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By R. J. Roman

The "mass balance" is unquestionably the most common class of problems for the process engineer'. Closely related, mathematically, is the "heat balance". Every laboratory test requires a mass balance to describe the results. Mass balance calculations can be subdivided into several sub-categories based on whether the results are time dependant or not and depending on whether the input data are measurements that contain errors or are hypothetical values with no errors. Time dependent mass balances are dynamic process simulations and in addition to the conservation of mass constraints require kinetic data input. They are one step beyond simple mass balances.

Jan 1, 1992

By Marcelo B. Mourao

Interactions of carbonaceous materials with liquid Fe-C melts have been investigated experimentally by determining the volatile yield due to rapid devolatilization (Flash Pyrolysis) and rates of dissolution at temperatures ranging from 1623 to 1873 K. The volatile yield increased with increasing the temperature. The comparison of results of different types of carbonaceous materials was possible by expressing the volatile yield in terms of Enhancement Factor, fE. The rates of dissolution of spectroscopic graphite and an industrial coke seemed to obey the correlation for natural convection under turbulent conditions. The experimental data for the graphite suggested that the rate of dissolution was controlled by the mass-transfer in the liquid boundary layer adjacent to the solid sample. The value for the empirical parameter correlating the dissolution coefficient and the operating variables was found to be 0.19 which was close to that reported in the literature. The comparison of the results obtained for the coke samples with those for the graphite revealed that the impurities and the porosity of the samples can effect the dissolution rates.

Jan 1, 1992

By Gerald K. Vellente

Producers of strip coated products are being approached by users to supply higher quality products and adhere to tighter specifications. Suppliers, in an attempt to assist the producers, must consider new technologies for equipment. In the past several years, the induction melting and heating industry has made great strides in developing new and innovative equipment, while improving existing technology. In the past several years, the induction melting and heating industry has made great strides in developing new and innovative equipment, while improving existing technology. In the past several years, the induction melting and heating industry has made great strides in developing new and innovative equipment, while improving existing technology. This paper will review recent developments to include improved refractory systems for ceramic pots, new channel-type inductors which are more efficient, new power control systems for existing channel-type pots, and innovative use of multi-purpose lines. Additionally, new heating applications such as galvannealing, edge heating, and post heating will be reviewed. Advanced math models for controlling heat will be discussed. Producers can easily meet the demands of their customers because of the flexibility provided by the equipment reviewed.

Jan 1, 1992

By C. H. Quan

Solvent extraction tests were carried out on a rare earth chloride solution derived from monazite processing to determine the effect of extractant and diluent on the distribution coefficients between organic and aqueous phases, and the separation factor between rare earths. The extractants were 20% by volume di-2-ethyl-hexyl phosphoric acid (DZEHPA) or 2-ethyl-hexyl phosphonic acid (Ionquest® 801). Four Shellsol diluents were tested ranging from nil to 100% aromatic content. D2EHPA gave the highest rare earth extraction for a given pH but was less selective than Ionquest. The geometric mean separation factor between adjacent rare earths varied from 2.41-2.56 for D2EHPA to 2.62-3.01 for Ionquest. The nil-aromatic diluents (Shellsol 2037 and 2358) gave better separation factors in Ionquest but, in D2EHPA, were slightly inferior to the 100% aromatic diluent Shellsol AB. Yttrium behaved as a pseudo-heavy rare earth with a distribution coefficient lying between Ho and Er, as expected from its ionic radius.

Jan 1, 1992

As part of remote sensing research on an abandoned mine lands (AML) site in the Colorado Springs, Colorado area, a geographic information system (GIS) database was generated. This GIS database contains information on the locations and extents of abandoned underground coal mines, the geology of the area, subsidence features and degrees of subsidence risk, topography, drill hole locations, and lineaments (linear features) related to subsurface geologic structures. A GIS database allows the reproducible and accurate comparison and analysis of any data sets which geographically overlap and are within the same coordinate system. The database has been released to the public domain so that government agencies, researchers, educators, and the general public can access this coherent database for the purposes of better understanding the study area and GIS technology. Data files and maps are available in formats that are compatible with the GIS software used in the research project and with most CAD systems so that as many people as possible can make use of the majority of the database. This document serves as the data dictionary for the database by providing descriptions and origins of the data files.

Jan 1, 1992

By W. DR. Fritz

Technical progress depends on strategic objectives and a concept showing how to benefit from the effects of novel techniques in an innovation process and how to implement them creatively in harmony with manpower capabilities. With the invention of prime movers, it was initially power engineering which dominated the development of industrial history before it was replaced by production techniques resulting from the more widespread use of machines. With the advances in the field of data processing and with the introduction of novel communication techniques, it is information technology- which today is having an ever increasing impact on technological progress. The main objectives of information technology in this context are a positive influence on the ?time? factor as well as the provision of tools to handle the complexity governing many operational processes through a concentration of information for the decision-making process. The German hardcoal industry became aware of the chances inherent in these new technological possibilities for the optimization of operational sequences and of decision-making and planning processes as a potential for success at an early stage and it has worked out a purposeful concept for their implementation.

Jan 1, 1992

By A. S. Usmani

The flow associated with the pouring of molten metal into moulds has been modelled on the basis of certain simplifying assumptions. A finite element based Navier-Stokes equation solver has been used to analyse the flow. The velocities obtained from the Navier-Stokes equation solver are used to advect a pseudo-concentration function for modelling the fluid front. A simple problem with a known analytical solution is solved first to test the model. Subsequently, several more examples with varied geometrical configurations are modelled, including one with curved flow boundaries.

Jan 1, 1992

By Gail L. Achterman

Most mining companies today perform site assessments and operational or compliance audits regularly. The purpose of these audits is to review company facilities and operations to determine whether they comply with applicable federal, state and local environmental laws and regulations. Why Audit? Companies adopt assessment and audit programs for legal and business reasons. The business reasons include: (1) ensuring efficient and cost-effective compliance through early problem identification and resolution; (2) planning and implementing business transactions such as real estate conveyances, loans, mergers and acquisitions, and waste disposal service contracts; and (3) employee training and relations. Legal reasons for audits include: (1) avoiding enforcement actions and penalties; (2) meeting environmental permit certification requirements; (3) avoiding corporate officer liability; and (4) meeting Security and Exchange Commission disclosure requirements. The Environmental Protection Agency ("EPA") encourages environmental auditing by regulated entities. The EPA Environmental Auditing Policy Statement was published in the Federal Register on July 9, 1986 (51 Fed Reg 25,004). Although the existence of an auditing program does not create a defense to or otherwise limit a company's regulatory responsibilities, EPA considers compliance programs in setting inspection and enforcement priorities. If a company makes an honest effort to identify and correct its own problems, EPA's enforcement approach is influenced, especially if violations are promptly reported. Perhaps more significant to many executives, the U.S. Department of Justice issued guidelines last year on when it will pursue criminal prosecution for environmental violations. See Department of Justice, "Factors and Decisions on Criminal Prosecutions for Environmental Violations in the Context of Significant Voluntary Compliance or Disclosure Efforts by the Violator," (July 1, 1991). It is now commonplace to read about major companies pleading guilty to criminal violations and paying millions of dollars in penalties. For example ALCOA recently agreed to pay criminal fines and civil penalties totaling $7.5 million for unauthorized excavation of PCB-contaminated soil and improper dumping of spent caustic solution. No executive wants to explain to the Board of Directors or shareholders why the company was criminally indicted. The Department of Justice considers factors such as voluntary disclosure, preventive measures and compliance programs, such as a regular compliance auditing program, the effectiveness of the disciplinary system for employees who violate the company's environmental policies, and subsequent compliance efforts by companies to remedy ongoing noncompliance. The Department of Justice looks closely at whether audit recommendations were implemented in a timely way and whether environmental compliance was a standard by which employees were judged. The Lawyer's Role. The role of the lawyer in an audit team deserves special attention. When enforcement action or litigation has begun or is contemplated or a government agency has asked for information, attorneys always should be directly involved in environmental audits. In most situations, however, environmental audits are management tools, and the attorney's role should be to advise the team. The attorney can help make sure the team understands the laws and regulations the facility must

Jan 1, 1992

By Robert B. Hopler

Emplacing explosives in the borehole by bulk methods is utilized today for about 35% of all of the explosives used in the United States. Although different from today's methods, some bulk emplacement has been utilized throughout the history of explosives. This paper provides an overview of the evolution of the industry from primarily packaged to primarily bulk materials and methods.

Jan 1, 1992

By M. P. Board, J. K. Whyatt, T. J. Williams

The U.S. Bureau of Mines has been conducting a series of rock mechanics investigations at the Lucky Friday Mime in the Coeur d'Alene Mining District of northern Idaho. In the present study, the energy release rate (ERR) index was used to evaluate three underhand stope backfill parameters--cement content, density, and placement gap-to determine their influence on rock bursts. This index provides a relative measure of the likelihood of rock bursting for a given rock mass. It is known that the elastic idealization of the rock mass inherent in this method causes underestimation of stope closure and hence underestimation of the influence of backfill on rock bursting. However, this evaluation still showed that (1) changing from present practice to one in which backfill was omitted altogether would increase the ERR by 42 pct and (2) perfect placement of backfill would reduce the ERR below present practice levels by 28 pct. The easiest step toward perfect placement would be elimination of the placement gap, which accounted for half of the difference in ERR between present practice and ideal placement conditions. There was no indication that increasing initial fill strength through increased cement content would affect the ERR.

Jan 1, 1992

By Dogan Paktunc, Larry J. Hulbert, Robert C. Carne, D. Conrad Gregoire

A thin layer of stratiform Ni-Zn-PGE sulfide mineralization of sedimentary-diagenetic origin was deposited during the Middle to Upper Devonian in the euxinic "Nick basin". The mineralized unit (=3 cm thick), which seems to have been developed over the entire sedimentary basin of > 80 km2, consists of pyrite, vaesite (NiSz), and sphalerite. The average grade of the mineralization is about 5.30/0 Ni, 0.73% Zn, =770 ppb (pGE+Au), and up to 61 ppm Re. Anomalous Se, As, Mo, P, Ba and U are present. A minimum of 0.90 x 106 tonnes of Ni were deposited in the basin (based on a bed thickness of 3 cm) during the Devonian. The unique metal association, extensive lateral distribution, persistent metal grade, mineralogical makeup, and stratigraphic control demonstrate that this is a new deposit type and a new geological environment for Ni and PGE + Au. The sulfide layer occurs at the base of a Phosphatic Chert Member which is underlain by a distinctive marker unit consisting of concretionary limestone structures. The limestone spheroids may represent a vent-specific carbonate facies developed adjacent to faults that emanated nutrientrich hydrothermal discharges just prior to the main mineralizing event. The suite of elements associated with the Nick mineralization suggests that the ore-forming metals were originally bound to organic matter derived from decaying marine organisms. Discharge of hot brines bearing organic matter-bound metals took place along numerous conduits within basin faults that are now manifest as bitumen veins. Our syndiagenetic model proposes that these fluids were discharged laterally from the conduits into the unconsolidated bottom sediment (ooze). The introduction of this metalliferous fluid, rich in organic matter, stimulated biological activity and bacterial reduction of its contained 804 to sulfide. Hot, dense, laterally migrating hydrothermal fluid precipitated thin sulfide-rich larninae within bottom sediment. Published thermodynamic studies suggest that the diagnostic vaesitepyrite assemblage crystallized at approximately 138°C. The 034S values range from -14.7 0/00 to -10.00/00 and are up to 340/00 lighter than locally surrounding sulfides and age-equivalent mineralized strata elsewhere in the Selwyn Basin. The Ol3C values of calcite in the footwall of the mineralized unit (- 12 0/00 to -6 0/00) are isotopically much lighter than regional values. The lighter isotopic character is attributed to the hydrothermal discharge of fluids enriched in organic compounds. Although geochemical profiles of the lower Earn Group sediments that host the Nick mineralization reveal that these black shales are not distinctive, the unusual Ni, Zn, PGE, U, Ba, and P elemental associations and their anomalous concentrations in stream sediments can be used to explore for this deposit type.

Jan 1, 1992

A Good Product Range - So What! While in terms of water, waste management and environment protectrion, the Gippsland Basin may appear to have a good product range, what does this really mean? What it means is that, like any product range, the virtues of the product range must be sold and accepted by a majority of the public. The social, economic and environmental benefits of any enterprise using these products must be sold and accepted by the regional population. Many a budding entrepreneur has failed because he assumed that the public would accept his product, so good did it appear to be! However, we know that such an assumption must be avoided and that a great deal of time and effort needs to be invested in promoting and gaining acceptance of a product to ensure a long term and viable market.

Jan 1, 1992

One of the major unknowns in the use of iron and copper is the quantity of various low level impurities, particularly hydrogen, that may be introduced during the deoxidizing process prior to casting. Introduction of hydrogen results in the embrittlement of components made from these metals. In addition, hydrogen bubbles in castings of copper result in the formation of blisters and swelling of the casting. During the last year, a significant effort has been made at the University of Missouri-Rolla to understand the permeation of hydrogen in galvanized automotive steel components and the hydrogen absorption during the electrodeposition of copper. The galvanized steel components consisted of automotive upholstery clips, seat belt holders and brake clips. Although the process of galvanization protects the steel from corrosion the process invariably causes the steel to pick up enough hydrogen to make it susceptible to brittle fracture.

Jan 1, 1992

By Ross W. Seedsman

The in situ behaviour of claystone floors associated with the Wallarah, Great Northern and Fassifem Seams has been studied using a comprehensive suite of stress and displacement monitors. The instrumentation was supplemented by in situ and laboratory testing of the claystone materials. The instrumentation demonstrated that the presence of claystone floors is associated with floor heave, extra rib spall, and settlement of the pillar into the floor. Horizontal floor extensometers showed that the depth of extrusion of clay was limited to 1-2 in. A pore pressure transducer installed in a claystone floor demonstrated the possible existence of short-term undrained behaviour of the claystone. Long term swelling of destressed claystone was also documented. Settlement of pillars into claystone floors can be analysed using simple elastic theory. The assumption of plane strain is valid for most claystone thickness/pillar width aspect ratios. Floor heave can be analysed using bearing capacity concepts. However, it is considered that heave is the result of local bearing capacity failure in the rib spall zone. The advantage of this model is that the bearing capacity equation can be applied without resort to unrealistically high factors of safety.

Jan 1, 1992

By C. Haycocks

Damage prediction during multi-seam mining is an essential precursor to optimizing mine design. Ground control problems associated with interaction are influenced by both fixed geological and site conditions as well as mining variables which may be controlled to varying degrees. To quantify interaction effects across an affected seam a hazard map approach was selected, which allows interaction data to be presented in a form that can facilitate future planning. Study mines were analyzed using boreholes as sources of geological and spatial data, together with information from mine maps which gives the extent of mining activity. To demonstrate the method the safety factor against interactively caused shear failure in the lower seam roof was computed. Input data included depth of cover, inner burden thickness, remnant pillar size, extraction ratio, immediate roof type, seam thickness, percent sand-stone, and rock strength values. These safety factors were then contoured to produce a hazard map. An assumption was made to assign a high safety factor at the outcrop line to permit realistic contouring of the safety factors. The software also allowed mine workings to be drawn onto the map to facilitate interpretation of the overall results. Hazard analysis permits delineation of unsuitable mining areas within a seam. The application of the method for refining mine design and improving reserve recovery is verified using case studies.

Jan 1, 1992

By D. Watson

The Henderson mine has more than 20 years experience and has placed a combined total of more than 400,000 m3 (520,000 cy) of shotcrete and concrete. Over the last 20 years the mine has used a variety of equipment for placing concrete, wet shotcrete and dry shotcrete and is constantly trying to cut costs and increase efficiencies. Henderson has recently received a state of the art wet shotcrete placer, automated its batch plant, fabricated a mobile concrete form jumbo and is soon to receive a new concrete transport truck.

Jan 1, 1992

Over the years, numerous studies have been conducted to characterize the floatability of coal pyrite. Unfortunately, many of the results obtained using isolated samples of coal pyrite are not directly applicable to actual coal flotation systems where liberation and entrainment may be the major factors affecting pyrite rejection. In this paper, the association of pyrite with other coal constituents is investigated, and the data are presented for feed and product streams obtained from release analysis tests. Release analysis is used to minimize the effects of entrainment. Particle distributions for each stream are presented as functions of size and composition in order to discern the behavior of free and composite particles.

Jan 1, 1992

By Clayton V. Deutsch

Indicator Kriging (IK) is being commonly applied to mineral resource assessment problems. More recently, indicator simulation has also been used for sensitivity analysis and difficult change of support problems. The essential theory underlying indicator geostatistics has not changed since its introduction 10 years ago; however, the last decade has produced many important developments in its implementation. The objective of this paper is to consider some of the more important implementation details. Examples from the Porgera gold deposit in Papua New Guinea are used to illustrate the steps in an indicator geostatistical study and the importance of various implementation decisions. Specifically, in many precious metals deposits the continuity of the grades is typically quite anisotropic. This anisotropy varies in both magnitude and direction throughout the deposit. Building a model of this anisotropy can considerably improve the local kriged or simulated points. One approach to build this model is presented. In addition, there is typically more than one mineralization style and geological rock type; the spatial character of the mineralization can be quite different within each geological rock type. The rational treatment of anisotropy and geological subdivisions is common to all mineral resource assessment procedures; the importance of this qualitative geological information is not diminished with more sophisticated techniques such as indicator kriging. This paper presents an overdue comprehensive look at the practical aspects of indicator methodology. Many of the techniques and procedures documented in this paper have been developed during the course of detailed mine feasibility studies.

Jan 1, 1992

By Kenneth S. Graham, S. C. Gambrell

A short term, simple roof bolt load cell which uses a birefringent (photoelastic) coating as its sensing element has been developed. The load cell is installed between the bearing plate and the nut/washer and measures the initial force after installation by the bolting machine. The load cell can be removed from the bolt and used again to measure initial force in another bolt if desired. Because temperature and humidity changes in the mine cause creep/relaxation of the coating and/or adhesive, the load cell is useful for accurately measuring force for a period of only two weeks after installation. Force in the bolt is determined by referring to a calibration curve for the load cell.

Jan 1, 1992

By J. Y. Kim, R. W. Stanley, L. Rosato

Silver contained in zinc calcines undergoes several phase changes as it proceeds through the leaching circuit of a roast-leach-electrowin zinc plant. In this study, the flotation response of silver, from leach residues prepared under a variety of carefully controlled operating conditions in the pilot plant has been examined. Flotation of neutral leach residue is shown to be technically viable and to merit consideration for those plants without a high-acid leach circuit, but having significant silver values in the feed. Residue leach conditions must be kept slightly acidic to promote the formation of Ag2S, (AgCu) 2S and Ag2S rims on residual unroasted sphalerite, while simultaneously avoiding the hydrolysis of soluble iron, which depresses silver recovery and grade. Factors to be considered during integration of a flotation process into an electrolytic zinc plant are discussed.

Jan 1, 1992