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By Palmer C. Sweet

Mining-related wastes, which are increasing, are being utilized more and more as valuable resources in Virginia. The Environmental Protection Agency (EPA) divides mining-related wastes into two categories: those generated from mineral extraction and beneficiation and those generated from mineral processing. Materials from both categories are produced in Virginia, where waste (by-product) materials are present at a variety of mining sites and processing plants; some of which have been exploited for various uses in the past and/or present. These materials include: used concrete recycled for roadbase material; pyrite coated with magnetite for use in portland cement; minor amounts of fly ash for use in concrete block, lightweight aggregate, and flowable structural fills; granite and diabase quarry fines for use as agricultural and asphalt filler; lime kiln dust for use in neutralizing and stabilizing coal refuse; soapstone aggregate for use in terrazzo heat retention panels; kaolin for use as a filler product and as an ingredient in white cement; slate quarry fines used as landcover and combined with aggregate for crusher run and as a filler in asphalt; and coal refuse for use as fuel in a lightweight aggregate plant. There are some materials available that have never been utilized, although several ideas were investigated to turn them into usable commodities. One such material is a high-alumina scrap produced as a by-product at a ferrovanadium processing plant. However, large quantities of waste materials from metal mining, industrial mineral, and fossil fuel operations remain to be disposed of in an environmentally safe and economic manner. In 1989, almost one million tons of fly ash were produced from burning of coal at eight coal-fired power plants in Virginia. Present uses for this waste such as an ingredient in concrete block, concrete aggregate, and in structural fills cannot dispose of all the available material; however, increased use of fly ash as a soil/rock substitute for structural fills and embankments may solve the problem of its disposal. Another waste material is calcium carbonate precipitate paste produced at a lithium carbonate processing plant and presently being used for back filling an on-site inactive underground limestone mine. Flue gas desulfurization (FGD) wastes in the form of CaS04 will probably increase threefold. If this material contains a minimum of 95 percent gypsum and negligible chloride, it may have a value to a wallboard manufacturer as we move toward the year 2000. Thought must be given how this increasing waste can be disposed of in an environmentally safe manner.

Jan 1, 1995

By B J. Kennedy, G W. Sengstock

During the last two decades, many advances have been made in open cut coal mining technology as new mines have come on stream and old mines have faced increasingly difficult mining and operational conditions. The need for close control of operating costs has necessitated consideration of modified excavation methods.

Jan 1, 1995

By Durucan S

The southern Attiki peninsula is a very interesting area from an environmental point of view. The port and the city of Lavrio is situated at the east coast of the peninsula with about 10 000 inhabitants and there are also a few villages in the vicinity. The south-eastern part of the peninsula hosts the famous Lavrio mines which exploited the silver bearing orebodies of the area for more than 25 centuries. As a result, soils around the city of Lavrio are polluted with high heavy metal loads. The area is also of archaeological interest, as there are well preserved remnants of ancient mining and processing plants and archaeological sites. Soil samples collected from an area of approximately 120 km2 around Lavrio were analysed for their metal contents and the spatial distribution of the concentrations of ten selected elements were estimated from these data sets. The spatial data analysis and transformation capabilities of Geographic Information Systems, combined with extensive mining and geological data, helped the authors to identify the extent and causes of metal pollution around Lavrio.

Jan 1, 1995

By Alan G. Galley

"Advances in our knowledge of the petrochemical attributes of deposit environments and of the character and extent of hydrothermal systems associated with certain deposit types has resulted in increased application of lithogeochemistry to exploration programs. Lithogeochemistry can be used to vector an exploration program toward an area of high potential through the use of a series of collapsing scales of analysis from a tectonic subprovince down to a particular stratigraphic segment. In the case of volcanogenic massive sulphide (VMS) deposits this involves the recognition ofsuitable volcanic domains, and the identification of subvolcanic intrusions and cogenetic felsic extrusive complexes. The recognition of chemical vectors within regional-scale alteration zones and associated chemical sedimentary rocks allows the geologist to identify the stratigraphic units with the most potential for hosting a base metal deposit.An integrated lithogeochemical program requires the judicious use of major, trace and rare-earth element and isotopic analysis. Standard discriminant plots may be employed to identify suitable tectonic and lithologic environments. Analysis of the chemical and mineralogical variations in broad-scale, semi-comfortable alteration zones provides a useful set of vectors to VMS mineralization. These may include contouring raw data, element ratios on XY plots, normalizing data against known rock values, or calculating mass changes in alteration zones."

Jan 1, 1995

By J. E. Dutrizac

A mineralogical study of a weak acid leach residue from the Clarksville zinc plant of Savage Zinc Inc. was carried out. The study focused on Pb and Cd as these elements most significantly impact on the environmentally acceptable disposal of the residue. The residue consists of major amounts of bassanite, zinc ferrite and various Zn-Pb-Fe-Cd silicate species. Also present are lesser quantities of PbSO4, sphalerite, Fe2O3 quartz, Mn-Pb-Fe oxides, SrS04, (Pb,Sr)SO4 iron gel-silica gel, jarosite and Ti oxide. The principal Cd carriers are the zinc ferrite, which contains up to 9.00% Cd and likely accounts for -45% of the total Cd content of the residue, and the various silicate species which contain up to 6.97% Cd and account for about 45 % of the total Cd. The sphalerite is a minor Cd carrier containing an average of 0.35 % Cd and accounting for -5 % of the total Cd; the other carriers contribute only trace amounts to the total Cd content. The major Pb carriers are PbS04, Pb-bearing silicates and Mn-Pb-Fe oxides. Minor proportions of the total 1.09% Pb content of the residue are carried by SrS04 and (pb,Sr)S04' Trace Ph carriers include the iron gel-silica gel, Fe-Zn-AI oxide and bassanite. The residue after the toxicity characteristic leaching procedure (TCLP) is mineralogically very similar to the initial weak acid leach residue; the amounts of calcium sulphate are approximately the same in the two products. The principal Cd and Pb carriers are also the same as those noted in the initial residue, except that some dissolution and reprecipitation of Pb-Sr sulphate takes place. That the residue fails the TCLP test is likely a consequence of the superficial dissolution of Pb and Cd from species such as PbS04 or Zn-Pb-Fe-Cd silicate.

Jan 1, 1995

By Faustino G. Prado

In the, quest for an economical and environmentally friendly reclamation of metallurgical dusts generated during pyrometallurgical operations, our goal has been the separation and recovery of most of the components, as well as the complete recycle of all the reagents. Effluents have been avoided, within acceptable economic parameters. This presentation, which can be applied to a large spectrum of dusts and other residual-materials-, has focused on the dusts generated by the operation of Secondary Copper Smelters. Those dusts show a wide range of components, including zinc, lead-, copper, cadmium, tin, chlorine and-alkalies. Our present work deals with the use of ammonium salts in the separation and recovery of-the above mentioned elements in a marketable form. Most of the chemistry and techniques involved have teen already confirmed in commercial scale operations. Others have gone through pilot scale tests or bench scale tests. The recycle of reagents has also been- confirmed at the same operating levels. A preliminary evaluation indicates that the chosen route, in addition to a viable economy, offers a complete and safe reclamation within the most strict environmental regulations.

Jan 1, 1995

By Durucan S

Uncertainty due to spatial and temporal variability of different pollutants found in soil, water and air is an important issue in the modelling of environmental impacts. Recognition of spatial environmental patterns is relatively straightforward to achieve by applying most of the well-known artificial neural networks or adopting a stochastic approach. However, it is the temporal component of the environmental variables that makes modelling of the environmental pollutants particularly complicated and challenging. This paper presents the results of a case study investigating the artificial neural network performance when modelling the spatio-temporal behaviour of environmental pollutants. The test case involved the modelling and prediction of the distribution of water quality indicators along a river from the point of discharge of treated mine effluents. The behaviour of river water quality indicators is rather complex and shows a lot of fluctuations due to a number of hydrochemical, hydrobiological and hydrodynamic factors. Results obtained in this study indicate that artificial neural networks provide a very powerful and robust method for simultaneous modelling of spatio-temporal behaviour of environmental pollutants.

Jan 1, 1995

By Waldo Valderrama, Luis Magne, Paola Grandela

The effect of liner shape on power consumption was studied in a small laboratory mill under various operating conditions. It was found that the angle subtended between the lifter front face and the face in contact with the mill case has the most significant influence. The increasing height of lifter reduced power consumption, whereas the lifter spacing did not show any influence. The effect of height is less relevant at lower front angles. Highest power consumption is achieved with a 45" front angle. A comparison of cylinders and balls under identical conditions gives higher power consumption for ball charges. The data does suggest that, for maximum power draw, slip in the outer layers of the charge and the early recirculation of energy to the mill case should be avoided. Both factors prevent an efficient energy transfer to the mill charge.

Jan 1, 1995

The sedimentary basins of this region developed in the collision zone of thePacific Ocean plate and the continent. Stresses were transmitted thorough wedge-like lithospheric blocks, such as the Okotsk Sea, East Kamchatka, Aleutian and other smaller blocks. Compression and inversion were more active at the boundaries: ***INSERT EQ*** and ***INSERT EQ*** in places. Tension, rifting and the increase in the rate of sedimentation were marked in P1-2, P3, N12, and also in N2 û Q in places. Structural plan changes of the sedimentary basins and possible oil, gas and fluid migration occurred more actively at the boundaries: ***INSERT EQ***.

Jan 1, 1995

By Evans R, McCallum P

Modem blast initiation systems allow users many options for connection and application in the field, and have resulted in more innovative and complex uses of sequencing to influence blast outcomes. However, no tool existed which allowed the blaster to easily and quickly assess the effect of different options. The original requirement was for a computer program which allowed the easy input of blast patterns and the associated initiation sequence, and then permitted the evaluation of different options with respect to established criteria such as the number of holes per delay and angle of initiation. The implementation of this goal saw the development of the SHOTPIan blast sequence design software, with particular emphasis on an easy-to-use menu driven interface and visualisation of the blast sequence. Extensive trialling during development saw the incorporation of additional features requested by industry such as the ability to import from established mine design software packages, and further features such as the calculation of burden relief times. Case studies of the use of the program are provided, where the rapid evaluation of a number of options has enabled blast results to be optimised. Examples are also given of cases involving two-path initiation

Jan 1, 1995

By C Ross

This paper uses the results of research trials by Landcare Research and Forest Research Institute and assessments of reclamation plantings at mines and other drastically disturbed sites to describe methods of enhancing restoration of native forests. The characteristics of mine and forest environments are compared to highlight the difficulties facing restoration and techniques which result in successful restoration are described. Selection of the most appropriate technique is illustrated by describing restoration of lowland beech-podocarp forest at a West Coast coal mine. The key to successful reclamation is to understand the factors controlling and limiting plant establishment and growth, then to design rooting media, surfaces and management regimes to create a favourable environment. This paper concludes with a summary of the planning and technical factors which are critical for successful restoration of native forest.

Jan 1, 1995

By S. M. Robinson

Wollastonite is recognized as one of the most unique, non-metallic minerals in the world. Its history for use in industrial applications is recent compared to other minerals, however, its distinctive physical properties, such as acicular particle shape, and alkaline pH creates incorporation possibilities ranging from bowling balls to automotive fascia, from ceramic tiles to automotive brakes, and from thermal insulation board to industrial and trade sale coatings. Its future use will be impacted by the exploitation of deposits which will ensure maintenance of the acicularity and purity of this naturally occurring mineral. Additionally, closely held surface treatment technology will open up additional niches requiring highly engineered performance.

Jan 1, 1995

By G. M. Rao, P. N. Deo

Graphite is soft and easily floatable but it is quite difficult to obtain high purity concentrate at coarse sizes. Chemical treatment can produce high grade concentrate but it is an expensive process. Graphite containing plus 96% fixed carbon (FC) with coarse flakes commands high price in international market. Such graphite concentrate containing plus 96% FC was produced in Indian Bureau of Mines (IBM) by using newly developed reagent (mixture of different hydrocarbons and terpenes, IBM/D7) instead of commonly used frothers viz. pine oil, MIBC, kerosine etc. and regrinding in a special type of mill with special grinding media instead of grinding in a conventional ball/ rod mill followed by cleaning. Both the new reagent (frother) and special grinding media are inexpensive and readily available. The process is under patenting. This paper focuses application of this new grinding methodology for flake size protection, and the new reagent for selective flotation of high purity graphite.

Jan 1, 1995

By Carl W. Dalrymple

A wide variety of contaminants (heavy metals, suspended solids, colloids, oils, organics) have been successfully removed from wastewater using an electrocoagulation process. An innovative electrocoagulation system is described. This process involves a procedure which subjects dissolved and suspended wastewater contaminants to the simultaneous addition of metal ions in the presence of direct current. During the treatment process Ionic and other charged particles in the wastewater are neutralized with oppositely charged ions generating the coagulation of contaminants: The process Is called CURE, and' presented here with application to wastewaters containing mainly heavy metals.

Jan 1, 1995

To develop a comprehensive, practical method for designing longwall gate entries that considers coal pillar size, mine roof quality, and artificial support in an easy-to-use computer program.

Jan 1, 1995

By Sukru Sumer

East Pit Lake is an artificially created lake that resulted from the remediation and reclamation of surface coal mining operations at TransAlta Utilities' Whitewood Mine in the Wabamun area west of Edmonton, Alberta. The original excavation resulted from the creation of a mine end cut at the northern extent of the mining operation. The area of the surficial drainage basin that feeds East Pit Lake was relatively small. Therefore, most of the inflow and outflow from the lake would result from regional ground water flow. There was a concern about the lake's ability to provide a suitable habitat for a sportfish population. To determine the final recovered water level and rates of recovery, a two-dimensional ground water flow model was used. Data supplied by nested piezometers in and around the mine were used to calibrate the computer simulation and assess predicted recovery.

Jan 1, 1995

By Katsunori Okaya, Toshio Inoue

Application of the discrete element method incorporating the simple kinetic model of the ball-to-ball and ball-to-wall interactions enables us to visualize the details of the grinding actions prevailing in the ball mills. We have developed a computer program to represent a generic mill model with which we can simulate tumbling mills, vibration mills, centrifugal mills and planetary mills. While the program can be used for various purposes including design of new equipment, one obvious application of it is the analysis of the conventional tumbling ball mills for better understanding and improvement. The purpose of this paper is to present a model and to observe its behavior in particular attention to the spatial distribution of the energy dissipation as well as the energy spectrum and their dependence on the major parameters such as mill speed, ball filling, liner configuration, slurry viscosity and the hardness of the ore.

Jan 1, 1995

By A. F. Raschenko, V. V. Elschin, Y. E. Golodnov

Kinetics and mechanism of gold and silver sorption from thiocarbamide solutions by activated carbon were studies using tne method of equilibrium-kinetic analysis. The intradiffusonal character of the process was determined and the kinetic and thermodynamic constants were calculated. The electrostatic component of the adsorption interaction was estimated by the electro - chemical investigations. The optimal parameters of the desorption of noble metals thiocarbamide complexes were determined. The intensification of gold and silver desorption process is reached through the use of activating additions to the eluent and electro - chemical polarization of activated carbon. Methods for complex and selective extractions of gold and silver from thiocarbamide solutions and pulps by activated carbons were developed.

Jan 1, 1995

By Jr. Gabler

Because of concern over the availability and reliability of an uninterrupted supply of manganese and other materials, the U.S. Congress requested that the U.S. Bureau of Mines (USBM) study the /low of strategic and critical materials in the economy to delineate and quantify the production areas where metal values are lost. As a result, the USBM developed a generic computerized commodity flow model that is readily amenable to updating. The original model developed for cobalt, with slight modifications, was used to track the flow of manganese. This report follows the flow of manganese through its metallurgical and chemical applications and highlights areas where significant losses occur owing to downgrading, export, or disposal. The study indicates that materials containing 695,000 short tons (st) of manganese were consumed domestically in 1990. Scrap recovery specifically for manganese recycling was insignificant. However, considerable manganese was recycled through processing operations as a minor component of ferrous and nonferrous scrap and steel slag. The major loss category is manganese lost in steel processing, 323,156 st or 46 pet of the 1990 apparent consumption. Most of this loss reports to steelmaking slags. Recovery from slags is technically feasible, but is not economically feasible.

Jan 1, 1995

By Allan E. Hall, Kuda R. Mutama

Jet fan (ductless fan) ventilation in underground mines and tunnels is a subject requiring further attention. At present there are no accepted procedures or guidelines for this type of ventilation. The main reason has been the absence of sufficient general data, which has hampered the development of rules. There is great potential for using jet fans in terms of both effectiveness and economics because they eliminate the need for ventilation tubing. In the present studies a procedure is described and results are presented from a jet fan modeled in a square section wind tunnel. The major purpose of the studies was to provide fundamental data on jet fan performance after it was realized that previous work had been limited and too site specific. The jet fan position in relation to the tunnel walls was varied in order to study the influence of confining walls on entrainment rates and the resulting aerodynamics. A clearer understanding of the fundamental principles of jet fan applications was obtained.

Jan 1, 1995