified experimentally.1. IntroductionIsothermal solidification can be applied to form strong bonds at relatively low temperature which remain solid at higher temperatures. The general principle of this type of joining processes is illustrated in Fig. 1. An interlayer of a low melting component, Lo, is provided as a foil or a thin film coating between the high melting joint components, Hi. The assembly is heated under moderate pressure to the bonding temperature, T 8 , and a liquid filler forms, either because the melting point of Lo is exceeded or due to a eutectic reaction between Lo and Hi. This molten filler initiates a rapid interdiffusion or reaction diffusion between Lo and Hi and the subsequent approach to an equilibrium state results in isothermal solidification. The solid phases formed at T 8 in the joint region exhibit a remelt temperature above T8 •"

Jan 1, 1996