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By J. Finch, W. Petruk, R. G. Pinard

An investigation was conducted to determine the minimum number of samples that must be studied by image analysis of polished sections to characterize a mill product and determine the apparent mineral liberation. It was found that a representative polished section cannot be prepared from an unscreened sample that has a wide size range of particles. Similarly, individual screened fractions are not representative of the sample because minerals are partitioned during screening, and the quantities of soft brittle minerals are increased in fine grained fractions, whereas the quantities of hard minerals are increased in coarse grained fractions. It is assumed that results obtained by combining data for a series of narrow size range screened fractions (one Tyler size range) are representative of the sample, and relatively accurate apparent mineral liberation data can be obtained for a mill product by analyzing each fraction and combining the data. Somewhat less accurate data would be obtained by analyzing a series of screened fractions that have a wider size range of particles (five Tyler size ranges).

Jan 1, 1987

By J. S. Murty

In this paper, a report is given of studies undertaken in a laboratory rod mill to obtain the optimum conditions for the desired particle size distribution for long-distance transportation of coal through slurry pipelines.

Jan 1, 1987

On the basis of field observation, four principal styles of hydraulic breccia are recognised, and their characteristic features noted. In practice, hybrid styles are most commonly encountered. Numerous examples will be illustrated during the oral presentation, and the potential for definition of a formative environment is emphasised. In one example presented, it is suggested that more than 50 episodes of hydraulic fracturing can be recognised. In all cases at least sane useful conclusions can be drawn in the context of modeling for drill targets.

Jan 1, 1987

By G. W. Reimers

Conditions in the underground mine environment can cause self-heating of sulfide ores as a result of exothermic oxidation reactions, which may result in mine fires. This Bureau of Mines report describes thermal analyses of finely ground chalcopyrite, chalcocite, galena, pyrrhotite, marcasite, and arsenopyrite, to characterize their responses under oxidizing conditions. Thermal gravimetric analysis (TGA) and differential thermal analysis (DTA) were used, in the temperature range 1000 to 5000 C. Chalcopyrite showed an initial weight gain, due to formation of sul-fates, a weight loss, caused by ignition of iron sulfide to iron oxide, and a final weight gain, indicating the conversion of copper sulfide to sulfate. Chalcocite did not ignite in the temperature range studied but exhibited a rapid weight gain, because of the rapid conversion of copper sulfide to sulfate. Likewise, galena failed to ignite but underwent a steady weight gain when oxidized in a moist atmosphere, showing conver-sion of lead sulfide to sulfate below the ignition point. Marcasite underwent a rapid weight loss, indicating ignition, at 2000 C. Moisture in the oxidizing atmosphere lowered the ignition point of marcasite and arsenopyrite but not that of pyrrhotite. All the sulfides exhibited exothermic behavior at temperatures below the ignition point.

Jan 1, 1987

The techniques used by the State Electricity Commis- sion of Victoria to handle and store brown coal in the both the raw coal and boiler bunkers are outlined. These tech- niques were adopted in agreement with the science of modern bulk solids handling. By successful balance between practical requirements and bulk solid handling system design require- ments the Commission expects to confidently attain reliable coal flow even for the most adverse of coal flow properties. Attainment of this goal demanded full attention to channel detail selection. An outcome of this attention has been the development of a novel bunker and discharge arrangement for handling extremely difficult to handle coals. Due to the novel features of this slot bunker outlet arrangement it's ad- vantages and disadvantages are discussed.

Jan 1, 1987

Thermodynamics and kinetics? of the removal of Va elements (As,Sb,Bi) from copper were investigated 1n the fire relining by alkaline carbonate fluxes such as Li 2co3 , Na 2CO3 and K2CO3. The distribution coefficients of As, Sb and Bl between alkaline carbonate fluxes and mo) ten copper were ?obtained at 1200°C under the different oxygen potentials. As and Sb were easily removed from copper to fluxes as pentavalent oxide form. On the other hand, Bi was hardly removed except by a Ll2CO3 flux. The removal rates of Va elements from copper were also measured In the temperature range of 1150°C.- 1250°C. The removal rates of As and Sb were much higher than that of Bi. The removal rates of Va elements showed the same order of the distribution coefficients. The removal rate could be expressed by following equation. (1).

Jan 1, 1987

By H. S. Kibler, A. E. J. Gallagher, J. J. Sebesta

A review will be made of the nature, value, costs, and factors associated with industrial minerals production in general. Comparisons will also be made between some of these data and similar criteria for metallic mineral production.

Jan 1, 1987

By J. G. Wargo

In situ leaching of disseminate gold deposits has been studied from a theoretical perspective to outline the operating environment for the process. Rock permeability and the relationship of permeability to the site of gold particle deposition are key factors in predicting the efficiency of in situ leaching. Permeability measurements, however, have rarely been made during gold exploration, so that secondary geologic features of the deposit must be used. This paper examines some of the geologic characteristics of disseminated gold deposits and comments on the problems and possibilities of in situ leaching of gold.

Jan 1, 1987

By Ronald L. Pariani

To date, significant advances have been made regarding the development and commercial implementation of full deposit stripping in the copper industry such as practiced at Copper Refineries, LTD in Townsville, Australia. The paper describes the history and current practice of Electrowinning (EW) plants which may be coupled with solvent extraction. The modular nature and degree of automation are described in relation to the various sizes of operations. Reference is made to the expansion capability of commercial equipment plus associated economics of the mechanical processes for producing full cathode deposits. It is recognized that the technology described may be adaptable to other nonferrous refining areas where feasible. The paper highlights the state of the art in mechanized stripping equipment as applied to current and planned SX-EW plants.

Jan 1, 1987

By Paul D. Dupree

Introduction Trapper mine is a dip-line strip coal mine, located about 10 km (6 miles) southwest of Craig, CO. The mine provides the Craig Generating Station, operated by Colorado-Ute, with about 2 Mt (2.3 million st) of coal annually. The Trapper mine is situated on a hillside that climbs in elevation from 2 to 2.5 km (6500 to 7400 ft) at average grade of 15%. The coal seams dip at about 16% down-grade and they outcrop near the top of the hillside. They exceed maximum stripping depth in 1 to 1.7 km (3500 to 5500 ft) of pit length. Stripping in the three existing pits is performed with three Page 752 23 m3 (30 cu yd) walking draglines. Two of the pits are currently being cast blasted. Until the active cut, the Derringer pit was cast blasted only where the lower mined seam exceeded stripping capabilities and the pit was a single seam operation. Now, a 9-m (30-ft) interburden bench has been incorporated into the stripping plan. This bench protects the first seam of coal from shear when the overburden is cast blasted. The cast blasted section of the 1.6 km (53,000 ft) long pit has been increased from the 457 m (1500 ft) casted previ¬ously to 1 km (3500 ft). High speed films show the coal losses due to shear of the blast are minimal. The pit width in Derringer pit is 61 m (200 ft). This is necessary for efficient spoil side stripping of a relatively thin interburden in the two-seam section of the pit. The Enfield pit is entirely cast blasted. The single seam pit is 46 m (150 ft) wide, 1.1 km (3600 ft) long, and varies from 15 and 46 m (50 and 150 ft) in overburden depth. The overburden strata at the mine consists of medium-hard layers of sandstone, shale, and

Jan 1, 1987

By P. Somasundaran, J. T. Kunjappu

Spectroscopic techniques are becoming increasingly popular for characterizing the interior of adsorbed layers of surfactants and polymers at solid- liquid interface as well as in the identification of com- pounds on mineral surfaces. This review encompasses the application of fluorescence and ESR spectroscopic techniques to reveal the microscopic environment of the adsorbed layers of surfactants and polymers on minerals with a special reference to the adsorption of anionic surfactants (e.g., sodium dodecyl sulfate) and polyelectrolytes (e.g., polyacrylic acid) at positively charged mineral (e.g., alumina) - water interfaces. Finally, the utility of XPS and auger techniques to identify the surface elemental composition of different mineral species has been related to their flotation efficiency.

Jan 1, 1987

By J. K. Whyatt

The Bureau of Mines, under a cooperative agreement with Callahan Mining Corp., measured rock displacement at the 4,7S0-ft level of the 5,100-ft-deep rectangular, timbered Caladay Shaft in northern Idaho. Displacements were measured with multiple-position borehole exten-someters (MPBX) installed 4 ft above the face and timber extensometers (TE) installed with the timber sets. This report presents the displacement data along with preliminary, qualitative observations of rock behavior. The measured displacements showed an instantaneous response to shaft sinking and significant time dependency. The relative magnitudes of displacement measured at the shaft walls were heavily influenced by local geologic structure and distance from the shaft bottom.

Jan 1, 1987

By K. D. Hester

"1.0 INTRODUCTIONThe uranium industry started in Canada with the reopening of the gravity concentrator at Eldorado's Port Radium mine in the North West Territories in 1942. In 1948, uranium exploration and processing was opened to the private sector, and the Federal government offered special pricing incentives to the industry. Eldorado explored the Lake Athabaska deposits in northern Saskatchewan, and in 1953 opened the Beaverlodge mine. Other mines in the area soon followed. In 1953 also, the deposits in the Blind River - Elliot Lake area and in the Bancroft area of Ontario were discovered. Mines and mills were quickly developed in these areas.Canadian uranium production peaked at 15,900 short tons of U3O8 in 1959. In that year, uranium exports at $300,000,000 exceeded those of all other minerals in value. On October 1, 1959, Canadian uranium operations employed 13,900 people.Up to 1956, it was a seller's market. By 1958, world production of uranium was far ahead of requirements. Accordingly, in November of 1959, the USAEC announced it would not renew it's options for continued delivery of uranium from Canadian mines. This led to the ""stretchout"" of existing uranium contracts, and many mines were shut down (see Table 1) .In the early 1970's, a commercial uranium market seemed to be developing. In Ontario, at Elliot Lake and Bancroft, mines reopened. But competition was coming from the Athabaska basin of Saskatchewan. Currently it is these high grade, open pit deposits of northern Saskatchewan which are in the forefront of Canadian uranium developments. Canadian developments since 1942 reflect the political and market forces, as well as metallurgical progress and changes in environmental standards. This paper attempts to show these process changes in broad perspective."

Jan 1, 1987

By G. M. Wilemon

The Bureau of Mines conducted preliminary investigations on the use of an acid-alcohol leaching technique for recovering phosphate values from phosphate matrices. H2S04 and methanol were used as the leaching agents. Starting-matrix particle size and acid-apatite ratio were found to significantly affect the efficiency of phosphate leaching. Phosphate extractions of more than 80 pct were obtained when minus 200-mesh ore was used and the acid-apatite ratio was 8:1 or more. The iron and aluminum oxide impurities (R203) present in the crude acid products were monitored, and R203-P205 ratios are reported. Phosphate extractions in excess of 80 pct also were obtained when phosphatic clay wastes were leached. Typically, leach slurries filtered using test leaf filters ex-hibited filtration rates of 100 lb/(h·ft2) or more.

Jan 1, 1987

By J. A. Hrabik

The feasibility of mining deep phosphate deposits by a borehole mining system was compared with mining by proven conventional techniques. An economic comparison of the borehole mining system with conventional dragline and bucket wheel excavator mining systems was completed at various mining depths and production rates. Hypothetical phosphate deposits, with various overburden thicknesses and reserve tonnages, were defined. Geologic conditions necessary for the application of the borehole system were identified. Discounted cash flow analyses based on derived capital and operating costs were used to generate rates of return and product prices. Borehole mining was found to be more economical where overburden thickness was 46 m (150 ft) or greater. However, at 15- and 30-m (50- and 100-ft) thicknesses, conventional surface mining was more economical. Overburden thickness has a great effect on the economic feasibility of the conventional mining systems but less effect on the economics of borehole mining. Economies of scale are only realized in conventional mining, since larger equipment is used to achieve greater production, whereas increased production from borehole mining is achieved using additional equipment units. A comparison of the environmental effects of borehole and conventional surface mining systems showed that borehole mining is environmentally more desirable.

Jan 1, 1987

By J. P. Landriault, F. W. Harrison

"Zinc-iron alloy coatings can be produced by either thermally alloying hot-dipped galvanized steel or by electro deposition. Stelco Inc. produces a thermally alloyed Zn-Fe alloy-coated steel, which is mechanically wiped to remove free zinc.A more extensive use of Zn-Fe alloy-coated steel has been predicted for unexposed autobody and structural part applications, since this material is characterized by good spot weldability and formability, and provides superior corrosion resistance under automotive primers.This investigation has examined the coating composition, corrosion resistance, spot weldability and formability of Stelco's Zn-Fe alloy-coated steel and found its properties to be similar to those of Zn-Fe alloy-coated steel produced by post coating annealing.IntroductionRecently, there has been increased automotive interest in galvanneal, which is characterized by good spot weldability, good paintabilityt and good corrosion resistance when primed. Stelco produces a thermally alloyed zinc-iron coated sheet product similar to galvanneal. However, this product is produced by mechanically wiping the free zinc from the surface of hotdip galvanize to expose the underlying zinc-iron alloy.The surface of Stelco zinc-iron alloy-coated sheet is matte gray and has longitudinal streaks which result from contact with Kevlar wipers during production (Fig. I). This paper describes the coating composition, corrosion resistance, weldability, formability and surface appearance of Stelco zinc iron alloy coatings and, wherever possible, compares these properties to those of galvanneal."

Jan 1, 1987

The Hunter Fracture Zone can be traced into the Fiji group, and onshore SE Viti Levu in the form of NE-trending morphostructures. NW- trending morphostructures offset the NE elements. Structural mapping of Suva Harbour indicates that the NE elements are grabens bordered by faulted monoclines. Faulting is characterised by block-rotations and dip-slip displacements. The NW morphostructures are faults displaying elements of both dip-slip and strike-slip movement. Structural overprinting suggests that the NW faults represent the youngest phase of deformation, and current seismic activity occurs on this trend. A conceptual, geomechanical model of the deformation invokes toppling and wedge failure at the edge of the Fiji platform, translating material downslope into the Hunter Fracture Zone. The interference pattern produced by the superposition of the NW on the NE structures consists of a series of circular features bearing superficial resemblance to volcanic centres. Known mineral deposits in SE Viti Levu correspond closely to these features. The formation of the circular features postdates mineral genesis, suggesting that the features provide a focus for the enhanced exposure of mineral deposits rather than a source of mineralisation. There is a close association between mineralised exposures and interference patterns in extensional structures in SE Viti Levu, and a correlation between these structures onshore, and the Hunter Fracture Zone cum South New Hebrides Trench offshore. Future mineral exploration in the SW Pacific will benefit by closer consideration of the geologic structure of Pacific islands bordering the extensional regimes of deep oceanic trenches.

Jan 1, 1987

By Fletcher A. E W

Ever since it made its debut in 1962, in the form of a Robbins 31R, the raiseborer has become an accepted tool in the mining and civil construction industries. The first raiseborer to be used in the Witwatersrand goldfields made its appearance in 1968. This was a Robbins 42R which could raisebore 185m deep holes to 1,22m diameter. From 1968 to 1973 capability increased with the introduction of first the 61R, then the 71R and finally the 83R, which could raisebore 610m deep holes to 3,66m diameter. This created a demand for larger holes but the cost of bigger, more powerful machines requiring larger, stronger drill pipe, cutters and other accessories was prohibitive. To avoid replacing existing models such as the 71R, and in order to increase their capability, the concept of reaming in two stages sequentially was developed jointly by a German drilling equipment manufacturer, Wirth, their South African subsidiary, Transbor, and a local contractor, Rocbor Raiseboring and Mining Contractors. The result, the Sequential Reaming Head, proved most successful and existing machines, normally limited to 2,44m diameter holes, could now ream to 3,66m diameter. This created a demand for even larger holes. In order to maximise the use of the sequential reaming head to meet this demand the HG330, and subsequently the HG330SP raiseborer were developed. Using a 4,26m/6,02m cutting head, these machines have raisebored holes 1000m deep in hard rock. The raise- boring of the first major hole to be excavated by this combination, the 484m deep x 6,02m diameter surface shaft at Premier Mine is described. Reference is also made to six other shafts which have been completed or are under construction.

Jan 1, 1987

By A. D. Agate

In developing nations, novel mineral processing methods like bacterial leaching are gaining prominence. The principles and practices for isolation and preservation of cultures used in bacterial leaching are discussed with special reference to cultures used in leaching copper from Indian ores. In all, 145 potentially useful microorganisms such as iron- and sulfur-oxidizing bacteria were isolated from various ecosystems of the copper mining areas in the country. The major organisms isolated by enrichment culture technique belonged to T. ferrooxidans and T. thiooxidans species. In addition, thermophilic cultures like Sulfolobus sp. and thermophilic thiobacilli were also isolated. The process of copper leaching was scaled up to the 300-kg level in PVC columns. Since the preservation of efficient cultures in active state was vitally important, a new method was devised that preserved the activity of thiobacilli for a period of more than two years. The novel method of storage in sterile chalcopyrite ore at 8°C can be considered an important advance.

Jan 1, 1987

The distribution of p(~rphyt1 copper deposits, in time as well as place, is used to propose an occurrence model based on the genesis models of Sillitoe and Rona. A magmatic source of the metals is accepted. The characteristic metallogenic epoch and the migration of the mineralization event along an elongate metal province are explained as the result of subduction of an obliquely- oriented strip of mineral-enriched material on the oceanic plate. Two mineral-enriched trails emanate from a hot-spot source of high-intensity hydrothermal activity in an oceanic rift. Because the whole plate system moves relative to hot spots, the hydrothermal source appears to migrate along the rift, and the two trails are not parallel to transform faults, but form a broad "V" centred on the hotspot. Source loci are spaced at intervals of about 3000 km, resulting in the possible repetition of metallogenic epochs, in a subduction zone province, at about 100 m.y. intervals. The position of the mineral-enriched strip can be found graphically, given ages of a series of deposits in a province, and the plate convergence vectors. This knowledge provides an exploration tool at regional scale and, by reflection across the rift, the potential for exploration is extended across oceans. The model has implications for commodities and deposit types other than porphyry coppers.

Jan 1, 1987