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A non-contacting under-belt capacitance and gamma-ray backscatter technique has been developed for the on-line measurement of moisture in coal. In this technique, moisture was correlated with radio frequency susceptance and conductance determined using an under-belt capacitance sensor in which a fringing electric field Interrogates a layer of coal on the conveyor belt directly above the sensor. To compensate for variations in the density and thickness of the coal layer, an under-belt gamma-ray backscatter gauge was used to measure an equivalent volume of coal.A plant trial of the technique was conducted at Stockton Borehole Colliery, SW Australia, where the gauges were installed on the coking coal product conveyor. Product moistures, in the range 7 - 14%, were determined with r.m.s errors of 0.50 and 0.25 wt% using on-belt and static off-belt gauges, respectively. The difference in the on-belt and off-belt gauge measurement accuracy was attributed to sampling errors in the calibration of the onbelt gauge.

Jan 1, 1989

By P. R. A. Andrews

"Talc ore from Bakertalc, High water, Quebec analyzing about 60% talc, previously dry ground to about 95% minus 53 µm was beneficiated in an 11.4 kg/ h pilot-plant flotation circuit. A concentrate of 95.9% talc (necessary for paper-grade) was obtained at a recovery at 75.3% by employing 53 g/t of Dowfroth 250 collector at pH 9.2; further cleaning increased the grade to 97.2% talc at a recovery of 57.5%.Flotation of fresh ground 60% minus 44 µm ore at a feed rate of 18.6 kg/ h produced a grade of 96.4% talc with a recovery of 78.2%, using Aerofroth 70 collector a six carbon-branch chain alcohol, at pH 9.2.The similarity in the concentrate grade and recovery between pre-ground and fresh-ground ore indicated that it was not neces¬sary to grind to 95% minus 53/2m to achieve comparable selectivity. A grind of 60% minus 44 pm corresponds to 100% minus 300 µm.Flotation retention times obtained with fresh ground ore indicate 33 min. for combined rougher/scavenger, and 15 min. each for the first and second cleaners.Talc-magnesite flotation separation is explained in terms of physico-chemical forces, with reference to surface charge and adsorption mechanisms."

Jan 1, 1989

By Wan Pu

Chrysotile asbestos samples from different mines have been studied by SEM and TEM, including high resolution electron microscopy, to find reasons for differences in physical properties of different types of asbestos fibres. The results show that the inner diameters of fibre tubes and the lattice images of fibres are different for soft and hard asbestos fibres. These differences are related to temperatures and geochemical conditions during the growth of chrysotile asbestos.

Jan 1, 1989

By Denni Nikols, Farrukh Z. Khan

"Highvale Mine, located at Wabamun, Alberta, produces thermal coal for TransAIta's Keephills and Sundance generating plants. Overburden stripping in the mine is conducted by draglines which normally operate on top of the overburden bench. In certain areas oj the mine, however, these overburden benches are susceptible to slope failure. In these areas, due to safety considerations, the draglines are utilized in the less productive chop-cutting mode, supplemented by mobile equipment where the bench height exceeds the dragline chop-cutting limit. This paper proposes maintaining the draglines in their normal digging mode through areas of unstable or jailed overburden, by utilizing a dragline carried toe buttress 10 ensure adequate bench stability. The data requirements and methods of slope analysis to design a toe buttress across an unstable highwall area are examined in rigorous detail. INTRODUCTIONLocationHighvale Mine is owned by TransAlta Utilities Corporation and operated under contract. It is Canada's largest coal mine with an annual coal production in excess of II million tonnes. The mine is located approximately 80 km west of Edmonton on the south shore of Wabamum Lake (Fig. I) and production is currently provided by three pits 02. 03 and 04 (Fig. 2). The entire coal production is consumed at the nearby Sundance and Keephills power generating plants.ScopeThe mining operation at Highvale Mine has had occasional slope stability failures of its high wall overburden bench. This paper examines one such failure which occurred in the summer of 1983 at Pit 03. In addition to an investigation of the failure, Terracon was asked to recommend mine operation procedures which would minimize the impact of these slide zones on dragline productivity. A method of removing the failed material by utilizing the dragline in its normal digging mode is designed. The method's advantages and disadvantages as well as the required support procedures are reviewed."

Jan 1, 1989

By Kwan Soo Han

A thermodynamic model for predicting the distribution coefficients has been developed by taking into account the extraction mech-.ism and the chloride complexation when Sm, Eu, Gd, Tb, Dy and Ho for single component systems are extracted from acidic chloride solutions by di-2-ethylhexyl phosphoric acid and 2-ethylhexyl phosphonic acid mono-2-ethylhexyl ester in kerosene, respectively. The model equation includes two constants, of which one corresponds to the apparent extraction equilibrium constant and the other is due to the variation of the activity coefficients of organic species. These values are determined from a few experimental data by the curve fitting method Then, the distribution coefficients under untried conditions have been predicted from only the initial data by iterative calculations. Bromley's formulation is used to estimate the activity coefficients of aqueous species and the interaction parameters for some rare earth chlorides are reported in terms of molality and molarity using data from Spedding et al. The validity of this method has been confirmed by excellent agreement between the experimental and the predicted distribution coefficients.

Jan 1, 1989

By M. H. Ghandehari

Sintered (Pr,Sm)Co5 displays a multi-phase microstructure in which closely related intermetallic compounds are formed during the process of fabricating useful magnets from over-stoichiornetric compositions. These compounds have much lower magnetic crystalline anisotropies compared to those of SmCo5 and PrCo5. Despite a careful control of the microstructure in producing "single phase" PrCo5 base magnets, sufficient concentrations of the lower anisotropy phases are formed which act as nucleation centers for domain reversal, resulting in a drop in coercivity. This article describes the use of sintering additives, primarily oxides, to prevent the formation of the magnetically soft phases in the final microstructure.

Jan 1, 1989

By A. C. Bonnier

"INTRODUCTIONI have been asked to make available our method of determining the ""Live Inventory"" within a gravity type thickener. The ""Live Inventory"" being that tonnage compatible with the optimum underflow density that satisfies the process requirements.One prerequisite of the calculations is the proper determination of the final pumpable underflow density. A further requirement is that, prior to shutdown, the thickener has been operated properly, particularly that it has not been operated for storage capacity.Until recently I had few chances to check the method. However, I was most fortunate to have had a recent opportunity covering several months on a 300 ft diameter thickener at a plant in the U.S.A., wherein the method was tested and verified many times. The method proved accurate in that our calculated tonnage checked with the actual dried physical inventory of the drying facility.At the precise moment that the feed to the thickener was shut down, a per cent solid determination was made at the critical place and the tonnage in ""Live Inventory"" determined. Let us say that at the moment the thickener U' Flow solids was 20%. The thickener then was allowed to cperate until the U' Flow solids dropped below 20%, at which time the thickener was deemed to be relieved. Anything much less than 20% was not suitable to the subsequent centrifuge operation.Most large metallurgical thickeners have a configuration of three slopes at the thickener ""bed"". These slopes are dictated by the raking blades and are shown on the manufacturers' erection drawings. The first slope is from the outer periphery and generally takes up a distance of about 60% of the radius, the second slope generally taking up the remaining 40%. Within this 40% area, there is usually another slope taken up by the cone on ""B"" type thickeners or an actual steeper inner slope on ""C"" type thickeners."

Jan 1, 1989

By T. S. Krishnan

Among the established permanent magnets, SmCo5 magnet occupies the foremost position as it offers a unique combination of high energy product, coercivity and curie temperature. The SmCo5 magnets are thus extensively used for high field applications. These are also best suited for use in environments where high demagnetising field and high temperature are operative. Also, for applications where high performance and miniaturisation are the over-riding considerations, the choice again falls on SmCo 5 magnets. The main deterrent to the widespread use of SmCo5 magnet is its high cost. Both samarium and cobalt metals are high priced, and the magnets prepared from their directly melted alloy are thus naturally very expensive. An alternate process involving calcium reduction of their oxide intermediates has, therefore, been studied and the alloy prepared by this process has been evaluated and found satisfactory for magnet production. The process essentially involves compaction of the charge mix containing samarium oxide, cobalt oxide (or metal) and calcium metal and' reduction of the charge compact at 1000-1300°C in hydrogen atmosphere, followed by water and acid leaching, drying and classification. The calcium reduction process offers three distinct advantages over the conventional melting processes: (i) The oxide intermediates are relatively cheaper and do not pose any handling problems. (ii) The operation temperatures are comparatively lower and hence precise composition control is possible as samarium losses due to volatilisation

Jan 1, 1989

By J. Drew Potts

The U.S. Bureau of Mines identified respirable dust sources and controls on four continuous auger mining sections, two with relatively low dust levels and two with high levels. Factors adversely affecting dust levels included auger equipment design, continuous haulage, and low seam height. Dust controls included ventilation practices and spray systems. Maximizing airflow seemed to reduce dust levels most. Air leakage and shock loss can be reduced by constructing stoppings with brushed-on mortar containing fiberglass and by keeping areas between curtains and ribs free from obstructions and storing equipment not essential for face activities in outby crosscuts. Curtain configuration, setback distance, and installation can also affect dust levels. Use of both blowing and exhausting curtains is the most effective configuration. Setbacks from the face should not exceed 15 ft. Installing brattice curtains at least 5.5 ft from ribs, when entries are 26 ft wide, minimizes velocity head. Installing curtains tightly against the mine roof and floor helps maintain a forward airflow movement in the center of the mine heading; curtain overlap can create a tighter seal. The wet-auger spray system also effectively controls dust, provided the mine is already exercising good ventilation practices.

Jan 1, 1989

By T. Janke

When Homestake Mining Company's Mclaughlin Gold Project was being evaluated for development, it was apparent that recovery of gold from mined ore would be difficult and relatively expensive. The ore was refractory, averaging less than 50% recovery in conventional direct cyanidation milling tests. Extensive testing narrowed the processing choices to either autoclave or roaster oxidation before cyanidation. Roasting was ruled out due to higher capital and operating costs --the Mclaughlin mill would be the first large-scale application of autoclave oxidation of a refractory gold ore.

Jan 1, 1989

By M. A. Weaver

This paper will investigate the historic and present state of the bituminous coal industry within the Commonwealth of Pennsylvania, with special emphasis on surface mining operations. It will address pertinent parameters such as production, markets, quality, number and size of operations, price, and productivity from a statistical viewpoint. In addition, relevant statistical parameters of select areas of the Appalachian Coal Region will also be presented and discussed.

Jan 1, 1989

By J. W. Tsai

Both diamond crystals and diamond films were grown on silicon and copper substrates using a methane/hydrogen gas mixture as a precursor with thermal CVD techniques at low pressure environment. In addition to diamond particles, other crystalline phases including graphite and aluminum silicon carbide were observed on the substrate surface. ?The grown materials were analyzed with X-ray diffraction, electron microscopy, Auger electron spectroscopy and optical microscopy. Most synthesized diamond crystals were twinned. The flow rate of reactant gases, substrate nature, substrate temperature, decomposition temperature of the precursors, total pressure of reaction chamber, methane/hydrogen ratios and other possible parameters were varied during the growth processes, and the significant effects of these factors on nucleation and growth rate were evaluated.

Jan 1, 1989

By Baxter J. L

Post-tertiary training programmes have been designed and produced for geologists at different levels of understanding and expertise in the relationship between gold mineralization and shear zones. A workshop format was used as it allowed both clients and facilitators to participate in the learning process. Evaluation by facilitators and participants refined the workshop programme as an effective skills oriented learning process. The general observation is that post-tertiary training in small, interactive, practical, learning oriented groups is far better than lecture oriented short courses for developing skills based learning. The evaluation indicates that the process in post-tertiary training must include aspects which are both useful and used.

Jan 1, 1989

By C. Chapman, P. Cowx

"INTRODUCTIONTetronics Research and Development Co. Limited has installed several plasma torches for steel heating in continuous caster tundishes. An extensive demonstration program on a 14 tonne tundish reported the following advantages of plasma heating.• close control of steel temperature to ± 5°C;• a reduction of the furnace tapping temperature of up to 20ºC, leading to savings in energy and refractories costs ;• improvement in steel quality, to produce a slab product with an equi-axed crystal structure and a reduced number of large sub-surface slag inclusions;• the virtual elimination of oxygen pickup in the tundish; and• the capability of making ferroalloy trim additions to the tundish to permit a change of steel grade during casting, greatly decreasing inventory costs.The Need for Tundish HeatingIn the continuous casting of steel, the function of the tundish is to transfer the molten metal between the ladle to one or more continuously fed casting moulds. Figure I shows a typical temperature profile of molten steel in the tundish over the first cast cycle. It is observed that a rapid drop in temperature occurs both at the start of the cast, due to the tundish refractories absorbing heat, and also during ladle changeover. In addition, as a result of thermal losses through the ladle sidewalls, there is a gradual decline in the bulk steel temperature over the entire heat cycle. Consequently, in normal tundish operation, it is necessary to cast with a high superheat (25°C to 30°C + above steel liquidus temperature) in order to prevent freeze-up of the strand. Problems of high temperature variation and the potential of the steel solidifying in the tundish are greater for small caster units of low thermal mass . A high steel superheat increases the steelmaking vessel process time and refractory wear and prevents the formation of a uniform equi-axed solidification structure in the cast steel, resulting in centre line segregation and porosity. The large drop in the casting temperature that occurs during unsteady state operation causes an increase in the number of sub-surface inclusions, reducing the value of the product. Accordingly, plasma heating may be employed to maintain the molten steel at an optimum temperature to produce a slab of consistent quality."

Jan 1, 1989

The first continuous pressure disk filter took up industrial-scale operation in Germany in 1976. This paper comments on major components of pressure filter facilities from the point of view of industrial-plant suppliers. For lack of time aspects of economy have not been commented upon. The paper elucidates a number of process-engineering inter-relations. It outlines important development trends from the angle of a machine-building company.

Jan 1, 1989

By G. Gafner

The paper gives the reasons for the development of a gold alloy of 990 fineness with good colour, durability, and mechanical properties, and explains why titanium was chosen as the alloying metal. Methods are described for the alloy?s production, solutionizing, and age-hardening. Mechanical properties are given as a function of deformation, age-hardening time, and temperature for three different starting states, and these properties are compared with those of some standard 14 and 18 ct jewelery alloys and pure gold. The effects of various salts and fluxes on the composition of the alloy after heat treatment at 1150, 800, and 500°C are discussed. These indicate how alloy scrap can be refined to pure gold, and how solutionizing and agehardening can be conducted without the use of vacuum equipment. The results of wear tests indicate that the alloy is more durable than normal coinage and jewelery alloys. Tips are given on the grain refining, soldering, and casting of the alloy.

Jan 1, 1989

By Warren L. J, Horsley R. R, Meagher L

Mineral concentrators often use process water that is very saline and/or hard. In this paper the effect of increasing concentrations of sodium chloride and calcium chloride on the rheological properties of 70 wt% quartz suspensions (d5o - 10.6 ¦m) is reported. The apparent viscosity at 100 s t in 5 mol dm -3 sodium chloride solutions (approx. 300,000 ppm) was nearly 500 times the viscosity of water without salt or particles present. Part of the increase in viscosity is caused by aggregation (coagulation) of the suspension.

Jan 1, 1989

By G. M. Wilemon, B. J. Scheiner

The Bureau of Mines conducted investigations on extracting phosphate values from fine-particle wastes generated during the mining and beneficiation of phosphate ore by leaching dried wastes using a H2SO4-methanol mixture. Although phosphatic clay waste contains up to a third of the phosphate originally present in the ore, recovery of these values represents a significant challenge due to the fine grain size of the material, the particles averaging less than one micrometer in diameter. Waste samples obtained from two Florida producers yielded phosphate extractions of 71 and 84 pct, respectively, when leached under ambient conditions and at a stoichiometric acid ratio of 1.4:l. Elevated temperatures did not improve the amount of phosphate extracted. Undesirable A12O3, Fe2O3, and PlgO impurities were largely rejected; higher grade wastes gave acids that meet established industry impurity standards and lower grade samples yielded acids that marginally fell short of the standard. Separation of the crude acids from the insoluble residues was accomplished via vacuum filtration through either filter paper or commercial filter cloths. Both filtration rates and solids retention were improved by the addition of 0.5 lb/ton of poly(viny1 acetate) (PVAc) or poly(ethy1ene oxide) (PEO) to the methanol-acid slurries. These results show potential for substantially increasing the reserves of an important domestic resource.

Jan 1, 1989

By Simon D. Strauss

This paper discusses the ways in which the metals industries dealt with surplus capacity in the past, primarily the twenty years, 1950 - 1970. During this period, the bulk of metals production in the market-economy countries was controlled by private sector companies. Since then, public sector companies have played an increasingly important role in the metals industries of the market-economy countries. Of course, the change was not overnight. It occurred gradually over a period of many years. Indeed, by 1965, several developing nations had adopted policies of government control of metal operations previously in private hands. The metals industries are so many, so large and so diverse that the constraints of time make it impossible to deal with all segments. To illustrate the problems of surplus capacity in the metals industries during the period, this paper focusses primarily on three metals. One experienced rapid market expansion between 1950 and 1970; one had a growth more or less in line with the expansion of the world economy; and one lagged well behind the pace of industrial expansion. No one will be surprised if aluminum is identified as the metal with rapid growth; copper is identified as the metal that kept pace with the world economy; and tin is identified as the laggard. Individual computations of the rate of growth for these metals show some variations, but most estimates place the increase in aluminum consumption in the market economy countries between 1950 and 1970 at a compound annual rate of about 8%. The corresponding figure for copper is a compound rate of 4%. Tin consumption showed no growth. A widely accepted point of view is that sharply rising demand will force the price of a commodity to increase substantially in order to attract a necessary expansion of supply. The corollary to this is that stagnant demand will hold prices down, as there is no need to stimulate new supply and it may be necessary to force marginal producers out of the market. The experience with aluminum, copper and tin in the years 1950-1970 does not support this theory. In 1950, the average prices in the United States market as reported by the American Bureau of Metal Statistics were 17.74 a pound for aluminum, 21.24 a pound for copper, and 95.54 a pound for tin. The corresponding figures in 1970 were 28.74 a pound for aluminum, 57.74 a pound for copper and 174.24 a pound for tin. Aluminum, with the greatest market growth, rose by 60%, whereas tin rose 82% and copper by 172%. Clearly, other factors were a more important influence on price than was the trend of demand To revert now to the capacity issue, during the period under review aluminum demand was rising so sharply that that industry had no sustained problem with surplus capacity. Instead, if anything, capacity may at times have been a constraint on demand. The industry succeeded in attaining explosive market growth through imaginative research and promotion programs. Some of this growth was the result of substitution of aluminum for other commodities – steel, copper, wood and glass as examples. But much of the growth was the consequence of developing entirely new products through technological innovation. Prior to World War 11, the number of aluminum producers was extremely limited. Alcoa and Alcan in North American and Pechiney and Alusuisse in Europe were the dominant firms. The developing countries had virtually no production and in Japan and Germany production was only a small fraction of the North American output. During the War years the United States had financed the construction of many new facilities. After the war these plants were sold by the government to Reynolds and Kaiser in order to foster more competition in the market. Subsequently many other concerns became aluminum producers, both in the United States and elsewhere and competition for markets intensified.

Jan 1, 1989

By J. A. Voigt

In an effort to determine the optimum conditions for preparing high purity, fine particle size high temperature superconducting oxide powder, we have investigated how calcination conditions influence the conversion of a chemically prepared hydroxycarbonate precursor powder to YBa2Cu307. We find that the precursor can be converted to phase pure YBa2Cu307 in either oxygen or synthetic air (20% 02. 80% N2) at 850°C. This temperature is substantially lower than the temperature (>900°C) normally used for the calcination of mixed-oxide powders. The lower calcination temperature prevents particle sintering and maintains the desired fine particle size. Powder processed in synthetic air shows a low degree of crystallinity indicating it may be more sinterable than the highly crystalline powders produced when an oxygen atmosphere is used. Intimate contact between powder particle surfaces and a flowing gas atmosphere promotes the reaction between the BaCO3 component of the precursor powder and the Y and Cu constituents.

Jan 1, 1989