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By G. Q. Liu

"The application of oxygen-enriched cyanidation to three Canadian gold ore samples has been investigated. The results showed that the use of oxygen can improve gold dissolution kinetics, reduce grinding time, and lower cyanide and lime consumptions. To obtain the same gold extraction, the required cyanide leaching time was reduced from 48 hours in slurry containing 8 ppm O2 to 12 - 24 hours in 20 ppm O2 slurry. Reagent consumptions were reduced by 23 - 37% for cyanide and by 35 - 54% for lime. There was little advantage to further increasing the dissolved oxygen to 32 ppm from 20 ppm. Gold extraction from the +200 mesh fraction improved 4 - 14% in oxygen-enriched slurry. A general kinetic model derived from the cyanidation of three ore samples can be described by the following equation: <equation>where E is the gold extraction (%) at time t (hours), EI is the ultimate gold extraction (%) , and &apos;P and k are constants depending on cyanide concentration, level of dissolved oxygen, and the characteristics of the ore samples. Comparative studies of conventional carbon adsorption and carbon adsorption in oxygen-enriched slurry have also demonstrated that oxygen enrichment resulted in more favourable conditions for gold adsorption."

Jan 1, 1995

By O. Guyot, A. Broussaud, J. Björkman, P. Söderman, P. O. Samskog

Model-Based Expert Control systems (MBEC) are on-line supervisory dynamic optimization systems which combine the ability of a phenomenological model to generate a large amount of information about the state of the process and predict its evolution, with the flexibility of a rules-based approach to take plant constraints into account and apply a complex control strategy. For its new concentrator started in 1995 in Kiruna (Sweden), LKAB has implemented a progressive grinding flowsheet with closed-circuit autogenous grinding followed by closed-circuit pebble grinding with ore pebbles. The standard for instrumentation in this new plant is very high. The control hardware consists of a Distributed Control System (DCS) through which the operators interact with the plant, supplemented by a site-level Management Information System (MIS). A state-of-the-art MBEC system was imbedded in the MIS by the authors before plant start-up. It consists of several modeling and expertise software modules: a phenomenological process model and a Kalman filter estimate continuously the state of the process, an optimizer calculates an optimum feedrate, while rules-based modules establish production targets and key process set-points. The decision to install the MBEC system as an integral part of the new plant before start-up illustrates the current maturity of the technology, i.e., enough know-how was accumulated through former projects to design and develop the system to a large extent without accessing the plant. The feasibility and the power of dynamic optimization systems were previously demonstrated in Kiruna pre-existing concentrator by the authors. First, a MBEC system was installed on the three existing pebble mill circuits, providing both an increase in quality (stabilised size distribution) and a 10% increase in capacity. An on-line expert control system with limited modeling capabilities was also installed in the existing flotation plant, with the aim of stabilizing phosphorous content in the concentrate and optimizing collector additions. Both objectives have been achieved.

Jan 1, 1995

By Robert B. Parsons

"The last edition of Tax Notes expressed concern about two proposed tax changes in Finance Minister Paul Martin&apos;s 1995 budget that could have detrimental effects on Canada&apos;s mining industry. This month, Tax Notes expands on these concerns. This article is based on a paper that the author presented at ClM &apos;95 in HalifaxIntroductionOn a global basis, there are more investment opportunities in the mining industry today than at any other time in history. Countries in Central and South America, Eastern Europe, the CIS, Central Asia, and Asia are competing aggressively to attract investment to all sectors of their domestic mining industries. Today, the demand for investment dollars exceeds the amount of dollars that are available for investment in mining. It is not surprising, then, that the established mineral producing nations are witnessing a decline in spending on exploration and development on their home turf, and an increase in spending in developing countries. In the context of a developed country such as Canada, there are two manifestations of the problem of declining investment: (I) Foreign investors are allocating more of their capital budgets to new opportunities in developing countries; and (2) Canadian juniors and seniors are spending proportionately more abroad. This shift in global spending patterns is the source of some concern for the future of Canada&apos;s mining industry, particularly because it is widely believed that the current rate of discovery of ore reserves in this country is too low to replenish depleting reserves.""Government bashing"" has always been a popular pastime in Canada. Invariably, this pastime has focussed, at !east in part, on taxation. In view of the intense competition that Canada faces on the global mining scene, it is important that the role of taxation in the decision-making process be kept in perspective. This paper seeks to put the role of taxation into perspective."

Jan 1, 1995

By Marco Olper

After two years of extensive research a new and innovative modification to the CX-EW process has been exploited. This process, called CX-EWS, avoids completely all the critical aspects of the previous process which affected the cost of the energy, of the chemicals and of The maintenance of the insoluble anodes. All these benefits reflect a saving of about 30% of The operating costs compared to the present traditional production and allow for a total operating costs of less than 6.5 cts/lb. lead (net of raw material cost). With this new technology it is allowed for the first time the treatment in the same plant facilities of both primary lead sulphide concentrate and spent batteries. The paper describes the technical and economical aspect of the new process with a feasibility study for 150,000 t/y spent battery facility throughput.

Jan 1, 1995

By Carlie JC

Many low sulphidation epizonal gold and zinc-lead vein deposits within magmatic arcs are situated on basement highs, and post-date both the main volcanic episode and porphyry copper (gold) mineralization. These features are best explained by emplacement of a flat batholith a few kilometres beneath each mineral district, as recently demonstrated by geophysical data in the Baia Mare district of Romania. The batholith provides heat for the hydrothermal system, and results in extensional faulting both through up-doming of the overlying rocks, and in some arcs through incipient collapse of the thermally weakened crust under regional extensional stress. More water-rich magmas emplaced at greater depths could explain some deep epizonal and mesothermal gold deposits situated outside magmatic arcs.

Jan 1, 1995

By Dean J. Soderstrom

Soil and sands were contaminated with depleted uranium from weapons testing. This resulted in the formation of a complex mixture of uranium compounds. Characterization studies of the soil indicated the uranium was present as uranium metal, uranium oxides, silicon-bearing metallic uranium, and uranium silicates. A process was developed to selectively remove dense uranium compounds using gravity separation and a chemical extraction system to remove uranium which was not available for separation by gravity methods. Results from characterization studies and pilot scale testing are presented for background information. The primary purpose of this presentation is the report of the results achieved in the field application of the processes.

Jan 1, 1995

By P E. H Gregg, D Horne, R B. Stewart, N Bolan

The Tui mine site is situated on the NW flank of Mt. Te Aroha, at approximately 400 m altitude. During underground mining operations two lead-copper-zinc ore bodies were exploited and processed on site. The legacy of the mining operation is a barren dam containing over 100 000 mm of sulphide-rich tailings. The Tui mine site is arguably the worst case of environmental degradation resulting from past mining activity inNew Zealand. Although the impacted area (approximately 4 ha) is extremely small by international standards, acid mine drainage (AMD) emanating from the abandoned tailings dam and mine adits has severely contaminated local streams and prevented natural plant recolonisation of the site for more than 20 years. &nbsp; The suitability of the tailings as a potential plant growth medium was assessed with the end view of revegetating the tailings dam and alleviating AMD. This paper outlines characterisation work conducted on the tailings and summarises preliminary results from plant growth trials. The tailings contain up to 5% Fe, 1.15 % Pb, and 0.45% Cu in the form of sulphide minerals. The distribution of heavy metals, sulphate and total sulphur with depth indicates that the top 200 - 300 mm of the tailings have been extensively weathered since their deposition. The oxidation of sulphide minerals, particularly pyrite (FeS2 ) has reduced the pH of the tailings to nearly&nbsp;2 in places. Below 300 mm the sulphide minerals are largely unweathered and the theoretical acid generating potential of the tailings exceeds 170 Mg CaCO3/1000 Mg tailings at certain depths. Plant growth trials were conducted to study the effects of lime and organic matter addition on the establishment of vegetation on the Tui mine tailings. Several plant species were assessed including some cultivars bred for their tolerance of heavy metals.

Jan 1, 1995

By Jean Goldschmidt

Recycling of fine oxidized particles of non-ferrous metals usually cannot be carried out by pyrometallurgical methods. &apos;Hydrometallurgy provides an alternative technology to reintroduce? the resulting products as secondary raw materials into the industrial cycle, thereby saving resources and energy while keeping the environment a little cleaner. The paper summarizes the methods employed by Hydrometal to achieve these objectives and? stigmatizes the latest counterproductive international regulations which create ever more obstacles to environmentally sound recycling.

Jan 1, 1995

By V. L. Stolyarova

As part of an effort to develop the fluoride electrolysis route for the production of rare earth metals and alloys, a study of the thermodynamic properties of DyF3 has been carried out by Knudsen cell mass spectrometry. A quadrupole mass spectrometer QMS 420 was used in conjunction with the Knudsen cell arrangement. The experiments were carried out in the temperature range 1280-1440 K. Vaporization was carried out from platinum, molybdenum and tantalum cells. The Dy*, DyF+, DyF2+ fragment ions and the DyF3 parent ion were identified in the mass spectrum of the DyF3 vapour. The DyF, vapour pressure was obtained by the complete isothermal vaporizadon method as well as the ion current comparison method, and the enthalpy of sublimation of DyF3 was evaluated. From the DyF3 vapour pressure data obtained at different temperatures, the enthalpies of formation of DyF3 in the gaseous as well as condensed phases have been evaluated. The experimental data are compared with the thermodynamic information available in literature.

Jan 1, 1995

By M. H. Staia

A Venezuelan ilmenite concentrate has been chlorinated at a temperature of 700" C by carbon tetrachloride. In the experimental rig, built at laboratory level, the direct chlorination process yielded a TiCI, recovery of approximately 85% after 280 minutes processing. The partial pressure of carbon tetrachloride was nearly atmospheric (0.94 atm). Product vapors from the reactor were fractionally condensed in a condenser which was maintained at a temperature of 250°C meanwhile TiCl, vapors were condensed in refrigerated coils at a temperature of -20°C. The concentrate used in this investigation was obtained by applying gravitational and magnetic concentration methods to the black sands. The experimental results have shown the need to asses the influence of the weight ratio of ilmenite to carbon tetrachloride on the resultant products. The equilibrium of the heterogeneous system has been calculated taking into account the initial experimental conditions.

Jan 1, 1995

By Robert C. Dunne, Maurice E. Freeman, Denis S. Yan

A laboratory tower mill was used to investigate the effect of some variables on the power requirements of a plant mill. The grinding laws were tested for fine grinding and Charles&apos; law and Rittinger&apos;s law found to be most closely satisfy the experimental data. The effects of ball size, ball charge mass and media type were investigated. The screw speed was altered to control the power input as required. The results indicate that changes in these variables will change the grinding kinetics but in terms of the grinding efficiency they have no effect on the size-energy relationship. The main factor in the specific energy efficiency is the transfer of the input energy to the charge by variation of the agitation mechanism. The efficiency of a tumbling ball mill and a pin stirred mill were tested for comparison.

Jan 1, 1995

The number of employees required to operate a continuous operation was determined. The fixed and variable costs of the operation were separated, generally along the lines of labour and stores components. Proprietary `MicroPlanner&apos; scheduling software was used to assess resource utilisation under the constraints generated by seven-day operation to determine the level of resources required and ensure that the maximum use was being made of all resources. The mine economic model was used to account for both the fixed and variable costs of the various task to determine the cost and net revenue of the various scenarios. The analysis indicated that mine output could be increased while reducing the unit production cost. Several eight- and 12-hour, seven-day rosters were sourced and ranked for their potential to improve production and communication, and for their effect on employee health and lifestyle.

Jan 1, 1995

By Xu C

This paper describes the structure and operation of an interacth.. computer program for mineral industry financial analysis and production planning. It includes comprehensive risk analysis with correlated variables and optimal production scheduling using Lane&apos;s balancing cut-off grades and the general dynamic programming approach.

Jan 1, 1995

By David Logan, Sigurdur Finnsson

This project, which is intended to provide effective sewerage services to the Blue Mountains community, is located in the Blue Mountains National Park, about 60 km west of Sydney, Australia. The sewerage scheme consists of about 40 km of tunnels, out of which approximately 22 km have been completed. This paper describes the last major tunnelling operation on this project, the Hazelbrook to Katoomba tunnels. These tunnels, which mainly traverse the Hawkesbury Sandstone formation, are being excavated by a new 3.4 meter diameter Jarva Mk12C TBM. The mucking system consists of a continuous conveyor, which has allowed for some very impressive advance rates. The paper will consist of three main sections; the general geological conditions expected along the tunnel will be described in the first section. The second section will discuss the design and main features of the TBM, back-up system and continuous conveyor. The third section of the paper will describe the operational aspects and various performance data of the machine.

Jan 1, 1995

By Cox N

Fragmentation control is perhaps the most critical aspect of quarrying operations, potentially impacting on the costs of all down stream processes, and sometimes even on the economic viability of an operation. The focal points of studies to control fragmentation are generally the pattern of blastholes, the accuracy of drilling, and the most appropriate powder factor. Recent studies suggest that the performance, and consistency of performance, of explosive detonation in the blastholes may also be a significant factor impacting on blast performance in hard rock quarries. This paper presents the results of studies of bulk emulsion and watergel explosive performance, using blasthole velocity of detonation measurements, and its impact on fragmentation. Field studies show a strong correlation between blasthole VoD and blast fragmentation. Another aspect of explosive performance impacting on ease of excavation of blasted rock is muckpile displacement, from which estimates of effective heave energy have been made for different bulk slurry (emulsion and watergel) products.

Jan 1, 1995

By Downing Terry L.

Dry mineral beneficiation methods have been developed for separation of borate minerals from montmorillonite claystone gangue. The methods include the use of newly developed dry high intensity magnetic separators. The application of these methods has the potential for economic benefit at U.S. Borax Inc. in three areas: ? Processing surface impoundments (ponds) material. ? Pre concentrating ore to be fed to primary refinery. ? Concentrating borate minerals to produce potential products.

Jan 1, 1995

By R. Kuhns

The western coast of South Africa hosts a significant diamond resource within gravels associated with paleo-shorelines, channels and transgressive lag deposits. Diamonds were transported from the Kaapvaal Craton to the coast largely during the late Cretaceous via the paleo-Orange river systems. On shore and near shore environments are underlain by Proterozoic metamorphic and granitic rocks which provide gully and pot hole-type traps associated with paleo-channels, basins, bays and beaches. Inner and mid-shelf environments are covered by diamondiferous, poorly lithified upper Cretaceous and Tertiary sediments. The upper Cretaceous gravels were reworked along the sediment-starved coast during much of the Tertiary. Reworking was mainly achieved during marine flooding events which produced lag gravels along the paleo-shorelines. This process reworked the diamonds from low-grade Cretaceous gravels and concentrated them in higher-grade Tertiary gravels.

Jan 1, 1995

By J. A. Reizes, C. A. J. Fletcher, T. Jancar

Spirals play an important role in fine coal and mineral processing. To date, almost all spiral designs have been empirically based. Although many operational units have evolved utilising this approach, it does not necessarily lead to optimal spiral designs. This paper presents the preliminary results of a collaborative computational and experimental research program to understand the detailed separation process which will ultimately lead to a parametric assessment of alternative spiral designs through computational simulation. Unlike the empirical approach, a computational simulation is only subject to the fundamental physics of the fluid flow. No prior knowledge of the generic spiral flow is necessary. The computer code implements a robust finite volume technique to predict the three dimensional fluid motion. A height function method is used to model free surfaces and the code is capable of handling arbitrary spiral geometries. Preliminary validation of the computational simulation is carried out through analysis of an existing spiral design -the Mineral Technologies LD9 unit. Computational flow predictions are compared with experimental measurements obtained using a number of techniques, including sampling and flow visualisation, for flow test cases where no solid particulate is present.

Jan 1, 1995

By J. J. Davis, C. A. J. Fletcher, M. Li, T. Jancar

This paper summarises the experimental approach to spiral modelling at the Julius Kruttschnitt Mineral Research Centre, University of Queensland, involving the use of plastic density tracers to determine partitioning performance on three models of coal spiral. This work has led to phenomenological models of the three spiral profiles most widely used in the Australian coal industry. The results from a parallel computational fluid dynamics approach to spiral modelling currently underway at the University of New South Wales are also presented. The computational simulation has been successfully applied to generic spiral geometries and is capable of predicting the fluid phase three dimensional flow fields and corresponding free surface profiles for moderate Reynolds&apos; number and Froude numbers. Simulation predictions are compared with experimental results from a Mineral Deposits LD9 coal spiral.

Jan 1, 1995

By H. Polat, B. Mohal, S. Chander

Several nonionic surfactants and one anionic surfactant were tested to enhance the flotation response of a low-rank coal. The nonionic surfactants included an ethoxylated octylphenol and several polypropylene-polyethylene block copolymers, and the anionic surfactant was a dioctyl sulfosuccinate. All of the surfactants improved the yield significantly, but the influence on grade was complex. To elucidate the mechanisms involved, separate studies were conducted to determine the emulsification behavior of the surfactants. For the nonionic water soluble reagents, a correlation between the emulsifying power of the surfactant and the flotation response was observed. An increase in the number of droplets produced was considered to he the main reason for increases in the yield. However, a small amount of surfactant adsorption on coal is essential to promote adhesion of oil droplets. When the surfactant was introduced into the flotation pulp prior to addition of dodecane, the benefits of the surfactant decreased significantly. The decrease was attributed to both a decrease in hydrophobicity of coal through increased surfactant adsorption and a decrease in the surfactant available for emulsification. When a surfactant dispersed in oil was used, the transfer of surfactant to the aqueous phase was minimal, and a considerable increase in yield was observed.

Jan 1, 1995