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By Hu Y, Li D, Qu G

In this paper the structural mechanism of the gold - lixiviant complex is investigated. The results show that there are two common characteristics in the outer orbitals for all the gold lixiviants: a) a (Y -type of HOEO to form the L-*Au co-ordination bond, and b) a it type f LUEOs, with symmetry the same as that of 5d orbitals of Au, to form L

Jan 1, 1993

By Gordon C. ‘Bud’ Presley

The pumice and pumicite review arrived too late for the June issue. Estimated domestic production of pumice and pumicite in 1992 was up compared with 1991, according to US Bureau of Mines statistics. The Bureau estimate of domestic production of 400 kt (440,000 st) for 1991 turned out to be 401 kt (442,000 st) of actual production, the lowest since 1989. In 1992, the estimated the value of pumice and pumicite sold or used in the United States was $11.6 million, up only $200,000 from the 1991 value. There was an increase in the mine, or mill, average price from the five-year low of $11.44/t ($10.37/st) in 1986 to $26.42/t ($23.96/st) in 1992. Estimated tonnage produced in 1992 was 439 kt (484,000 st). Apparent domestic consumption was 642 kt (707,000 st), up 135 kt (149,000 st) from 1991. Imports for consumption were estimated to be 215 kt (237,000 st) last year. Domestic production supplied 68% of the demand in 1992, with net imports supplying the remaining 32%. This compares with domestic production sup¬plying 53% and net imports supplying 47% of the apparent consumption in 1988. Exports were about 900 t/a (1000 stpy) for the period 1984 to 1988. In 1989, exports rose sevenfold to 7 kt (7700 st) and to 20 kt (22,000 st) in 1990. The Bureau of Mines reported that the amount of pumice and pumicite exported in 1992 was 12 kt (13,200 st). It is assumed that these exports were from the Pacific Coast because imports, mainly from Greece, continued to be a market factor on the East Coast and the Gulf Coast States in the United States.

Jan 1, 1993

By D. C. Yang, J. Ye

A comprehensive flotation study has been conducted on a Chinese fluorspar ore using the packed flotation column developed at Michigan Technological University (MTU). The results are compared with those for a conventional mechanical flotation method on the same feedstocks. Key factors controlling flotation performance of both methods are evaluated based upon a simple statistic design. The flotation concentrate produced in one stage of the packed column has 4% to 5% higher recovery and much lower silica impurity than the concentrate produced by up to six stages using a conventional mechanical cell. The results also show that the packed-column flotation process is particularly suitable for the recovery of finer fluorspar particles.

Jan 1, 1993

Ulan Coal Mines Limited operates an underground and open cut mine near Mudgee in the Central West of NSW. The mines are part of a Joint Venture managed by Exxon Coal and Minerals Australia Limited (ECMAL). Currently all the mines output of over five million tonnes per annum is sold into the export market predominantly as a steaming product.

Jan 1, 1993

By P. M. Lin, P. Tsang, S. S. Peng

This paper presents an overall stabilization method to eliminate the potential of reoccurrence of subsidence over abandoned mine lands (AML). The method considers column grouting at specific locations, including the destressed and stress concentration zones, instead of grouting around and beneath damaged structures. The latter method is currently commonly used for AML subsidence abatement. The finite element method (FEM) can be used to calculate stress distribution in the strata before and after grouting. A grouting pattern is generated that includes the location and number of grouting holes. Stress concentration can be reduced or eliminated. A comparative analysis, including the number of grouting holes, area of grouting influence, stress level and potential of subsidence reoccurrence, is also presented.

Jan 1, 1993

By G. K. Roset, L. R. Woodland, J. A. Stevenson, G. J. Hodges

The Stillwater Mining Co. (SMC) is a partnership of Pittsburg & Midway Coal Mining Co. and Manville Corp. Since the summer of 1990, SMC has operated a precious metals smelter at Columbus, MT for further upgrading of concentrates from its platinum-palladium mine. The facility's gas-cleaning system utilizes "oxidation/dilute-mode," dual-alkali scrubbing technology to capture sulfur oxide gases from the process gas streams. This paper describes the rationale for selecting the dilute-mode, dual-alkali system and summarizes the design parameters. Also discussed are the startup problems encountered and their solutions.

Jan 1, 1993

By Ellen S. Forbus

Reduction bleaching is used to improve the brightness and color of the kaolin pigments sold to the paper and speciality industries. The bleach re¬duces the iron oxide associated with kaolin deposits to a colorless form by the following reaction: Na2S2O42+ 6Fe+3 + 4 H2O -> 2 NaHSO4 + 6Fe+2 + 6H+ (Conley et al., 1964). At present, sodium hydrosulfite is used by the kaolin industry as the reductive bleach. It is often purchased commercially as a liquid solution and added into an acidified slurry. Before the use of commercial sodium hydrosulfite, kaolin plants manufactured zinc hydrosulfite on site by adding zinc dust to sulfurous acid made by passing SO2 gas into water. This process was abandoned in the 1970s due to environmental concerns about zinc in waste waters. In the 1970s, Engelhard patented a process that made sodium hydrosulfate from an iron hydrosulfate (Tiethof, 1978). Difficulties with separating the iron hydroxide byproduct from the bleach and a decrease in the cost of commercial bleach caused the project to be abandoned.

Jan 1, 1993

Mount Isa Mines Limited has been mining copper ore for 50 years. In recent years, this production has been entirely by open stoping methods with cemented backfill, mostly in the large 1100 orebody.This has been the major ore source for 20 years, with smaller amounts coming from the 400, 500, 650 and 1900 orebodies. At present, the 1100 orebody is the only source, and this situation will continue until the deep 3000 and 3500 orebodies begin producing in late 1992/93. Production rates have increased to almost 6 Mt/yr, and are planned to rise to 7 Mt/yr by 1995/96. In the future, there will be a move towards variations of the open stoping system as production moves to more lensy zones of the southern 1100 orebody and to the deeper 3000 and 3500 orebodies. This paper describes current operations in the 1100 Orebody, with some indications of future directions.

Jan 1, 1993

By C. Flores, R. Y. Wan, M. C. Fuerstenau, T. S. Jordan

Most oxidized manganiferous silver ores contain manganese associated with silver and are not amenable to conventional silver extraction methods, including direct standard cyanidation techniques. However, it is known that dissolution of the manganese might yield a suitable material from which silver can be recovered by conventional methods. In the segregation process, which involves heating the ore with a small quantity of salt and with a source of reducing agent to 680°C - 800°C, the silver is volatilized, migrates and is reduced to metallic silver particles. Conventional cyanide leaching is applied to the resulting calcine. Laboratory investigations have been conducted on a manganiferous silver ore analyzing 0.02 % Cu, 0.09 % Pb, 0.33 % Zn, 12.55 % Mn and 187 g/ton Ag to study the influence of roasting temperature and time, quantity of salt and quantity of coke on silver extraction by the application of segregation roasting followed by cyanidation. Cyanide leaching tests were carried out at room temperature on the segregated calcines produced by using an alkaline cyanide solution containing 2.0 lb/ton of NaCN at pH 11 for 72 hours. The results indicated that 97.8 % of silver extraction can be attained at 850°C, with 2.0 % salt, 1.0 % Coke and 30 minutes of roasting time.

Jan 1, 1993

By Allnutt S. L, Radojkovic A. M

Century, a major shale hosted zinc deposit in the Riversleigh Fold Zone of northwest Queensland's Mount Isa Basin, was discovered by CRA Exploration in 1989. A total of 322 drill holes, completed by the end of 1992, define a resource of 118 Mt of mineralisation averaging 10.2 per cent zinc, 1.5 per cent lead and 36 grams per tonne silver. Mineralisation is developed in the upper portion of Lawn Hill Formation Unit 4 (Pmh4). The intersection of the Termite Range and Little Range Faults, major regional structures, may have been important in controlling mineralisation development. Three listric normal faults, and an unconformity between Proterozoic rocks hosting mineralisation and overlying Cambrian carbonates, divide the deposit into three distinct blocks. The deposit is essentially blind, outcropping in only two places. The deposit is characterised by an extremely simple sulphide mineral assemblage, sphalerite being the most common sulphide phase. Pyrite, the most common phase in many other shale-hosted zinc-lead deposits, accounts for only five per cent of all sulphides present. Siderite is the principal non-sulphide phase present. Both sphalerite and galena have near stoichiometric compositions. Sulphides are confined to carbonaceous shale horizons. Intervening siltstones are essentially barren. Shale and siltstone beds forming the mineralised sequence can be correlated across the entire deposit area. Systematic grade variation occurs within each mineralised shale bed. Although sulphide laminae parallel primary lithologic layering, the point of most intense mineralisation development transgresses stratigraphy. Bituminous material is intimately associated with sulphide mineralisation.

Jan 1, 1993

By J. T. Ryan, Griffin. Wayne H.

This paper shows that if a drift has a brattice which is sufficiently leaky, changes in the operating point of the fan depend solely on the volumetric efficiency within the drift. Under this high leakage condition, an increase in the length of the drift causes very little shift in the fan operating point. For less leaky brattices, the operating point depends on both the fan characteristic curve and the volumetric efficiency. It is shown that for the fan curve and drift parameters used in this paper the fan operating point in a drift with a volumetric efficiency of 50% is essentially the same as a drift which has a zero efficiency. In this region of efficiency, an increase of 300% in the length of the drift causes only a 3% increase in fan operating pressure.

Jan 1, 1993

By A B. Christie, R L. Brathwaite

Since the first occupation of New Zealand in 800 - 900 AD, various useful minerals, rocks, and energy resources have been identified and extracted. The Maori prized greenstone for ornaments, tools, and weapons, used argillite and obsidian for tools, and decorated their carvings and bodies with colours made from clays, limonite, and vivianite. They were aware of coal (waro), but are not known to have used it for fuel. Before 1840, visiting whalers used coal from Shag Point to heat their trypots. Mining activities got underway in the 1840s, with the finding of manganese oxide deposits in the Bay of Islands, Kawau Island, Waiheke+ Island, and Taieri Mouth. Secondary copper ore was mined on Kawau Island (1846 - 1869), and native sulphur was exported from White Island to Europe. The discovery of gold at Coromandel in 1852 and a few years later in Northwest Nelson and Otago opened the way to gold rushes in these areas and subsequently in Marlborough and Westland. Mining of alluvial gold evolved through sluicing to the invention of gold dredges; first (1863) was the simple spoon design, but later (1881) large steam-powered bucket-ladder machines weighing around 3800 tonnes were built. Most of the gold dredges had gone by the early 1960s, following a revival in the 1930s, but one large dredge operates today on the Grey River. Other mining events included: underground mining of coal from 1849 and underground mining of lode gold from 1863 in the Coromandel, Reefton, and Otago fields. Most outcropping coal deposits had been discovered by 1870. Building stones were used by the early settlers for construction of houses, churches, banks, public buildings, and some universities from 1836. Aggregate for roads, railway ballast, and concrete, and limestone for cement and fertiliser, and clays for bricks and china have been quarried for many years.

Jan 1, 1993

By J. D. Miller, P. L. Sibrell

The nature of surface sites for the adsorption of gold from alkaline cyanide solutions has been investigated using samples of synthetic, highly-oriented pyrolytic graphite (HOPG). This HOPG material offers an idealized graphite structure enabling the independent study of the graphitic basal-plane sites and the edges, or defect sites, of the graphitic planes. Radiochemical and X-ray photoelectron spectroscopic experiments independently demonstrated that gold adsorption was much higher on the edges (defects) of the graphite planes than on the planes themselves. These results suggest that site-specific adsorption is prevalent in the adsorption of gold by graphitic carbons (including activated carbon, carbon black and graphite) and that most of the favored sites are at edge defects in the graphite crystal structure.

Jan 1, 1993

By Lee W. Abramson, Mee Shing Owyang

The Lake Merced Transport tunnel is 18 feet in diameter and 1.6 miles long constructed within dune sands, beach sands, and the Colma Sand Formation. It runs beneath highway right-of-way from an existing pump station near the shore of Lake Merced to a point near the Pacific Ocean, where it will connect with the existing transport/storage tunnel. The final tunnel lining was originally designed as a cast-in-place concrete lining to be constructed within steel ribs and wooden lagging initial support. The contractor opted to use a precast concrete segmental initial lining thus requiring a redesign of the final lining. The redesigned lining incorporates composite action from the initial lining thereby eliminating the need for outer steel reinforcement. A computer model was used for analyses which included operating conditions, ground and construction loads, and possible effects of liquefaction and earthquakes.

Jan 1, 1993

By Eisele TC

Horizontal perforated-plate baffles were shown to improve the cleaning efficiency of a flotation column when processing coal from two sources. The baffles consisted of flat plates with holes large enough to avoid plugging problems, and they improved the washing efficiency by making the flow patterns in the column closely approach plug flow. Tests with varying amounts of baffle open area showed that the optimum was between 30 and 40 per cent open area, which effectively prevented backmixing without seriously reducing capacity. The baffled column had previously been tested under ideal conditions with good results (87 per cent pyrite rejection at 85 per cent combustiles recovery), and so the tests reported here were intentionally run with difficult-to-float coals to determine the benefits of baffling under adverse conditions. For an original coal feed containing 38 per cent ash and 3.23 per cent total sulphur, the baffled column could recover 84 per cent of the combustibles while rejecting 84 per cent of the ash and approximately 54 per cent of the pyritic sulphur. Without baffles, the column recovered 88 per cent of the combustibles while rejecting only 76 per cent of the ash and 45 per cent of the pyritic sulphur. Subsequent tests with a dye tracer showed that the baffles reduced entrainment by approximately a factor of five, while the recovery was reduced by only a few per cent. Overall, the loss of capacity due to the baffles was more than offset by the improvement in product quality.

Jan 1, 1993

By R. J. Pugh

The surface chemical sites on several fillers (quartz, feldspar, calcite and granite) were studied by the adsorption of well defined acid and basic probe molecules (benzoic acid, benzyl alcohol, ethyl benzoate, pyridine and benzyl amine) from cyclohexane. The results provided a wide variation of adsorption data, emphasizing the extensive range of site heterogeneity on the filler surfaces. In addition, it was shown that the acidic probes were strongly adsorbed on all of the minerals, thus indicating that the basic surface sites dominate the acidic ones. Also, through FTIR studies with vapor-phase probes adsorbed on orthoclase, it was possible to identify the nature of specific sites and the type of bonding occurring between the filler surface and the probe molecule. These types of surface analytical techniques could give useful information for predicting the adsorption functional groups on dispersants, dyes, thickeners, etc. and could lead to enhanced interfacial bonding between the filler and the matrix.

Jan 1, 1993

Some fundamental aspects of recent single-particle fracture studies are reviewed. Findings from this research shed new light on the utilisation of energy during comminution operations and provide useful pointers to new research directions that could lead to significantly better comminution machines. Two methods for quantitatively predicting mineral liberation during comminution are reviewed. These methods have been developed into useful practical procedures, but they are almost unknown in the mineral processing community. Their use should promote the consideration of mineral liberation as an important variable to be considered during the design and operating control of comminution circuits.

Jan 1, 1993

By G. D. Hood, B. E. Davis

A problem that has continued to plague the Florida phosphate industry is loss of coarse phosphate in the flotation circuit. Attempts to remedy this problem such as floating the coarse material (plus 425 µm) in a separate circuit have resulted in limited success, but recovery is still not optimum. A fundamental examination of the mechanisms involved in the conditioning of the coarse phosphate has led to results that seem to supersede common paradigms. The Bureau of Mines investigated conditioning parameters such as fatty acid/fuel oil dosage, residual clay content in the feed, conditioning time, mixing intensity, and conditioner solids content. The study revealed that the effect of all these parameters was important. However, it was discovered that contrary to common beliefs, the conditioning time affected the grade of the rougher concentrate much more than the recovery. Specifically, the longer the conditioning time, the less quartz that was floated. It was also discovered that high mixing intensity conditioners could lower the conditioning time required for good grade. Many phosphate operators use low intensity drum type conditioners. Optimizing the conditioning time, mixing intensity, and other conditioning parameters resulted in a rougher concentrate grading 30 pct P.2O5, with an attendant recovery of 95 pct.

Jan 1, 1993

By Wakamatsu DT, Nakahiro Y

This present paper deals with the fundamental study of the separation of fine cassiterite and quartz by liquid-liquid extraction using iso-octane as an oil phase, dodecylamine acetate (DAA) as a collector, and sodium chloride as a depressant. With regard to the distribution of fine cassiterite and quartz between oil and aqueous phases, the effect of DAA has been investigated in terms of pH, DAA and NaCl concentrations, zeta potential, and adsorption density. From the results of the experimental work, a maximum recovery of cassiterite in the oil phase was obtained with pH around 6.0, DAA concentration of 1.0 x 10-5 mole/litre, and NaCl addition of 0.1 mole/litre. In these conditions of liquid-liquid extraction, most of the fine quartz remained in the aqueous phase. Thus it was found that NaCI was an effective depressant for fine quartz under optimum conditions. A series of separation tests by liquid-liquid extraction was then conducted for the mixed samples (6.0 per cent Sn) of cassiterite and quartz. By a single separating process, the per cent of recovery of cassiterite in the oil phase was about 92 per cent with a grade of 27 per cent Sn. The same results could also be obtained by using kerosene in place of iso-octane as the oil phase.

Jan 1, 1993

By J. Peck, M. J. Scoble, C. Hendricks

This paper is based on field studies in North American surface mines. The work involved the adaptation of microprocessor-based instrumentation to monitor various operating parameters on-board rotary blasthole drills and mining shovels. Following a review of instrumentation and monitoring methodology - drawing on experience gained under field conditions-the paper will focus on the application of monitoring technology within the framework of an Integrated Equipment Monitoring System. Such a system will permit real-time performance evaluation of key equipment involved in surface mine production. Drill performance monitoring has been demonstrated through work to date, to provide significant input into blast design, reserve estimation, mine planning and production control processes, through an improved facility for ground characterization. Monitoring excavation equipment has been proven valuable in assessing how effectively the input from drill monitored data has been used in the evolution of blast designs. This specifically refers to assessing blast efficiency through measuring associated levels of excavator performance in relation to muckpile characteristics. The medium-term goal of equipment instrumentation and monitoring has been to assist mines in optimizing the overall rock breakage and handling process. Based on the reported results, this has been accomplished. Long-term efforts now concern using a greater understanding of equipment performance and response to varying operating conditions as a foundation for the implementation of mining automation.

Jan 1, 1993