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By Richard S. Dennis

Acid recovery employs ion exchange (I-X) resin as separation media for inorganic acids from dissolved metallic salts by physical adsorption and without the use of chemicals. This technology has been used for years on spent etching and plating liquors to recover acid for reuse in the bath and to reduce waste acid neutralization costs. It is also used for electrolyte treatment to facilitate valuable metal recovery via acidity reduction. TETRA's ccrxr'" I-X contactor has been used successfully for acid separation from its metallic salt counterpart in a simple, continuous operating mode using strong base anion resins. Efficient separation is enhanced by acid reconcentration to nearly its original strength or as high as 14-20%. Continuous treatment also recovers heat to the tankhouse or bath and improves metal quality due to consistent acid quality. Conventional fixed bed ion exchange (I-X) systems are impractical for acid recovery because of complex control design and large resin inventories needed to process very low liquid-to-resin treatment ratios associated with strong acid concentrations.

Jan 1, 1996

By Abishev D. N, Balakirev V. F, Davydov G. I

The problem of recovery of cobalt products from poorly oxidised nickel ores (Kempirsaisk deposit) and pyrite concentrates with a low content of cobalt (Sokolovsk-Sarbaisky deposit) has not been solved to the present time in Kazakstan. The balance reserves of nickel ore of the Kempirsaisky deposit make up more than 35 million tons with a nickel content of 1.13 per cent and cobalt content of 0.05 per cent; besides there are 110 millions tons of out-balance ores (Anon, 1995). In a tailing dump of Sokolovsk-Sarbaisk Mining and Productional Association more than 320 million tons of tailings of wet magnetic separation have accumulated, which contain 7.2 per cent of sulphur, 0.022 per cent of cobalt, 0.012 per cent of nickel, 0.094 per cent of copper, 0.079 per cent of zinc, 16.45 per cent of iron, and from which a high quality pyrite concentrate car) he separated through flotation, containing 48 - 50 per cent of sulphur, 44.15 per cent of iron, 0.141 per cent of cobalt, 0.07 per cent of nickel, and 0.10 per cent of copper. The well-known technological flow charts for cobalt and nickel recovery from the tailings of sulphide-magnetite ores dressing (to give pyrite concentrate) and from oxidised nickel ores, are not profitable at the existing prices for metals, but are not worthless and require significant capital investments for the realisation of their value. The flow chart `sulphate roasting - leaching - solution processing' is used widely for combined processing of cobalt-containing pyrite ores and concentrates.

Jan 1, 1996

By Jr. Matthews

The Candelaria copper-gold deposit is located in Region m of Chile, 805 kilometers north of the capital, Santiago. Candelaria was discovered in 1987, following a six month exploration program. In late 1986, induced polarization (IP) surveys outlined an anomalously high response within the area of interest. The first test hole bad three intersections totaling 49 meters, with an average grade of 1.97% copper. Drilling eventually outlined approximately 390 million tonnes, grading 1.09010 copper and 0.26 grams/tonne gold. Production began in early 1995 and is estimated at 120,000 tonnes copper and 80,000 ounces gold annually.

Jan 1, 1996

By N. B. Prenn

Case Studies in Open Pit Design Using Whittle 4D will be discussing the following four examples: 1) Optimization of process plant design using Whittle 4D as a sizing tool. In this case, the home office and project team had different views of the size of the final project. The home office wanted to reduce the size of the project to reduce capital expenditure, while the project team suggested a larger project. Whittle 4D was used to determine Net Present Value and Internal Rate of Return using the Whittle scheduler (FDAN) to schedule many alternatives, and calculate the NPV and return for each alternative. 2) Comparison of pit optimization methods: Lerchs-Grossman vs floating cone. Many pits are developed based on floating cone economics. A comparison of methods in one large gold mine resulted in the stripping ratio of the pit being reduced by 10% in the Whittle 4D optimization as compared to the floating cone optimization. 3) Pit optimization to determine if a new mill is justified. A large heap leach gold and silver mine needed to determine if a new mill was justified. The planning and scheduling would take several man months if completed without pit optimization and scheduling software. Whittle 4D software proved to be very effective in providing optimized pits and a mine schedule in a short time frame. 4) Pit optimization to determine how to mine and size. Open pit optimization determined where the underground operation should start, and whether the material should be processed by milling or heap leaching. One of our clients asked for help in determining where the pit should end and a new underground operation start. We used Whittle 4D to help determine where the pit should end and where to go underground. In addition the operation needed to determine how to process the material.

Jan 1, 1996

By Roma T. Dec

Many industrial wastes may require preliminary processing to change their particle size, density, surface properties or flowability to become more suitable for treatment and recycle. This can be achieved by pressure agglomeration using roll presses. In the following paper an overview of various roll press processing methods like briquetting, compacting, compacting-granulating or densification is presented together with basics of process and equipment design. The emphasis is focused on major factors influencing compaction process and responsible for pressure build up and final product quality. Finally, two examples of roll press application for briquetting of steel plant wastes and compaction of alumina base catalyst tailings are introduced.

Jan 1, 1996

By J. W. Leonard

Comments The venerable straight-line equation Y = Bx + A is again being rediscovered, but this time by economists, mining engineers and geologists. Two economists, William Sharpe and Harry Markowitz, from the University of Chicago and Stanford University, respectively, won the 1990 Noble Prize in economics by showing that the price of individual stocks can be related to the Dow Jones industrial average (DJIA) using the straight-line equation. According to Bill Chidester, Investment Analyst, Scientific Investment, Sharpe and Markowitz strongly emphasized the role of the beta (B) value while considering the alpha (A) value to be "pretty unimportant." Chidester claims that alpha is the "mystery" value that causes individual stocks to behave independently of popular stock-market indices, such as the DJIA. For many years, mining engineers and geologists have routinely called alpha the "nugget" or surprise element in geostatistical analyses in which a designated distance (x-axis) is related to the variance of the grade (y-axis). Because the influence of the independent variable (distance) over the dependent variable (grade variance) is ideal when alpha is equal to zero, any increase in alpha represents a loosening of influence or control within the relationship. This can be good news or bad news - good news if you are an economist sorting out off-trend stocks and bad news if you are a mining engineer trying to predict sulfur in a coal seam. With many mining trends, such as those involving the relationship of distance to the variance of grade, a mathematical relationship can be formed. In geostatistical analysis, the point where a mathematical trend ends is known as the sill. If the difference between the variance of grade at the sill and at alpha can be determined, then an estimate of the relative control for a given distance can be obtained by comparing the sill value to alpha. The extent to which alpha approaches the value of the sill provides an indication of independence or loss of trend. The alpha concept may find application with distance, time or fluid problems. The point of change can be either a change in trend or the trend limit. However, even without a clearly defined point of change or trend limit, increasing alpha values always infer loss of trend. Alpha analysis should be regarded as a valuable tool when sorting out many sets of mining data. The application of this user-friendly concept to reserves, material transport, fluid flow and other areas has been, and will continue to be, the basis of many important past and future developments in mining and geology.

Jan 1, 1996

By Richard A. McIvor

"All mine shaft conveyances in Canada and most of the United States that are supported by a single hoist rope or attachment point and used for transporting persons are required by regulation to be equipped with safety catches and mechanisms. These safety mechanisms, commonly called safety dogs, are designed to stop and hold a free falling conveyance, with a full personnel load, in the event of a hoist rope or attachment component failure. The conveyance’s safety mechanism must be tested under dynamic conditions before it is used to transport personnel. This paper will discuss free-fall testing and it’s results on conveyance free-fall tests performed in the test tower at INCO Limited, Sudbury, Ontario.Topics covered will be free-fall tests on various wood types such as B.C. fir, Karri wood and Trusjoist MacMillan Limited Parallamwood (PSL), comparison of deceleration rates versus free-fall velocity and the influence of safety dog tooth design on deceleration rates."

Jan 1, 1996

By K. H. McDaniel

An interactive mine ventilation simulation software program (WIPPVENT) was developed at the Waste Isolation Pilot Plant (WIPP). The WIPP is a U.S. Department of Energy (DOE) research and development project located near Carlsbad, New Mexico. The facility is designed to provide a permanent, safe underground disposal of U.S. defense generated transuranic waste in bedded salt. In addition to its regular functions, the underground ventilation system is engineered to prevent the uncontrolled spread of radioactive materials in the unlikely event of a release. To enhance the operability system, Westinghouse Electric Corporation has developed an interactive mine ventilation simulation software program (WIPPVENT). While WIPPVENT includes most of the functions of the commercially available simulation program VNETPC (copyright © 1991 Mine Ventilation Services, Inc.), the user interface has been completely rewritten as a Windows ® application and screen graphics have been added. WIPPVENT is designed to interact with the WIPP ventilation monitoring systems through the site wide Central Monitoring System.

Jan 1, 1996

By T. K. Mukherjee, C. K. Gupta

"The importance of the processing of secondary resources such as solid industrial wastes and liquid effluents as well as byroducts for the recovery of the associated metal values hardly needs any elaboration. Such processing contributes in no small measure towards the augmentation of the availability and the supply position of resources. As an added benefit, it leads to a reduction in environmental pollution caused by the undesirable waste materials. As some typical examples of secondary resources in the Indian scenario, mention can be made of spent catalysts, metal/alloy scrap, ash, consumed batteries, flue dust, slag, sludge and slime, pickling solutions, spent acids, plating rinse solutions, spent etchants, waste water from synthetic fibre manufacture and from tanneries etc .. These wastes constitute a source of a variety of non ferrous metals. In the processing of secondary resources like these, the techniques of hydrometallurgy such as solvent extraction playa pivotal role.This paper outlines the efforts made to use solvent extraction to recover (1) base metals such as copper, zinc, nickel and cobalt from a number of secondary resources like cake, and sludge (2) refractory metals like molybdenum and vanadium from sulphidic byproducts and spent catalyst and (3) nuclear metal like uranium from phosphoric acid. In the case of base metals, process flowsheet involving the use of acidic extractants such as DEHPA and PC88A have been optimised. The problem of iron removal from the leach liquor, which influences the metal recovery process significantly, has drawn a special emphasis. In the case of refractory metals, basic extractants like Alarnine 336 has been pressed into service to produce kilogramme quantities of pure salts of molybdenum and vanadium. Finally, the paper gives a brief account of plant experience in recovering uranium from phosphoric acid, using a solvent system comosed of DEHPA and TOPO."

Jan 1, 1996

By Ray Y. Lin, Randall A. Blue

"Joining of silicon carbide with infrared using a mixture of Si-30wt.%C as the brazing material has been investigated. Joining was performed at a temperature of 1500 °C in a flowing argon atmosphere for processing times ranging from 5 to 60 seconds. The joining filler materials include thin film silicon obtained by thinning down silicon wafers to about 70 /!m and graphite powder of a 15 /!m average particle size. Joint strengths were determined with a specially designed shear-in-compression jig for testing shear strengths of brittle materials. Cross section examinations of the joined specimens with optical microscopy, scanning electron microscopy and transmission electron microscopy have shown that all joints are essentially void free with excellent wetting between the base SiC and the brazing material. Silicon carbide in the B form has been identified as the reaction product in the joining zone with a transmission electron microscope (TEM) and selected area diffiaction (SAD) analysis. At 1500 °C with a joining time of 60 seconds, the joint has consisted of primarily SiC. With such a high SiC content in the joint, the joint strength is comparable to those by other joining techniques, such as diffusion bonding, as reported in the literature. A kinetic model for the formation of SiC from liquid silicon and carbon is proposed to explain the observed joint microstructural evolution.IntroductionSilicon carbide is of great interest for high temperature structural applications because of its excellent high temperature strength, wear resistance and anticorrosive characteristics [1]. Even though the interest in SiC is high, the use of the material has been limited by the high cost and difficulties involved in forming components of complicated shapes [2]. It is these limitations that necessitate the development of effective joining techniques that are cost effective and able to provide strong joints."

Jan 1, 1996

By Brian Balmforth

Solvent extraction has been applied successfully to the recovery of a range of metals from a variety of process streams. Particular benefits are derived from the use of new highly selective extractants. These will be exemplified by case studies including the recovery of zinc from sulfate and chloride media using ZENECA's new extractants which show a very high selectivity over iron and the recovery of antimony and bismuth from copper refinery electrolytes using ZENECA's strong and selective extractant DS5834. The conclusions are drawn that solvent extraction is a cost effective technology for metal recovery and recycling, even when used to treat relatively small volume/low concentration process streams, and that it can provide the essential enabling components of a larger system for waste minimisation programmes.

Jan 1, 1996

By H. R. Thompson

The Grant Town Power Plant is a nominal 80 MW (net) Waste Coal-Fired Electric Generating Plant which is located in northern West Virginia, approximately 15 miles southwest of Morgantown. The Steam Generator consists of two (2) Pyro-Power Circulating Fluidized-Bed Boilers (CFB), each rated at 400 000 lbs/hour @ 1,350 psig. Main Steam. The Turbine Generator is a single GEC Ahlstrom unit rated at 95 MW gross and 80 MW net. The Plant began commercial generation during April, 1993. The facility is owned by American Bituminous Power Partners, L.P. (AmBit), and operated by Mission Operations and Maintenance, Inc.

Jan 1, 1996

By Keith M. Axler

This report addresses issues specific to the generation of hydrogen fluoride via reaction of calcium fluoride with sulfuric acid. This process has been established on a commercial scale and is under consideration for treatment of calcium fluoride residues from uranium processing. Magnesium fluoride slags are also available as a product of uranium processing. The technique of using sulfuric acid for the production of hydrogen fluoride from magnesium fluoride is also under consideration as a residue processing scheme. In the current study, thermodynamic modeling was used to investigate these chemical processing systems. The results presented herein reveal information relevant to the selection of processing temperatures and conditions. Details include predicted effects in system composition based on operating temperatures for both the calcium fluoride and the magnesium fluoride systems.

Jan 1, 1996

By L. A. Puchkov, Mesentsev. V. K., I. O. Temkin

The problem of increasing underground mine ventilation efficiency is still of top priority. The complication of geological conditions with the depth of underground mining processes and reinforcement of requirements to technological and ecological safety are extorting the necessity of solving this complex problem with using of new information technologies. There exist different approaches to the ventilation problem. One of them, which the authors adhere to, is based on the concept of monitoring (under special mining and geological conditions-automatic control) of mining atmosphere and operative re-distribution of underground mining air among consumer , in accordance with the criterion of optimality [ 1.3 1. ] The set of tasks which should be decided in the frame of con- crete ventilation system depends on the peculiarities of deposit, technological schemes and so on. Nevertheless, some ventilation tasks such as: defining of ventilation network parameters; finding of dependence between these parametrs; operative redistribution of air streems, could be interpreted as universal ones. Main aspects of practical solving of different ventilation problems and their classification were investigated and considered in detail before [I ,2 ]. Some years ago we have began our investigations to develope quite simple and effective methods for decision of ventilation tasks on the base of neural network technology. It is well known that ventilation net, formed by various mine workings, is the main component of underground mining ventilation system. In general, network air distribution may be described by some functional F(Q,R,H), where Q- is a vector of air consumptions; H- is a vector of depressions; R- is a vector of airdynamic resistences. (Q,R,H) - are the informative entities , characterising every branch of the net. There exist some fundamental tasks which should be decided during the process of control of mining ventilation: calculating of natural air distribution Q = Q,{R, H,}, or Q = Q2(R, Q?}, where H, - is the maximal depression of the ventilation net, Q, - is the air consumption in the ventilation shaft; identifying of airdynamic resistance for some branches on the base either of air-depression removal or operative monitoring: [ ]

Jan 1, 1996

By Benoit Bissonnette

"The need for production of a competent fill was recognized early by the project partners. Consequently, a 4000 Ud paste fill plant was constructed and commissioned in early August 1994.In order to fine tune the process without risk to the underground workings, a closed pumping loop was devised on surface. After two months of this exercise, the first underground slope was filled according to specifications obtained from the pilot plant trials.This paper will focus on the operational problems encountered and the solutions adopted so far, and on a comparison between expected and actual fill production and characteristics.RésuméLa nécessité de produire un remblai de propriétés mécaniques suffisantes a été rapidement reconnue par les partenaires du projet. Conséquemment, une usine de production de remblai en pate, utilisant les residus du concentrateur d'une capacité de 4000 t/j a été construite et l'opération a débuté au mois d'aôut 1994.Dans le but de roder le précedé sans mettre en danger les installations souterraines, l'usine a été testée dans un circuit de surface. Après deux mois d'essais, le premier chantier souterrain a été rempli avec du remblai en pate selon les specifications dérivées de l'usinage pilote.Cet article présente les problemes d'opération rencontrés et leurs solutions, en plus de faire une comparaison entre les résultats prévus et ceux actuellement obtenus sur la production et sur les charactéristiques du remblai."

Jan 1, 1996

By S. R. Nandargikar

Construction of open foundations for the Second Thane Creek Bridge was indeed a challenging task. Some major problems were encountered during the construction of foundations for pier No. P22 (S/N), P.6(S) and P.12(S) of this bridge. This paper describes these problems briefly and also highlights how they were solved.

Jan 1, 1996

By A. W. Khair

Laboratory studies indicate that the specimen size influences the compressive strength of coal significantly. In the past, the diameter/height ratio of coal and rock specimens with different geometry and its influence on failure characteristics was discussed (Khair, 1993; Khair, 1994; Khair and Xu, 1994). In the current attempt, tests are designed and carried out under uniaxial condition in the laboratory to investigate the influence of specimen size. Cubical specimens of coal with edge dimension ranging from 5 cm (2 in.) through 20 cm (8 in.) were prepared according to the standards and tested uniaxially. Results show that compressive strength of coal is dependent on specimen size until certain level and later the change in specimen size would not yield significant change in compressive strength. Cubical specimens were chosen for testing because they are not only in close resemblance to underground pillars, but they are also the most stable shape under loading. The failure characteristics of these specimens were analyzed and their applicability to pillar design aspects in coal mines is studied. A detailed analysis of the physical and mechanical properties of the tested coal seam is also presented.

Jan 1, 1996

By E. V. Kuzmin

The rock properties improvement means the exchange of natural properties: increase of stability, strain and compress tension, reduction of gas-liquid filtering property, increase Jung- module, other mechanical and physical parameters of rocks by injection the hardening materials, such as polymeric pitches, micro-or geocements by special technology under high pressure, to fill cracks. Flow of liquid materials between the rock units and hardening under high pressure create full redistribution of rock pressure in rock massif. There are many reasons to use this technology in underground mining, tunnelling, creation barrier technology in raioactive, chemical and other danger material site etc.

Jan 1, 1996

Major Francis Hamilton Buchanan coined the term `laterite' (Latin; brick-rock) in 1807 for the red earths used for building blocks in southern India. Although these earths were actually weathered basalts, the term is now applied to weathering profiles developed upon a wide range of bedrocks. The Ni-laterites are a special class within the broad laterite family.

Jan 1, 1996

By Mackenzie W. R, Harding C. G

The Islamic Republic of Mauritania is a large country of over 1 000 000 square kilometres situated on the Atlantic coast of north-west Africa. It is bounded to the north by Western Sahara and Algeria, to the east by Mali, and to the south by Mali and Senegal. With the exception of a narrow strip in the south along the Senegal River valley, the country lies entirely within the Sahara. The north of the country is largely devoid of vegetation, and it is estimated that 90 per cent of the population of 2.1 million people live in the southern quarter of the country. From about the turn of the century, Mauritania was ruled by the French from Dakar in Senegal and, until 1960 when it obtained independence from the French, Mauritania did not have a capital. Today, the capital is Nouakchott, home to an estimated 600 000 Moors of mixed Arab, Berber and African descent. After independence in 1960, disputes over Spanish Sahara to the north led to a military coup in 1978 and it was not until 1991 that a democratic constitution was adopted. The new constitution declares Mauritania to be an `Islamic, African, and Arab Republic.' It provides for an executive president, elected for a six-year term, and for a bicameral legislature, consisting of a national assembly and a senate. The first presidential and legislative elections were held in 1992 under United Nations' supervision. Mauritania's economy is predominantly pastoral, and the country depends heavily on foreign aid. Its principal export industries are iron ore mining (about ten million tonnes per annum from mines near Fderik in the north) and fishing. Mines d'Or d'Akjoujt SA (MORAK), a company in which General Gold Resources NL (GGR) has 42.5 per cent equity, produces over 50 000 ounces of gold per annum, which represents the third largest export industry in the country.

Jan 1, 1996