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By J. C. Vreugdenburg, W. A. H. Poppmeier

An overview of methods of manufacture is presented, as well as the results of laboratory experiments on the making of stainless clad steels. , It is concluded that stainless clad steel can be made in South Africa with existing rolling equipment, and that good bonding between the two materials depends on clean mating surfaces, proper edge welding, and a minimum reduction of 25 per cent at a rolling temperature of 120O"C. In practice, a minimum reduction of 70 per cent at 1100cC is recommended. : Suggested applications for clad steel include parts and equipment for the chemical, petrochemical, marine engineering, and mining industries, for the building sector, and for household appliances.

Jan 1, 1991

By William Petruk

The capabilities of SEM/image analyzers for determining quantitative mineral data which have a bearing on extractive metallurgy have given applied mineralogy a new dimension. The capabilities include automatic mineral identification, unattended operation, search for rare minerals, and measurements of (1) mineral quantities, (2) grain and particle size distributions, (3) liberation characteristics of minerals in ground ores, and (4) mineral associations. Data on mineral quantities define the distributions of elements among minerals, provide background information on characteristics of the samples, and provide a data base for a mineral-materials balance. Size analysis data of the minerals in unbroken ores are used to predict the grind required to liberate minerals. Data on liberation analysis can be used in many ways. One application is to process the image analysis data for feed, concentrate and tails by a materials balancing technique to calculate the recovery of liberated and unliberated grains at each point in a circuit. The calculated recovery data define the behaviour of an ore in a concentrator, pilot plant or bench test, and indicate whether recovery improvements are possible and/or feasible for a particular ore.

Jan 1, 1991

By James D. O, DeLa&apos

Multicomponent materials are common in nearly all areas of materials science and technology, yet the use of phase diagrams to represent these complex systems is hampered by the requirement of three or more dimensions for explicit graphical representation. In the present work, the "solid-modeling" capabilities of a computer aided design (CAD) system have been applied to the representation of three-dimensional phase diagrams. Relevant phase diagrams for a hypothetical quaternary eutectic system were constructed and used to demonstrate the capabilities of the technique. These capabilities lead to relative ease of phase diagram construction and improved access to qualitative and quantitative information. Results of this work are contrasted and compared to previous efforts toward computer ,representation of phase diagrams. It is concluded that solid-modeling of three-dimensional phase diagrams can be used to advantage in both education and research.

Jan 1, 1991

By J. Markussen

The Falconbridge Matte Leach Plant was based on leaching Ni-Cu matte with strong hydrochloric acid in rubber lined equipment. It operated from 1968 to 1983 as a precursor to Nikkelverk's present C12 Leach. The process comprised two S.X. systems. NiC12.4H20 crystallization, crystal drying, NiC12.H20 pyrohydrolysis and HC1 gas recovery. The naphtha fired fluid bed pyrohydrolyzer produced granular NiO, subsequently reduced with H2 to granular nickel for sale. The development and operation of the pyrohydrolyzer are described

Jan 1, 1991

By James E. Fisher, Roger Cotton

"The legal background f or environmental issues, and the growing emphasis both from government and private concerns of corporate and management liability for environmental problems provides one of the driving forces behind the growing concern with environmental law for the future. One prime objective must be the identification and minimization of potential liability, both for the corporation and its officers, directors and employees.This paper will identify the basis for liability of individuals and corporations for environmental matters, focussing on current legal requirements, and the appropriate legal response to events of such potential liability. It will also consider the reduction of liability through the implementation of management systems and environmental policies in order to ensure due diligence both with respect to corporate responsibility and the responsibility of the individuals within the corporation.IntroductionConsolidated Professor Mines Ltd . and its predecessor have been exploring in northwestern Ontario for about sixty years . During the last twenty years, the company has been interested in developing a gold mine, the Duport Project, on Stevens Island in Shoal Lake . The lake straddles the border between Ontario and Manitoba and is a drinking water supply for Winnipeg and environs.The Duport Project involves the mining of 450 t/day grading an average of 0.35 oz Ault of ore . At the minesite, located on Steven s Island in Shoal Lake, only preliminary processing of the ore will take place, to produce gravity and flotation concentrates for final gold recover y at a mainland plant well removed from the Shoal Lake watershed. No hazardous chemicals will be used at the island site."

Jan 1, 1991

By C. J. Bise

Continuous mining accounts for about 69% of the nation's underground coal production. This level is not expected to change much in the near future. This is because continuous mining represents the primary means of under- ground coal production. It is also the primary means of driving development entries for underground coal mines, including longwall mines. The continuous miner worksite contains many characteristics that can lead to personnel accidents. It continues to be an area of concern for mine managers, safety engineers, and training coordinators. In an effort to assist mine management in attempts to reduce the number of accidents and injuries sustained in this area, this paper presents a loss-control-based, non-intrusive strategy for conducting safety evaluations at continuous miner worksites.

Jan 1, 1991

By P. R. A. Andrews, R. K. Collings

"There are more than thirty-five deposits or occurrences of celestite in Canada, chiefly in Newfoundland, Nova Scotia, New Brunswick, Ontario and British Columbia. Deposits of economic interest are the Lake Enon and MacRae deposits in the Loch Lomond district of Cape Breton Island, Nova Scotia. Two Cape Breton deposits were operated from 1969 to 1976 by Kaiser Celestite Mining Limited, which supplied an upgraded celestite concentrate to an associated strontium carbonate plant at Point Edward, near Sydney.The MacRae deposit is of current interest because of its possible development for strontium carbonate production using the ""black ash"" process. This process involves chemical leaching, rotary kiln calcining with petroleum coke, washing and treatment with carbon dioxide.Celestite is the basic material used in the manufacture of strontium chemicals, principally strontium oxide, carbonate, nitrate, chromate, chlorate, chloride, sulphide and phosphate. Strontium chemicals, in turn, are used in the manufacture of glass and ceramics, in pyrotechnic devices, in the production of strontium metal and in other metallurgical applications. Recently, strontium ferrites have been introduced into permanent ceramic magnets."

Jan 1, 1991

By T. Chong, R. Pesalj, B. Marchant, Z. Nikic

"The Mount Polley copper/gold project is located in central British Columbia and is currently being developed by Imperial Metals Corporation. Extensive laboratory and pilot plant testing was required to develop acceptable metallurgy for recovery of both sulphide and oxide copper-gold mineralization. Copper recovery is highly sensitive to oxide copper content of the feed whereas gold is primarily associated with the copper sulphide minerals. A conventional flowsheet where sulphide flotation is followed by sulphidization and oxide scavenging is described. The conventional flowsheet was used in a feasibility study which resulted in a favourable production decision at Mount Polley. Detailed engineering and permitting are in progress.More recently, laboratory and pilot testing of a new flotation reagent, S-6493*, an oxide specific collector, has indicated that improved copper recovery can be accomplished with reduced reagent consumption, including elimination of the sulphidization step, using S-6493 compared with the conventional flowsheet. The comparative metallurgical results using S-6493 and conventional sulphidization methods are presented, from both bench scale and pilot testing. Comparative economics of the conventional flowsheet and that using S-6493 are also presented. Advantages of S-6493 include reduced reagent costs, increased revenues from additional copper recovery, and overall reduction in capital and plant operating costs due to the simplified flowsheet. INTRODUCDONThe Mount Polley copper/gold property is located in Central British Columbia, 56 air kilometres northeast of Williams Lake. The first recorded exploration was in 1964. By 1989, a total of 238 diamond drill holes, totalling 27, 522 meters, was completed to detail reserves on the Mount Polley prospect. A number of drill core composites were submitted, containing a variety of oxide copper levels, for metallurgical flowsheet development. Six bulk samples were collected from surface trenches for additional bench scale testing and for pilot plant testing."

Jan 1, 1991

By D. III Earley, R. L. Blake

The Bureau of Mines is investigating the potential for in situ mining (ISM) of gold and silver mineralization. This preliminary study examined samples from several types of deposits. It used light optical microscopy and the electron microprobe to characterize the ore and gangue minerals and textural features of these samples. This included the spacial relations between the target minerals and likely natural fluid channel ways. Low-grade disseminated deposit types from the western US were found to contain fracture- hosted or matrix-hosted gold and silver minerals, some of which are encapsulated by quartz or pyrite. Successful ISM application to gold and silver deposits needs this data in order to understand potential problems of the lixiviant reaching the ore minerals.

Jan 1, 1991

By Aureo D. V. Machado

An experimental study to obtain zirconia powders (ZrOz) from carboxylate zirconium solutions followed by hydrogen peroxide stripping and precipitation, has been carried out. Zirconium carboxylate was prepared by solvent extraction from a chloride aqueous phase using magnesium carboxylate as organic phase. The variables examined in the precipitation reaction were: Temperature: 25 - 90 ?C ? H202= concentration: 0.3 - 5% wt/wt - pH: 1 ? 9 Organic/Aqueous ratio (1/1) and reaction time (30 minutes) were maintained at constant levels. The optimum results (98% precipitation) were achieved at 25 °C, 5 % wt/wt H202=, and pH = 5. The precipitates were composed of large amorphous aggregates (<I00 micrometers). After calcination for 1 hour at 1000 OC, monoclinic ZrO2 with a large variation in particle size (1 -100 micrometers) was obtained.

Jan 1, 1991

By S. Banisi, J. Marois, A. R. Laplante

"This paper compares the behaviour of gold and ore in the grinding circuit of Hemlo Mines Ltd. Particular attention is given to grinding kinetics, classification behaviour, and liberation. For grinding kinetics, laboratory grinding of gold flakes and silica, 840 µm to 1200 µm in size (14/20 mesh), was also performed to provide a standard for comparison and to study in a controlled environment the mechanisms of breakage, folding , smearing and impacting.Grinding kinetics were characterized at laboratory scale with breakage and selection functions. The breakage function showed that 75% of gold disappearing from the 840 µm to 1200 µm class reported to the 600 µm to 840 µm; this figure is much higher than for silica (46%) or most other minerals, and implies that comparatively fewer fine fragments are produced from the breakage of gold flakes, on account of gold&apos;s malleability. The selection function of silica was four times that of gold. At plant scale, the ratio of the selection function of ore and gold increased from 6 for at 50 urn to JOO pm to 20 at 500 um to 1000µm.Observation of original flakes and their fragments with the scanning electron microscope showed that the main mechanism of ""grinding"" from the 840 µm to 1200 µm to the 600 µm to 840 µm class was folding rather than actual breakage. This was confirmed by a measure of individual flake weight. The postulated breakage cycle is that relatively globular flakes become increasingly serrated through grinding; they can then regain their original shape through folding and reflattening into cylindrical and spherical shapes, as the majority does; however, some fragments will at this point undergo actual breakage. Photograhic evidence is presented to support the proposed mechanisms.Smearing of gold unto silica was observed when silica was ground after a gold, and embedding of silica into gold flakes when gold was ground after a silica. Both mechanisms occur whenever gold and harder minerals are jointly ground, and result in ""unliberation"" of gold. It is postulated that smearing of gold onto other minerals plays an important role in explaining how gravity recovery can increase over-all gold metallurgy, especially when used ahead of flotation.Classification of gold in the primary hydro cyclones takes place at a much finer cut-size than ore, 20 µm vs 57 µm. This and the slower grinding kinetics result in high gold circulating loads in the primary loop, 6700%, and a gold content in the primary cyclone underflow (PCUF) is twenty-four times that of the ore. The gold size distribution for primary cyclone overflow is much finer than that of the ore, although they are essentially similar in the PCUF.Liberation, or more accurately ""gravity recoverability"", was assessed with a 7.5 cm (3 in.) Knelson concentrator. It varied between the thirties for the primary mill discharge and two cyclone overflows, to highs of 89% and 92% for the PCUF and secondary mill discharge."

Jan 1, 1991

By Dods G. H, Hewitt W. V

Ashton Mining Limited is currently one of the active companies undertaking gold exploration in Indonesia. Presently 7 Contract of Work areas are being explored for hard rock and alluvial gold. Hard rock exploration is focussed on the Tertiary volcanic arc terrains in which a variety of epithermal mineralisation styles have been identified. At the regional stage remote sensing techniques using Landsat, Spot and SLAR imagery where available, and photogeological studies are carried out in parallel with regional reconnaissance fieldwork programmes. These involve geological mapping and geochemical drainage sampling. Remote sensing techniques have proven useful in both the extrapolation of known geology and the identification of tectonically favourable settings as controls to mineralisation and volcanicity. The variety of mineralisation styles and settings is reflected in the highly variable geochemical signatures encountered. This has necessitated the refinement of sampling methods and sample preparation techniques for pan concentrate, stream sediment and soil samples in specific project areas. At the detailed prospect stage, mapping with particular attention to structural controls, wallrock alteration assemblages identified by petrog- raphy and XRD clay mineralogy, have proved useful in focussing drill targets. Drilling to date has utilised conventional diamond core drilling methods, the use of lightweight, man-portable "Winkie"-type rigs and hammer auger bedrock sampling systems. Geophysics methods successfully employed on various projects have included airborne magnetics and radiometrics, detailed ground magnetic surveys, VLF-EM and SIROTEM.

Jan 1, 1991

By R. C. Bryan, D. B. Jamison

This paper describes a procedure for minimizing the operational costs associated with blending sodium in coal at a surface mine in the Powder River Basin. Mine site blending is performed by adjusting daily production rates for high- and low-sodium pits. These adjustments are designed to produce a consistent sodium value called the blending target. The mine&apos;s contractual limit for sodium is sufficiently close to the field average value that any decrease in the sodium blending target may result in an opportunity cost, if the number of potentially minable tons is reduced. Conversely, any increase in the blending target may result in a higher sampling cost if more information is required to keep the blend within contractual limits. Blending parameters were defined using a geostatistical block model of sodium content that was based on analyses of hundreds of in-pit sample holes. Variograms for these data were used to compute the marginal costs of opportunity and sampling for a series of hypothetical in-pit drilling patterns. These marginal costs provided a basis for selecting optimum values for key parameters such as the blending target, production variance and in-pit sampling density. The benefit of implementing these optimized parameter values is that operational costs of sodium blending will be minimized over the long-term. At the mine where this procedure was developed, each dollar spent to increase the sampling density to the optimum value was shown to generate a $10 savings in opportunity cost.

Jan 1, 1991

By Svante Lundbrink

A new generation hydraulic rock drill featuring more than 50 percent higher performance than other drills has been introduced by Atlas Copco. In conjunction with the new rock drill, control systems have developed and refined to handle the higher drilling output, and to maintain an acceptable service life of drill string components. These improved features are built into the Rocket Boomer, a new high-performance drill rig, used at the recently completed Hanging Lake project in Colorado. Experiences from this project will be reported together with results from a highway tunnel construction project in Italy.

Jan 1, 1991

Cordeaux Colliery is more logically sited than the historic escarpment Corrimal Colliery, on the same reserve. At Cordeaux the modernisation of mine plans and equipment and the introduction of high production longwalls have created a record achieving producer of both steelmaking and export coals.Further changes achieved have been in employee related attitudes and performance, enhanced by business strategies and total quality control and particularly benefiting from innovative employee input With this present example of co-operative effort Cordeaux Colliery will continue to improve through management of total quality. resources, development rates and customer satisfaction.

Jan 1, 1991

By J. G. Groppo, B. K. Parekh

A series of performance studies were conducted using countercurrent column flotation to recover a marketable clean coal product from existing preparation plant fine waste streams. The test work was conducted at several preparation plant sites in Kentucky and Virginia using a 150-mm (6-in.) inside diameter column that was 5.8 m (19 ft) high. Both thickener feed and classifying cyclone overflow with a typical size distribution of 150 µm (100 mesh) X 0 were tested. The percent solids of the column flotation feed varied from 1.5% to 15% while the ash content ranged from about 30% to 60%. The concentrates produced contained 2% to 10% ash with Btu recoveries of nearly 90% using 0.12 to 1.25 kg/t (0.25 to 2.5 lbs per st) fuel oil and 0.12 kg/t (0.25 lbs per st) MIBC. These results were consistent with or better than results obtained in preliminary laboratory scale column flotation evaluation. Test results from seven different seams are discussed as well as scale-up relationships used to design a full-scale installation presently in operation.

Jan 1, 1991

By V. Rajagopal

Corrosion and abrasion properties of a series of chromium-containing cast iron balls with Cr contents ranging from 0 to 29% was evaluated and compared with austenitic stainless steel and mild steel balls. Marked ball wear tests were performed on artificial ore samples consisting of 95% quartzite with either 5% pyrrhotite or 5% chalcopyrite under a nitrogen or oxygen atmosphere. The electrochemical mechanism was investigated by correlating the corrosive wear with the corrosion currents obtained from potentiodynamic polarization curves under abrasion. An offset in their electrochemical activities was observed somewhere between 16 and 26% Cr. In fact, 26 and 29% Cr cast irons showed an excellent corrosion resistance approaching that of austenitic stainless steel. Flotation recoveries were estimated on a 95% quartzite + 5% pyrrhotite sample ground with various cast iron ball materials under an oxygen or nitrogen atmosphere. Electrochemical results are found to be in good agreement with corrosive wear obtained from marked ball wear test and with flotation results.

Jan 1, 1991

By K. M. Kinealy, A. R. Ramsden, D. H. French

A negative correlation exists between sphalerite composition and gold content when gold is transported as Au(HS)2(-); however, there are spatial and temporal differences within a single deposit. A previous model for the formation of volcanogenic massive-sulphide deposits within thermally intensifying and waning hydrothermal sytems in much the same way as is observed around modern sea-floor vents is supported. The results also emphasise that recognition of the mechanisms of gold transport in ancient deposits depends critically on an understanding of their mineralogy and stratigraphy

Jan 1, 1991

By C. -S. Jiang

In most copper refineries, addition agents are added at predetermined rates with no further monitoring of their activity or concentration in the electrolyte. Increasingly stringent cathode quality requirements, and a desire for better process control in tankhouse operations, have recently directed a number of refineries to search for a better addition agent control strategy. Extensive development work has been carried out at the Noranda Technology Centre for the monitor in of glue and thiourea in copper refinery electrolyte using cyclic voltammetry (cv~. Data from both synthetrc and commercial electrolytes are presented, showing the ability of CV to produce reliable and easily identifiable fingerprints of addition agent concentrations in copper refinery electrolyte.

Jan 1, 1991

By M. L. Apel

A conceptual approach to the bioremediation of uranium mill tailings (UMT) is presented., This approach focuses on, biosorption to remediate the. effluent solution and bioleaching remediate the. solid fraction. Comparative biosorption studies were performed with synthetic single metal solutions using a commercially available biopolymer. The maximum rate of metal sorption by calcium alginate was found to be 5.43, 6,39, 6.48, and 9.74 mg dm-3 min-1 for U022*, Ba2+, Cd2+ and Zn2+, respectively. Activation energy (AEa) for barium uptake by calcium alginate beads was determined to be 11.5 kJ, indicating a diffusion controlled reaction mechanism. Thermodynamic values (AG+ AH+ and ASt) of the metal-alginate activated complex, as reported in the literature, were found to be in agreement with those calculated from this research. Results show that this biopolymer can be effectively applied in the removal of select metals prevalent in uranium mill tailing effluents and associated waste streams.

Jan 1, 1991