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By M. C. Williams

As the flaws in the population balance model (PBM) comminution model are examined more deeply, further errors and problems were discovered. The Levenberg-Marquardt algorithm for systems of constrained non-linear equations was used to solve the dynamic PBM grinding equations to obtain the grinding selection and breakage rate functions. The fact that the PBM model equation Inverse Problem is degenerate or underspecified is demonstrated. Multiple solutions to the same PBM equations are provided. It is shown that there is no unique solution to the Inverse Problem unless additional constraints are provided or assumptions are made such as the Arbiter-Bhrany normalization assumption. The severity of the non-uniqueness problem for dynamic grinding is demonstrated. Each solution to a dynamic PBM, while giving the same prediction for a given grinding time interval, gives different solutions or predictions for mill composition for other grinding times. Actual experimental grinding data was assessed to determine the functionality of mill selection and breakage functions.

Jan 1, 1993

By Charles L. Kimbell

The concept of data availability must be addressed, because there are perceptible changes from year to year, and the availability of accurately reported, precisely defined statistics and nonstatistical information provides the only sound basis for analytical studies required for government policy planning or industry market analysis. As the countries of Eastern Europe and the former U.S.S.R. undergo the transition from centrally planned economies to market economies, there has been a perceptible increase in information availability for rather obvious reasons. Any industrial operation seeking economic assistance from Government and/or private sources outside the country in which the facility is sited must provide some appraisal of its operations at the time it seeks assistance, as well as some information on previous performance to serve as tools in evaluating its potential under the proposed development scheme for which it seeks financial assistance. Additionally, there was growing governmental recognition that concealment of much of the national mineral production, trade, and consumption data for purposes of national military and/or economic security probably never was very successful, never was really necessary for most commodities, and certainly proved unnecessary with the end of the so-called cold war. Indeed, the long-term unwillingness to publish uniform statistical series of reliable,

Jan 1, 1993

By Michael R. Norland

Surface and subsurface stabilization of mining-related wastes through revegetation depends upon the physical, chemical, and biological condition of the waste following mining. Mining disturbances can significantly alter the soil physical, chemical, and biological characteristics of a site, reducing or eliminating mycorrhizal fungi from the soil. Mycorrhizae are economically and ecologically important because they can alleviate environmental stresses caused by lack of proper soil condition and because they are vital to stabilization of mining waste by increasing plant survival and biomass through increased nutrient and water uptake. This report discusses some of the ecological factors that may affect mycorrhizae-plant associations on mining-related wastes and provides general information on mycorrhizae inoculation technology.

Jan 1, 1993

By L. J. Lutz

The U.S. Bureau of Mines has developed an electrorefining process to recover Ni, Co, Cr, and other metals from mixed and contaminated superalloy scrap. The superalloy scrap is cleaned then directly electrodeposited as a Ni -Co deposit. The process recovers approximately 90 pct of the Ni-Co available from the scrap as a 99t pct pure Ni-Co alloy. During electrorefining the electrolyte undergoes a purification process which results in Cr and other refractory metals reporting to the purification residue. Operating data is given for a 3-L compartmented electrolytic cell. Techniques for the removal of Fe, Cr, and trace impurities from the recycled electrolyte are outlined. The economics of a facility producing 15 mt/d of a Ni-Co alloy are also discussed.

Jan 1, 1993

By S. S. Szoke

The concrete masonry industry, represented by the National Concrete Masonry Association has significantly expanded its markets since the industry's inception. The concrete masonry industry has developed and refined concrete masonry units by producing a variety of quality products on automated machines. In the sixties, architectural concrete masonry units gained popularity. In the seventies, the concrete paver market expanded. In the eighties, segmental retaining wall units became popular. The industry continues to research and develop new products and applications for concrete masonry to satisfy the needs of designers, specifiers, installers and owners. Both existing and innovative technologies in the concrete masonry industry are discussed.

Jan 1, 1993

By M. Ghiani, R. Ciccu

After a short review of the basic concepts underlying the application of selective flotation and electrostatic separation to the beneficiation of phosphate ores, the paper deals with the results obtained with these two technologies for a number of run-of-mine ores of different origin and distinct mineropetrographic features. Problems are discussed in the light of the minero-petrographic characteristics of the ores.

Jan 1, 1993

By J. Sottile, J. L. Kohler

Component failures in the electrical control circuits of mining machines account for a large percentage of the total downtime of the machine. Once a failure has occurred it is always a tedious and usually a time-consuming task to locate the failed component. Moreover, the pressure to quickly locate the cause of a delay can lead to compromises in safety. Thus an onboard diagnostic system, essential for an automated machine, would be a very useful addition to existing machines. This report details U.S. Bureau of Mines development of a generic procedure for synthesizing diagnostic systems for electrical-control-circuit failures in mining machinery. A continuous mining machine is used as the testbed to illustrate the application of the developed methodology. Substantive differences among mining machine control circuits made it impossible to achieve a generic diagnostic system, but a generic approach for the synthesis of the diagnostic system was possible. As the research progressed, it became apparent that an algorithmic approach was better than an expert- system-based implementation. A prototype system was constructed and used to evaluate the diagnostic system. Prototype implementation issues are also examined.

Jan 1, 1993

By Howlett P. F, Courtley S

A problem with secondary breaking at one of the mines of Pasminco Mining led to a study of new rock breaking technologies. Many of the techniques being developed had emerged from the thrust in the USA for continuous drill=break excavation. Such approaches to rock breaking highlighted the applicability of what would normally be classified as tunnelling techniques, to the secondary breaking sector - and possibly the reverse. As a direct result of the investigations for suitable technologies, Pasminco Mining supported the development of two improved rock breaking methods specifically targeting secondary breaking, one of which could be applied to continuous excavation.

Jan 1, 1993

By Xiangwen Wang

Electrochemical measurements associated with the electrowinning of lead metal from concentrated brine (NaCI) - lead chloride (PbCI,) electrolytes at temperatures in the range 328 to 353°K (55 - 80°C) were conducted. The electrodeposition of lead metal onto a lead rotating-disk electrode may be described by the electrodic reaction: {PbCl 4 2 + 2e- = Pb° + 4Cl-} The deposition-overpotential requirements are low (approximately 41mV per decade of current density - Am+), with a corresponding high exchange current (approximately 0.018 A.cm2). The diffusion coefficient of the electroactive PbC142- species in a 3.5 NaCl electrolyte at 353°K was insensitive to the total PbCI, concentration (0.01 to 0.1M), and its value was found to be (1.21*0.1)~10-5 cm2Is with a temperature-sensitivity coefficient (E,/R) of approximately 1.98x103K-1 (328OK(T<353OK).

Jan 1, 1993

By C. H. Lee, F. Concha, L. G. Austin, P. T. Luckie

The Concha-Almendra batch-settling treatment for concentrated suspensions of single-diameter spheres has been modified. This modified version is used in the differential equations of simple batch settling of a particle size range of different density materials. The equations have been programmed for a finite difference solution, and a number of test cases have been analyzed. By cutting the settling column at a fixed fractional height, the material below this height can be treated as underflow and the material above as overflow. The predicted partition curves obtained from treating the settling in this way have Sharpness Indices in the range of 0.5 to 0.6, in the absence of dispersion effects. The Sharpness Indices decrease as dispersion increases. When the feed size distributions are of the Rosin-Rammler form, the partition curves (corrected for the bypass fraction) fit the Rosin-Rammler equation with reasonable accuracy. The predicted Sharpness Index of a component of a mixture of two materials of different densities was unchanged from that of the same materials settled alone. However, for the same, feed size distribution and volume fraction of solids in the feed, the heavier material settled faster, and the lighter settled slower, than when settled alone.

Jan 1, 1993

By S. I. Sobol

Completeness of cobalt recovery from slag requires decomposition of maggemite and non - ferrous metal desorption with polymerized silicon-acid. Cobalt losses are reduced in leaching tai1s up to 200 g/t of iron.

Jan 1, 1993

By B. J. Arnold

Froth removal rate is perhaps the most important parameter in scaling up from laboratory tests to plant froth flotation circuits. The WEMCO froth factor, the percentage of the froth height over the lip of the cell, accounts for the difference between laboratory and plant froth removal rates. As laboratory tests are generally run with a high pulp level, laboratory results are directly comparable to plant results only when a high froth factor (high pulp level) is run in the plant. When a plant does not have a high pulp level, laboratory results must be modified by using a ratio between laboratory and plant kinetics to predict plant results. This ratio, which accounts for the froth factor is important in testing any new reagents or reagent dosage levels. CQ Inc. researchers have used predictive scale-up equations using this froth factor coupled with equations for kinetics and the residence time distribution in the froth flotation cells. These equations show that modifying the froth factor in the plant can have a large impact on flotation cell yield and reagent use. EQUATIONS DESCRIBING FROTH FLOTATION Scaling up from laboratory- to plant-scale coal froth flotation has been the subject of much research and debate over the years. Determining the proper rate equation to describe flotation kinetics and an equation to describe the residence time distribution in a bank of flotation cells have been particular areas of study. As shown in Tables 1 and 2, various rate equations and residence time distribution equations have been proposed in the literature. These equations consist of one or two parameters giving the rate constant(s) in units of time-1 and a parameter for recovery at infinite time, [Roo]. Dowling, Klimpel, and Aplan (1985) evaluated the rate equations in Table 1 for their ability to fit froth flotation kinetic data and found that all of the equations give reasonably low standard errors. Several of these equations, however, proved to have superior confidence limits for the parameters. Other equations have also been proposed to describe the recovery versus time profile. Most recently, Diao et al. (1992) proposed a first-order form with a sine wave distribution. As indicated in Table 2, investigators have suggested many equations to describe the residence time distribution in continuous froth flotation. To measure the water residence time distribution in a bank of cells, a soluble tracer is often used, with the level of tracer being measured over time at the tailings discharge. This response is then put on a dimensionless basis as described by Austin et al. (1984) in order to compare mixing behavior between cells or under different conditions. Coal flotation cells are generally of the flow-through or hog-trough variety allowing for some degree of backmixing and short-circuiting. While the water residence time distribution (see Figure 1) at the end of one cell in a bank of 1.4 cu ft WEMCO froth flotation cells may approximate perfect mixing conditions (Arnold, 1989), the water residence time distribution at the end of a bank of cells does not. Figure 2 shows the RTD for various flotation cell types compared to that for perfect mixers in series. To better describe the water residence time distribution in coal froth flotation cells, Van Orden (1986) used an equation similar to the perfect-mixers-in-aeries equation. This

Jan 1, 1993

By J. F. Hutwelker

A pilot plant was constructed and operated to investigate the column flotation of 20 x 200 mesh North Carolina phosphate ore, using high throughput, high solids operating conditions developed at the NCSU Minerals Research Laboratory. Flotation was performed at 45% solids in a 9.5 cm (3.75 in.) diameter by 2.26 m (7.4 ft.) tall column at throughputs of 19.1 t/hr/m2 (2.0 stph/ft2) and 31.7 t/hr/m2 (3.3 stph/ft2). Recoveries in excess of 98% of the phosphate value were obtained at the lower throughput -- while obtaining concentrate grades containing over 28% P205 (61.2% BPL) at that recovery. Recoveries of about 95% of the phosphate value were obtained at the higher throughput, while making a concentrate averaging 27.6% P209 (60.3% BPL). In addition, a better understanding of the variables governing the column flotation of coarse nonmetallic minerals was gained. Low air flow rates adversely affected concentrate grade at the lower throughput. At the higher throughput, phosphate recovery decreased at an elevated air flow rate. An unexpected result of the study was the effect that frother type had upon phosphate metallurgy. Use of Nottingham Econofroth 925 provided better flotation selectivity than American Cyanamid F-65 at the low throughput. This is significant since the high&apos; throughput tests were conducted with F-65 exclusively. It is reasonable to expect further improvement in high throughput performance when the optimal frother type and dosage are determined.

Jan 1, 1993

By T. W. Camm

The Bureau of Mines conducts studies of the economic impacts of regulations on federal lands. These studies are part of the Bureau Potential Supply Analysis (PSA) program. To meet the needs of these studies, a methodology was developed to estimate operating and capital costs for a mineral deposit given its tonnage, grade, and depth. The format for the cost models in this study was developed at the Bureau&apos;s Western Field Operations Center (WFOC), Spokane, W. A., for studies of known and undiscovered resources on Federal lands. These cost models are described in a Bureau publication by Camm (1991).

Jan 1, 1993

By Raymond G. F

Geostatistics - a tool used by geologists and mine planning engineers to estimate grades and rapidly evaluate alternative mining strategies has reached an advanced stage of development for the silver-lead-zinc orebodies at Isa and Hilton Mines. Geostatistics has been used for over a decade in the massive copper orebodies but the stratiform lead-zinc orebodies are much more complex and provided a completely different set of challenges. Recent increases in computer processing speed and power provided by the Integrated Mine Planning System (IMPS) has aided the development of the geostatistics package. Also the formation of a project team and the subsequent in-house development which has drawn together the expertise of geologists, engineers and system analysts has contributed significantly to the success of the project.The most important feature of any approach to modelling the lead-zinc orebodies is that the kriging search must consider estimate and sample points according to their positions relative to bedding surfaces. By transforming co-ordinates as perpendicular offsets from a plane representing the local strike and dip, it is possible to elongate the ellipsoidal influence to parallel bedding. By interactively modelling surfaces using CAD facilities and then specifying these surfaces as &apos;hard&apos; or &apos;soft&apos; boundaries, the geologist has complete control over the kriging process.

Jan 1, 1993

By Alesse V, Belardi G

A new class of collectors, Mercapto-Benzo-Oxazoles (MBO), exerting selective action on copper sulphides in the presence of Pb, Zn and Fe sulphides (galena, sphalerite and pyrite), has been synthesised in co-operation with Enichem&apos;s Donegani Insitute. The collectors have a mixed aliphatic-aromatic structure and contain functional groups which form chelates with copper. Some reagents of this class having hydrocarbon chains of various lengths have been laboratory tested on a complex sulphide ore containing chalcopyrite, galena and sphalerite in pyritic gangue. Comparative flotation tests have permitted selection of the best collector for chalcopyrite, namely Methyl-Mercapto- Benzoxazole (MMBO). Systematic flotation tests have been performed with this reagent, varying collector concentration, grain size of the feed, pH and flotation time. The results obtained show that the synthesised collector is much better than potassium-amylxanthate (KAX) as regards selectivity towards Pb and Zn. Moreover, it is possible to work at natural pH (6-7) and the flotation rate is higher. In fact in the rougher stage with 80 g/t of collector at natural pH, a copper grade of 7.14 per cent was obtained with a recovery of 73.87 per cent, while the grade with KAX did not exceed 2.11 per cent for a recovery of 73.54 per cent. The amount of Pb and Zn reporting in the copper concentrate was eight per cent and ten per cent respectively, while with KAX it was no lower than 24.34 per cent and 22.71 per cent in that order. After two minutes flotation a copper grade of 5.2 per cent with 52 per cent recovery could be attained, against a grade of 2.5 per cent and a recovery of 44 per cent in the case of KAX. The efficiency of this new collector has been ascertained on two samples of complex sulphide ores of diverse mineralogical composition.

Jan 1, 1993

By R. J. Pugh

The coagulation of dispersions of weakly magnetic oxide mineral ultrafines (such as natural hematite or chromite) in an external magnetic field can be described from inter-particle forces. Essentially, coagulation occurs when the short range London-van der Waals interactions and the long range magnetic forces outweigh the stabilizing electrical double layer repulsion. From the classical colloid chemistry theory, we have calculated the various components of the potential energy for different sized particles at a series of ionic strengths and magnetic field intensities. We have related this theoretical analysis to experimental studies where the magnetic field-induced coagulation of ultrafines of natural hematite and chromite in aqueous suspensions was investigated using a laboratory scale electromagnetic solenoid. The experimental results relate the coagulation process (as determined by magneto-sedimentation analysis) to the particle size, the slurry pH and the external magnetic field. In the magnetic fields, maximum coagulation occurred near the pH of zero point of charge (pHzpc) of the minerals (where the electrostatic double layer repulsion was reduced to a minimum) enabling the particles to enter the "primary minimum" energy sink. On the other hand, in cases where the electrostatic repulsion was not suppressed, then the long range magnetic forces enabled coagulation to occur in the "secondary minimum". This caused the formation of chains which appeared to be relatively stable during sedimentation.

Jan 1, 1993

By P. Mottahed, E. K. S. Passaris, J. Q. Ran

"The jointed roof of underground mine openings in stratified rock can be analyzed in terms of a voussoir beam. Because of the essential indeterminacy of the structure, previous attempts of theoretically solving the equilibrium equation have been unsuccessful. Numericalanalysisby the finite element method taking the geometrical and joint non-linearity into consideration combined with the experimental method has been adopted to study the performance isopara of the voussoir beam. Deformation and failure mechanism is analyzed in relation to the failure modes. Equations are proposed to estimate the elastic buckling strength and the crushing strength of the voussoir beam and to verify the failure mode of shear sliding. For application of the mechanism of the voussoir beam in mining operations, methods are described to predict the stability of a jointed roof and to design the dimensions of mining openings.IntroductionThe roof stability of an underground mine opening has direct effects on the selection of support methods, opening dimensions and, more importantly, on the safety of mining personnel. The prediction of the roof stability can be of importance in the design of a mining method and in mining operations. The jointed roof of mine openings in stratified rock can be stable under transverse load depending on the roof geometry and properties of the roof material and joints. The stability of this type of roof can be analyzed in terms of a voussoir beam which was introduced by Evans (1941) to study the strength of underground strata. Brady and Brown (1985) analyzed the voussoir beam and suggested that the mechanism of the voussoir beam could be used in the design of underground mine openings in stratified rock instead of the traditional continuous beam theory."

Jan 1, 1993

By H. T. Mulryan

Talc is used as an essential ingredient in a variety of plastics applications ranging from polyester body patch compounds through polypropylene automotive, appliance and household furniture components to high performance parts made from liquid crystal engineering resins. This paper focuses on polyolefin applications, the three-tier market for talc in polypropylene, the effects of various tales in typical compounds and trends in each market segment. Emphasis is given to emerging markets, examples of which are polypropylene compounds that mimic higher cost resins, and polyethylene films. Customer requirements, for tales for these purposes are discussed.

Jan 1, 1993

During the 1960s chalcocite ore was mined from the Black Rock open cut. A large amount of this uneconomic material was not treated by the No 3 Concentrator at the time and as a consequence a surface stockpile was created which contained 750 000 tonnes of material at an average of 1.5 per cent copper.Laboratory trials indicated that due to oxidation, an average of 25 per cent of the copper was water soluble and the remaining copper was leachable using a sulphate/ferriclbacterial leach. On the basis of these trials it was decided to investigate the feasibility of producing copper via a leach SX-EW process. The investigation proved the process was feasible, so began the design, construction and commissioning of a 10 tpd (cathode copper) Copper Leach SX-EW Pilot Plant. CMPS Pty Limited in a joint venture with John Holland Engineering Pty Limited were awarded the turnkey contract for the design, construction and commissioning of the Pilot Plant.

Jan 1, 1993