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By R. I. Grauch, Michael D. Glascock, Chen Nansheng, Jr Coveney, James B. Murowchick

"Unusually rich molybdenum ores (cutoff grade = 4.10/0 Mo) hosted by Lower Cambrian black shales have been mined since 1985 near Zunyi in the province of Guizhou in China. Similar ores were once worked for Mo and Ni near Dayong in the province of Hunan. In both mining areas, mineralization occurs in Lower Cambrian black shale (Niutitang Formation and stratigraphic equivalents) as a single sulfide bed or lens with exposed thicknesses up to 15 cm and reported thicknesses up to 35 cm. In addition to high Mo values (4% to 7%), ore samples contain up to 7% Ni, 2% Zn, 2.5% As, and several hundred ppb Au and Pt-group elements, but the precious metals have never been recovered from the ores. Sporadic occurrences of Mo-Ni sulfide ore beds are found in at least five provinces stretching approximately 1600 Ian from Yunnan to Zhejiang. None of the Mo-Ni ore-bed occurrences has any obvious connection with mafic or ultramafic source rocks. Similar occurrences containing elevated values for Ni, Mo, and PGE exist in Devonian black shale in the Yukon. Future exploration for Pt, Au, Mo, and Ni deposits should consider this previously unknown type of sediment-hosted mineral deposit.Sommaire - Des minerais anormalement riches en molybdène (teneur-limite = 4.1% Mo) provenant de schistes argileux noirs du Cambrien Inferieur ont été exploites depuis 1985 près de Zunyi dans la province de Guizhou en Chine. Des minerais semblables ont déjà été traire pour Mo et Ni près de Dayong dans la province de Hunan. Dans ces deux régions minières, la minéralisation se présente dans le schiste argileux noir du Cambrien Inferieur (Formation Niutitang et équivalents stratigraphiques) sous forme de couche ou lentille unique de sulfures avec des épaisseurs exposées de plus de 15 cm et des épaisseurs rapport6es de plus de 35 cm. En plus des fortes teneurs en Mo (4%-7%), des échantillons du minerai contiennent jusqu’ à 7% de Ni, 2% de Zn, 2.5% d'As, et plusieurs centaines de ppb d'or et d'éléments du groupe du platine; toutefois, les métaux précieux n'ont jamais été récupérés des minerais. Des présences sporadiques sous forme de couches de minerai sulfure de Mo-Ni se retrouvent dans pas moins de cinq provinces s'etendant sur 1600 km de Yunnan a Zhijiang. Aucune de ces présences de minerais, sous forme de couches, ne semble associée a des roches du type mafique ou ultramafique. Des présences similaires contenant des teneurs élevées en Ni, Mo et EOP se retrouvent dans le schiste argileux noir Devonien du Yukon. L'exploration future pour des gisements de Pt, Au, Mo et Ni doit prendre en considération ce type de gisement encore inconnu précédemment."

Jan 1, 1992

By A. T. Robles, L. Buckingham

"When certain gold ores containing pyrite, graphite, humates and fumates or other organic compounds which are possibly adsorbed on clay minerals are treated with aqueous solution of alkali metal cyanide, the aurocyanide complex which forms is adsorbed by these ""pregrobbing"" species in the ore. Dissolution of gold proceeds until chemical equilibrium is attained between the cyanide complex adsorbed by the ore and in solution.Sodium lauryl sulfate (SLS) may be used to decrease the adsorptive activity of the prerobbing species in the ore. It has successfully improved recovery at Holt-McDermott Mine and is highly biodegradable.INTRODUCTION Precious metal-bearing ores containing preg-robbing species are poorly amenable to standard cyanidation techniques. The ""preg-robbing"" impurities with which they are associated tend to adsorb the gold cyanide complexes and carry them through the circuit to the tailings. Also, gold may be associated with these impurities in the ore and not be leached by the cyanide complexing agents used in conventional cyanidation techniques.Methods for dealing with the problem of preg-robbinq impurities in gold ores are:Carbon-in-Leach (CIL), in which granular activated carbon is added to compete with preg-robbing species for the gold cyanide complexes. This process can improve gold recovery in mildly preg-robbing ores especially when fine carbons with very high activities are used. However, with severely graphitic ore, the carbon associated with the rock may outperform the granular activated charcoal.Chemical Oxidation, in which the ore is subjected to preliminary chemical oxidation techniques to oxidize carbonaceous materials using such diverse reagents including ozone, sodium hypochlorite, calcium hypochlorite, chlorine gas, permanganates, perchlorates, chlorates and oxygen prior to subjecting the oxidized ore to standard cyanidation treatment to extract gold. This is generally a costly method and will not prove economical on a low-grade ore."

Jan 1, 1992

By Fejes A. J

The U.S. Bureau of Mines installed surface and subsurface instruments at a mine site in Colorado to monitor and characterize the overburden response to longwall mining. Instrumentation included a time-domain reflectometry (TDR) cable, a multiple-point borehole extensometer (MPBX), vertical- deformation surface monuments, and in-mine pressure cells for monitoring abutment, pillar, and gob loads with respect to the longwall face position. The purpose of the study was to collect data that could be analyzed to correlate the design of the mine layout to the resulting overburden failure response. Determining the extent of caving and fracturing is important in the and and semiarid Western United States because of the possible consequences to the fragile underground hydrologic systems upon which the land owners and users depend. This study is unique from past investigations because the overburden contains massive sandstone members that impose special conditions on the caving process and pressure redistribution above the longwall panels. This paper presents the results of this correlation study.

Jan 1, 1992

By Walton M. C

A combination of flotation and smelting technologies is proposed as a cost-effective means to maximise the revenue of base metal operations. The proposed treatment route breaks the grade - recovery nexus associated with the treatment of ores exhibiting difficult mineralogy in conventional plants. Aspects of the two technologies are reviewed and typical capital and operating costs presented. A significant improvement in revenue is demonstrated in a worked example, where a copper-lead-zinc operation is examined in terms of the conventional and proposed treatment options. For the selected ore, the net smelter return per tonne of mill feed improved 57 per cent, from US$89.70 to US$141.10 with the proposed treatment option. This represents an additional US$51.4 million in annual revenue. Metallurgical operating costs increased by US$20.12 per tonne of mill feed for an incremental capital requirement of US$30.3 million for an existing operation.

Jan 1, 1992

By F. M. Doyle, J. P. Dwyer

Introduction The mining industry has a poor public image. It is often perceived as a despoiler of the landscape and a polluter of the environment, and there is little recognition of societal needs for the raw materials and fuels that this industry produces. There are many reasons for this poor image, but an important one is that a substantial number of mining operations have caused significant damage to the environment. Many of these operations, particularly those that now are abandoned, continue to have an adverse impact, principally in the form of water pollution.1 In some cases, the damage caused by this pollution extends well beyond the immediate region around the mine. Chemical contamination of ground and surface waters can, and does, occur in nature when these waters flow through or over undisturbed, mineralized rock masses. However, the problem is greatly exacerbated by mining because the mining activities increase, by several orders of magnitude, the permeability and the surface area of rock that can be contacted by percolating water. Water flowing through either the mine workings or the waste rock dumps becomes contaminated. Pollution can also arise if leachate from tailings ponds enters either groundwater or surface waters. This leachate may contain chemicals used in processing the ore. The magnitude of the threat posed by mining wastes depends on the type of minerals in the deposit, and on the chemicals used to process the ore. The magnitude of the threat also depends on two other, site-specific factors. One is the volume of water flowing into the mine and through the dumps, which depends on rainfall patterns, topography, and whether the mine workings are surface or underground. The other is the proximity of the pollution source to groundwater or surface waters, which depends on both the climate and geology. These factors influence the concentration and the quantity of polluted water forming and reaching the receiving water. Mining activities present a potential problem of enormous scale. Vast amounts of rock are mined each year2 and, as noted above, substantial problems have arisen at some mine sites. These problems are usually exceedingly costly to address, and it is imperative that these mistakes not be repeated. There are indications that we can accomplish this goal; we now better understand the processes that cause pollution and have methods to prevent or contain it. In addition, in the past few decades society has started to recognize the need for all industries to operate in a manner that maximizes the health and safety of workers and the public and minimizes adverse environmental impacts. A variety of recently enacted federal and state laws regulating public health and environmental hazards reflect the increasing concern over these issues. Many statutes, such as the federal Clean Air Act and the Clean Water Act, encompass activities undertaken by the mining industry. Other laws, such as the Surface Mining Control and Reclamation Act, have been written to regulate specific hazards posed by this industry. At the present time, the federal government. through the Environmental Protection Agency (EPA), and several state governments, are preparing new regulations specifically tailored to control the disposal of mining wastes. Given the magnitude of the potential environmental and health risks posed by disposal of mining wastes and the regulatory costs to the mining industry (both of which are due to the tremendous volume of waste generated), it is especially important that regulators have a good understanding of the different types of mining wastes and the risks they are likely to pose in various geographic and climatic circumstances. Only then can a regulatory program be designed with suitable procedures and substantive criteria to protect the environment and ensure compliance, while avoiding unnecessary or wasteful expenditures. California has long enjoyed a large, active mining industry. Today it produces a wide range of mineral commodities. The revenue from production of non-fuel minerals in California ($2.85 billion in 1988) greatly exceeds that of any other state. About a third of this revenue is from the production of inert sand, gravel and crushed stone. However, the remainder is from the production of a wide range of materials. These include boron minerals, rare earths, asbestos, talc and pyrophyllite, and gold. In earlier decades, an even broader range of minerals was produced, including mercury, copper, lead, zinc, and barite. There are acute environmental problems at some of these early mine sites. Because in 1987 the state of California was engaged in a revision of its regulations for mining waste disposal, the legislature commissioned a study by researchers at the University of California at Berkeley to investigate and review: the magnitude of the problem posed by these wastes, • the best feasible control measures available for waste management and disposal, • the problems of abatement and cleanup at so-called "problem" mine sites, • the current regulations imposed on mining waste disposal by various federal, state, and local agencies and the effectiveness of these regulations. This paper summarizes the principal findings from this study (Mining Waste Study, 1988). The lessons from this investigation are likely to be of general interest because of the diversity of mineral products produced, and the wide range of geographic and climatic conditions encountered. The acute problems seen at some of the older mines are typical of the western United States, and teach useful lessons on strategies that should be implemented at new mines to prevent recurrences of these problems.

Jan 1, 1992

By Douglas C. Peters, Valois R. Shea-Albin, Dennis R. Dolinar

An accurate assessment of the vertical stress on a coal seam at depth is important for mine design. Vertical stress calculation techniques presently available either are not sufficiently accurate or cannot handle complex surface topography. Therefore, the U.S. Bureau of Mines developed a computerized method to calculate vertical stress exerted on surfaces at depth that includes the effect of topography. Two input data sets are required: a digital elevation model containing topographic elevations and a coal seam file defining coal seam elevations at depth. Boussinesq's equation then quantifies the vertical stress resulting from topography. The computerized method was tested on a coal seam overlain by a complex topography where a vertical stress map encompassing several square miles was produced. Results show that depth mitigates the affects of surface topography, while the coal seam topography has a direct effect on the vertical stress. In comparison to the computerized method, the direct stress method overestimates stress under hills and underestimates stress under valleys. The largest difference between the two methods occurs under the steepest topographic relief. A limitation of the computerized method is that stresses cannot be accurately determined near an outcrop.

Jan 1, 1992

By S. A. Moffatt, S. K. Kawatra, T. C. Eisele

This paper describes the decomposition of bulk samples to fine particles using alkali metal vapors. Basalt, pyrite, alumina, pyrex and quartz glass samples were exposed to sodium vapors at elevated temperatures for different time periods up to 30 hours. Examination of the particles showed that fragmentation occurred preferentially along grain boundaries. Emphasis of this paper is on the theory of the degradation mechanism and the size distribution of the particles produced.

Jan 1, 1992

By Kurt Westerlund

Three. years operating experience of the FLUXFLOW waste heat boiler (WHB) 20.000 nm /h at Boliden Ronnskar Sweden on a TBRC smelting palena (PbS). Operating experience from the Kivset flash WHB 11.900 nm /h at Samim, Porto Vesme, Sardinia, Italy. Conceptual features of the 93.600 nm3 /h FLUXFLOW (WHB) on the Isasmelt smelting in melt furnace for 180.000 t Cu/a at Mount Isa, Australia.

Jan 1, 1992

By E. J. Dorward-King, R. J. Kadeg, S. Pavlou

Risk assessment, risk management, and engineering/economic feasibility analysis are presented as three effective, practical tools for decision making in the remediation of contaminated soils. Risk assessment is applied to evaluate the extent, magnitude and sources of contamination, to identify appropriate contaminants of concern (COCs). Risk management is then applied to identify the acceptable contaminant residual levels for the COCs. Finally, engineering/economic feasibility analysis is used to define the appropriate cost-effective remedial action and associated target contaminant action levels that will achieve the acceptable contaminant residual levels. A real site application of this decision making approach is presented. This site illustrates that through appropriate engineering, acceptable risk-based contaminant residual levels can be achieved with higher action levels.

Jan 1, 1992

By J. Y. Hwang

Coal cleaning with traditional magnetic separation usually yields unsatisfactory results because minerals associated with coal, such as quartz, clay, pyrite and calcite, are weak-or non-magnetic. Magnetic reagent technology is a new mineral processing technology with the capability to enhance the magnetic property of minerals selectively. This reagent can be adsorbed selectively on minerals through the control of surface chemistry and, thus, result in selective magnetic enhancement. The application of this technology on coal cleaning has been experimentally demonstrated. Good separation results can be obtained at low to medium magnetic field strength. Comparison with other processing technologies is included.

Jan 1, 1992

By W. E. Cobb

The financial implications of environmental liabilities are becoming staggering, particularly for mining companies. The Environmental Protection Agency's (EPA) Record of Decision (ROD) list for Superfund mining sites has some pretty hefty financial commitments, such as the $10 million operable unit remedy for the Yak Tunnel at California Gulch (in Colorado) or the $40 to 60 million remediation at Bunker Hill (in Idaho). These costs are driven by the large volume and areal extent associated with historical waste management practices at mining sites. (It's difficult to have a low-cost remedy for a 20-square-mile site.) Unfortunately, there are other ways of generating environmental liabilities besides Superfund, such as non-compliance with Clean Air Act provisions, stormwater permits, or National Pollutant Discharge Elimination System (NPDES) permits. In the last 2 years, EPA has increased enforcement in its regulatory programs, which has resulted in increased fines and criminal actions. Leaders in other industries (primarily the chemical and manufacturing industries) are viewing environmental liabilities as a strong motivator to select engineering approaches carefully based on technical, legal, economic, and philosophical perspectives. Industry interest in waste minimization programs comes from the concept that it is economically advantageous not to create waste in the first place. Waste minimization programs typically balance increased front-end capital investment with the minimization of potential long-term environmental liabilities as a way to achieve the lowest total-or life-cycle-cost. A side benefit of waste minimization programs is that they tend to improve overall regulatory compliance. Waste management practices are also becoming philosophical, as evidenced by a May 11, 1992, Business Week article: Companies that incorporate innovative thinking on sustainable development will do more than clean up or prevent their own pollution. They'll make and distribute a product more efficiently than ever, worry about its lifelong environmental impact, plan for recycling, and get their suppliers on the bandwagon. This type of approach will require a new mind-set, new tools, and adjustments throughout the organization. A key aspect of waste minimization or life-cycle waste management programs is the incorporation of environmental costs into economic analyses that compare various waste management alternatives. However, the incorporation of environmental costs into an economic analysis can be more difficult than initially thought. As noted above, new tools-or even a new toolbag-are needed, such as new accounting methods that track and assign the true lifetime environmental costs of a particular product. One piece of the new toolbag is life-cycle cost analysis, which is discussed in this paper. To simplify the discussion, this paper looks at the total costs associated with a given mining site. The concepts presented in this paper, however, can be applied to any mine waste management decision. The ultimate extension of life-cycle costing, as presented in the Business Week article, is to include the potential environmental costs throughout the life of a metal. At this point, I am perplexed on why, let alone how, to include the potential downstream environmental costs (i.e., the costs associated with smelting, manufacturing, use, and recycle or disposal) throughout the life cycle of mined copper, lead, or zinc.

Jan 1, 1992

By Gordon N

The in situ behaviour of claystone floors associated with the Wallarah, Great Northern and Fassifem Seams has been studied using a comprehensive suite of stress and displacement monitors. The instrumentation was supplemented by in situ and laboratory testing of the claystone materials. The instrumentation demonstrated that the presence of claystone floors is associated with floor heave, extra rib spall, and settlement of the pillar into the floor. Horizontal floor extensometers showed that the depth of extrusion of clay was limited to 1-2 in. A pore pressure transducer installed in a claystone floor demonstrated the possible existence of short-term undrained behaviour of the claystone. Long term swelling of destressed claystone was also documented. Settlement of pillars into claystone floors can be analysed using simple elastic theory. The assumption of plane strain is valid for most claystone thickness/pillar width aspect ratios. Floor heave can be analysed using bearing capacity concepts. However, it is considered that heave is the result of local bearing capacity failure in the rib spall zone. The advantage of this model is that the bearing capacity equation can be applied without resort to unrealistically high factors of safety.

Jan 1, 1992

By D. E. Munson

To assure the safety of a radioactive-waste repository, the performance of the repository must be predicted far into the future. The Waste Isolation Pilot Plant (WIPP) Program is responsible for developing the technology for such performance predictions in bedded salt. An important technology-development activity concerns the, fielding of very large-scale in situ tests to determine the time-dependent deformation of underground openings in salt as a basis for validation of the predictive technology. This technology is necessary to predict repository seal performance and final closure times of rooms and may be of value to the salt and potash mining community, as well.

Jan 1, 1992

By R. W. Bartlett

The extensive central Idaho black sand placer deposits are a potential source of rare earth elements, particularly the heavy rare earth elements that are not prevalent in commercial bastnasite deposits. These placers derive from the Idaho batholith. The geology, occurrence, and extent of these deposits are reviewed and the diverse mineral assemblages and complex mineral chemical compositions of these sands are described. Niobium, yttrium and thorium are also present in significant concentrations. The results of prior mining practice, including concentration and separation of the heavy minerals are reviewed. Technical approaches to extraction of rare earths from Idaho black sand concentrates are discussed.

Jan 1, 1992

By William A. Faust

At Gold Fields' Chimney Creek Mine, major reviews of the reclamation and closure plans are done concurrently with the annual mine planning required for budget preparation. This review includes identifying and scheduling reclamation work that can be done within the next few years and development of associated costs. Longer term mine, leach pad and waste dump development are examined to take advantage of any design changes that can reduce ongoing reclamation or closure requirements and reduce costs. The success and cost effectiveness of past efforts are continually evaluated to determine the best methods for reclamation.

Jan 1, 1992

By Gaulton R

The Commission maintains a data base first computerised in 1957 and containing information from over 18 000 boreholes located mainly in the Latrobe Valley area. Some of the borehole derived information dates from the turn of the century, although most of it has been collected as a result of Commission investigations conducted over the past 40 years. The Resource Data Base contains not only information gained directly from the drilling itself but includes the results of chemical and physical testing on many hundreds of thousands of samples retrieved from boreholes. Replacement value of the Resource Data Base has been estimated to be around $200 million, and it's integrity and accessibility is clearly of paramount importance, not only to existing mining and power generating functions but to the future evaluation and use of the vast brown coal Resource.

Jan 1, 1992

By Dunne R, Defilippi J

Dump leaching began at Teller in late-1988 at a rate of 4 MTPA and has been progressively expanded to the present rate of 10 MTPA. Teller's on-going commitment to dump leaching is driven by the amenability of gold ores to the process and the availability of large tonnages of low grade gold ore. The sequence of evaluating ores for dump leaching involves rolling bottle tests on coarsely ground ore, followed by small and large column leaching and finally trial heaps. Trial heap tests are very expensive and an alternative approach to this is large diameter column leaching.A four-column permanent facility was built at Teller to specifically evaluate the leaching characteristics of new dump leach ores. Details of construction, operation and dismantling are discussed in the paper. Capital cost for the four column facility was some $45 940, while operating costs are about $24 800 per column.

Jan 1, 1992

Lightweight polymer grids have recently been introduced to the mining industry. They are currently being used for roof and rib control, longwall shield recovery, safety guarding or barricade, highwall screening, internal reinforcement of gunnite/shotcrete applications, sub-base reinforcement, construction of steepened slopes, retaining walls, mine reclamation (i.e. erosion control, turf reinforcement), and in numerous mining waste related projects. These polymer mining grids utilize a strong, lightweight polymer, usually special grades of polypropylene or polyethylene. High tensile strengths are achieved by molecular orientation of these polymers in the manufacturing process. The first step in the manufacturing process is to extrude the polymers into thick continuous sheets. These sheets are then punched, and drawn into open grid structures. Aperture size and configuration are controlled by the geometry of the punched hole and the degree to which the grids are stretched. The drawing process is the key to the molecular orientation required for the tensile strengths. These long chain polymer molecules in their natural state have a random orientation. When stretched, the molecules are pulled into a parallel alignment, thus creating a lightweight product with tensile strength comparable to Steel.

Jan 1, 1992

By Franklin M. Grynkewicz

As part of the Boston Harbor clean up project, the new 1,000 mgd Deer Island Sewerage treatment plant includes ten 240 feet high egg-shaped "residuals" tanks. Contract documents called for these structures to be supported on 2,600 sixteen inch concrete filled pipe piles. The project site is underlain by highly variable glacial and marine deposits. Subsurface conditions vary from one extreme where firm glacial deposits exist at subgrade to the other extreme where 70 feet of medium stiff clays overlying weathered bedrock must be dealt with. The most common profile consisted of 15-20 feet of sands, 20-40 feet of marine clays, and 20-60 feet of stratified glacial deposits (commonly called tills) overlying Argillitic bedrock. Post bid redesign work, initiated as a cooperative effort between the owner and the general contractor, demonstrated that an $8 million savings could be realized if high capacity 48 inch diameter caissons replaced the specified pipe piles. A highly unusual arrangement of having the general contractor and specialty subcontractor providing input to the owner's engineering team allowed the redesign work to proceed on a "fast-track" schedule.

Jan 1, 1992

By Y. Luo

Surface subsidence monitoring is the most effective means for investigating the nature of, and developing the techniques for predicting, the surface movement and deformation process. However, because of imperfection in survey equipment and field practices, the surface movement data collected from field survey are not error-free. Also due to lack of proper numerical techniques for computing surface deformation from the measured surface movement data, a relatively large portion of the subsidence data collected could not provide more information other than surface movement. In this paper, the sources and magnitude of errors in the measured surface movements and calculated surface deformation are discussed. Techniques for improving the accuracy of the calculated deformation indices (i.e., slope, strain, and curvature) are developed. The proposed techniques include: (1) proper selection of monument spacing for subsidence monitoring; (2) a data smoothing technique for data pre-processing; and (3) a number of numerical methods and/or procedures for calculating surface deformation indices from the measured surface movement data.

Jan 1, 1992