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By Carl H. Hobbs

The needs of the on-going basic maintenance operations and proposed enhancement and hurricane protection projects in the City of Virginia Beach exceed the capability land-slide sources of sand. Through the past several years our studies have concentrated on locating and defining suitable quantities of sand appropriate for use on the area's beaches and assessing some of the consequences of dredging in shallow offshore areas. By providing information concerning the geological setting of sand resources, the local wave climate, and benthic infauna, the overall research project has strengthened the knowledge and understanding of several facets of Virginia's inner continental shelf. We have identified three distinct settings for deposits of beach-quality sand, two of which (filled channels and surficial shoals) are distinguishable in relatively unprocessed sub-bottom profiles and cores. The third, a sand facies within a larger stratum, is discernable only with a suite of cores. Sandbridge Shoal, about 5 km offshore of the resort and residential community of Sandbridge appears to contain a substantial quantity of sand that could be exploited with comparatively few problems. It already is designated as the source of material for use in a shoreline protection protect for a federal facility. Fluvial(?) fill of a late Pleistocene channel lust offshore of the main, commercial, resort area may offer a proximal alternative to existing and proposed resources. Ongoing work to describe the local wave climate and the possible impacts of anthropogenic alterations of the bottom topography on wave transformation and studies of the biological community as it might be affected by dredging will help fill-out our series of studies. Prior to utilization of the resource additional work is needed to provide better definition of the limits and magnitude of the sand bodies. Finally decisions concerning the use of specific resources will have to include physical, biological, economic, technical, and social considerations.

Jan 1, 1996

By M. J. Gula

In the solvent extraction -electrowinning recovery of copper from oxide or sulfide ores there is a continuous transfer of iron and other impurities from the primary leach solution to the copper electrowinning electrolyte via chemical transfer or mechanical entrainment. Iron is the principal impurity that has to be controlled in the electrolyte by a "bleeding" of the electrowinning solution. This bleeding transfers copper and sulfuric acid back to the primary leach circuit along with the iron. Copper is recovered via the solvent extraction process and generally the sulfuric acid is used as a reagent in leaching. Unfortunately, cobalt, which is added to the electrowinning solution to modify the anodic process, is irreversibly lost through the bleeding operation. This cobalt loss represents a significant operating cost to SX-EW copper producers. DiphonixTM ion exchange resin contains diphosphonic acid and sulfonic acid functional groups on a polystyrene-divinyl benzene matrix. This resin has been found to strongly and selectively extract ferric ion from copper sulfate -sulfuric acid solutions containing cobalt. Thus, an ion exchange process using DiphonixTM resin for the control of iron has been developed to replace the conventional bleed stream process. The new process minimizes the loss of cobalt from the electrowinning circuit and strips the iron into a sulfate based solution suitable for leach solution makeup. In addition, this process can effect a lowering of the total iron concentration in the electrolyte circuit with an associated increase in current efficiency. In this paper, data on the loading and elution of iron are presented. Laboratory and pilot scale data will be discussed along with information on process design and comparative economics.

Jan 1, 1996

The theme of the conference this year is diversification. One way to diversify is through acquisition. The principle underlying the winner's curse is that in competitive bidding situations where the value of the asset bid for is uncertain the winning bid will overstate the true value of the asset. The successful bidder is blessed with the winner's curse. What this paper will explore is to what extent this is true; how acquirers can avoid being blessed with the winners curse; and show how joint venture deal structures are used within the mining industry to avoid the winners curse.

Jan 1, 1996

By Doug Williams, Kent J. McGrew, Dr. Jack Murphy

For some time, selenate has eluded water treatment by conven­tional means such as precipitation and clarification. This has been due to the nearly universal solubility of all oxidized sele­nium species, the low levels required for surface discharge, and almost identical chemical behavior to all forms of oxidized sul­fur. The last characteristic makes selenate particularly difficult to deal with in acid mine waters where sulfate can easily be on the order of one gram per liter. Approaches such as ion exchange or reverse osmosis often tum into total demineraliza­tion schemes for the sake of removing a "trace" selenium species that may be present on the order of 108 sulfate/selenate. Reduction of selenate to selenite or elemental selenium by chemical means has been relatively unresearched. Some limit­ed success has been reported (Murphy, 1988) using ferrous hydroxide as a reducing agent; however, the reaction time as reported is too slow to be useful in a practical plant design. One significant difference between selenate and sulfate is that selenate has been discovered to be reducible in acid solution by elemental iron when catalyzed by soluble copper. Since the +4 or zero valence states of selenium are rather easy to deal with by coprecipitation with iron salts or alum, the elemental iron dis­solved in the process contributes to the overall process by pro­viding sludge upon raising the pH that can be separated by con­ventional clarification. Commercial production of selenium using copper catalyzed reduction of selenite to selenium metal via sulfur dioxide is well established, however, at the < 5 ppb requirements for surface discharge this reduction process equili­brates at levels far too high to be useful to low level selenate removal criteria. The reaction reported herein uses elemental iron for reduction of selenate with copper acting either as a cata­lyst or as a coprecipitation agent. This method, employed with conventional sludging, clarification and filtration can provide an economic method to achieve non detectable selenium (< 0.005 mg/I). Iron consumptions for the conditions tested have been on the order of 3 lbs/1,000 gallons treated. This represents as little as $0.06 or $2.00 per 1,000 gallons based on using a scrap source of iron or the purchase of electrolytic iron for the process.

Jan 1, 1996

By Robert W. Bartlett

Heap biooxidation of sulfidic refractory gold ore requires large amounts of oxygen, as shown in Figure 1. Bacteria, Thiobaci/lus ferrooxidans, are donnant at oxygen concentrations below about 3% in air (1 ppm in aqueous solution) because ofmonod kinet­ics. Hence, the maximum possible utilization is only about 75%, and it may be much less than that due to poor air sweep effi­ciency. At the maximum oxygen utilization, an ore containing two percent pyrite requires nearly 100 cubic meters of air per tonne (4,000 cubic feet per ton). The stoichiometric air require­ment to oxidize arsenopyrite is similar to that of pyrite. While the leaching solution percolating through the heap introduces some dissolved oxygen, the amount is insignificant because of the low solubility of oxygen in water, 7 to 8 ppm at atmospheric saturation. There are only three ways to provide oxygen to the heap: either air flow by natural convection, diffusion of oxygen from the surface (through stagnant air in the air-filled void space in the heap), or forced air ventilation of the heap. Each of these processes will be reviewed.

Jan 1, 1996

By Paul D. Chamberlin

In the author's selenium report of 1994 (1), the literature was culled for selenium removal technologies that had a chance of producing effluents with <10 ppb of total selenium. Very few processes could achieve such low concentrations. The EPA dictates such low concentrations. Discharges to fishery waters must be <5 ppb total selenium. The federal max­imum contaminant level ( MCL) for drinking water is 50 ppb. The EPA regulations are for total selenium, not for the species, perhaps because an approved EPA assay method is atomic absorption and it cannot distinguish between species.

Jan 1, 1996

By John J. Mancini

Elastomeric liner products have been used for over two decades in a wide variety of uses including pond liners, hazardous waste barriers, dam face rehabilitation and mining applications. Asphalt blended with polymers is enjoying renewed interest in the engineering community because of its durability, high yield attributes, fewer CQA steps due to seamless installation, and ease of installation and repair. As in other lining technologies, advancements in polymer chemistry and improvements in installation techniques have had dramatic impact on the quality of fluid-applied asphalt (FAA) membranes. Membrane 6, man­ufactured by Deery Oil, Inc. for over 16 years is a hot-applied polymer modified asphalt membrane that can be applied to a variety of substrates in a reinforced configuration or installed directly on an asphalt surface. By blending thermoplastic polymers with asphalt, very favorable stress/strain characteristics can be achieved (Chambers, 1980). Typically the membrane will yield under rel­atively low stress and also exhibit high elongation capability. In service applications where puncture resistance is a concern, fluid applied asphalt materials have the flexibility and com­pressive strength under heavy loading that leach pad designers may find attractive. Additional security is achieved if long term service life is important as in the case of radioactive waste con­tainment. The Department of Energy selected Membrane 6 over seamed liners for a surface barrier that must isolate and contain radioactive waste for 1000 years. Asphalt has a long history of use as a water-stop material and it is believed that this natural construction material combined with SBS polymers will per-form for a millennium. (Freeman, 1994) The process of installing Membrane 6 varies according to job size and the type of surface to be protected. Lining applica­tions on compacted substrates require the membrane to be applied to a scrim cloth (fig 1). Some early pioneers in FAA technology neglected this step and therefore never achieved per­formance levels that satisfied regulatory guidelines. The scrim provides a cohesive surface that promotes membrane flow while achieving high impermeability (2Xl0 '11).

Jan 1, 1996

By John G. Banker, Arthur L. Forrest

Titanium solves corrosion, maintenance and environmental problems in many reactor and autoclave applications. Titanium clad construction permits autoclave designers a great deal of flexibility combined with significant cost reduction. Titanium alloys can be selectively applied in specific regions of the auto­clave to accommodate local environmental conditions. Resistance to general corrosion, crevice corrosion, abrasion, and ignition conditions can be accomplished selectively and eco­nomically. Explosion clad pressure vessel fabrication and perfor­mance have been proven through three decades of experience.

Jan 1, 1996

By John W. Greene

ennec?tt's Bameys Canyon Mine personnel developed an mnovahve process to extract gold from a small (1.8 million tons) sulfide ore zone in an oxidized ore body located at the Bameys Canyon Mine. This approach consists of extracting the sulfides from the ore via flotation, shipping the concentrate to Kennecott's new smelter, and mixing the flotation tailings with the oxide ore, agglomerating the mixture, and stacking the resultin tailings/oxide ore combination on the heaps. Conventional heap leaching technology is utilized to recover the gold from the mixed materials. Overall, the total gold recovery from the sulfide ore is esti­mated to be 90%. This approximation is based on a smelter gold recovery of 98% from the concentrate and an 88% recovery from the tailings during heap leaching

Jan 1, 1996

By Bruno Sceresini

Prospectors and small scale mmmg companies have long expressed the wish for a highly mobile mineral processing plant. This is especially so in the case of gold mining as relatively small deposits can be highly profitable due to the relative ease of producing a marketable product when compared with the refming and marketing costs incurred with base metals. This paper will concentrate on gold ore treatment in fitting with the theme of the 1996 Randol Gold Forum but the principles may also be applied to base metal ores. The development and application of the Atomaer Filblast Gas Shear Reactor as a cyanidation tool has removed the con­straints of plant size in pulp cyanidation applications. KC Dodd and Associates, Consulting Engineers and Australian Mining Advisers, Pty Ltd, have designed a 1,000,000 and a 250,000 tpa fully modularised ore treatment plant. Various module configu­rations can be arranged to treat a wide variety of ores ranging from simple gold ores to gold-copper and base metal ores. This paper will limit the discussion to comparing the capital and operating costs of a conventional and a modularised 1 million tpa gold treatment employing a number ofnovel concepts which complement the compact, high capacity Filblast Cyanidation Process and the AARL pump Cell Adsorbers. The design described in the paper not only reduces equip­ment sizes and allows for rapid deployment of a sizeable capac­ity plant but also offers significant capital and operating cost benefits.

Jan 1, 1996

By Peter Mason, Chris Walker, Mike Costello

The Phase I electrowinning system at KCGM's Fimiston Operation utilised the well proven technology of electrowinning precious metal values onto steel wool followed by calcining and direct smelting to bullion. The above process, while reliable and successful, was to some extent labour intensive. The Williams Mine in Ontario, Canada had published conditions under which precious metal values are electrowon onto woven stainless steel and directly removed using high pressure sprays. The current paper describes the testwork which was carried out to check the applicability of the Williams criteria to KCGM eluates arising from the elution of highly loaded carbon from the calcine circuit and lowly loaded carbon from the float tails circuit. Information is also given on the commissioning and opera­tional experience which occurred.

Jan 1, 1996

By Mark William Johns

Carbon-in-pulp (CIP) is the preferred method of gold recovery om cyanided plp. However, other gold adsorbents (namely, ton-exchange resms) are being introduced to the industry as they are considered to have several advantages over carbon for the recoery of gold. A set of test methods have been developed by the industry to evaluate the quality of different carbons. owever, many ?f these tests are not applicable to evaluating ton-exchange resms. Hence, a need has arisen for a method to evaluate the different adsorbents. This paper introduces a philosophy to evaluate an adsorbent that results in an estimation of the capital cost and the operating cost associated with the adsorbent. Tests that have been devel­ oped to evaluate the ability of an adsorbent to adsorb gold (in­solutton . counter-current) and to evaluate the optimum adsorbent for a specific pulp (in-pulp batch) are introduced. A method of converting the test data into an economic dimension is present­ed. Case studies are presented to highlight the discussion.

Jan 1, 1996

By Marc E. Orman, Mark E. Smith

Regulatory and environmental concerns continue to broaden the range of mine wastes that must be capped with low permeabili­ty liner systems at closure. The mining industry has been a leader in developing liner technology for leach pads and tailings impoundments, but it is a newcomer to cap designs. Closure of waste piles, leach heaps and tailings require special design con­siderations. Factos such as differential settlement, surface ero­sion, veneer stability, vegetation and burrowing animals must be considered.

Jan 1, 1996

By Norbert Steiner, Roy Norcross

For the desulfurization of weak SO2 gas streams, Degussa developed a process using dilute H2SO4 solution containing H2O2 instead of conventional gas scrubbing with all solid absorbent medium (limestone, MgO). The process is based on fast reaction of H2O2 with SO2 yielding H2SO4 up to 70% strength, depending on off-gas tem­perature. Compared to the conventional systems with typically < 95% efficiency, independent on the raw gas SO2 concentra­tion, residual SO2 concentrations of less than 20 mg!Nm3 can be easily achieved, corresponding to nearly 100% removal. These features render the H2O2 process a very attractive, low capital cost technology to retrofit existing conventional desulfurization plants.

Jan 1, 1996

By Richard Ladyman, Ken Baxter, G. B. Siddall

The IPS process, developed by Baxter and McAuley, was first applied in Australia in 1984 at Browns Creek in NSW where a small 300kg batch plant was in operation for a number of years. To date a further 14 plants have been installed. While a number of engineering companies have engineered applications of the technology, a majority of the plants constructed to date have been constructed by Como Engineers who have a reference list of 9 installations with batch capacities up to 3.0 t.

Jan 1, 1996

By J. H. Lammers, John Turney

The Eskay Creek Project was interesting in many respects, includ­ing extremely high grade of precious metals, refractory nature of the ore, carbonaceous content of ore resulting in preg robbing, and high content of many heavy metal sulfides in addition to the usual iron sulfides. Although the process plant was never constructed, extensive testwork was conducted and a flowsheet for the treat­ment of the effluent form pressure oxidation was developed as a basic engineering package. The flowsheet included removal of iron and gypsum by neutralization, selective recovery of copper by zinc precipitation, and recovery of zinc by solvent extraction and electrowinning. The zinc recovery produced a significant impact on the project economics. The waste water from the process met the environmental requirements for British Columbia.

Jan 1, 1996

By G. A. Hayes

The range of gold ores tested at AMMTEC LTD over several years has resulted in the requirement to analyse for the mode of occurrence of gold in order to assist selection of ore processing options. The aim of this paper is to describe the laboratory testwork and analytical procedures which have been of benefit in detail­ing the mode of occurrence and mineral associations of gold and hence being of value in developing an optimised ore processing route. The range of ore and mineral assemblages described include relatively simple pyrite and free milling ores, more complex pyrite plus arsenopyrite gold ores and the quite com­plex associations of gold in copper bearing ores or with car­bonaceous mixed sulphide ore assemblages. The aim of this paper is to describe the laboratory testwork and analytical procedures which have been of benefit in detail­ing the mode of occurrence and mineral associations of gold and hence being of value in developing an optimised ore processing route. The range of ore and mineral assemblages described include relatively simple pyrite and free milling ores, more complex pyrite plus arsenopyrite gold ores and the quite com­plex associations of gold in copper bearing ores or with car­bonaceous mixed sulphide ore assemblages.

Jan 1, 1996

By Gerd A. Schroth

For many years, the automatic preparation of samples prior to elemental analyses has become quite common in several indus­tries, including aluminum, cement, non-ferrous and steel. Modem automatic preparation of powdery, granular or metallic samples which initially emerged as leading edge technology, has become state of the art and a proven technology.

Jan 1, 1996

By I. Dunlop, A. Goulsbra, R. Dunne

Mineral liberation or more aptly the particle size at which cost effect liberation is attained is an important mineral processing parameter. This implies that not all the mineral is liberated as further size reduction is not economically warranted. For ores of low grade minimising both the comminution capital and operating costs are crucial aspect to ensure project visibility. As a consequence the focus of attention for the most part is direct­ed to 'coarsening the grind" ahead of any downstream process­ing treatment. In most cases, recovery will be sacrificed to pro­vide for 'more tonnes' of capacity and in general this is eco­nomically justifiable. Preferential liberation and its measurements is an aspect of mineral processing that has created much attention and contro­versy. It is not the purpose here to discuss this matter in depth other than to state in broad terms that if an ore from the same source is subjected to comminution by two different methods, such that the product particle size distribution is similar, and subsequent downstream treatment demonstrates substantial dif­ferences in recovery, then there is reason to believe that prefer­ential liberation has occurred. Comminution by high pressure grinding rolls (HPGR) is a relatively new technology claimed to have two major advan­tages over conventional comminution. Firstly and more impor­tantly is the ability to improve comminution power efficiency. Power reductions of 10 to 40 percent being claimed. (Pagett et al (1995), Sargent (1995)). A secondary benefit claimed is that preferential liberation can occur. Generally, for HPGR there is a natural tendency of the product to have a skewed particle size distribution to the finer size. This in its own right could manifest itself in improved leaching and preconcentration performance. The question remains that if in using another comminution device, other than a HPGR, to produce a similar product size distribution as the HPGR, will there be any difference in downstream between the products from this and a HPGR.

Jan 1, 1996

By E. J. Rogans, W. N. Cartner

Carbon technology has largely superseded filtration plants as the more acceptable gold recovery technology. This has, over the last two decades, provided a tremendous driving force for the development of new equipment. One of the main focus areas of this technological development is the development of effi­cient interstage screening systems. Several variations of exter­nal and internal screens are available, with the more recent shift away from air cleaned units to mechanically swept units. This paper discusses the development of one such mechanically swept interstage screen and how the development led to the suc­cessful implementation of a carousel type of CIP operation. The first generation Pump-cell emerged as a consequence of the success achieved with the mechanically swept NKM screen, The idea was to modify the screen to incorporate the functions of pumping, screening and agitation in a single drive unit, the screen generating sufficient lift for interstage slurry flow so that all contactors would be at the same level. This sys­tem was further incorporated as a high intensity modular CIP contactor, i.e. low slurry residence times combined with high carbon concentrations. A discussion on the kinetic gold adsorp­tion theory and its manipulation in the design of the pump-cell concept is discussed in a paper published in a previous Randol Conference< 1), Testwork carried out at Vaal Reefs proved the concept of the Pump-cell on a pilot plant scale<2), which resulted in the building in 1990 of the first large Pump-cell plant at West Witwatersrand Gold Mine designed to treat 340m3 of pulp per hour and , even though the plant operated successfully with respect to gold recovery performance, a few problems were experienced with the basic engineering design(3),

Jan 1, 1996