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By R. Kramer

The Process Mineralogy review arrived too late to appear in the May issue. The Process Mineralogy Committee scheduled programs with both SME and The Metallurgical Society. At the 1991 SME Annual Meeting in Denver, CO the committee sponsored five sessions containing 31 papers. Four process mineralogy sessions were sponsored at the 1992 annual TMS meeting in San Diego, CA. Process mineralogy is used to understand and evaluate mineral behaviors during mineral beneficiation, phase reactions during metallurgy, recoveries and reactions of precious metals during processing and mineral and phase behaviors with respect to environmental problems. The most recent refinement in mineralogical studies with respect to mineral beneficiation has been the wider use of image analysis and combined materials balancing techniques of image analysis data. Image analyzers that can perform analysis with respect to mineral beneficiation are expensive. They are used only for solving major processing problems. Nevertheless, the methodology of analysis continues to be refined. Much better data are collected, and methods of evaluating the data continue to improve. One interesting development involves modifying the ultrasound unit used in medical studies to perform a three-dimensional analysis of ore particles.

Jan 1, 1992

By J. Mark Richardson

Steady-state flowsheet simulators for mineral processing plants have evolved to a current high level of utility and accuracy. Reliable, general-purpose, semi-empirical models now exist in nearly all unit operations categories particularly in the areas of comminution and classification. .These models, installed as user-selectable functions within the integrated frame- work of flowsheet balance-solver software systems, can be strung together to represent any plant configuration. In addition, CAD-like graphics, data reconciliation and model parameterization functions have become standard features of the current generation of integrated plant simulators. These advances have given engineers the capability to investigate many different plant scenarios while requiring a minimum of actual plant testwork. This paper describes a methodology and an integrated software package which are being successfully applied in a number of operating plants worldwide to predict plant performance under changing conditions. Those conditions which can be changed include effect-of ore type, feed size, water addition rates, equipment geometries and flowsheet modifications. By using data from actual plant optimization exercises in real mills, the paper illustrates and out- lines a technique which includes plant data collection, ore breakage testing, flowsheet simulation, model-fitting (parameterization), data adjustment and model experimentation. Brief descriptions of some unit operations models, such as autogenous mills and cyclones, are provided as examples of the current state of such models. Ore breakage testing and its relation to certain models is also discussed. Computer- generated size-distribution graphs, along with tabular data generated by the simulator, round out the presentation and serve to demonstrate the real- ism and accuracy of the models. The paper concludes with a partial list of cases where this technology has been successfully applied.

Jan 1, 1992

By Klau Meyer

"At Teck-Corona Operating Corporation's David Bell Mine, a successful water quality management strategy has been established. This resulted from the development and application of process technology, allowing year round discharge of an effluent exceeding the chemical and biological standards set by the Ministry of Environment. This strategy aims at minimizing contaminant levels of effluents through optimization of reagent selection and reduction of effluent volumes through maximizing reclaim water usage. Concentrator and effluent treatment plant operating practices, process chemistry and the results of the water quality management strategy are reviewed.IntroductionThe David Bell Mine is located in the Hemlo gold camp 42 km east of Marathon, Ontario. The concentrator has a design throughput of 1000 tonnes per day. The processing of the run of mine ore ( - 15cm) involves the following unit operations: grinding in a semi-autogenous mill followed by a ball mill, thickening, pre-oxidation , cyanidation, and carbon-in-pulp gold recovery followed by electrowinning and refining.The David Bell Mine water quality management strategy is composed of the following items (Goodfellow and Meyer, 1991):• natural destruction of cyanide contained in the tailing water in a large shallow tailing pond ;• preliminary treatment of reclaim water in the grinding circuit for cyanide and heavy metal removal;• pre-oxidation of sulphide minerals in pipe reactors to reduce cyanide consumption using pure oxygen;• pH control in the grinding, pre-aeration and leach circuits to minimize the dissolution of stibnite while maximizing gold recovery; • close control of cyanide addition rates to the leach circuit to maintain the lowest possible levels;• a carbon column for gold recovery;• an effluent treatment plant for antimony and heavy metal removal; and• the use of final treated effluent for industrial water underground to minimize fresh water consumption."

Jan 1, 1992

By Peter N. Gabby

In 1990, the Bureau of Mines conducted a mineral resource investigation of the 12.321 acre Black Warrior study area, one of several proposed additions to the Sawtooth Wilderness. No identified mineral resources were delineated. There were 123 lode and placer claims in or adjacent to the study area. There is a known hot spring adjacent to the study area, but presently no geothermal leases are pending. Lode mines in pr adjacent to the Black Warrior study area have produced 4,022 tons of ore from which 1,981 oz of gold and 811 oz of silver were recovered. None of the vines are currently active. During the field study 125 rock samples were taken. Significant gold assays and favorable geologic characteristics at seven properties indicate that gold occurrences and resources with byproduct metals may exist in the study area. Two other sites yielded anomalous gold assays; however, sage favorable geologic characteristics are lacking. Presently, identified gold resources are being delineated by drilling programs in the nearby Atlanta and Rocky Bar mining districts. These districts have geologic characteristics similar to the Black Warrior area. During the field study 22 placer samples were taken. In most places where an anomalous concentration of gold was found, the stream channels are too narrow for operations other than recreational suction dredges. However. One area is estimated to contain over 2 million yd3 of gold-bearing gravels.

Jan 1, 1992

By E. D. Sehnke

The refractory materials industry provides the largest commercial market for nonmetallurgical grade bauxite. Refractory grade bauxite is prepared from bauxites having low iron, titania, and alkali content by calcining at temperatures near 1,650° C. Although there are substantial bauxite reserves in the world, premium grade bauxite ores suitable for use in refractory applications are limited to only a few specific sources, primarily in Guyana and the People's Republic of China. Consumption of bauxite for refractory use is closely associated with the production and consumption of primary metals, in particular iron and steel. Barring major disruptions within the principal producer nations, sufficient supplies of refractory bauxite will be available to meet world demand well into the next century, and raw material costs will continue to determine the availability of markets for bauxite-based refractory products.

Jan 1, 1992

By John L. Watson, Suren Mishra

Many of the wastes produced by modern steel plants are pulps or sludges containing significant concentrations of iron and displaying some ferromagnetic characteristics. These waste materials are often suited to treatment by magnetic cycloning to produce a high solids content underflow and a clean water overflow. Alternatively in the classification mode, the magnetic cyclone can produce a high iron underflow product for recycling by discarding fine non-magnetic material to the overflow. Results for the treatment of a variety of steel plant wastes in 5.0cm, 2.5cm and 1.25cm diameter cyclones, operating with and without an applied magnetic field, are presented. It is demonstrated that the magnetic cyclone increases solids recovery to the underflow product, especially at finer particle sizes and for higher solids content feed pulps.

Jan 1, 1992

By Tomás Vargas

The catalytic influence of a pure strain of Thiobacillus ferrooxidans (ATCC 19859) on the dissolution of natural pyrite crystals was studied using electrochemical techniques. The results showed that this microorganism catalyze the leaching of pyrite by both, oxidizing ferrous iron in solution and depolarizing the reduction of ferric ion on this sulfide. In addition, studies of bacterial corrosion under applied potential showed that pitting on the pyrite surface centers on weak sites of the sulfide structure in which bacteria has attached, but occurs only when the ferric iron in solution induces an adequate level of anodic polarization on the mineral.

Jan 1, 1992

By A. F. Edwards

The Main Pass sulphur and oil deposit is located at Main Pass Block 299 in the Gulf of Mexico, 30 miles east of Venice, Louisiana, in 210 feet of water. The deposit was discovered by Freeport-McMoRan and its joint venture partners, IMC Fertilizer and Homestake Mining, in late 1988-early 1989. The sulphur deposit contains 67 million long tons of recoverable sulphur. The sulphur occurs in bio-epigenetic limestone replacing anhydrite caprock on top of a salt diapir. Recoverable reserves of 39.4 million barrels of oil and 9.1 billion cubic feet of gas are also contained in the limestone caprock and in supracap sandstone stringers.

Jan 1, 1992

By Ronald S. Conti, Harry Dobroski

Re1iabl e monitoring a1ong an underground mine belt line is of great concern because of combustibles, electrical apparatus, and friction. Belt entries are strategically located where a fire can have rapid and disastrous consequences. This paper reviews conventional distributed temperature sensing systems based on resistive, thermistor, and thermocouple effects. These are shown to provide limited benefits. A new system tested by the U.S. Bureau of Mines based on fiber optics and time domain reflectrometry, promises much better temperature and spatial resolution, faster response, inexpensive cable, longer distance, and comprehensive data analysis. Test results in a small, controlled, in-mine fire are given.

Jan 1, 1992

By M. S. Celik

Beneficiation of boron minerals by flotation with well defined systems has been very little investigated in the literature. The difficulty arises from the fact that boron minerals cover a spectrum of solubilities. Colemanite, a calcium containing relatively insoluble boron mineral, and borax, a highly soluble boron mineral have been used to exemplify the flotation of boron minerals. The floatability of both minerals using sodium dodecylsulfonate and dodecylamine hydrochloride exhibits considerable differences in their response to flotation. This has been ascribed to variations in the solubilities 0f boron minerals and the presence of the cations in the lattice structure. Flotation tests along with zeta potential measurements are used to elucidate the mechanisms involved in the flotation of boron minerals.

Jan 1, 1992

By C. P. Mangelsdorf, Richard A. Allwes

At the request of the U.S. Department of Labor, Mine Safety and Health Administration (MSHA), the U.S. Bureau of Mines evaluated the suitability of using tri-sets for protecting mine personnel in roof-fall prone areas. A steel-set arch provided by MSHA served as a basis for evaluating the performance of the tri- set. All tests and analyses were conducted according to the arch canopy test and design procedures developed by the Bureau. Theoretical resistance functions were established for the steel-set arch and tri-set and were representative of their experimental behavior. The resistance functions were used to determine the energy absorption capacity of the structures and to predict their dynamic response to impact loading. The dynamic tests demonstrated that the arch canopy design procedure is appropriate for tri -sets and yields conservative designs for both steel-set arches and tri-sets. As a result of this work, it is recommended that tri-sets may be considered for protection against roof falls, provided that the arch canopy design procedure is utilized for each application and that the principles underlying the design procedure are understood.

Jan 1, 1992

By Liu Zhonghua

Hydrogen reduction of cobalt sulfide (Co9S8) was experimentally investigated in the temperature range 813-1053 K. The results revealed that the reaction kinetics can be described by the shrinking core mod¬el in chemical control regime at low temperatures, it is of first order with respect to hydrogen concentration, and the reaction activation energy is 67.4 kJ/mol. The SEM second electron images of the samples before and after experiments showed that the swelling of the sample above 973 K is due to the formation of metallic cobalt whiskers.

Jan 1, 1992

By C. E. Jordan

The Bureau of Mines investigated a simultaneous elutriation and flotation technique for separating polyethylene terephthalate (PET) from polyvinylchloride (PVC). The Tuscaloosa Research Center, through a cooperative agreement with a recycling company, devised an elutriation-flotation method for beneficiating the mixed heavy plastics portion of municipal solid wastes which is composed of polystyrene (PS), PET, and PVC. A sodium carbonate brine was used to remove the lighter PS from the heavier PET and PVC. Over 98 pct of the PS was recovered in a high purity PS concentrate containing 99.7 pct PS, The remaining PET and PVC mixture was washed to remove the brine salts that would be harmful to the flotation process. The clean PET and PVC mixture was conditioned in a solution of 45 g/t gelatine and floated in a short (l-m) column flotation cell in an upward flow of water. In a single flotation step, over 75 pct of the PET was recovered in a high purity product containing 99.8 pct PET. The bubbles attached to the PET lowered the effective density of the PET-bubble agglomerate and allowed successful separation of these agglomerates from the PVC plastic pieces. This method separated two-thirds of the mixed plastics fraction into high purity PS and PET products suitable for recycling and left only one-third of the plastics in the mixed plastics product.

Jan 1, 1992

By A. Dadgar

The adsorption kinetics of AuBr4 on Dowex ® -21K ion-exchange resin were studied and found to be independent of the initial gold, bromine, and base metals concentrations. A commercially-available undivided hypochlorite generating cell was used to generate bromine from simulated mixed halide (Br-/CI-) solutions. Electrolyses were performed with solutions containing very low Br' ion concentrations. The current efficiencies were 80-90%, and Br- ion utilization was maximized. A detailed economic assessment was made considering the capital and the operating costs for a 1000 mtpd gold ore processing plant. The toxicity and discharge levels of bromide, bromine, and cyanide were compared from a detailed analysis of the published literature data. Comparing bromine vapor with hydrogen cyanide gas for a given length of exposure, the lethal concentration of bromine is about 3 times less than hydrogen cyanide. The toxicity of sodium bromide is similar to that of sodium chloride. Acute poisoning to bromides and chlorides is rare because of their low toxicities. The allowed discharge levels of Br-, Br2, and CN- in fresh water are 250, 0.1, and 0.005 mg dm-3, respectively.

Jan 1, 1992

By R. R. Oder, R. J. Gray

We report measurements of the effects of rank, type, and grade of coal on grinding energy and grinding media consumption in a Pitt Mill. The rank of coal has a greater effect on grinding energy than does coal type. The effect of coal grade on grinding energy depends upon the relative grindability of the mineral matter and of the hydrocarbon components of the coal. The mineral matter is primarily responsible for abrasive media wear in a Pitt Mill. The widely recognized HGI test for coal breakage may yield misleading results, particularly for multiple-banded bright and dull coal where the screening procedure used in sample preparation favors the testing of the hardest coal fraction. The work reported here indicates that the Pitt Mill, which grinds the whole coal in a single stage and which yields easily interpreted results, is an excellent candidate for testing coal pulverization characteristics including energy requirements and equipment wear. The measurements of the effects of coal characteristics on grinding energy and on media consumption have been used to estimate the cost of fine grinding in a Pitt Mill. The results, based on a conceptual level evaluation of grinding at the rate of 1 TPH, show that there are trade-offs possible between the cost of energy and cost of media consumption which involve choice of grinding media size. The use of fine-size grinding media to lower grinding energy and to increase throughput can be deceptive because the total cost of grinding must consider both energy and media consumption.

Jan 1, 1992

By M. Solomon

Abstract -Giant, sediment-hosted lead-zinc deposits in northern Australia formed during development of Mid-Proterozoic extensional basins that overlie Lower Proterozoic basement. The basement in the Mount Isa area, exposed by folding and faulting, contains fractionated, high-heat-producing granites. These granites generate heat at a rate of about 6 ?Wm-3, probably sufficient to form giant lead-zinc deposits either by (a) driving episodic convection of saline basement and basin fluids for periods of 105 to 106 years at temperatures of about 230°C, or (b) heating basin fluids moving under the influence of topographic relief or fault movement. The presence or absence of such granites may form a vital component of the genetic model. Ore-forming fluid flow was probably initiated by continent-scale, extensional basin fracturing.

Jan 1, 1992

By G. L. Mowrey

One critical element of the US Bureau of Mimes computer- assisted mining research program is the development of a reliable coal interface detection (CID) system. Several promising CID concepts currently being investigated by the Bureau include natural gamma radiation (NGR), vibration and passive infrared. To help establish which CID sensor technologies need to be developed for a given seam, coal and adjacent rock samples (immediate roof and floor) are being collected from selected major coal seams in the US and are being analyzed in terms of NGR and other geophysical measurements. This paper provides a brief overview of the Bureau's work in these CID areas.

Jan 1, 1992

By Zvonimir Jam?ek

In Rudarski Institut Ljubljana (RIL), i.e. Ljubljana Mining Institute, we have developed CADRIL, a smaller CAD package which purpose is to overcome the difficulties by introducing Computer Aided Design in our mines. Program CADRIL is a graphics shell for several computer applications in mining. With the basic version of CADRIL all 2D working maps for daily use can be produced. Inserting different program blocks into CADRIL we get versions MAPRIL, TAHRIL, SECRIL and so on. The main purpose of all versions is graphics design. The main and most innovative feature of CADRIL is the screen four-word command menu. Not having pull-down or tablet menus is the speciality of this program. CADRIL contains 500 achievable commands. Each of them can be composed by choosing two to four expressions stored and shown in a specific four- column menu, sorted as objects functions, parameters and modes. Thus all commands are immediately accessible. As a result of its plainness and adaptability to the present working methods of mining engineers, CADRIL quickly attained a good reputation in our mines.

Jan 1, 1992

By Stanley R. Riggs

Onslow Bay is a broad, shallow, high-energy shelf system bounded by the Cape Lookout and Frying Pan shoals. It is generally a sediment-starved shelf system dominated by hardbottoms with a scattered and discontinuous veneer of mobile Holocene sediments. Phosphate-rich beds of the Miocene Pungo River Formation crop out in a belt 150 km long and up to 50 km wide across the continental shelf in Onslow Bay, North Carolina. Previous research has demonstrated that a few of these beds contain vast quantities of potentially economic phosphate resources that occur in the surface and shallow subsurface sediments. Onslow Bay contains five phosphate-bearing beds predicted to include up to 20.7 billion tons of in-place phosphate concentrate with total sediment grades ranging up to 22.9% P2O5 and adjusted average concentrate grades of 29.8% P2O5. These phosphates are lithologically and chemically similar to phosphates currently being mined in the nearby Aurora phosphate district in North Carolina. Various lithologies of the Pungo River Formation and associated rock units of Oligocene and Quaternary age crop out on the sea floor to form extensive hardbottom habitats that dominate almost 100% of Onslow Bay. A large proportion of these hardbottoms appear to be sea floor deserts, whereas others are virtual oases with rich associations of benthic organisms. These important differences in benthic community structure appear to be greatly influenced by one or more of the following variables: 1) geologic framework (geologic formation, hardbottom composition, morphology, and spatial orientation relative to dominant currents and waves), 2) texture, movement, and accumulation of surface sediments, and 3) flow rates and chemical composition of discharged submarine groundwater.

Jan 1, 1992

By Louis W. Cope

INTRODUCTION Various methods for sampling placer deposits have been mentioned by Wojcik in Chapter 2. Here, a brief description and comparison of these methods will be given as related to bulk versus drill sampling. The advantages and disadvantages inherent to each will also be given. The means of sampling can be grouped into bulk or drill samples. As a generality, drill samples over a five-foot length will run from I/,, to 1 /, cubic yard, depending on the diameter of the drive shoe on the drill casing. Bulk samples can be expected to be in the range from one to many cubic yards each. SAMPLE METHODS Bulk Bulldozer-dug trenches and dozer or front-end loader pits are two methods to excavate large bulk samples. Smaller bulk samples can be obtained by digging small dimension shafts through the deposit, by hand or caisson-like drills. It is not recommended to split samples by alternate bucket-loads or by other means, as the effect of a nugget falling into one or the other fraction will seriously alter the sample.

Jan 1, 1992