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By Larry Whittle

Gold milling activities generate waste streams containing dissolved metals and cyanide, among other contaminants, that require some form of treatment prior to discharging to the environment. To date, this treatment has involved the destruction of cyanide through natural degradation, chemical oxidation, or a combination of both followed by the precipitation of metal hydroxides. Although these processes have been proven to be capable of achieving. regulatory levels for metals and cyanide, they often generate significant levels of cyanate and, at times, ammonia, that may be toxic to rainbow trout and thus undesirable for regulatory compliance. Tallon Metal Technologies Inc. (Tallon) has developed Vitrokele™, a chelating resin that has the ability to capture metals (including gold), both total and weak acid dissociable cyanide, as well as thiocyanate from both slurries and solutions. The loaded resin is eluted and returned to the recovery circuit while metals and cyanide are recovered from the eluent stream. This process was demonstrated at pilot scale at B.P. Resources' Hope Brook Gold Mine in Newfoundland, and more recently at Canamax's Bell Creek Mine near Timmins, Ontario. The results from these pilot programs showed metal and cyanide recoveries of 99% or more with the concentration of cyanide and metals in the effluent reduced to levels with minimal or no toxicity to rainbow trout. Furthermore, neither cyanate nor ammonia were generated from the process. The loaded resin was effectively stripped and re-introduced to the recovery circuit; cyanide was captured in the eluent stream and made available for recycling to the mill leaching circuit; and metals were captured for re-use, sale or disposal. This paper summarizes the results obtained from the pilot tests at the Bell Creek and Hope Brook Gold mine sites.

Jan 1, 1992

By Thomas M. Goodell, Timothy D. Arnold

Dilute-phase pneumatic conveying has been used in the mining industry since the 1920s. It has primarily been used for the hoisting of coal and salt ores, and as a transportation medium for backfill material. More recently there have been investigations into a wider variety of applications, which this paper addreses. The paper will point out some deficiencies in the system. It 1s not the "champion" of the mining industry, but rather an excellent srste?1 with a variety of applications that may not have been studied m enough detail. The most imaginative applications to the Redpath Pneumatic Conveying System have been initiated by persons needing an innovative application to a specific predicament.

Jan 1, 1992

By C. A. Fleming, C. J. Ferron, E. S. Makande, P. Mason

Several small mines are producing refractory gold concentrates in Zimbabwe and, owing to the small scale of most of these operations, their output is processed in a central custom roaster in Kwekwe. Owing to the wide variations in the feed to the roaster, the efficiency of the old Edwards roaster is deemed unsatisfactory with gold recovery from concentrate as low as 70%, and alternative processes were evaluated to improve this situation. Various processes for oxidizing refractory arsenopyrite/pyrite concentrates to liberate gold prior to cyanidation are known. In practice, only two have to date met with wide industrial acceptance, pressure oxidation and roasting. Owing to the ·high arsenic and antimony levels of some concentrates in Zimbabwe, the only viable roasting alternative would be two-stage air-roasting of concentrates in two reactors, as practiced at Giant Yellowknife, Campbell Red Lake and New Consort. This process, however, creates an arsenic disposal problem, and produces gas of fairly low SO2 content, requiring a large gas handling system for acid production. On the other hand, there are currently four commercial pressure oxidation plants treating refractory gold ores (McLaughlin, Mercur, Getchell and Goldstrike) and three treating concentrates (Sao Bento, Porgera, Campbell). One other concentrate oxidation plant is being constructed (Con), and several more are being considered.

Jan 1, 1992

By J. Jeremy Burden, Bruce S. Brown

A major question in the design and permitting of a tailings storage facility is the quality and quantity of seepage which will occur from the base of the tailings facility into the underlying foundation and groundwater regime. A corollary to this is what liner system, if any, is necessary to protect the groundwater regime from unacceptable contamination. Modern tailings storage facilities are generally designed as drained tailings deposits whereby all free water is removed from the facility by decant, drainage and evaporation. This removes the source of on­going seepage and allows for efficient and timely reclamation of the facilities. Quantifying the residual seepage from the base of the tailings deposit is complicated due to the following factors:

Jan 1, 1992

By Kenneth L. Myers

The net balance of the inflow and outflow of water in a tailings storage facility has major economic implications in any large mining and milling operation. In a net precipitation environment it can control the ultimate size and storage capacity of a facility or dictate the need for an expensive treatment and discharge program. In a net evaporation environment it can control the extent of the water rights acquisitions required for makeup water and dictate the number and size of expensive wells and pumping and delivery systems. The elements considered in a water balance analysis include the anticipated production rate, the water content of the slurry used to deliver the tailings, inflow from precipitation and snowmelt, and losses from evaporation and seepage. The mine can exert significant control over only one of these elements: the production rate. All others are subject to considerable uncertainty from month to month and year to year. The traditional approach is to analyze in a spreadsheet environment by making simplifying assumptions and using monthly mean or "average" values for precipitation inflows and evaporation losses. Often the analysis will be repeated with values subjectively assigned to represent a "wet" year or "dry'' year. The probabilistic approach uses the same basic spreadsheet model in conjunction with a probabilistic simulation add-in program allowing probability distributions to be substituted for any of the deterministic variables. The resulting analysis shows the full range of variation possible for each parameter of interest (i.e., available return water, makeup water required, storage, seepage losses) and estimates the exceedance probabilities for each. The potential uses and advantages of the probabilistic approach are discussed.

Jan 1, 1992

By W. Baguley

There are many carbon-in-pulp and resin-in-pulp screening devices which are at present in use in the South African mining industry. Each one of these screens has been an improvement, from the very basic air cleaned and 'EPAC' types which were either circumferential or · diametrical launder screens, which were developed for C I P in the early 1980's, through to the more sophisticated LAP and Kambalda Screens. Each one of these screens not only increased the performance or throughput per square metre than its predecessor, but also addressed maintenance problems, wear, reliability and the ability to handle surge conditions, thereby preventing tank overflow. However, very little theory has been presented concerning, the flow of pulp through internal screens, carbon loss and screen wear rates. Almost all this information is based on empirical data. The NKM screen continued this trend and was able to offer flow rates in excess of 180 cubic metres per square metre of screen per hour and an average screen life of approximately six months. However, with increasing sophistication of the screen and the use of wedge wire as opposed to the normal woven wire, the mass was significantly increased and costs began to mount. Therefore, Mixtec undertook to develop a radically different screen, which incorporated many of the advantages of .the existing equipment and combined a few of its own.

Jan 1, 1992

By J. Patrick Glynn

The paper compares the METSIM model simulation and the actual operating data at Sleeper Gold Mine in Nevada. The simulation utilized by the model is a combination of Bond's models, models for breakage and selection functions and the Krebs model for cyclones.

Jan 1, 1992

By Gail I. Bakker, Mark E. Smith, George Sintay, Allan Young

The Snow Caps mine was an open pit and conventional cyanide heap leach gold project located 10 Km east of Independence, California in the Owens Valley. The project is unique in that it is one of the first projects to go full-cycle, from design through closure, under California's Chapter 15 mine waste regulations adopted in 1984. The property was acquired by Sunshine Mining Company in 1985. During 1986, final design and permitting were completed and the facility was commissioned in 1987. Mining continued to mid - 1990, when the minable ore body was depleted, and heap leaching continued into early 1991. Rinsing of the spent ore was completed in 1991, and final closure will be complete in 1992. The spent ore will be left on the leach pad for its final disposition. The focus of this paper is the permitting and closure aspects of the project as required by California's Chapter 15, Article 7 regulations.

Jan 1, 1992

By F. W. DeVries, J. Brent Hiskey

The search for noncyanide lixiviants for treating gold and silver ores and concentrates is not a new endeavor. However, in recent years, the overall activity to seek a less environmentally controversial reagent than cyanide has occasioned considerable developmental work. While the elegant economy and simplicity of cyanide, because of its selectivity and the ease of recovering gold and silver from the cyanide complexes, is well recognized, two failings have justified the search for alternates: increasing concerns and costs to assure avoidance of environmental damage from cyaniferous liquids and solids, and the need to simplify recovery of gold and silver from refractory ores. Generally, process development work to date on the alternate reagents has lacl<::ed environmental focus ( Hiskey and Devries, 1992). This paper covers briefly the chemistry of various alternates to cyanide and reviews their environmental implications. In each case, environmental overtones are reviewed following the chemistry. For ease of follow-up, the authors have listed sources of information in detail. Alternates examined include:

Jan 1, 1992

By Frank Kitzinger, Jacques Nantel

Under special circumstances, electrical energy can successfully replace chemical ex­plosives for blasting rock. High pressure plasma can be generated in the confines of a drillhole, by a powerful electrical dis­charge. The energy level can be adjusted to replicate the effect of a high explosive. The main difference is the almost total ab­sence of gas generation with electric blast­ing. Once the rock fractures, the small amount of matter used for generating the plasma rapidly cools off and regains its former volume. High speed film studies clearly show, that the initial speed of blasted rock fragments is the greatest, no further gas propelled acceleration takes place .. Figure 1, shows a typical electric blast of an oversize boulder of quarzite in an open pit mine.

Jan 1, 1992

By Mark Godfrey, Wickus Slabbert, Debra Miller, Dave Dew

Sao Bento Mlnerai;;ao Mine (SBM), located 100 kms northwest of Belo Horlzante, Brazil, was commissioned In 1987t1l to produce 185 kg per month of gold from 240 tpd of refractory sulphide flotation concentrate. The concentrate Is processed by a Sherrill Gordon design pressure oxidation circuit followed by conventional CIL gold recovery process (Flgur .. J). The original plant design foresaw expansion to 480 tpd, and In this regard the acidic effluent neutralisation, CIL and carbon circuits were designed for future expansion to treat the higher tonnage. The pressure oxidation section was sized for 240 tpd with the Intention to double the Installed plant equipment to provide 480 tpd capacity when required. This decision was based In part on the novelty of pressure oxidation to treat refractory sulphide concentrates in 1984 when the process design was finalised. General Mining, Metals & Minerals (Pty) Ltd (GENMIN), has been actively Involved for the past 30 years in the development of bacterial process for the oxidation of refractory gold concentrates; the results of this development program have provided the registered process BIOx®. The successful Implementation of BIOx® technology for treatment of refractory gold concentrates at GENMIN's Fairview Mine In October 1986t2l, as well as the substantial experience accumulated in laboratory and pilot testing of some 40 other sulphide concentrates, Justified reconsideration of the oxidation process best suited to provide the Incremental sulphide oxidation capacity planned for SBM.

Jan 1, 1992

By Jean Paul Duterque, Morris J. V. Beattie

In many parts of the world, pyrite and arsenopyrite occur together in sulphide ores either as the only sulphide minerals or in conjunction with other valuable sulphides. It is desirable to produce separate concentrates of the various sulphide minerals, including pyrite and arsenopyrite, so that the contained desirable metals can be recovered economically. It is common, for instance, for gold in an ore containing both pyrite and arsenopyrite to be associated almost exclusively with the arsenopyrite. It is desirable in this instance to produce an arsenopyrite concentrate for gold recovery while rejecting the barren pyrite.

Jan 1, 1992

By William M. Schafer

Mining projects which contain sulfide mineralization face increasing regulatory hurdles due to environmental concerns over acid rock drainage (ARD) and the ability of long-term reclamation to protect water quality. Among regulatory agencies, much of the perception about sulfide projects has been based on conditions at historic mining sites at which little or no effort was made to control ARD. With proper design measures, ARD production can be greatly reduced or eliminated. The science of ARD prediction and control must be expanded to enable mine planners to anticipate the effect of various facility design options on ARD potential. Some common-sense examples of geochemical prediction techniques and mitigation measures for waste rock dumps, spent ore heaps, and mine pits are described.

Jan 1, 1992

By P. R. Altringer, R. H. Lien, B. E. Dinsdale

The Bureau of Mines, U.S. Department of the Interior, is investigating biodegradation of cyanide as a means of decommissioning heap leach operations. Biological oxidation decreased weak acid dissociable (WAD) cyanide in process solutions from 50 to 170 ppm down to 0.1 ppm. The tests were conducted both in trickling column reactors, using quartz as the growth surface, and in upflow columns, using activated carbon as the growth surface. In addition, exploratory tests indicated that bacteria will destroy residual cyanide in leached ore. A flowsheet has been proposed for closure of heap leach operations in which the metals processing portion of the plant, possibly the carbon adsorption columns, or a collection pond is used as a bioreactor. The cyanide in the process solution is destroyed in the bioreactor and the treated water is used to rinse residual cyanide from the spent heaps. The water is recycled until the effluent WAD cyanide concentratio� meets discharge standards.

Jan 1, 1992

By A. B. Phillips

The Randfontein Estates Gold Mining Company (Witwatersrand) Limited (REGM) operates three metallurgical complexes for the recovery of gold from the Witwatersrand Gold Reefs at the town of Randfontein, 40 kilometers west of Johannesburg. Mining operations in the. area commenced in March 1889 and ceased temporarily in 1965 when the viable ore reserves had been depleted. Exploratory drilling in the 1960's indicated viable deposits of gold in the Elsburg reefs, south of the Witpoortjie Horst Block, _which formed the Southern limit of the previously exploited areas. Three shaft complexes have been established to exploit this area, known as the Cooke secti'on. In 1983 the Doornkop shaft was sunk to the north of the Cooke section to mine Kimberley reef and the South reef.

Jan 1, 1992

By Stuart K. Nicol, Malcolm D. Engel, Neville T. Moxon

Ion flotation of gold is a process continuing to be developed to selectively beneficiate dilute aurocyanide liquors using a novel surface­active complexing agent. Aeration of these liquors causes accumulation of the precious metal species in the froth concentrate produced in a flotation column. Successful development of ion flotation for concentrating solids-free liquors would offer a low--cost method for recovering specific metals from heap leach runoff or waste tailings solutions. The cost of constructing and operating a 100 tph gold ion flotation facility has been compared with the relevant carbon adsorption plant costs. Reductions in operating costs of 25% and installed capital of 40% are possible in relevant expenditure areas. For an 'average' processing plant, this equates to annual operating savings of A$ 170 000 and a capital saving of A$ 515 000, with a three-point increase in total (mine and plant) site DCF ROI. High gold inventories are eliminated and the number of processing steps is reduced. The application of gold ion flotation will initially be confined to heap leach operations in the western U.S.A., although use of the process in mine abandonment programmes elsewhere is also an area of future development.

Jan 1, 1992

By Peter Krag, Rob Henson

It is well known that titanium and zirconium alloys offer superior corrosion resistance in the oxidizing sulfuric acid environments present in sulfide pressure leaching operations. The use of these materials is limited, however, due to their pyrophoricity; several accidents attributed to titanium equipment have been described in technical literature, and other, minor incidents·occur regularly1 • We describe an application of a commercial titanium alloy, Nb-55 Ti, with suitable mechanical properties, corrosion resistance similar to Grade 2 Ti, and featuring a significantly reduced field of ignition conditions

Jan 1, 1992

By Richard H. Follis

Activated carbons used for precious metal recovery from carbon-in­pulp (CIP), carbon-In-leach (CIL) and carbon-in-column (CIC) circuits often become fouled with Inorganic precipitates (i.e., CaCOa, CaS04, SI02), and adsorbed organics (I.e., petroleum distillates from lubricants, dissolution products from wood) (1,2). These contaminants occlude carbon pore structure, such that diffusion controlled adsorption and desorption (elution) of Au(CN)2-and Ag(CN)2· are lmpeded(3,4l. Thus, after only short exposure to the hydrometallurgical environment, the characteristic carbon activity is reduced(5l. By frequently regenerating circuit carbons, activity losses associated with fouling can usually be minimized. Regeneration typically Involves (not necessarily Is this order): 1) elution to remove adsorbed ionic species (e.g., until they are removed from the carbon pore structure, Au(CN)2" and Ag(CN)2-are contaminants )(6l; 2) acid washing with 3-15% (wt/wt) hydro­chloric acid, to dissolve soluble Inorganic precipitates such as CaC03; 3) neutralization and/or water rinsing to remove residual acid; 4) thermal regeneration at 350-650 °C to remove adsorbed and/or pyrolyzed organ­ics; and 5) screening to remove fine carbon particles produced by Impaction and abrasion in the various stages of the hydrometallurgical circuit (i.e., adsorption, elution, and regeneration). The overall process Is purposed to reopen the circuit carbon pore structure, and to maintain the activity and qualities of virgin (new) carbon(7,8l. While most CIP, CIL and CIC operators regenerate circuit carbons, few evaluate the effect of the process on carbon quality in a systematic way. Process control usually Involves Iterating critical regeneration parameters such as: acid concentration; time frames for acid washing and water rinsing; and temperature and residence time for thermal regeneration. Carbon quality control frequently comprises only sporadic activity tests performed on non-representative grab samples dipped from conve­niently accessed carbon storage bins. So, regenerated carbon quality may vary and (at times) be unacceptable for effective hydrometallurglcal circuit operation. To verify the efficacy of the regeneration process and assure accept­able adsorption and elution rates for Au(CN)2· and Ag(CN)2·, operators should systematically assess regenerated circuit carbon quality. This paper, then, suggests methods for effectively assessing circuit carbon quality, Including: carbon sampling procedures; standardized physical and chemical test methods; and criteria and general procedures for comparative adsorption rate (activity) testing. Also, a two tier quality control testing scheme is proposed, and techniques for presenting and interpreting test data are demonstrated.

Jan 1, 1992

By W. Baguley, L. P. H. Greenhalgh, R. P. Riley

The traditional impeller system for aeration and suspension of slurries, e.g. in bacterial oxidation plants, is the vertical flat blade turbine (VFBT) . This type of impeller is energy-intensive, which results in a heavy-duty design of shaft, gearbox and drive. The Mixtec BX04 agitator development programme is designed to evaluate the use of the new generation of hydrofoil impellers which consume less power and thus have potential for capital and operating cost savings as well as being possibly less damaging to the bacteria. The early tests on pyrite oxidation in a 300 litre laboratory pilot tank using the Thiobacillus ferro oxidans bacteria, showed that hydrofoil impellers had superior characteristics to the VFBT impeller and to air-agitated pachucas, with lower energy input. The geometry of the air sparge ring was found to be very important in optimizing the system. These early successes resulted in a prototype impeller and sparge ring beinq tested in a 9m3 tank where oxygen uptake in water, impeller cavitation at different impeller speeds and air flows were evaluated. Resulting from this work was the supply of an agitator unit to an operating bacterial oxidation plant where it has been successfully evaluated. This paper describes the development work so far carried out

Jan 1, 1992

By Somia Gurunathan, Harry Castrantas

Hydrogen peroxide and calcium peroxide are used to improve the extraction of gold/silver and reduce cyanide consumption in heap leaching and mill leaching operations. FMC's standard grade H2O2 and FMC's Permeox™ solid peroxygen, a formulated product containing cao2, was used for the experimental work. It was found that the rates of release and the longevity of these peroxygens in ore-cyanide mixtures are significantly different. When choosing a peroxygen, one of the key factors is extrac­tion time, with the longer extraction times of heap leaching primarily favoring calcium peroxide and the shorter extraction times of mill leaching primarily favoring hydrogen peroxide. A series of laboratory leach tests showed the choice between H2O2 and CaO2 to be ore and process specific. H2O2 and/or Permeox™ improved the gold extraction in four out of five ores tested. (2 sulfide and 2 oxide). Mixtures of H2o2 and Permeox™ were also found to significantly increase the gold extraction rate. A fifth ore (sulfide) did not respond to peroxygen treatment. In addition, savings in NaCN consumption was obtained with Permeox™. Both peroxygens offer economic incentives to gold processing.

Jan 1, 1992