Search Documents

By S. I. Sobol

The results of the study of the mechanism of a cathode process of cobalt electrolysis to explain disagreements in a form of kinetic equations of autoclave reduction of nickel and cobalt have been used.

Jan 1, 1993

By Liuming Wu, Willis Forsling

The complexation of Alizarin Red S (ARS) at the surface of hydrous fluorapatite particles has been investigated at 25.0 C by means of potentiometric titrations, adsorption experiments in 0.1 M NaCI ionic medium, and Diffuse Reflectance Infrared Fourier Transform spectroscopy (DRIFT) studies. A chemical model describing the reaction at the aqueous mineral surface has been established under equilibrium conditions according to the reaction [== -CaOH2 + HA2 - « _ =PO CaA2 - z + H30&apos;; to (int.) = -5.61 ± 0.02 3 a =PO- logBs-1110(int.) ( ) within the range 8.40 <_ -log[H ] <_ 9.80.] Experimental data were evaluated using the computer program FITEQL on the basis of a constant capacitance model for the electric double layer. The surface complex structure, has been proposed to involve the quinoid and alpha phenolic oxygens of ARS coordinated to the calcium sites on the fluorapatite surface.

Jan 1, 1993

By Gerald T. Homce

A system capable of monitoring mine electrical power systems and detecting impending component failure could significantly improve power system safety and reduce unscheduled equipment downtime. Such monitoring would require a method of evaluating electrical parameters, calculated from terminal values, for indications of component deterioration. The U.S. Bureau of Mines has targeted electrical failure of squirrel cage induction motors and examined the use of mathematical models to aid in this evaluation. The initial stage of this work is complete, and has produced polynomial networks called adaptive learning networks (ALN&apos;s) that can detect and quantify winding insulation leakage simulated on laboratory motors. In this modeling process, empirical data from laboratory motors were used to select the electrical parameters most significant for assessing motor conditions, and mathematical expressions relating these parameters to simulated deterioration were formed. ALN&apos;s developed thus far can process readily measured motor terminal information and quantify power and current levels of laboratory-simulated leakage to within 1% and 3% of full load values, respectively, for motors in the 10- to 150-hp size range. The next stage of this research is validation of these ALN&apos;s for actual motor failures; this stage is currently underway, using accelerated life testing of laboratory motors.

Jan 1, 1993

By Chaves AP

This paper describes an investigation on the surface properties and mechanisms involved in the agglomeration of iron ore. For this purpose, an organic binder (carboxyl-methyl-cellulose (CMC)) was used in substitution of bentonite, the classic binder in iron ore concentrate agglomeration. Recently, a renewed interest of the iron ore producers in Brazil to replace bentonite for an organic binder, because of the economy that can be achieved in the, blast furnace operation. These savings are mainly due to the lower aluminum silicate addition which decreases slag volume and the improved pellet metallurgical properties which have the potential for lowering hot-metal production costs. Also organic binders are effective at lower addition levels, which results in lower storage and transportation costs. It is very important in Brazil because of the vast geographical area since transportation is made mainly by truck. Another advantage of organic binders is that they have low ash contents, and therefore most of the binders bum. off during the pellet firing operation. Previous studies have demonstrated the possibilities of the use of CIVIC, but in addition to its high cost, the pellets presented improper behavior at high temperatures or when prepared with high moisture levels. In the investigation here described, these problems have been solved through the addition of other reagents to CMC.

Jan 1, 1993

By C. B. Mapes, E. C. Dowling Jr.

"To reduce concentrate dewatering and drying costs, the Concentrator Division at Phelps Dodge Morenci, Inc. investigated available filtration technologies. Numerous methods were explored, including: drum, disk, belt, pressure, hyperbaric, and ceramic media filtration. An economic evaluation of the individual filtration technologies indicated the advantages of ceramic media filtration for Morenci concentrates. This paper discusses the technological development culminating in the first full scale application of ceramic media disk filters in North America. Low moisture contents are obtained at high production rates and greatly reduced operating costs.INTRODUCTIONPhelps Dodge commissioned the Morenci Concentrator Filter Plant in 1942 with four 8'6"" Dorr-Oliver cloth disk filters. That year, the filter plant processed 265,537 tons of concentrate grading 20.5% Cu. The filter cake production averaged 9.3% moisture. In 1944, the Extension Filter Plant commenced operation with three additional 8'6"" Dorr-Oliver cloth disk filters. This coincided with the expansion of the concentrator. Production that year totaled 451,567 tons of concentrate grading 23.8% Cu. Moisture averaged 9.4%.Through the years additional filter units have been added in response to increased concentrate production. An Eimco drum filter was installed on the extension side and an additional Dorr-Oliver disk filter was installed on the original side in the 1950's. In 1961, two 8'6"" Peterson disk filters were installed, one on each side to replace two worn-out DorrOlivers. The installation of four 10xl2 foot Peterson drum filters was completed in 1974, coinciding with the Metcalf Concentrator startup. An Eimco belt filter was installed later.The greatest change to concentrate dewatering at Morenci occurred in 1963 with the addition of a 10x60 foot rotary gas fired dryer. The installation also included a number of conveyors to deliver filter cake from both plants to and from the dryers. Other ancillary systems included dust scrubbers and their slurry pumps. The commencement of drying was undertaken due to the rapid increase in cake moisture as a result of the LPF process and the recycling of acid plant scrubber dust slurry from the smelter. In 1972, a second dryer system was installed to increase capacity."

Jan 1, 1993

By D. C. Lynch

While a sizable amount of data exist as to the activity and distribution of minor elements between matte and metal, there has been no unifying theory presented delineating the form of dissolution of these elements in molten sulfides. In order to alleviate that deficiency the literature concerning the behavior of As, Sb, Bi and Pb in mattes is reviewed. Models present in the literature, regarding the thermochemical behavior of minor elements, are tested, and new models are presented and evaluated using thermodynamic theory. The results of those analyses are used to predict optimum conditions for the volatilization of minor elements. The dearth of data on the behavior of minor elements in nickel mattes requires that this review focus on copper- iron mattes. An effort is made, however, to utilize basic knowledge regarding nickel sulfides and the interaction of nickel with the minor elements to predict the behavior of those elements in nickel-copper and nickel-iron mattes.

Jan 1, 1993

By R. J. Grant, D. W. Scott, M. A. Cooper, E. R. Shannon

"The Brunswick No.12 site concentrator processes 10,500 tonnes per day of a complex lead, zinc, copper and silver ore producing four concentrates by differential flotation. Research over the years has led to increased understanding about the mineralogical and flotation characteristics of the ore. A pilot plant study conducted at Lakefield Research, primarily designed to investigate the technical feasibility of semi-autogenous grinding, provided an opportunity to test recent theories about grind size,, reagent schedule and flowsheet configuration.A fundamental approach was taken with each of the unit processes involved in grinding and flotation. Basic operating and metallurgical criteria were established in each area and a step-by-step implementation program initiated in the plant.Significant improvements in metallurgical and financial performance have been realized through the application of basic grinding and flotation principles using conventional milling equipment and without major capital expenditure. Current operating practice is detailed and metallurgical advancements cited.INTRODUCTIONBrunswick Mining and Smelting operates one of the world's largest lead and zinc mines near Bathurst, New Brunswick. Brunswick is a publicly traded company with majority ownership held by Noranda Minerals (63%). In addition to the No. 12 underground mine, the company operates a lead smelter and phosphate fertilizer plant in Belledune, N.B. and maintains a 25% interest in a joint venture with Noranda Minerals' Heath Steele mine near Newcastle, N.B. Through the four operations, a total of 2000 people are directly employed with fixed assets totalling Cdn$187 million (BM&S, 1991)."

Jan 1, 1993

By W. E. Lindquist

Roasting of refractory gold ores has the primary goal of oxidizing sulfides and organics to improve gold recoveries prior to leaching. Commercial installations currently utilize bubbling and circulating fluidized beds. The principle of flash roasting is aimed at a more cost effective method of whole ore roasting for large throughput applications. Results of pilot plant testing and scale up to commercial design will be discussed in further detail in this paper.

Jan 1, 1993

Mineral exploration is the business of finding and defining ore deposits. Ore bodies are developed into mines and mines supply every mineral and metal upon which our society is built. Whether it be steel for our bridges, cement and aggregate for our concrete, coal for our power stations, copper for our wire, phosphate for our fertiliser or gold for our jewellery it first must he found, then mined and processed before we can use it. There is no other way.

Jan 1, 1993

By J. R. Hindman

The vermiculite review arrived too late for the June issue. In 1992, production of commercial vermiculite in the United States increased 1 % to 170 kt (187,000 st), according to the US Bureau of Mines. The estimated value of vermiculite concentrate was $13.6 million, yielding an average value of $80/t ($72.50/st). Vermiculite is used in several physical forms. Use of the thermally exfoliated product include light weight aggregates, horticultural growth media, thermal insulation applications and absorbents for spill control and liquid waste containment. The untreated commercial concentrates are used as intumescent fillers in plaster board, gaskets and paints. Several chemically modified vermiculite products include clay-sized dispersions and granules for treating flue gas. South Africa was the only major foreign source of vermiculite used in the United States. It exported about 40 kt (44,000 st) to the United States last year. In 1992, Palabora Mining Co. began processing vermiculite in a new beneficiation mill at Phalabowra. It produced about 164 kt (181,000 st). Minor sources of foreign vermiculite concentrates consumed in the United States included about 140 kt (154,000 st) from China. Brazil also exports some concentrate to the United States.

Jan 1, 1993

By Timothy J. L. Haley

The population of the Rhondda underwent a spectacular rise as energy requirements increased in the mid-nineteenth century. The rapid expansion in the demand for coal transformed the population from a few hundred sheep farmers in the eighteenth century, into a thriving coal-based economy of some 168,000 inhabitants in 1924. Cochrane (1958) put forward the idea that the differential migration of more healthy men from the Rhondda Fach during the period since the peak of population in 1924, had resulted in a respiratorily-impaired residual population. This idea was used to explain the reduced survival of miners & ex-miners aged 55-64 years from this valley as compared with a similar group from Leigh in England. Using the proportional hazards regression model of Cox (1972), a comparison is presented of the exact twenty-year mortality of migrant and non-migrant miners & ex-miners and non-miners from the Rhondda Fach. The analysis makes allowance for the pattern of migration throughout the twenty-year period and adjusts for the confounding influence of variables such as age, occupation, and category of Simple Pneumoconiosis. The results indicate that contrary to expectation, any effect of migration upon mortality is manifest only at higher ages. Furthermore, for these men, the migrants have worse survival than the non-migrants. Also, contrary to expectation in the light of work by the British Coal Board (Soutar et al, 1982) there is no evidence of increased mortality amongst men with category I simple pneumoconiosis. INTRODUCTION [The Background] In September 1950, the Medical Research Council&apos;s Pneumoconiosis Research Unit at Penarth in South Wales initiated a study of lung disease in the smaller of the two Rhondda Valleys - the Rhondda Fach. At that time, the primary interest was in assessing the possible role of pulmonary tuberculosis in the aetiology of the serious (complicated) form of coal-workers&apos; pneumoconiosis, i.e. Progressive Massive Fibrosis. The Rhondda Fach is situated in South Wales, some 25 km north-west of Cardiff. It is a narrow winding river valley about 12 km long, and approximately 1 km wide. The name means Little Rhondda; there is a corresponding Big Rhondda - the Rhondda Fawr. Together, these valleys make-up most of the Rhondda Municipal Borough. Following the initial survey in 1950-51, there have been several follow-up studies of this population. In addition, amongst numerous other investigations to unravel the aetiology of coal-workers&apos; pneumoconiosis, Medical Research Council teams studied various other (sample) population groups, particularly in the industrial areas of the adjacent Aberdare Valley, and in Staveley and Leigh in England. The agricultural areas of the Vale of Glamorgan in South Wales, and Annandale in Scotland were also studied.

Jan 1, 1993

By Mohammed Z. Islam

As cities are growing all over the world, the need for urban transportation facilities are on the rise. Designers (of these facilities) today are faced with a number of constraints for their design, of the most is the space limitation and impact of new construction activities to the community. A typical subway station, as the focus of this paper, is approximately 600 to 1000 feet long, 50 feet wide and 2 to 3 story high. With such a large volume of construction activities, it is easily realized why underground stations are becoming obvious choice for larger cities eventhough the cost could be 2 1/2 to 3 times as much as an aerial station and 4 to 5 times that of an at-grade station [O&apos;Neil et. al.(1977)]. Since cost is an important factor which is always increasing, therefore, the designer should have a good planning, consider alternatives for design and come up with a realistic design with minimum impact to the community. This paper is about the geotechnical considerations that the designer should be aware of. PLANNING A 1977 report [O&apos;Neil et. al.(1977)] on the construction costs for a number of underground subway stations indicate that about 4 0% of the cost is site-controlled, 35% is structural items, and 25% is finish and equipment. It is seen that of opportunity exists for cost savings in the site selection and proper use of the site. Once the site is selected, the cost of construction become controlled by urban conditions at the site, geotechnical conditions, station size and depth. Therefore, the design-solution is very much site-specific. The geotecnical designer should collect the following information at the early phase of the design:

Jan 1, 1993

By Trent A. Tempel

In 1989 Newmont Gold company initiated a project to develop a treatment process for higher grade refractory gold ores to be mined from deposits along the Carlin Trend in Nevada. Extensive laboratory and pilot testing have identified a unique whole ore roasting process for oxidizing these ores prior to gold recovery by conventional cyanidation techniques. Subsequent detailed engineering studies by Fluor Daniel evaluated three different dry grinding flowsheets for feed preparation to this roasting circuit. The selected flowsheet will incorporate a two compartment ball mill with an attached drying chamber that is driven by a 11.2 MW (15,000 hp) wrap-around motor.

Jan 1, 1993

By Jia X

Three-dimensional microscopic modelling techniques involving specific calculations based on direct computation of the Brownian, van der Waals, Born, electrical double layer repulsion, bulk, hydrodynamic and external forces (gravity, magnetic etc) acting on and between each particle in a mineral dispersion are now feasible using advanced computer processor architectures. This contribution surveys the hardware requirements, the advantages and limitations of the approach for enabling prediction of dispersion behaviour a priori. The notion of developing a generic particle simulator, akin to the use of molecular modelling in the area of drug design, based on inputting process-relevant data (solution chemistry, mineral solids properties, hydrodynamics etc) is discussed. The methodology is illustrated with application examples involving: predictions of coagulation of mineral fines; shape and size of magnetically-flocculated hematite; and the kinetics of fouling of membrane surfaces and walls.

Jan 1, 1993

By D. J. McCracken

The lithium review did not arrive in time for publication in the June issue The estimated consumption of lithium minerals as raw materials to the glass, ceramic and metallurgical industries in 1992 was 85.5 kt (94,200 st). That equates to about 12 kt (13,200 st) of lithium carbonate equivalent (LCE). An additional 150 kt to 200 kt (165,000 to 220,000 st), or 7.5 kt to 10 kt (8200 to 1100 st LCE), were used in the production of lithium chemicals. The 1992 consumption represents an overall decrease of 3.5 kt (3800 st), or 500 t (550 st) LCE, from 1991. This was a direct result of a worldwide reduction in glass demand due to the economic recession. There are three major producers of lithium minerals. Gwalia Consolidated Ltd. (formerly Lithium Australia Ltd.) in Western Australia and Tantalum Mining Corp. (Tanco) in Manitoba, Canada, both produce spodumene ore. Bikita Minerals, in Zimbabwe, is the largest producer of petalite. Bikita also has the capacity to produce small volumes of spodumene concentrate. The Cyprus Foote spodumene operation at Kings Mountain, NC, ceased production in 1992. It once produced about 2 kt/a (2200 stpy) of "high iron spodumene" for uses other than in the manufacture of lithium chemicals. The lithium products of the major producers are shown in Table 1. The current resources of 13 Mt (14.3 million st) of LCE in the western world will supply demand for more than 50 years.

Jan 1, 1993

By Jim Weeks

In July 1986, the United Mine Workers of America (UMWA) asked Secretary of Labor William Brock to form an advisory committee to advise the Mine Safety and Health Administration (MSHA) on rules and regulations concerning the use of diesel powered equipment in underground coal mines. The request was made under the Mine Health and Safety Acts of 1969 and 1977. The union&apos;s principal concern was with the chronic and acute health effects of breathing diesel exhaust. In July 1988, the advisory committee recommended that MSHA promulgate a variety of health and safety regulations. It also concluded that diesel particulate matter should be considered carcinogenic (MSHA, 1988). Now, seven years later, there are nearly twice as many pieces of diesel powered equipment in underground coal mines. MSHA, however, has not promulgated a single regulation to govern the use of this equipment. MSHA must fulfill its public responsibility to protect the health of miners. Regulations that take account of the considerable body of knowledge concerning these health effects must be a top priority of the incoming assistant secretary of labor for MSHA.

Jan 1, 1993

By Robert S. Ondrey, Robert A. Haney, Kenneth G. Fields

As part of an MSHA program to assess the effectiveness of dust control parameters for longwall mining operations, respirable dust studies were conducted on six longwall sections. The purpose of these studies was to evaluate the influence of airflow and production on longwall dust control. The sections were sampled for 3 to 35 shifts. In addition to dust, ventilation and production measurements, other dust control and operational parameters were measured. The water spray system at each operation conformed with generally recommended practices. Therefore, improvements to the dust control system would be most appropriately achieved through improvements to ventilation along the face. Two methods of assessing the influence of ventilation and production were used. For two of the six mines where extensive sampling (22 and 35 shifts) was conducted, multiple linear regressions were used to relate the dust concentration versus airflow and production data. For these two mines, statistically significant correlations existed between concentration and both production and airflow. The multiple regressions fit to the data indicated that for every 0.47 m3/s (1,000 cfm) increase in airflow, there would be approximately 0.04 to 0.07 mg/m3 reduction in dust concentration; and, for every 1,000 ton increase in production, there would be approximately 0.15 to 0.50 mg/m3 increase in dust concentration. For the four mines with limited data (3 to 10 shifts), as well as for the two mines with extensive sampling, an average ratio of airflow per ton of coal mined was calculated by proportioning the airflow to production and the designated occupation personal respirable dust exposure to a 2.0 mg/m3 concentration. The airflow-to-tons ratio required to maintain a 2.0 mg/m3 dust concentration ranged from 0.0038 0.0071 m3/s per ton (8 to 15 cfm/ton). Both of these data treatments were used to calculate airflow requirements based on normal production rates. For the two mines where both the regression and airflow-to-tons ratio were calculated, results from the two methods agreed within 25 percent.

Jan 1, 1993

By Y. S. Roditis

Traditionally, open pit optimization has been used to produce a single outline which can guide the pit design. This paper describes how a series of optimum nested pits are utilized to: a. produce different mining sequences and to help in mine planning and phase design; b. evaluate different metallurgical processes, production scenarios and equipment size; c. investigate the sensitivity of a project to prices, recoveries, production rates, costs, ultimate pit slopes etc.

Jan 1, 1993

By M. Liu

The use of surfactants shows great potential for the removal of hydrophobic organics from soils by in-situ washing techniques. Lab-scale soil washing experiments were performed using sodium dodecylsulfate (SDS), an anionic surfactant, and anthracene, a highly hydrophobic compound. The results of this research show that the solubility of anthracene increases linearly with an increase in SDS concentration above the critical micellar concentration. Furthermore, SDS can be effective in removing anthracene from contaminated sand.

Jan 1, 1993

Segregation roasting tests were carried out on Zaire cobalt oxide ores assaying about 2% Co and 3.5 to 6.5% Cu. The major parameters tested during the laboratory investigations were temperature, dosage and type of reducing agent, dosage and type of chloridizing agent, and particle size. Results showed that standard conditions suited to the segregation of copper ores, i.e. low temperature and low dosages of reducing and chloridizing agents, resulted in the segregation of copper only, while conditions suited to the segregation of lateritic nickel, i.e. higher temperature and increased dosages of reducing and chloridizing agents, led to a successful segregation of both copper and cobalt. Under the best conditions, 88% of the cobalt and 98% of the copper could be recovered in a concentrate assaying 32.5% Cu and 8.5% Co. Alternatives to process such a concentrate are briefly reviewed.

Jan 1, 1993