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East Nelson and Marlborough, in the northeast of the South Island, contain a wide variety of metallic minerals, including gold, silver, copper, chromite, antimony and scheelite, but no sustained metallic mining industry has evolved. Gold was the most sought-after mineral during the first century of European settlement and numerous discoveries were made but these failed to live up to expectations. While traces of gold are widespread in east Nelson, including in quartz veins in Nelson City, no payable deposits were found. In Marlborough the probability of a gold discovery had initially seemed remote but all this changed with the finding of rich deposits in the bed of the Wakamarina River in 1864, which provided a much-needed boost to the provincial economy. However, the decline of gold mining in Marlborough began virtually as soon as it had commenced. Extensive floods in 1865 hastened the exodus of miners to the profitable new fields of the West Coast.

Jan 1, 1993

By Tack K

During its 28-year life the MHD ISP smelter has gone through two phases, each of about a dozen years. The first phase was a learning one; in the second phase the lessons were applied and throughput and production rose strongly. Early experience revealed the robustness and the flexibility of the Imperial Smelting Process. The experience was demonstrated by strong increases in the throughput of mixed lead-zinc concentrates and of secondary (oxide) zinc materials. Purchased material quantities rose from 175 000 tonnes/year to 200 000. The required capacity increase of the IS furnace to smelt the higher throughput was achieved by relatively minor modifications; for instance a change to the internal furnace profile gained an extra two square metres in cross sectional area. The furnace hearth area has remained practically unchanged over its entire history. The paper concludes that there is still more potential to be drawn from the process and MHD intends to sustain raw material input at a new level of 240 000 tonnes/year. However, this rate will have to be achieved under the imposition of more stringent environmental and product quality standards than ever before.

Jan 1, 1993

ILZRO sights are locked securely on the targets of the expanded applications and ever-improving quality in the major market for zinc-coated steel. A wide range of ILZRO-sponsored research projects examine issues of formability, paintability, and corrosion resistance for traditional hot-dip galvanising, electrogalvanising, and ILZRO's own proprietary zinc coating, Galfan. Recent research has focussed on the on the interaction between Galfan and different substrate steels to determine optimum combinations for different applications. ILZRO enjoys an evolving role in providing the connection between research laboratories and marketing divisions through supporting research and services for the Galfan Technical Resource Centreò(GTRC) and the recently formed North American Galfan Development Authority (NAGDA). GTRC has just produced a new problem-solving manual that provides a comprehensive source of hands-on solutions for the many Galfan licensees throughout the world, and should contribute substantially to the reputation of Galfan as a consistently top-quality steel-coating product. Meanwhile, NAGDA is advancing the market with new advertising for Galfan based on superior corrosion-resistant qualities proven through ILZRO-sponsored research. Practical manufacturing issues remain at the forefront of ILZRO priorities, with research emphasis on cutting and welding zinc-coated steel to provide direct assistance towards improved product quality and a more secure market. Moving to the arena of die casting, when the specifier looks to zinc to fill a design need, ILZRO-sponsored research projects provide comprehensive documentation on metallurgical characteristics for every zinc alloy under almost any imaginable application. On-going ILZRO-sponsored research is integrating this wealth of data with sophisticated computer programs that model die-casting designs with ever-increasing accuracy, as other ILZRO projects lay the market groundwork for zinc in applications ranging from vibration damping to electromagnetic shielding.

Jan 1, 1993

By Richard B. Stein

Bechtel's BEMSIM computer program is a useful tool for solvent extraction-electrowinning plant design optimization. Its power (up to 90 stream components, 240 process streams, 180 process steps) has been applied to investigate floweheet configurations in order to perform basic engineering, sizing of plant equipment and to optimize performance of commercial-size copper plants. Flowsheet variations presented include series, parallel and series-parallel extraction stages, while heat balances simulate operations in summer and extreme winter conditions. The BEMSIM program has also been applied to nickel-cobalt, gold and manganese extraction.

Jan 1, 1993

The Mammoth Mine is located some five kilometres from the town of Gunpowder which is approximately 120 km north-west of Mount Isa in Queensland.

Jan 1, 1993

In the new flowsheet for Inco Limited's S02, Abatement Project at the Copper Cliff, Ontario operations, a copper/nickel sulphide flotation concentrate will be flash smelted, then converted to Bessemer matte. As in current practice, this will be slow-cooled and separated into components by magnetic separation and flotation. The copper content will emerge as a chalcocite concentrate (impure Cu2S), containing some nickel. This copper sulphide will be converted to copper metal.

Jan 1, 1993

By Ronald L. Gibbs

IN THE BEGINNING Contrary to popular myth, the personal computer can trace its roots back to a time before 1981 and the IBM PC. The seeds of the personal computer revolution were probably founded in 1975 with the release of the Altair (kit) personal computer, first advertised in Popular Electronics. June of 1975 marked the beginning of the Homebrew Computer Club in San Francisco. The founding membership list of the Homebrew Club now reads like a "Who's Who" of those involved in the early development of the personal computer industry. The Apple I computer was created by Steve Wozniak in early 1976 from the newly manufactured MOS Technology 6502 chip. It had 4,000 bytes (4K) of Random Access Memory (RAM] memory, a revolutionary amount of memory in 1976. Another early pioneer, the Commodore Pet computer, was another 6502 machine, but with 8K of memory. Tandy Corporation made its name in the hobby industry with leather kits. They embarked on a new path with the production of the TRS-80 line of personal computers. Most were based on the Z-80 chip, but again, were memory limited. A number of other Z-80 based systems followed later, including the Osbourne and the KayPro Computers. These systems were based on the Digital Research CP/M operating system and had a maximum of 64,000 bytes of memory (64K). The Apple I1 Computer appeared in 1977. Newer models of the original Commodore Pet and an Atari computer followed. These machines were also limited to 64K of memory addressing, and the early models typically shipped with only 16K, 32K, or 48K of memory. The Z-80 and the 6502 were the first truly commercialized CPU chips touting boxes with key- boards, monitors (sometimes a TV), and the ability to expand (peripheral slots for serial communications, centronics parallel communications, etc.1. They all shared one technology, audio tape as a storage media. The use of a portable tape recorder provided inexpensive, if not always reliable, magnetic storage. The tape recorders were typically finicky and required patience to use. Adjustments to the volume control were often needed to find "just-the-right" setting for loading or saving information. This kept the personal computer from being accepted in many markets, and gave it a reputation as a hobbyist or experimenters' toy. In early 1979, Steve Wozniak finished the design of a floppy disk drive and controller. This was a revolutionary design which reduced the "then" standard number of controller chips from fifty-plus, to just eight. With the advent of an affordable floppy disk drive mechanism, the personal computer was about to gain respectability. From a business standpoint, it was now possible to save and reliably retrieve business information. It also provided a superior means of distribution for commercially created software. Commercial software became a commodity rather than an oddity.

Jan 1, 1993

By Ronald R. H. Cohen, Margaret W. Staub

Two pilot scale bioreactors designed to treat acid mine drainage primarily using sulfate reducing bacteria were constructed underground at the Eagle Mine Superfund site in Minturn Colorado. The project was designed to test th applicability of microbiological treatment on water with high metals concentration and to test the process in an underground environment. Objectives were, 1) to compare metal removal, pH increase, and sulfate reduction in a single stage reactor with a double stage reactor of equal volume at varying flow rates; 2) to determine where within the substrate treatment occurs· and 3) to examine volume versus surface ara as a design parameter for optimizing metal removal processes. Results from the reactors showed that the single stage reactor and double stage reactor performed equally well for the removal of Cd, Cu, Pb, Fe, Mn, and Zn. pH increased above 6.5 in both reactors. Greater than 97% of metals were removed within the first ten inches of substrate. Volume proved to be a more useful parameter for determining removal rates than area. Using volume as a design parameter rather than surface area enables PMDT systems to be constructed as packed columns rather than broad wetlands, Thus, space requirements are significantly reduced.

Jan 1, 1993

By L. Andrews, G. Smits, M. D. Adams, E. A. Viljoen

A new approach has been developed that is capable of ascertaining the ore component that is responsible for the preg­robbing of pregnant pulps. Many gold mines are currently treating ores containing a component that is detrimental to the recovery of gold, in that they "preg-rob" the pregnant pulp by adsorption of some of the dissolved gold. The identity of the preg-robbing component in this type of ore has been the subject of considerable debate over a lengthy period, th various suggestions including amorphous carbon, chlonte, chalcopyrite and layered silicates, such as the phyllosilicate minerals pyrophyllite, kaolinite, phlogopite and illite. A means is now available to identify and characterize the preg-robber in gold ores. This new approach consists of contacting the ore with a synthetic aurocyanide solution, identifying the mineral grains by optical microscopy and analysing each grain individually using high-sensitivity electron microprobe analysis. The approach is exemplified in this initial study by identifying the preg-robbing component in an active sample of gold-bearing shale to be an amorphous carbonaceous phase consisting of discrete particles of about 5 µm diameter interspersed with shale particles and agglomerated into grains of up to 100 µm diameter. Microanalysis of these grains as well as other mineral particles revealed that the gold content of some of the carbonaceous grains was close to 7000 g,lt, with no gold being detected in any of the other mineral phases that were found to be present (e.g. quartz, chlorite, muscovite, pyrophyllite, etc). Bulk analysis of the sample for carbon and gold confirmed that gold loadings of around 7000 g,/t would be expected if all of the gold were adsorbed onto the carbonaceous component. The carbonaceous constituent is probably also responsible for the anomalously high surface area measured for the material. It probably acts in a similar fashion to activated carbon, and the correct choice of organic blinding agent will decrease the extent of preg-robbing by lowering the activity of the material for gold, without causing any downstream problems such as fouling of the activated carbon used for gold recovery

Jan 1, 1993

By David Marsh, Mark W. Johns

Carbon-in-pulp (CIP) is a preferred method of gold recovery from cyanided pulp. However, the resin-in-pulp (RIP) process is considered to have several advantages for the recovery of gold. Mintek therefore undertook a research programme to develop a commercially-viable RIP process. The MINRIP RIP process and a novel gold­selective strong-base resin, Minix, were developed. The process has been successfully demonstrated at a scale of 100 000 t/month. Continuous countercurrent tests using synthetic solutions indicate that the relative performance of an adsorbent depends on the composition of the solution. Minix resin yielded a higher gold loading than that of carbon, while maintaining an acceptable barren value. Batch tests on a number of gold-bearing materials indicated that Minix has potentially a higher capacity than carbon, and loads gold faster than carbon. An economic appraisal that consolidated the countercurrent results and the economic study indicated that the capital and operating costs of the Minrip process are considerably lower than those of CIP. The amount of the cost advantage depends on the gold content of the feed and the throughput.

Jan 1, 1993

By Ronald K. Frobel, Christopher J. Wienecke

Geomembrane systems and associated geosynthetics such as geotextiles, geonets, geogrids and geocomposites have been used in precious metal heap leach and tailings facilities for many years. Geomembranes have been used in the heap leach process in pad design and solution recovery ponds as well as associated collection channels as the primary liquid barrier to contain and collect metal bearing leach solution. Geomembrane systems offer an effective, low cost alternative to other containment methods such as compacted low permeability soils, asphalt or concrete. In the 19BO's, rigid High Density Polyethylene (HOPE) liners were used to a great extent with a gradual transition to the use of the more flexible Very Low Density Polyethylene (VLDPE) and Polyvinyl Chloride (PVC). These three geomembrane systems have been used successfully in precious metal heap leach solution containment. Predominant material thicknesses have been 30 and 40 mil for PVC, 40 and 60 mil for HOPE and VLDPE. Variants in recent years have included roughened HDPE and VLDPE to provide higher surface friction characteristics, as well as newer polymer materials such as polypropylene. In addition to providing an economical method for providing enhanced solution recovery, geomernbranes are also providing the primary liquid barrier for prevention of groundwater contamination. Because heap leach solution chemical components and dissolved metal constituents are classified as toxic substances, they are subject to environmental regulation. Many regulatory agencies are still developing guidelines for heap leach pad design, however a geomernbrane liner system is often used as a single liner or in conjunction with other materials to form composite double or even triple lined systems. "Other" materials can include alternate layers of drainage aggregate, geotextiles, clay layers and other geomembrane or geocomposite layers.

Jan 1, 1993

By Michael N. Allenby

One of the least discussed areas in the ever-improving technologies of gold recovery from ore bodies and tailings is the chemistry of the waters used in the plants. Carbon-in­ pulp, carbon-in-leach, heap/dump leaching and iological oxidation processes are all affected by water quality. The remoteness of a lot of the plants means that the large water requirements can often only be met by a ground water source. The chemistry of waters from different sources poses different problems, but generally a lot of these waters are scale forming. Scale-forming tendencies can be described by calcium, magnesium, barium and strontium assays. They can be notated by Langelier and Ryznar indices. They can be plotted by computer programmes that print out scaling indices at different conditions. The propensity to scale can -be readily determined. The prevention of scaling -or at worst minimisation of scaling -is the ambition of the suppliers of scale inhibition programmes. This prevention/minimisation technology is discussed below.

Jan 1, 1993

By Harry M. Castrantas, James L. Manganaro, Craig W. Rautiola, James Carmichael

Caro's acid (peroxymonosulfuric acid) was successfully field tested as a cyanide detoxification agent at a North American gold mine. An on-site FMC generator injected Caro's acid into a mill tailings slurry sump. The WAD cN-(weakly acid dissociable plus free cN-) was reduced from 40-108 ppm to below the target level of 20 ppm using a 1/1 mole ratio of CA (Caro's acid) /CN-. At an inlet CA/CN-mole ratio of 1.8/1, WAD CN­concentrations as low as 4 ppm cN-were achieved. Raw material costs for the cyanide detoxification were cut by 60% compared to using hydrogen peroxide (H202) alone. Detoxification time with Caro's acid was much faster compared to H202. This resulted in completion of detoxification before the treated slurry reached the tailings pond thereby substantially reducing the probability of wildlife fatalities.

Jan 1, 1993

By A. L. Putz, G. Ladouceur, A. R. Laplante

A laboratory centrifugal concentrator was used to evaluate two gravity circuit configurations treating a flash flotation concentrate at a Canadian gold mill. The Initial circuit consisted of a 76 cm (30 Inch) plant Knelson Concentrator (PKC) for coarse gold removal. Later, a hydroseparator and spiral were Installed, with the hydroseparator underflow feeding the spiral and the spiral tailings plus hydroseparator overfiow reporting to a 51 cm (20 Inch) PKC. Gold recovery In the 76 cm PKC averaged 45%. Gold was recovered consistently In all size fractions greater than 38 µm, where recovery dropped to 22% for the -38 µm material. Changing the circuit to Include the hydroseparator and spiral decreased the Knelson unit recovery to less than 17%. The decrease was attributed to the spiral which recovered much of the free gold ahead of the Knelson and to changes In the mill feed (free gold portions were finer and less abundant). The spiral demonstrated erratic behaviour although It still recovered significant coarse gold (+75 µm) yielding unit recoveries of 18-44%. Although mechanical difficulties were experienced with the 76 cm PKC, Its performance was superior to that of the hydroseparator, spiral and 51 cm PKC configuration. Much of the gold In the ball mill recirculating load was found to be too coarse for significant recovery In the flash flotation cell and should be recovered by gravity from the cyclone underflow or ball mill discharge. The LKC proved to be a successful device to evaluate gravity recoverable gold content. Dilution of test samples with silica further enhanced this methodology.

Jan 1, 1993

By Joseph A. Dos Santos

Developed in 1983, High Angle Conveyors HAc®s, are proven versatile systems for elevating materials continuously from a lower to an upper level, Such systems may also be used to lower materials continuously. HACs have found commercial application in widely varying materials ( including coal, refuse, coarse ores, hot clinker, municipal sludge, wood chips, gypsum, slag, excavated earth, various grains and RDF), at widely varying throughput rates from 0.27 to 4,000 t/h. The conveying profiles have varied widely and elevating heights range from 3.66 m to 175 m. HACs have found application in coal, copper, gypsum and gold mining, coal preparation, in municipal waste treatment, rapid transit projects, pulp and paper mills, and cement plants, While noting a wide variety of applications in general, the present writing focuses on a very large HAG® system, consisting of eight (8) main HAG units to elevate nickel/copper ore continuously from under­ground, 1402 m (4600 ft,) vertically to the surface. It compares technical and economic aspects of such a system against traditional mine hoist haulage,

Jan 1, 1993

By Marlin D. Schutte, Graham M. Fraser, Paul M. Kubera, Ronald J. Weetman

Mixers play an important function in the operation of multi-phase reactors in the minerals processing industry. They must suspend solids, transfer oxygen, maintain pH and temperature uniformity, assist in heat transfer, and, in biological processes, avoid the development of excessive shear rates. The LIGHTNIN A315 impeller (Figure 1) effectively supersedes the older Rushton turbine (Figure 2) which has been classically employed in gas­Iiquid-solids applications such as bacterial oxidation, cyanide destruction, etc. Since a stirred tank reactor can be such a key part of the overall process, it is essential that the mixers be designed for long term reliable operation, both process and mechanical, to insure a high percentage of on-line availability. Mixers in gas-liquid-solids processes may experience extraordinary loading conditions which must be taken into account to guarantee a robust mechanical design. Given the recent trend towards the design of world-class process units with maximum capacity equipment, there is increased importance and emphasis on the integrated design of the complete agitation system -mixer, vessel, and structure -to insure trouble free, post­commissioning performance. This paper presents some of the considerations necessary to specify the process functions of the mixer in multiphase applications, as well as special considerations for the mechanical design of the integrated reactor system.

Jan 1, 1993

By Harry Holle, Ivan Hunter, Darrin Thomson, Gary Johnson

Over the past five years Dominion Mining Limited has directed an on-going effort towards optimising the performance of its milling circuits. The approach has been on a wide front, and has addressed a variety of issues associated with the design and operation of SAG milling circuits. Major projects have been conducted in the areas of flowsheet optimisation, mill liner efficiency, and dynamic circuit performance. As a result the initial designs of many of the Dominion circuits have been modified, mill liner specifications have been rationalised, and a robust automatic control system has been developed. A group-wide approach was taken on most of these projects, resulting in substantial benefits to both the individual operations and the company as a whole. By applying the projects group-wide a significant multiplier effect has been gained on the funds invested in each project. Extensive use of steady state modelling techniques has been made in order to understand the performance of the different circuits, and to highlight the potential areas in which improvements can be made. Liner optimisation has been primarily aimed at achieving predicability of performance, both metallurgical and mechanical. The development of a robust automatic control system has enabled the dynamics of the milling process to be controlled, and resulted in an additional increment in throughput being achieved. The combined effect of these efforts has been to raise plant availability to consistently over 95% (on a long term basis), to improve the power efficiency of comminution (in SAG mills) by 20% or more, and to enhance the dynamic performance such that a more than 10% increase circuit throughput has been demonstrated.

Jan 1, 1993

By Chris Cox, David Green

Outokumpu has developed the HG or High Grade flotation cell over the past decade. This machine gives upgrading and selectivity performance superior to conventional mechanical cells while maintaining their simplicity, ease of operation and recovery characteristics. The HG design is available in a tank cell configuration which provides a number of benefits in plant design and operation. This paper will describe the HG Tank Cell and the "Virtual Column" concept. Results are given from the operation of the HG Tank Cells at Lac Minerals - Est Malartic in Quebec, Canada. Further discussion of applications for gold recovery is also provided.

Jan 1, 1993

By Peter J. Lawson, John A. Rideout, Gregory W. Dicinoski

A considerable body of literature directed towards optimising the efficiency of gold and silver extraction from cyanide leach liquors has appeared in recent years. A few examples from dissolution to solvent extraction to adsorption in carbon-in-pulp (CIP) and resin-in-pulp (RIP) operations follow. Selective leaching of gold from copper-gold ores using ammonia-cyanide mixtures extends the % copper which may be tolerated in ores (Ruane, 1991, LaBrooy et al., 1991, Costello, 1991). The removal of copper and recycling of cyanide from high copper ores is another important development (Sceresini and Staunton, 1991). Solvent extraction of alkaline cyanide liquors (Riveros, 1990, Mooiman & Miller, 1991) and solvent aided elution in CIP (Muir, et al., 1985) look promising. Recent definitive papers on the mechanism of adsorption of aurocyanide by activated carbon should lead to more efficient use of CIP (Adams and Fleming, 1989, Klauber, 1991). Strong and mixed weak-strong base resins have been applied in RIP for aurocyanide extraction in Russian Plants since the 1970's (see for example Borovskii et al., 1985, and references cited in Fleming, 1988a). Fundamental studies on applications of commercial weak and strong base resins-in-pulp (Fleming & Cromberge, 1984a, b, Fleming 1988a, Hosking 1984, Riveros and Cooper 1987) have generated much interest in RIP. Detailed comparisons of CIP vs RIP efficiencies at Mintek in South Africa (Fleming et al., 1988b), and the inefficiency of CIP in contact with clay led to the commissioning of the strong base RIP Golden Jubilee plant in 1988. Its operation and improvements have been reported (Seymore and Fleming, 1989, Fleming & Seymore, 1990). The use of anion exchange membranes for aurocyanide extraction shows some promise (Mauthoor et al., 1991). However, the development of new gold specific resins at Mintek (Green et al., 1984, 1986, 1990, Johns and Green, 1991) and elsewhere (Asker et al., 1987, Wilson et al., 1987, Harris et al., 1992) should improve the viability of RIP processes. The polydiallylamine gold specific resins (Hodgkin & Eibl, 1988, Fawell et al., 1992a, b) have high capacities for auro cyanide recovery from high concentration liquors. The use of guanidine based liquid and solid ion exchange extractants for gold was recently reported by the Henkel Corporation (Kordosky., et. al., 1993). Such specific resins tailor made for gold and/or silver cyanide extraction should lower overall cost by improving metallurgical efficiency. In the case of strong base resins this selectivity largely eliminates the problems of poor base metal elution and/or poisoning. The work reported here outlines the approach taken at the University of Central Queensland to synthesize sterically hindered strong base anion exchange resins which are designed to have high selectivity for auro- and argentocyanide complexes. It summarises selectivity tests on low grade cyanide leach liquors from several mines. It also examines an RIP vs CIP comparison, and investigates the elution properties and cycling of one such promising resin.

Jan 1, 1993

By C. J. Ferron

Gold occurrence in operating plant tailings ranges from gold in solution, fine free gold, gold associated with sulphides/arsenides/tellurides and gold occluded within iron oxides or arsenates and silica gangue. This paper briefly presents various alternatives to reprocess gold tailings, with examples. These include the use of centrifugal gravity separators, CIL, magnetic separation, flotation and pressure oxidation.

Jan 1, 1993