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By Mark G. Aylmore, Eric J. Grimsey

Anenopyrite, both pure and in some cases associated with pyrite, was laboratory roasted either isothermally or at a constant heating rate, at temperatures mainly between 723 and 923 K and under environments of air, sulfur dioxide, oxygen and argon, as well as S02/02/H20/N2 mixtures. The mineralogy, arsenic contents and in some cases surface areas of the calcines were evaluated so as to provide an enhanced understanding particularly of the conditions under which the important transformations to pyrrhotite and magnetite occur. A thermodynamic analysis is also undertaken to rationalize the observations and provide some guidance for the operation of commercial roasters.

Jan 1, 1990

By Thierry De Nys

A direct leaching process of sulphidic zinc-based concentrates in aqueous sulphuric acid solutions has been developed by the V.M. R & D Department. By a very accurate control of the oxidation potential of the leach solution, this process enables a separate recovery of the zinc, copper, silver, lead and sulphur of the concentrate and makes it extremely attractive for treating more complex ores. The iron, solubilized during leaching, is eliminated out of the zinc solution by means of the V.M. goethite process. Alternative flow sheets for a conventional zinc electrolysis plant are presented.

Jan 1, 1990

By R. S. Sheeta, C. J. Bise

The search for a more effective means of coping with methane liberation has resulted in the expanded use of seam degasification. Its advantages are measured not only in reducing the hazards due to methane, but also in producing a marketable commodity, the gas itself. However, the success of a methane drainage system is the culmination of many complex factors, the most important being the coal seam permeability. The two most popular drainage techniques used in mining today are the vertically stimulated borehole method and the in-seam horizontal borehole method. The objective of this paper is to determine the permeability range in which the selection of the degasification technique is based primarily on equipment and economic analysis. A discussion of the equipment involved will be incorporated into examples evaluated by the Pennsylvania State University coal methane simulation model.

Jan 1, 1990

By L. G. Austin, R. C. Klimpel

Batch breakage kinetic tests were performed in a mill of 0.3 m diameter for a range of mill conditions. Accurate simulation required the measurement and use of factors which accelerated the specific rates of breakage of the top sizes as finer material accumulated in the slurry. These factors depended on the size distribution expressed relative to the top size, not the absolute size, suggesting that they are due to a packing effect not a rheological effect. The data simulated correctly a series of steady-state continuous tests in a mill of the same diameter providing values were corrected to the hold-up, ball load, slurry density, and size distribution measured in the continuous mill tests.

Jan 1, 1990

By Bruce R. Sutherland, Jim B. Ramsden, Gerry L. Bolton

Conductive metal powders are important building blocks for today's micro-electronic circuitry. Formulated into inks, they provide the interconnects needed to complete a complex integrated circuit and the means to enter the world of miniaturization. Traditionally, the inks have been based upon expensive metals such as silver, palladium, platinum and gold because of their excellent electrical conductivity and resistance to corrosion and oxidation. The use of a copper based ink, as an alternative to precious metal inks, recently has received considerable attention. Instability in the prices and limited supply of certain precious metal systems have driven up production costs, making the development of a lower cost copper system more attractive to manufacturers. However, lower production costs are on1 y real ized if performance and reliability can be maintained. While the development has been driven by cost, copper does offer some significant performance advantages over noble metal systems: conductivity as good as silver and 4W better than gold; leach resistance better than silver and equal to gold; stability at high frequencies better than gold or silver; strong film bonding characteristics; and compatibility with most solders. These benefits, however, do not come without cost. The inherently reactive nature of pure copper, while providing unique performance properties, makes it difficult to process. Unl i ke precious metals which can be fired in air, copper would oxidize and so requires special furnaces and atmospheres. Despite these difficulties, the transition from precious metal thick film systems to copper is gaining momentum. Manufacturers of high density, high performance circuitry are exploring the performance advantages of copper over gold and silver and the manufacturers of consumer products are considering the potential cost savings of copper over silver-palladium. Sherritt has developed a fine copper powder for this industry. Through association with the ink manufacturers, it has been found that performance properties of the ink vary with the physical and chemical characteristics of the powder. Production Process The production of very fine copper powders at Sherritt is based upon the disproportionation of cuprous ions as outlined in Equation [1] (1).

Jan 1, 1990

By Z. D. Hora

"There has been a number of new developments in British Columbia's industrial minerals field over the past few years. Several new industrial operations were started to diversify the line of British Columbia mineral production by magnesite, perlite and fuller's earth. Industry activities and geological projects have identified occurrences of rare earth minerals, niobium, kaoline, fireclay and zeolites. The Geological Survey Branch significantly improved its database on industrial minerals. New geological concepts based on recent work are opening a number of new opportunities f or further industrial minerals' exploration and development in British Columbia.IntroductionTraditionally, the value of industrial minerals produced in British Columbia in any given year comprises between 100/0and 15% of the combined value of minerals, coal, petroleum and natural gas. Over the years a wide variety of industrial minerals has been produced , often with different levels of marketings success. For some products, such as dimension stone and clay or shale products, initial strong demand gradually dissipated; for others such as asbestos and magnesite, new discoveries or new industrial activities created demand and new markets . In some cases, such as fluorite , talc, pyrophyllite and perlite, wider use has been prevented by small size, poor quality or remote location of the deposits. Also, British Columbia , with 2.6 million inhabitant s, provides only a limited market and the industry therefore has to look beyond provincial borders."

Jan 1, 1990

By D. K. Storer, W. Lee, S. Tkach

"A microcomputer-controlled multi-probe K-40 monitoring system was developed internally for the Phase II mill at the Lanigan potash mine. The K-40 probes were mounted in a variety of positions in several process streams, ranging from dry ore on a conveyor belt to brines and slurries. A description will be presented of the objectives, the equipment and the difficulties encountered in correlating results.IntroductionThe successful control and optimization of most metallurgical processes involves monitoring not only physical parameters such as flow rate and temperature, but also the chemical compositions of critical streams. Composition has proven difficult to measure on -line in industrial scale processes. However, in potash processing there is a convenient chemical parameter that has long been utilized to measure in situ the concentration of potassium chloride (KCl). Potassium has a long-lived isotope which is slightly radioactive. K40 decays by beta elimination to Ca40, ultimately radiating a characteristic gamma-ray photon. This gamma emission when detected by scintillation counter can be used to estimate the concentration of potassium in a process stream."

Jan 1, 1990

The projection of operating costs for mining, processing, and other site operating costs is an exercise which can be fraught with considerable peril. Not only are the physical characteristics of each mineral property unique, but a range of other factors will influence the consultant's approach to compiling cash flow estimates. This paper details some of the techniques used in estimating operating costs for use in order-of-magnitude cost studies and feasibility studies, and describes how to avoid common areas of difficulty. A series of examples relating to open pit gold mining and processing cost estimates illustrate these problems, and various corrective methods are described. The mining and treatment processes, and their associated cost elements, are followed in sequence of operation from on-going ore delineation through to disposal of the product. In addition the problem of assigning management, administration and overhead costs along with taxation allowances is addressed. Of critical importance is the application or possible misapplication of accrual procedures to the cost elements. In many cases such misapplication can introduce more pronounced errors with projects of short duration, such as the typical open pit/C.I.P. gold operation commenced in the last decade. The importance of providing verification of estimates depending upon the standard of the cost study is also investigated, and opinion is provided upon the minimum levels of verification necessary at various stages. Finally, the amalgamation of the various individual cost elements into a coherent whole is reviewed.

Jan 1, 1990

By M. J. Walker

The lead .smelter at Cominco's operations at Trail, B.C. has been undergoing. a modernization program since 1986. In that year a contract agreement was reached with German-based Lurgi GmbH which allows Cominco to construct and operate a lead smelter using Lurgi's QSL process. Cominco Engineering Services Ltd. (CESL), a subsidiary of Cominco Ltd., was contracted to provide project management, engineering, procurement and construction management? services for the project. The new smelter replaces the existing sinter-blast furnace plant ?and will have a capacity of up to 1601000 tonnes per year of refined lead. This new smelting proc.ess results in significant operating cost reductions and major environmental .improvements. Start-up of the new plant is scheduled for the fall of 1989. The metallurgy and the operating parameters, important to the design of the new smelter, are described together with projected deportments of lead, zinc, silver and minor metals. A plant description, will be given for the following major areas that make up the modernization project: the pressure filter operation for the preparation of ,zinc leach residues feed material, the QSL reactor and boiler itself, together with its feed system and process gas treatment, and the drossing plant with a new continuous drossing furnace and oxygen softening and thallium removal. Slag from the QSL reactor will be treated in existing slag furnaces until a subsequent second phase of the modernization is completed in the 1990s.

Jan 1, 1990

By Thatcher R

In areas where land suitable for development is a scarce resource, an upgraded post-mining land use can result in economic benefits to both the mining company and to the community.A study undertaken at Aberdare Colliery near Ipswich during 198611987 assessed the costs and benefits of developing the site following mining for grazing, forestry and residential uses. The proposed fmal land use plan comprised a combination of these uses that can be upgraded to higher valued uses once subsidence monitoring of backfilled open-cut areas and dumps indicates that total settlement has reached acceptable levels for development to proceed.The study involved the documentation of existing site environmental parameters and the delineation of site opportunities and constraints. The unpredictable nature of settlement over backfilled open-cuts and overburden dumps represents the major constraint to urban development on mined areas.

Jan 1, 1990

By G. C. Marino

The performance of the V-Day Mine near Danville, Illinois has been evaluated from data extending over about a 20 year period. The area included in this study involves over 16 acres. Essentially this entire area has progressively subsided. Extensive data has been collected on the geologic and mining conditions, the subsidence movements, as well as on the response of the surface structures to the subsidence. In this paper a detailed summary of the site conditions is given, and the mechanics of progressive failure of the studied room and pillar mine is postulated. These progressive long-term failures of the V-Day are then compared to other similar mine failures in Illinois. Some overall, but tentative, long-term strength evaluations are presented as well.

Jan 1, 1990

By Hommert P. J, Brown B

Early attempts at estimation of stress wave damage in blasting by use of finite element analysis met with limited success due to numerical instabilities that prevented calculations from being carried to late times. An improved damage model based on microcrack growth in tension allows finite element calculations which remain stable at late times. Estimation of crater profiles for blasting experiments in granite demonstrate successful simulations with this model.

Jan 1, 1990

By F. M. Boler

The U.S. Bureau of Mines has configured a flexible data acquisition and analysis workstation, which incorporates control and analysis software written in-house for use in mining research experiments conducted in the laboratory and in operating underground mines. This data acquisition system combines computer-automated-measurement-and-control (CAMAC) modular instrumentation with a Unix-based graphics workstation. The data acquisition front-end hardware can be interfaced to almost any computer. CAMAC instrumentation modules adhere to mechanical, electrical, and digital interface standards and can be custom designed or purchased off the shelf. Communications along the CAMAC bus are regulated by the crate-controller module, which contains the only hardware link to the computer interface. Software support for the data acquisition and analysis workstation consists of a series of functions and programs written in the "C" programming language designed to provide flexible and fast data acquisition, processing, and analysis. The user can interactively control the digitizers and other CAMAC modules by sending standard CAMAC read, write, and command function codes from a menu-driven program. Automated data collection is achieved through software that responds to hardware interrupts triggered by acoustic emission or microseismic events. Graphics display routines are used to plot part or all of the data and provide the ability to process and store signal information selectively.

Jan 1, 1990

By Nigel J. Cook

"Detailed mineralogical examination of gold-bearing rocks, ores, concentrates and other samples should be considered an integral part of any study of a deposit for which exploitation is being planned. Adequate mineralogical study, although time consuming and often costly, can significantly improve understanding of the mineralization, can help to optimize the results of any metallurgical testing and can be of great value in case of potential trouble-shooting. The advantages and disadvantages of various examination techniques are discussed with reference to a number oj mineralogical studies oj Canadian gold-bearing samples.IntroductionVarious authors, notably Gasparrini (1983), Harris (1989) and Henley (1990), have stressed that mineralogical study of gold ores is critical to successful and efficient beneficiation. Only in cases where diagnostic cyanide leach testing is successful can detailed mineralogical examination be disregarded. Such examination of gold-bearing rocks and metallurgical products is all too often neglected because the methods involved are believed to be time-consuming, costly, and may carry a considerable degree of inaccuracy. Commonly, bulk metallurgical testing is, carried out without prior or concurrent mineralogical examination, causing the results of the testwork to be difficult to interpret, or in some cases, misleading. This, in turn, may lead to> significant delays to the project at the feasibility stage or mean that understanding of the sample is limited, preventing the introduction of prudent modifications at a later stage if problems arise. Mineralogical studies may guide the successful implementation of a metallurgical test program."

Jan 1, 1990

By William D. Mayercheck

The U.S. Bureau of Mines is conducting research aimed at providing technology for a low-cost, high-recovery, environmentally acceptable mining system to recover the vast thin-seam coal reserves existing in the mountainous areas of the Appalachian region in the Eastern United States. As part of this research, the Bureau is evaluating new techniques to address these coal resources. This report summarizes the results of a worldwide technical search on thin-seam coal mining, the formulation of various methodologies for mining mountaintop thin seams, and the implementation and status of a physical model test program to validate and further develop the most promising concept-the "roof-fall-tolerant" mining system.

Jan 1, 1990

By R. W. Guill

"The Apex Mine is currently scheduled to be brought back into production by Hecla in the first quarter of1990. Its projected productivity rate will be exceptionally high for a small underhand cut and fill mine.The ore mined at the Apex Mine occurs within a pipe-like structure as a series of iron oxides containing both gallium and germanium, plus significant amounts of silver, zinc, lead, and copper.Ground conditions in and around the ore zone have dictated that unique approaches be utilized. To date, these have included a prototype 0.5 cu. yd diesel LHD, and the use of fibrous shotcrete in 4ft by 7ft headings, and the first pneumatically-placed cemented backfill in North America. Above all else, it is the combination of new technologies with a small and dedicated workforce which has allowed for the successful development of this ore body.IntroductionThe Apex Mine is an example of the typical small underground project. It has high grade, but low tonnage and is deposited in poor ground. In such cases, conventional planning and thinking generally results in an uneconomical evaluation and negative production decision. Fortunately, some unconventional thinking was allowed to take place during the planning and evolution of the Apex Mine development. The result now serves as an example of how such unconventional thinking can lead to the type of innovations described below.The job necessitated the development and use of new equipment and materials to execute a highly flexible underhand cut and fill mine design/pneumatic backfill concept, that must be constantly modified as different than assumed conditions become evident in and around the ore zone."

Jan 1, 1990

By Howard W. Kilau

The U.S. Bureau of Mines is investigating surfactants added to water sprays to enhance the control of dust during coal mining operations. The objective of the present work was to establish the general applicability of adding sulfate ion to anionic surfactant solutions in order to improve wetting action. This was pursued through laboratory wettability testing of four anionic surfactants and one nonionic surfactant in combination with various concentrations of sulfate ion. The experimental results demonstrated that the addition of sulfate ion enhanced the wetting characteristics of all the anionic surfactants when applied to hard-to-wet coals, while easy-to-wet coal showed more complex wetting behavior. Sulfate ion in the presence of nonionic surfactant enhanced wetting only slightly or not at all. Surface tension measurements of the dilute aqueous surfactant-sulfate anion solutions indicated this property was not important in coal-wetting phenomena, as long as the value was below the critical value for coal. Sulfate ion helps surfactant reduce surface tension but primarily appears to affect wetting action by altering the adsorption characteristics of surfactant on the coal surface.

Jan 1, 1990

By J. E. Udd, L. B. Geller

"Mine-shaft wire-rope discard regulations include, among other criteria, a limited amount of permissible loss-of-breaking-strength (LBS). Currently, this parameter is estimated on the basis of non-destrutive-testing (NDT) with electro-magnetic (EM) type instruments. This paper analyses the accuracy with which these estimates have, so far, been obtained in practice.It concludes that while certain types of testers have produced better results than others, the desired accuracy level has not been attained. Also discussed are the putative reasons for this situation, and appropriate actions that the mining industry might wish to take."

Jan 1, 1990

By D S. Clarke, K B. Sporli

Structure is an important control in the localisation of gold mineralisation in epithermal systems. There has been, however, only limited investigation of the structural elements involved; such a study is currently directed at the gold deposits of the Coromandel Volcanic Zone (CVZ). Here, mineralised veining and brecciation ranges up to tens of metres in thickness. Dips of veins are mostly steep, but not vertical, and there is a significant number of low angle veins. The structural control of epithermal deposits may be considered on four scales. At the mega-tectonic scale, pre-volcanism fault patterns mostly relate to separation of the New Zealand micro-continent from Gondwana. The major structural controls on mineralisation at this scale, however, are associated with the volcanic arc processes responsible for the CVZ. Post-mineralisation faulting are linked to the Hauraki Rift and the Colville Ridge-Havre Trough system. Regional scale faults controlling the distribution of gold deposits are the product of these tectonic events; much of the faulting may relate to rifting and calderas, but further work is required to demonstrate this. Detailed study is also needed on vein systems at the prospect scale to validate models of brittle deformation responsible for such systems. Evidence that a variety of structural mechanisms dominated in different deposits is found at the vein scale, with Coromandel gold deposits being classified according to their different styles of vein-fill texture.

Jan 1, 1990

By M. Craig Miller

As the trend continues in the U. S. toward inceased capital investment in longwall mining equipment and wider panels. the risk also increases for gotential financial and production loses due to undetected geologic anomalies. This paper describes how RIM Sm (Radio Imaging Method) is utilized in conjunction with more traditional exploration and interpretive methods to delineate fluvial channels. displacement faults and poor roof conditions in a Southeastern Ohio coal mine

Jan 1, 1990