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By Dai Yongnian

"The feasibility to vacuum distillation of a crude metal or an alloy was discussed. The equilibrium relationship between vapor phase and liquid phase in A-B system - - - - - PA/PB =BAa*/b has been derived. The separation coefficient, BA = rAPA/(rBPB) is a judgment criterion. By calculation PA/PB, the equilibrium composition diagram of vapor phase and liquid phase was drawn. By use of the equation derived by M. Olette, the relationship among the volatilization amounts of various impurities in a crude metal (yi) was further solved. 1-(X/100)= C =(1-Y1/100)1/02i . From yi value obtained in practice, 2i, Pi and then can be calcu-lated. The correct volatilization order of various impurities was obtained. These results can be applied to determine the practical conditions (temperture, vacuum degree, type of distilla¬tion furnace, times of distillation and control of product composition) in distillation of a crude metal or an alloy.INTRODUCTIONRefining and separation of various impurities from nonferrous crude metals by vacuum distillation have many the advantages of high metal recovery, impurities recovered in metallic state, flowsheet simplified, good enviromental protection, low operation costs and in complex equipment. So in recent years this method has been adopted widely.Vacuum distillation has also been studied and used in separation of various elements from non-ferrous alloys and the area of its application is being extended rapidly.At this situation, some problems have been put up: What kind of impurities can be removed from crude metals? What kind of alloys can be separated by vacuum distillation? In present paper, attemps have been made to answer these problems and combine with practical results to analyse some valuable data obtained from testwork on vacuum distillation of crude tin and Pb-Sn alloy."

Jan 1, 1988

By Arthur S. Klein, Hugh R. Lowry

"The Levitation Casting Process is a new continuous casting method that uses an electromagnetic levitation field, instead of a mold, to support and contain a column of solidifying metal. By counteracting gravitational forces and hydrostatic pressure on the metal column, this process eliminates friction and adhesion at the interface between the solidifying metal and the cooled walls of the casting chamber. The process inherently provides high casting speeds, excellent dimensional control and smooth, continuous emergence of solidified product from the top of the casting chamber.Of major importance is that the electromagnetic field produces an intense stirring of the liquid metal both before and during solidification. As a result of this stirring, the cast product has a homogeneous, equiaxed, fine grain structure generally suitable for immediate drawing or other forming operations without the need for hot rolling or other expensive additional processing.This paper reviews the fundamentals of the Levitation Casting Process, results obtained in casting various pure metals and alloys, and the production sized system at Lowell, MA, that uses this process. IntroductionThe Levitation Casting process was specifically developed to meet several requirements including:• Economic at low casting rates• Usable with pure metals and alloys• High, uniform product quality suitable for fine wire drawing or cold rolling into flat strip and tape• Easy cast product shape and size changes• Process inherently stable and easily automatedIn meeting these criteria it was also desired to retain the advantages of General Electric's well known Dip Forming continuous casting process; namely the inherent ""fail-safe"" properties of upward casting, solidifying metal by means other than pressure contact with a cooled mold, and use of a sealed furnace, casting chamber and cooling tower, filled with a protective atmosphere, to prevent oxidation of the molten metal or cast product."

Jan 1, 1988

By Groves D. I

The Norseman-Wiluna Belt (Fig.1) is a richly mineralized (production 1900 tonnes Au), Archaean greenstone belt, up to 800km long and 200km wide, which forms the major part of the Eastern Goldfields Province within the Yilgam Block. The Belt evolved ca. 2700 Ma ago as an oblique-slip mobile belt between flanking portions of an older greenstone terrane. Volcano-sedimentary successions in the Belt represent two distinct tectono-stratigraphic associations. Sequences of metamorphosed caic-alkaline intermediate to silicic volcanic rocks interlayered with tholeiitic basalts probably represent the remains of a dissected Archaean volcanic arc (or arcs), and sequences composed dominantly of ultramafic to mafic lavas and intrusions, with minor interflow tuffaceous, sulphidic or cherty sediments are interpreted as remnants of the floor of an ensialic marginal basin (Barley and Groves, 1988). Ultramafic volcanism at Kambalda has been dated at 2692 ¦ 2 Ma (Claoue-Long et al., 1986). The dominantly volcanic associations are locally overlain by coarse clastic sedimentary succes- sions. The Belt is also typified by major north- to north-northwest-striking fault systems, shear zones, and tectonic lineaments, many of which are traceable for more than 300km. As well as defining the boundaries of the belt, these structures have accomodated much of the regional strain and acted as conduits for hydrothermal fluids during deformation, metamorphism and mineralization. As a result, most of the epigenetic gold deposits in the Belt occur in subsidiary structures related to these fault systems (Eisenlohr et al., 1988). Deformation involved oblique compression resulting in a closely spaced network of low-angle faults (thrusts) as well as upright folds and oblique- to strike-slip faults (Archibald, 1987; Veamcombe et al., 1988). This was accompanied by regional metamorphism and granitoid emplacement. At Kambalda, regional deformation and metamorphism were synchronous with the emplacement of the Kambalda Granodiorite which has been dated at 2662 ¦ 4 Ma (Hill and Compston, 1986), approximately 30 Ma after volcanism.The tectonic history and style of deformation of the Norseman-Wiluna Belt are similar to those of Phanerozoic oblique- slip mobile belts at continental margins, which are also a major source of hydrothermal gold mineralization.

Jan 1, 1988

By Ken J. Fair, Vicken H. Aprahamian, Gus Van Weert

A consortium of Canadian mining companies, engineering firms and the Ontario Government has supported Hydrochem's efforts in the last year to design and cost a 10 tpd NITROX PROCESS® demonstration plant. A 5 kg per hour mini plant was installed at the Hydrochem facilities in Brampton, Ontario. This paper describes design testwork on Dickenson Mines arsenopyrite concentrate and application of the findings to the demonstration plant flowsheet. The control of nitrates in discard solids and stack gases is discussed in detail. Nitric acid oxidation of arsenopyrite results in significant ele- mental sulphur formation, enough for it to be detrimental to sub- sequent cyanidation. Flowsheet variations aimed at dealing with this process characteristic are discussed and testwork results on one option (hot liming) are described.

Jan 1, 1988

Chief Geologist, Groundwater and Engineering Geology Branch South Australian Department of Mines and Energy The six papers submitted for consideration during this session include two dealing with techniques for measing rock mass behaviour, including permeability, in boreholes, one describing the use of surface geophysical methods to delineate pollution plumes in groundwater together with analytical modelling of the plume, and one presenting a biological tracer technique applied to the determination of the origin of water entering underground mine workings. A paper describing dewatering at a base metal mine in Queensland includes an account of the investigation techniques employed to establish a conceptual model as a basis for the evaluation of various dewatering strategies. Of considerable interest is the use of a field gravity survey to delineate a zone of highly weathered rock which forms the major aquifer at the site.

Jan 1, 1988

By J. Allan Tice

In the past fifteen to twenty years, the use of drilled piers to support high capacities in coastal plain deposits has become more and more common. With improved construction techniques and better understanding of pier behavior, drilled shafts with capacities of 200 to 500 tons are not unusual. The purpose of this presentation is to review several drilled pier installations from North Carolina to north-east Florida as a means of illustrating the different types of design concepts and installation techniques which are presently being used. ACKNOWLEDGEMENTS The information in this presentation was obtained from work performed by many individuals and companies. The section on limestone socket caissons in South Carolina is an abridged version of a paper prepared by Rob Smith and Neil Gilbert of Law Engineering's Charlotte, North Carolina office, and is used with permission. The section on pier installation in northeast Florida is an abridged version of a paper prepared by Kirk Mcintosh, Tom McDaniel, and Randy Knott of Law Engineering's Jacksonville, Florida office, reprinted here with permission. Additional data discussed in this presentation has been obtained from Farr Foundation Company, McKinney Drilling Company, and Peterson Drilling Company.

Jan 1, 1988

By P. Hanniala, J. Sulanto

"The requirement for the reduction of sulphur dioxide emissions from copper smelters is becoming more and more important. Therefore, the most important question in smelting technology will be how to produce even, high strength SO2 gas in smelter and how to combine smelting and converting. The best sorution in certain cases is to eliminate converters totally.Outokumpu is already responding to this challenge. As a result of extensive research work, Outokumpu Oy has developed the Flash Smelting Process for direct smelting of blister copper from concentrates in one step.The newest process development is the Kennecott-Outokumpu Flash Converting process, where solidified copper matte is converted into blister copper. The production of low volume high SO2 content gases, separation of smelting and converting operations to allow increased on-line availability, and simplified process control are the major benefits of the process which translates to reduced smelter capital and operating costs.Also, it has been studied the use of the same Outokumpu furnace for smelting and converting alternately when the production capacity is low.In this paper, the developments and improvements of the Outokumpu Process are described from the operation and investment cost standpoints"

Jan 1, 1988

By Mark P. Schmidt, Douglas D. Schlepp

Water Only cyclones were introduced into commercial operation for cleaning of metallurgical and steam coal around 1950. Since its original introduction as a primary cleaning device, the employment of Water Only cyclones as recleaning and scalping devices has also grown in popularity. Examined are examples and uses of the water only cyclone as primary, re- cleaning, and scalping devices for fine coal cleaning. Also evaluated are conditions that should exist to ensure favorable cleaning in Water Only cyclones.

Jan 1, 1988

By V. A. Marple, K. L. Rubow

"In our laboratory several impactors have been developed in the past which have penetration characteristics that approximate that of the ACGIH or the British MRC respirable curves. In these impactors the large nonrespirable particles are collected on an impaction plate of a multiple round nozzle stage where the nozzles are of different diameters. The principle for designing a respirable cut impactor is quite simple in that the respirable curve is divided into two or more segments and the nozzles are designed with the correct diameters and number of nozzles to have collection characteristics with 50% cutpoints at the center of each segment. The particles not collected on the impaction plates are then collected upon a filter. These particles represent the respirable fraction of the aerosol. Therefore the respirable curve is approximated in a stepwise fashion with the approximation becoming better as the respirable curve is divided up into increasing numbers of segments. It has generally been felt that three segments is satisfactory for most cases.A new version of the respirable impactor has recently been developed in our laboratory. This impactor approximates the ACGIH respirable curve in three steps at a flow rate of 30 liters per minute. However, unlike previous models where all of the particles larger than the three cut points designated by the three steps are collected upon one impaction plate, a separate impaction plate is now used for each of the three cut sizes. To approximate the respirable curve in three steps, the cut sizes must be 2.2, 3.5 and 5.8 microns diameter. Therefore, on each of these stages the particles collected will be the mass of particles that are larger than these three cut sizes. By determining the mass of particles collected on each of these three stages plus that on the after filter using Gravimetric techniques, some information can be obtained on the size distribution of the aerosol being sampled. Furthermore, the impaction plates of the three stages are rotated and the nozzles are placed in such a position such that a uniform deposit is obtained on each of the impaction plates. Therefore, the deposits collected are suitable for X-ray fluorescence analysis or other types of analysis where a uniform deposit is required."

Jan 1, 1988

By Thomas M. Barczak

The effect of load rate on the load-carrying capabilities of wood cribs is investigated in this Bureau of Mines study. The modulus of deformation (stiffness) of wood crib blocks has been shown to increase with increases in rates of load application, causing larger load reactions for increases in convergence rates. Since wood cribs are tested in the laboratory at convergence rates that are orders of magnitude faster than typically would occur underground, wood cribs tested in the laboratory will react larger loads than the same cribs would react underground for the same displacement. Tests conducted in the Bureau's mine roof simulator on green wood crib blocks indicate that the increase in stiffness for increasing load rates diminishes at displacement rates beyond 0.1 in/min, making crib load nearly independent of load rate for rates faster than 0.1 in/min. Seasoned wood specimens were not as con-sistent in load-rate dependency. Some possible explanations of observed load-rate behavior on wood crib specimens are also postulated in this paper.

Jan 1, 1988

By J. P. Schde

The authors deal with nickel production and usage patterns, nickel's first-use and end-use, examples of nickel applications in modern technology, e.g., energy generation and conservation, environmental protection, the oil and gas industry, construction and machinery, food production, conservation and distribution, consumer durables and the like. A special section of the paper is devoted to new applications of nickel in the electronic industry, modern corrosion control and the building and construction industries. The need to defend traditional markets for nickel while striving to find new applications, is also stressed.

Jan 1, 1988

By E. S. Geskin, W. L. Chen, A. Vora

"This paper is concerned with the application of an abrasive waterjet for metal shaping. The waterjet cutting technology uses water compressed to the pressure up to 55,000 psia which is accelerated in a cylindric nozzle. Abrasive particles are then supplied into the water stream and accelerated by the water. Cutting occurs via the interaction between the water-particles stream and a workpiece that causes material erosion at the impingement zone. The mechanism of this interaction enables shaping of practically any material with a minimal effect on the metallurgy of subsurface. The motion of the jet penetrating through a material body is guided by a robotic arm. A waterjet cutter is becoming one of the principal tools for shaping titanium, super-alloys and other hard-to-machine metals and composites. The shaping, resulting from the waterjet cutter, is very similar to laser beam cutting. However, unlike laser processing, there is no damage to the subsurface structure.The presented work discusses the experimental study of cutting of titanium plates. The results of these experiments demonstrate the potential of the abrasive waterjet as a shaping tool. IntroductionOne of the main avenues in the development of metal shaping is the use of high energy beams as cutting tools (1,2). There are a number of advanced beam oriented material removal technologies, such as laser, electron beam, plasma and abrasive waterjet (AWJ) cutting. The advantages of AWJ cutting are well understood and documented (3-14). This technology has the potential of becoming the principal tool for netshaping and netsurfacing of parts. However, the use of AWJ is currently limited to cutting of hard-to-machine materials such as titanium, superalloys, glass, composites, etc. The cost of A W J cutting is much higher and the productivity is much lower than those of the thermal cutting. At the same time abrasive waterjet can be used for shaping any existing technological material from fabrics, plastics, aluminum to glass, composites, and diamonds. The material losses during AWJ shaping are minimal. The roughness and waveness of the surfaces generated during AWJ cutting are substantially less than those of the thermal cutting. Due to the size of the jet cross-section total force exerted by the jet on a workpiece does not exceed 30-50 newtons. This terminates the need in the use of complex fixture for material holding. Low applied forces and low surface temperature prevent the damage of metal subsurface in the course of cutting. The small size of the impingement area will determine the limited width of the kerf. Due to the size of kerf and unidirectional character of the water jet the formation of practically any metal contour is possible."

Jan 1, 1988

By Michael S. Wieland

The stress waves generated during delay blasting in underground or surface mines not only fracture the surrounding coal, rock, or other strata, but also impact delayed charges remaining in neighboring boreholes. This crossing wave interaction is a ubiquitous fundamental damage mechanism, ultimately responsible for numerous occurrences of misfires and flyrock. The hazards and waste from wave-induced malfunctions are Just the recognized tip of the iceberg. Undetected marginal performance of damaged delay detonators and desensitized charges poses a tremendous unresolved problem, resulting in the reduction of mining profits and the certain retention of unwanted risks.

Jan 1, 1988

By Joan Weinberg

Real gross national product (GNP) grew at a seasonally adjusted annual rate of 2.2% in the third quarter, down from a revised 3.0% in the second quarter, according to preliminary data from the U.S. Department of Commerce (table 1). The slowdown in the rate of growth was attributed to the summer drought, a larger trade deficit, and a decline in Federal spending for defense. Exports slowed from the second quarter, as the dollar, compared with other industrial country currencies, edged up. Imports of both consumer goods and capital goods rose sharply, with consumers buying more foreign cars, computers, and electrical machinery. Although net exports of goods and services deteriorated slightly from the second quarter, the U.S. trade position continues to be much improved from 1987 and first quarter, 1988. Business spending for new plant and equipment rose at a 4.6% pace, well below that recorded earlier in the year. The 3.5% increase in consumer expenditure was accounted for mainly by nondurable goods and services; expenditure for durable goods--those products lasting more than 3 years--rose only 0.4%. Inflation, as measured by the fixed-weighted GNP price index, rose at an annual rate of 4.9% in the third quarter. Prices rose slightly less than they had in the second quarter, when inflation reached a 6-year high. In September, 1988, the President signed a U.S.-Canada free trade agreement (FTA) which will eliminate all tariffs and most nontariff barriers between the two countries by 1999, thereby creating the world's largest open market. In 1987, U.S.-Canadian bilateral trade totaled $161 billion. The expansion of trade is expected to generate 5% higher growth for Canada and up to 1 % higher growth for the United States by the end of the century. The higher growth for the United States translates into an estimated 750,000 jobs, and $2.4 billion in exports. Canadian parliamentary approval of the agreement is still required before the treaty can take effect. The debate in Parliament is continuing, and the issue is not expected to be resolved until after the November 21 election.

Jan 1, 1988

By Freeman NV

The concept of an in stream analysis probe was developed at The Zinc Corporation (now Z.C. Mines) in the late 1960's and commercialised quite rapidly, by Phillips and then AMDEL, as an alternative to the established centralised systems (Courier, etc.). The developments which have taken place since that time are reviewed and current procedures and performance are described. An audit of the system, recently undertaken by AMDEL, has highlighted areas where improvements can be made. In 1988 the ISA system will become an integral part of a substantially upgraded process control system.

Jan 1, 1988

By A. K. Haines

Hydrometalurgy, particularly leaching, is a highly topical subject and always generates great interest in the mineral industry. This was evident right from the start of the organization of the SAIMM Colloquium on Leaching, which was held at Mintek on the 8th and 9th November, 1988. The response to the cal for papers was so good that the Colloquium was extended to two days, instead of the usual one day.

Jan 1, 1988

By Vernon R. Degner

The past two decades has seen the application of the mechanical flotation machine, originally developed primarily for metal1iferous ore beneficiation, increasingly applied to cleaning coal in the 28x0 T. Mesh size range. Internal cell hydrodynamic studies of mechanical flotation machines of all sizes, as well as computer aided modeling studies of flotation kinetics has, within the last five years, established a basis for optimizing coal flotation circuit design and machine operation, and has a1 so pointed a way toward improvements in mechanical flotation machine design for the future. Consideration of the trend toward increased fines produced by current mining techniques, as well as the environmental need for a progressively cleaner product, lends support to basing the design of the mechanical coal flotation machine of the future on finer feed; below 100 microns in size. Future types of mechanical flotation machines, which may satisfy the fine coal cleaning requirements for a significant improvement in product grade while maintaining the combustible recovery levels of current technology, are discussed.

Jan 1, 1988

By Margaret R. Egan

A series of experiments were undertaken by the Bureau of Mines to determine the emission products of several types of conveyor belting and other combustible materials found in mines. These experiments were conducted under intermediate-scale, simulated mine conditions to determine smoke characteristics and gas concentrations. From these determinations, heat-release rates, particle sizes, obscuration rates, combustion yields, and production constants were calculated. Three types of belts were investigated: chloroprene, also known as neoprene (NP); polyvinyl chloride (PVC); and styrene-butadiene rubber (SBR). The belts were designated as ignitable or self-extinguishing depending on the length of the burning time and the subsequent combustion products. Under these experimental conditions, the SBR belts were the easiest to ignite. The PVC and NP belts tended to self- extinguish within a few minutes after ignition, but were still capable of maintaining a brief flaming period. These conveyor belt combustion results are compared with previous analyses of wood, transformer fluid, and coal fires. Together they form a data base by which findings from future experiments with other mine combustibles can be compared.

Jan 1, 1988

By Leonard J. Friedman

There have been considerable changes in systems, equipment design and materials used in the modern Sulfuric Acid process. Many of these will shape the metallurgical sulfuric acid plant for the year 2000 and beyond. Advances have come from all over the world, and include new scrubbing area designs, catalyst contacting devices, silicon stainless alloys for unlined acid systems, energy recovery from acid heat, stainless converters and heat exchangers, etc. This paper describes each of the process "advances" and presents a review and analysis indicating advantages, operating experience and limitations.

Jan 1, 1988

By Thomas H. Wilson

Common offset and refraction seismic data have been collected over four longwall panels at two different locations within West Virginia. Surveys prior, during and after mining were made in both areas. The velocity of seismic wave propagation in the overburden rocks is observed to decrease in response to panel emplacement. Variations in the magnitude of this reduction, apparent as an additional first arrival time delay in the after mining common offset surveys, do not appear to correlate directly to the amount of subsidence that has occurred. Velocity reduction and signal absorption zones are also produced in the cover beyond the panel face over the adjacent unmined areas. Signal absorption and velocity reduction zones have also been observed over room and pillar entry areas between mined panels. Velocity reduction zones have been- observed beyond the panel face in both shallow and deep mines, but the signal absorption zone has not been observed over the deeper mine. Changes in the compressional wave velocities of the cover rocks are associated with changes in their elastic moduli. Differences between borehole derived and surface seismic derived interval velocities, are related to differences in the properties of the bulk volume sampled by each method.

Jan 1, 1988