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By Gülhan Özbayoglu, Yusuf Ziya Akgök

The effect of cooling rate on the flotation behaviour of copper slags of flash smelter plant in Samsun was investigated. Fresh molten slag was solidified in laboratory scale in three different ways. All the samples were characterized by chemical and mineralogical analyses. The chemical analyses showed that samples prepared from fresh slag had 0.9 to 1 % Cu with 40 % Fe and 30 to 32 % SO2. Old pit slag samples contained between 1 to 3% copper. Microphotographs showed that rapidly cooled slags showed fine size distributions, e.g. the copper grains in granulated slag had sizes in 1-2 microns. On the other hand, the size of copper grains in slowly cooled slags increased above 40 microns. Flotation tests carried out by using potassium amyl xanthate and Flotanol-C showed that slowly cooled slag reduced the copper losses in the tailing and improved the grade of concentrate. Under the light of laboratory investigation, the pit dimensions of Samsun Plant have been modified which resulted in a pronounced improvement of the grade and recovery of concentrate produced at Samsun slag flotation circuit.

Jan 1, 1995

By P. C. O. Chukabarah

Many aerodynamic and thermodynamic properties (such as temperature, pressure, velocity and density) vary widely, and in random spatial and temporal manner for a given underground mine environment. Such variabilities are seldom evaluated statistically, even though the relevant theories and principles are both available and feasible. The main purpose of this paper is to introduce the methodology for applying aerostatistics to the analysis of multiple fan systems in mine aerology/ventilation. Pertinent data were obtained from a small multi-level European coal mine. Results confirmed that aerostatistical methodologies are computationally more efficient. Being grounded in solid engineering statistical theories, they can be used to analyze networked parameters in mine environmental engineering.

Jan 1, 1995

By Richard Hogg, Heechan Cho

Investigations of long-time grinding of fine quartz (to about 80% passing 0.35 pm) in a 0.6 liter stirred-media mill are described. Breakage rates and primary breakage distributions have been determined based on extensive characterization of the ground products by laser scattering/diffraction and gas adsorption. The results indicate that, while there is qualitative similarity between the breakage parameters for ultrafine and conventional (coarse) grinding, there are important, quantitative differences. In particular, it is found that primary breakage distributions become significantly narrower in the submicron sizes. The trend can be described using double-truncated log-normal distributions in which both a maximum (breaking) size and a grind limit are specified. The breakage distributions become progressively narrower as the size being broken becomes finer. Breakage rates follow a typical, consistent pattern in which the rate decreases with size according to a simple power law. Further decrease in the rates seems to occur after very long grinding times when the entire mill contents become finer than about 1µm. The effect is explained as a result of changes in the rate/size relationship in the submicron range.

Jan 1, 1995

By E. L. Gillenwater

Coal mine planning has three distinct decision levels: (1) decisions made at the upper level of management that determine production requirements for specific mines, (2) decisions made at the middle management level, the mine level, that determine how the mine satisfies its production requirements, and (3) decisions made at the operating level of management, the sectional level, that determine the sequencing of machine movements at the face. In this paper, the underground production scheduling problem is formulated in multi-stages using the Hierarchical Production Planning (HPP) approach. Two linear programming HPP models for accomplishing decisions at the first two levels are developed. Both models address the aggregate production planning process. The Mine Production Scheduling (MPS) model permits determination of monthly production and inventory levels. The Section Production Scheduling (SPS) model incorporates a quality blending requirement into the determination of weekly sectional production and inventory levels.

Jan 1, 1995

By R. J. Kriek, J. J. Cruywagen, W. J. Engelbrecht

Selective photo reduction, using the semiconductor TiO2 under UV irradiation, has been investigated as a possible recovery and/or separation method for the PGM's rhodium, palladium and platinum. The effect of pH value and concentration of the sacrificial reducing agent (ethanol) on the rate of reduction of Rh (III), Pd (II) and Pt(IV) ions have been determined separately for these ions as well as for some mixtures. Conditions favourable for the reduction and adsorption (or precipitation) on TiO2 have been established. It has been found that already deposited Pt or Pd metal promotes reduction of Rh (III) ions at a pH value where it would not otherwise be reduced. A method for the separation of a mixture comprising Rh (III), Pd(II) and Pt (IV), based on photo reduction and adsorption on the TiO2, is proposed.

Jan 1, 1995

By G. A. Weisenfluh

The successful application of factors limiting the? availability of coal in eastern Kentucky depends on ac-curate assessment of the original resources. Examination of several previous coal-resource estimates for the region reveals significant differences among the outcomes. These differences relate to methods of analysis, biases in data and their utilization, and the problem of defining the lateral continuity of mineable beds. Improvements in the methods of estimating the original resources would greatly enhance the reliability of the results of the Coal Availability Program.

Jan 1, 1995

This paper reviews an analytical model that defines the relationship of weight-weighted or volume-weighted average haulage distance with bench height and other related parameters; presents the optimum bench heights under various conditions in terms of minimising the weighted average haulage distance of ore/waste during the full lifetime of an open pit mine, and discusses the truck-haulage economics of mining open pits by high bench, specifically by 15 m, 18 m and 20 m bench through marginal analysis. The observations from these analyses disprove the previous conflicting assertions that the overall weighted average haulage distance either increases or decreases monotonically with bench height. It is concluded that: (i) an increase of bench height to 15 m from 12 m is likely to be viable under the general conditions of large-scale deep open-pit mines; (ii) the reduction of haulage cost is limited with the case of increasing bench height to 18 m from 15 m; and (iii) the feasibility of mining open pits by 20 m benches is generally questionable. These conclusions may serve as a useful guide for those who advocate open pit mining by high benches.

Jan 1, 1995

By L. D. Snyder, J. K. Russell

"The Lower Jurassic Iron Mask batholith intrudes Upper Triassic Nicola Group volcanic rocks in the Quesnellia terrane of southcentral British Columbia and hosts Cu-Au mineralization. The batholith comprises three mappable intrusive phases, including: Pothook gabbro to diorite, Cherry Creek monzodiorite to monzonite and Sugarloaf diorite. The Iron Mask hybrid forms a fourth mappable unit that makes up to 45% of the areal exposure in the batholith. It is highly variable in texture and composition and subdivided into three types; Type I and II have abundant (partially digested) xenoliths, many of which are derived from the Nicola Group, whereas Type III is xenolith-poor and shows extreme outcrop-scale textural diversity.Pothook and Cherry Creek rocks are similar in texture, mineralogy, whole rock and mineral composition and style of alteration. Contacts between the two can be intrusive or gradational. Rocks collected from these two suites have compositions that are permissive of a single magma batch, although simple crystal fractionation does not explain all chemical variations within and between the two suites. The Sugarloaf unit comprises a diverse group of amphibole-phyric rock types and is texturally and mineralogically distinct from Pothook and Cherry Creek suites.The Iron Mask hybrid represents progressive stages of physical and chemical interaction between Nicola Group country rocks and Pothook magma. Magmatic assimilation (selective or partial) is supparted on the basis of field relationships, petrographic observations, and REB compositional data. Thermal dehydration and partial assimilation of Nicola Group rocks by Pothook magma is shown to be a valid means of promoting early and extensive volatile saturation in the Iron Mask batholith."

Jan 1, 1995

By Wade A. Narin, James K. Mitchell

Hydroblasting is considered a distinct soil improvement technique from explosive compaction, though the blast designs for the two techniques are similar. Hydroblasting is a three step process developed for densifying unsaturated, collapsible soils, especially loess. The required steps are: prewetting the soil to an adequate saturation, placing and detonating the explosive charges, and consolidating the soil (squeezing the water out of the pore spaces between the soil particles under gravity) to a denser state.

Jan 1, 1995

By A. De Daio, D. W. Fuerstenau, P. C. Kapur

Because of its pronounced tendency to undergo visco-plastic flow, coal ground in the energy- efficient high-pressure roll mill invariably comes out as a briquetted product which must be disintegrated in a conventional type of grinding device such as the ball mill. The aggregates comprise comminuted coal particles that are apparently extensively cracked and weakened during passage of the coal through the high-pressure rolls. Their deaggregation in a ball mill in the second stage is accompanied by further grinding of the coal with a relatively small expenditure of energy. Thus in spite of energy dissipation in briquetting in the roll mill and in disintegrating the briquettes in the ball mill, significant energy savings are possible in the fine grinding of coal in a two-stage serial grinding mode, as compared to ball mill grinding alone. It has been determined that for the best results the energy invested in the two grinding stages must be apportioned in an optimal manner, the energy consumption in the ball milling step is comparable to, even in excess of, the energy spent in the high- pressure roll mill; and 20 to 50 percent energy savings might be possible in grinding coal to minus 200-mesh size by this two-step process, as compared to conventional milling.

Jan 1, 1995

By Malcolm J. McPherson

There have been numerous recorded cases of mine explosions being initiated by falls of roof. The actual mechanism of the ignition has often been unknown. One possibility is incendive frictional sparking, particularly when the falling rock contains quartz. Another possibility that has received little attention is the increase in temperature of the air due to adiabatic compression under the falling roof. This paper analyses that possibility and concludes that falls which are extensive in plan area but not necessarily of great thickness of falling rock can, indeed, produce temperatures in excess of those required for the ignition of coal dust or methane.

Jan 1, 1995

By Staia. Mariana H.

Thermochemical equilibria of the heterogeneous system Ti-N-H-CI-Fe-Cr-Mo-Ni-Mn-C were calculated by using a commercial software based on the minimization of the free energy. Equilibrium calculations were done for temperatures varying between 800" and l 100°C and an initial molar relationship between reactants, a=NJTiCI,, of 0.1 to 2. The deposition process was considered to occur at atmospheric pressure. The activities of the alloying elements of the stainless steel were considered equal to their molar fractions. It was shown that for the conditions studied the substrate is no inert with respect to the gaseous phase. The existence of liquid chlorides was predicted for temperatures between 800" and 850°C and a ratio between 0.3 and 0.9. The most important metallic chlorides which appears to be present from the calculations in appreciable quantities in the gaseous phase are iron dichloride and manganese dichloride. In the low-temperatures zone and for low initial nitrogen contents, it result that the appearance of the liquid chlorides seems that partially inhibits the production of gaseous HCI. The highest deposition process efficiency calculated is obtained at a temperature 2 900°C and a N2/TiCI, ratios 2 0.7.

Jan 1, 1995

By E. R. Mueller

The natural lives of machines and components vary tremendously! Maintenance managers struggle constantly to maximize their equipment lives while minimizing their maintenance costs, but they normally lack the tools and techniques they need to do this properly. This paper proposes a methodology based on probabilities of failure and expected values for repairs that recognizes the variation among individual machines and components as well as the high costs associated with catastrophic failures. It enables a user to determine the optimum change-out intervals for many types of equipment. The approach proposed here is sophisticated enough to be reliable but simple enough to be applied by the maintenance staff on the shop floor. It will complement existing preventive and predictive maintenance programs.

Jan 1, 1995

There are several simulators available and are being used for analysis, improvement and optimal control of the grinding process. However, these tend to be developed on informal software engineering methodologies. The informal approach is not suitable for long term development and a formal design methodology is necessary to develop efficient, error-free, and easy-to-use and to maintain software. In meeting this goal, basic concepts of a software model for describing the mineral process objects has been proposed. The software model forms the basis for software design and efficient implementation of the simulation. This paper describes the development of software models for grinding circuits. The work constitutes the theoretical foundation for the development of an advanced simulator for comminution.

Jan 1, 1995

By A. E. Gran

"QIT -Fer et Titane Inc. currently produces and markets four main products: a titania slag named SORELSLAG for the white pigment production, a high purity pig iron known as SOREL-METAL mainly used in the ductile iron casting industry, an ilmenite ore for blast furnace applications called SORELFLUX and high quality steel billets SORELSTEEL employed in the wire rod fabrication. Moreover , QIT also manufactures high quality iron and steel powders labeled ATOMET for the powder metallurgy industry through its wholly owned affiliate. Quebec Metal Powders Limited. The company operates. rock ilmenite mine near Havre St. Pierre and produces its slag and ferrous products from its metallurgical installations located in the Sorel/Tracy region. QIT. born in 1948 from a joint-venture between Kennecott Copper Corporation and New Jersey Zinc Company, was acquired from BP Minerals by RTZ Corporation PLC in 1989 and remains its wholly owned subsidiary ever since.lImenite is a mineral rich in both titanium and iron oxides. QIT's proprietary mineral enrichment and electric smelting processes permit the concentration of the ilmenite ore and the separation of its main constituents to produce a 80% TiO2, slag and a high purity molten iron which is further transformed into iron ingots (pigs), steel billets, iron and steel powders.QIT's ilmenite deposit is located in the Lake TIo-A1Iard area, 43 km inIand from Havre St. Pierre, a community on the north shore of the St. Lawrence River some 960 km from Montreal. The orebody, covering some 542 000 m2, consists primarily of coarse-grained ilmenite (FeO.TiO2) with disseminated fine lenses of hematite (Fe2O3). The worthless mineral (gangue) associated with ilmenite is mainly anorthosite, a complex silicate. QITs mining operations are carried out using conventional open pit methods in a 500 m by 600 m horse-shoe shaped mine with nine benches developed. Primary blasting is performed on a weekly basis during the mining season. Blasted ore is trucked to the crushing station to be broken down to 15 cm and 7.5 cm sizes, respectively, by means of a primary jaw crusher and a secondary cone crusher. Minus 7.S cm ilmenite is then loaded into hopper cars for the 43 km trip to the Havre St. Pierre terminal where it is stockpiled and reclaimed by under-ground conveyor chutes to a ship loading tower at the dock. The crushed ore is shipped to QIT's smelter located in Sorel in 40 000 tonne carriers from April to December."

Jan 1, 1995

By S. S. Peng

In this paper, the precise definitions for a number of commonly used subsidence parameters are given. The subsidence parameters have been determined using an integrated approach for 110 subsidence cases collected in the major US coal fields. Attempts have been made to establish empirical formulae for the parameters. The results of this study indicate that some traditionally-held concepts should be changed.

Jan 1, 1995

Through partnering with mining customers, DYNO has been able to develop some specific technologies that benefit blasting operations particularly in underground mining. Some of these areas are: 1. Cost allocation and product tracking systems; 2. Borehole video surveys of breakthrough blastholes; 3. Borehole video photography for logging VRM blastholes; 4. Toe-load uphole loading for sublevel cave mining operations; 5. 3D blast modelling for underground ring blasting. This paper outlines these developments in the context of a Canadian underground metalliferous mine.

Jan 1, 1995

By N. Edmonson

An examination of the statistics of the world phosphate fertilizer industry since 1980 reveals an increasing tendency for fertilizer manufacturing activity to concentrate in phosphate rock mining areas. The economic justification for this resource-oriented strategy is clear. The choice between shipping phosphate rock, a comparatively low-value product, and shipping more valuable finished fertilizers will always be resolved in favor of the latter if cost considerations control the decision. The historical existence of substantial phosphate fertilizer manufacturing capacity oriented toward fertilizer-consuming activities and dependent on imported phosphate rock shows that narrow cost considerations have not always determined the industry's location. One is entitled to ask what conditions have changed to precipitate the observed relocations, and how permanent these changes are. These questions are the subject of this investigation.

Jan 1, 1995

By Hanguang Wu, V. Izaxon, Sukumar Bandopadhyay

This paper presents an analysis of the heat transfer process between the mine ventilation air and the frozen rockmass. The heat transfer model takes into account not only by the mutual change in air and rockmass temperatures, but also by the phase change of ice-water- ice. Based on the analysis presented here it is concluded that the mine thermal regime can be regulated by having the air enter the mine through mined-out excavations or development airways.

Jan 1, 1995

By J. E. Murphy, L. A. Walters, F. H. Nehl, G. B. Atkinson

The US Bureau of Mines investigated the selective electrowinning of Ag and Au from cyanide solutions contaminated with Cu with the goal of decreasing the amount of Cu codeposited. Decreasing Cu codeposited will reduce refinery costs. Direct current was applied to the cell in pulsed and square wave voltages at 0.7 A h/150 mL of solution. Times tested for each cycle ranged from 1 to 10,000 msecs. Graphite, lead and stainless steel were evaluated as electrode materials. Square wave electrowinning at 70°C (158° F) gave the best separation of Ag and Au from Cu. Applying 2.5 V during the duty cycle, 0.0 V the rest of the period, a duty cycle of 10% to 30%, and a period of 100 msecs to 1000 msecs gave the following results: Ag concentrations decreased from 34 µg/mL to 0.1 µg/mL. Au concentrations decreased from 54 µg/mL to 0.2 µg/mL and Cu concentrations remained almost constant at 560 µg/mL.

Jan 1, 1995