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By K. C. Liddell

"Cu/Ni multilayers exhibiting giant magnetoresistance were deposited from a single electrolyte under stepped potentiostatic control. To enable transport measurements to be made without remounting the multilayer film, we developed a novel method that involved plating on a thin metallic basal layer atop a rigid non-conducting Si substrate. Rotating ring-disk electrode techniques were used to monitor the composition and thickness of individual plated layers. Transmission electron microscopy confirmed that the interfaces between adjacent layers were sharp and that the structure of the layers was uniform throughout the film. Atomic force microscopy images indicated that the film's surface was smooth and free of defects.ELECTRODEPOSITION OF THIN MULTILAYER MAGNETIC MATERIALSI. IntroductionElectrodeposition of compositionally modulated films will in all likelihood continue to be used to produce the read heads for stored magnetic data. However, the next generation of head materials will require both improved sensitivity and reduced film thickness. Certain multi layers consisting of thin alternating ferromagnetic and nonmagnetic layers exhibit giant magneto resistance and consequently are promising candidates for read head applications. We have successfully made multilayer films with giant magnetoresistance that have total thicknesses as low as 25 nm, approximately 120 times thinner than the thinnest similar films reported in the literature. This paper describes early results from our work on electrodeposition and characterization of Cu/Ni multilayers, a model system with enhanced magnetic and mechanical properties, including the GMR effect. The structure and composition of the multilayers were determined using TEM, AFM, and electrochemical methods, and their magnetoresistance was measured by the standard four-probe technique. A novel method developed in this work enabled the transport properties of the ultrathin films to be measured reliably without the need to dissolve the cathode or handle the films. To provide a context for these results, short accounts of other work on giant magnetoresistance and multilayer electrodeposition are also included."

Jan 1, 1997

By S. M. Jarrett, W. B. Schmidt

Within the last year, the Nation has been shocked by two major tunneling disasters. Almost exactly a year ago 17 men died in the San Fernando Tunnel in an explosion attributed to gas. A few months later another 21 men died in an explosion laid to the same cause at Port Huron, Michigan. The analysis of the causes of these accidents is still continuing. While it appears that they differ substantially from each other in their specifics, they share the common trait that, like most industrial accidents, they might well have been prevented. Gas explosions in tunneling are neither new nor particularly unusual. Forty years ago, Assistant Director Jarrett was hired as a safety engineer on the Hetch Hetchy Aqueduct in California after an explosion that killed 12 men. Prior to 1946, in California alone, the Bureau of Mines had recorded 27 gas explosions incidental to hard rock mining and tunneling. The purpose of this paper is to review the status of the principal regulations affecting tunneling and to indicate some ways in which safer and more healthful conditions can be obtained. The Bureau of Mines was established by an Act of Congress of May 16, 1910. Since that time the Bureau has been making investigations and compiling and publishing health and safety data relating to mining and to tunneling. If any benefit is to come from an anaylsis of tunneling accidents, it must be the knowledge needed to prevent their repetition. The Bureau of Mines has also had informal discussions with the Department of Labor regarding the possibility of the Bureau's assuming that agency's responsibility for tunnel inspections.

Jan 1, 1997

By Rod Samuels, Rupert Allen, Thomas Harper

"Viceroy Resource Corporation of Vancouver, B.C., has recently developed and brought into production the Brewery Creek Mine, an open-pit heap leach gold mine, located 55km east of Dawson City in Yukon, Canada. Mineable reserves are 15.2 million tonnes of ore grading 1.45 grams/tonne, containing 22 tonnes (707,315 oz) of gold. Ore processing employs the heap leach technology using run-of-mine ore. Highlights of 1996 activity included construction of a 158,000 m2 of leach pad, placing 1.9 million tonnes of ore at a grade of 1. 46 gpt to the leach pad, construction and successful commissioning of the ADR plant, and pouring of the first gold bar on November 15th.Permitting of this mine has drawn significant attention because of the innovated heap leach technology; although this technology has been proven in other jurisdictions, it has not been used at such extreme northern sites where winter temperatures routinely reach -45°C for extended periods.ABSTRACT ONLY"

Jan 1, 1997

By G. L. Finfinger, F. E. McCall, A. A. Campoli, M. D. Zuber

Injecting pressurized water into a coalbed prior to mining reduces mining-generated respirable dust. Because of economic and geological barriers, water infusion for longwall dust control in the United States is now limited to the Pocahontas No. 3 Coalbed in Virginia. Water is pumped into the coalbed through underground boreholes that are drilled horizontally from the headgate toward the tailgate side of retreat longwall panels. This paper theorizes that the barriers to widespread utilization of water infusion for longwall dust control could be overcome by long-duration, low-pressure water infusion through vertical gob-gas boreholes. Currently, 43% of the 72 longwall mines in the United States employ vertical gob-gas boreholes. Computer coalbed-reservoir simulation suggests that one vertical surface borehole could infuse the same longwall panel area as four horizontal boreholes in the current water-infusion system for longwall dust control in the Pocahontas No. 3 Coalbed.

Jan 1, 1997

Cyanide is a significant contributor to the cost of producing gold. Any reduction in cyanide consumption that is achieved through more reliable measurement, and/or more efficient management of cyanide dosing rates, can produce a significant financial saving to the mine operation.

Jan 1, 1997

By C. A. Pickles, D. K. Xia

"In the last few decades, microwave energy has been widely employed in food processing, rubber and plastics curing, and in ceramic sintering. Recently, the application of micro waves as an energy source in extractive metallurgy has received considerable attention from a number of researchers. During the period from the mid-1960s to about 1988, the majority of the research was focussed on the behaviour of materials in microwave radiation. These research activities will continue to be important, since fundamental data on the interaction of microwaves with materials are vital for the successful application of the technology. Since1990, a number of potential applications of microwave processing have been investigated.These include: pretreatment of ores and concentrates, leaching, reduction, preheating of refractories, heating of slags and waste treatment. In this paper, the interaction of micro -waves with materials of interest in extractive metallurgy are reviewed and potential applications are discussed.IntroductionMicrowaves were first used in 1946 for the heating of materials, shortly after radar equipment was invented during the second world war. It was evident that microwaves were very effective for heating water and the technology was quickly adopted for drying and cooking. Since the introduction of the first microwave oven by Raytheon in 1952, many millions of domestic microwave ovens have been sold annually (National Research Council,1994; Atomic Energy of Canada and Voss Associates Engineering, 1990).In extractive metallurgy, microwaves are in the early stages of development (National Research Council, 1994; Atomic Energy of Canada and Voss Associates, 1990; McGill and Walkiewicz, 1987; Bradhurst and Worner, 1990;Peng et al., 1993). However, there are several reasons for the growing interest in the use of this technology in the field of metals extraction. These include the following potential advantages of microwaves: (1) rapid and selective heating of materials; (2) reactions can be catalyzed because the heating occurs on a molecular or atomic level; (3) clean and controllable energy source; (4) the gas volume is reduced and the atmosphere can be controlled as there are no gaseous combustion products; (5) the material is heated internally in comparison to external heating with conventional methods; (6)the temperature of the refractory can be minimized; and (7) the working environment is improved."

Jan 1, 1997

By R L. Keller

Hong Kong has some of the most restrictive practices regarding blasting than any place in the world. Regulations regarding vibration limitations are 1 in/sec for structures and 0.5 in/sec (or even less) for most utilities; with no recognition of frequency response or adjustment. The Hong Kong Geotechnical Engineering Office has one of the most conservative approaches and protective guidelines for pre-blast assessment of slopes subjected to blast vibration (SEE paper '96). The protective measures to control flyrock generally required by the Mines Division are additionally very stringent. It is not uncommon for the costs associated with protective measures or methods which must be employed to exceed the cost of the drilling and blasting itself - or to waiver blasting application unfeasible altogether. From these restrictions it can easily be imagined how blasting in this urban environment would be most challenging.

Jan 1, 1997

By R. F. Korcak

There exists a wide array of industrial byproducts that produce beneficial responses in the soil/ plant environment. These materials range from clean-coal-technology residues produced during the generation of electric power (particularly those high in gypsum) to mineral fines produced by the aggregates industry (i.e., sand, gravel and crushed stone). A number of these materials are examined in relation to potential nutritional interactions in soils and crops with emphasis on trace elements. The significance of utilizing these materials in agriculture as a component of sustainable agricultural systems are discussed.

Jan 1, 1997

By V. L. Stolyarova

The high-temperature Knudsen effusion method was used to study partial pressures of vapour species, activities of components and the Gibbs free energies in the DyF3-Dy2O3 system at the temperature (1357±5) K. Partial pressures of vapour species were obtained by the ion current comparison method, with the DyF3 partial vapour pressure over pure DyF3 as a standard. The equilibrium constant of the gaseous reaction DyF3 + DyOF = Dy2OF4 is evaluated. Thermodynamic data obtained are in a agreement with the available phase diagram of the DyF3-Dy2O3 system. Results of the present study illustrate the negative deviations from the ideal behaviour in the system.

Jan 1, 1997

By Croggon R

Passing a direct current through a jointed fine grained soft rock mass auses the movement of water by the process of electric-osmosis. There are other processes such as electrolysis which transport ions that interact with associated ions and can, in turn, be oxidised. This results in the dissolution products being transported towards the cathode electrode. In the cathode region the ferrous hydroxide is oxidised to ferric hydroxide %%ith consequent precipitation. The cracks and joints are current pathways, along which the ferric hydroxide is deposited. This deposition reinforces the joints and increases the shear strength. By adding calcium chloride to the anode, the rate of corrosion is increased with the concomitant increase of deposited ferric hydroxide along the joints. This, in turn, significantly increases the joint shear strength. The process is pervasive in that the current via the water paths travels through the crack and joint systems The result is that not only specific joints are reinforced but the cracks and mtciconnected voids are also reinforced.

Jan 1, 1997

"The pyrometallurgical method of recycling car batteries suffers from a potential for air pollution violations, which prompts the desire for a viable hydrometallurgicaJ alternative. Several Processes have been proposed, including leach-electrowinning routes using HBF4 and/or HzSiF6 based electrolytes, along with anodes of PbO2 on inert substrates.A study has been carried out to evaluate the proposed systems, with the intention of demonstrating a six month life of an electrolyte-anode combination. The work, which focused on the use of HzSiF6, has indicated that there was no acceptable anode, and has lead to the development of a technique to produce smooth, glassy, adherent coatings on graphite, and to the development of an anode composed of a series of copper cored graphite rods.The paper will present results on leaching and electrowinning experiments, as well as the description of a flowsheet for a pilot plant that will be used to produce one tone per day of refined lead from spent battery paste."

Jan 1, 1997

By Eggleton R. A, Taylor G

As the search for major orebodies continues, the regolith dominated areas of the Broken Hill region remain one of the major exploration frontiers. The past exploration philosophies emphasising bedrock related characteristics have been limited in their ability to effectively explore in the regolith dominated areas, that are a feature of most of the Broken Hill region (Figure 1). If mineral exploration is to be more effective across all of the Broken Hill region, particularly in the regolith dominated areas, an appreciation and increased understanding of the regolith and landscape features are a necessity. Ironically, there have been very few studies of the regional regolith and landscape features of this region. Owing to the previous lack of an established regolith-landform framework, this study initially concentrated on the general characterisation and variation in regolith types corresponding to the area of the Broken Hill Block, within NSW (Willis, 1989; Stevens, 1986). The approach has been to produce a regional regolith-landform map at 1:100 000 scale and conduct a complimentary program of regolith sampling and site descriptions. This was a basis to identify areas for more detailed regolith-landform mapping (1:25 000 scale) and for producing a regional stratigraphic framework and models for landscape and regolith evolution. This information can then be used to provide a basis for regional mineral exploration models and strategies. This paper highlights some of the regionally significant regolith-landform features and their general significance to mineral exploration. More detailed information on specific regolith-landform features and study sites may be found in Hill et al (1994; 1996; in press) and Hill (in prep).

Jan 1, 1997

By J. A. Herbst, A. E. Oblad, Y. C. Lo

The major cost in comminution is energy consumption, which can be as high as 50% of the operating cost. Improvements in plant operations have resulted in up to a 15% reduction in energy usage (kw-hr/t). These improvements have been made through the optimization of grinding efficiency and the use of expert model-based control systems. Optimization involves the determination of the levels of the critical-operating conditions that result in the most efficient breakage of ore in the mill. These optimal levels are identified through plant/laboratory test work and through computer simulation using advanced process models. Model-based expert control achieves the maximum performance from the grinding circuit by identifying the characteristics of the ore in the mill with an optimal on-line estimator. Using this information, the control system dynamically determines the operating point that will yield the optimal performance. Two industrial applications of grinding-circuit optimization and model-based control are presented to demonstrate the power of this new technology.

Jan 1, 1997

By J. A. Haggman

In a country richly endowed in mineral wealth, Climax Arimco Mining Corporation's (CAMC) Dinkidi porphyry Au?Cu deposit in Nueva Vizcaya province, Philippines, represents the most significant mineral discovery in the country in recent times. The deposit is located within a belt of young intrusive and volcanic rocks in the Sierra Madre mountain chain of north Luzon a region previously unassociated with porphyry-style mineralization. Since 1989, drilling of the Dinkidi deposit has outlined a resource of 124 million tonnes of 1.0 g/t gold and 0.41 % copper. Regional exploration throughout CAMC's 37,000 hectare FTAA has identified a further sixteen potential porphyry-related deposits. A new mining law was passed in March 1995 but prior to that CAMC had the first Financial and Technical Assistance Agreement (FTAA) granted by the Philippine government allowing 100% foreign ownership of mining projects.

Jan 1, 1997

By M. C. Ruiz

The leaching behavior of chalcopyrite concentrate in acidic CuC12-NaCI-O2 solutions was investigated. Experiments were conducted under continuos flow of oxygen at atmospheric pressures. The results indicated that among the variables temperature has the largest influence on the dissolution of chalcopyrite in this medium, and high copper extraction can only be obtained at temperatures near the boiling point of the solution. It was also found that the stirring speed did not influence appreciably the dissolution of chalcopyrite. An increase in the oxygen flow rate up to 0.1 1/min increased the copper extraction. The total chloride concentration affects the dissolution of chalcopyrite up to about 4 M. Copper extraction of 93 % was obtained in leaching chalcopyrite of size fraction -400 # Tyler at 105 OC in 2 hours.

Jan 1, 1997

By T. B. Szwilski

ISO 14000 series are voluntary international standards that address environmental management system standards, environmental auditing, environmental labeling, environmental performance evaluation, and life-cycle assessment. An environmental management system (EMS) is a facet of an organization's structure that addresses the immediate and long-term impact of a company's products, services, and processes on the environment. Many companies in the United States are taking a cautious wait-and-see approach before embracing ISO 14000. A few mining companies are reviewing the standards and using them as guidelines. The paper outlines the status, possible benefits to the mining industry, and options available to a company wanting to become involved in the ISO 14000 standards.

Jan 1, 1997

By James P. Dorian

Dramatic economic and political reform is under way in the transitional economies of the world. Transition extends beyond the restructuring of a nation's economy and political thinking. It also affects social, cultural and even religious aspects of society. Transition is a long-term process and generally unstable as the pace of reform is rarely the same across the many spheres of society. As nations modify their economies, industrial activities - including minerals exploration, extraction, processing and trade - are also being affected, according to a Financial Times of London management report. Mining policies are being revised to encourage greater foreign involvement, while legal regimes are being rewritten to protect foreign investments. From India to Peru, and South Africa to Russia, countries have been preparing, improving and expanding foreign investment laws, mining codes and economic stimulus measures to accelerate their minerals development. Privatization of mining is proceeding in many nations. Meanwhile, corporatization of former ministries and government agencies responsible for mining is also occurring. According to Minerals and Mining in the Transitional Economies: Poised For the Future, common objectives in the restructuring of a mining industry are to enhance overall economic and industrial growth, improve efficiencies in mineral recovery and use, acquire newer, advanced technologies, reduce environmental repurcussions of mining and improve safety conditions. The nature of mining is changing noticeably within the transitional economies. The industry is becoming more re¬sponsive to market forces and private sector concerns. The new report examines the changing characteristics of mining in the transitional economies. These include nations moving from centrally planned to market economies, as well as countries in the midst of economic and political reform, including the liberalization of industry. Information is presented to help business planners understand the impacts of transition on mining activities and re-evaluate their longterm strategies and market development policies. The document is divided into 10 chapters. Five of them are devoted to the evolving mining industries of Russia, South Africa, India, Peru and China. These countries were highlighted because their minerals sectors are undergoing changes. These include the opening up of their resources to foreign mining companies. According to the report's author, mining in the transitional economies during the next decade will be characterized by: ? Continued rewriting of national mining policies to create more favorable investment climates. ? Increased exploration for gold and selected base metals in newly opened regions. ? Innovative project financing schemes involving multiple partners and international lending institutions, such as the European Bank for Reconstruction and Development (EBRD). ? Increased gold and copper ore production capacity resulting from new investment and expansion of existing operations. ? Continued geographical shifting of metallurgical processing facilities from developed to other mineral-producing nations. ? Privatization of state-owned mining and processing assets requiring advanced technologies for improvement or expansion. ? Increased awareness of environmental concerns in business decisions related to mining and metallurgy.

Jan 1, 1997

Forty two new apatite and zircon fission track analyses on the Kubor-Marum-Bena Bena area of northern Papua New Guinea severely constrain the timing of tectonic events and hence the tectonic models for New Guinea, particularly arc-continent collision. In addition, the data can be analysed regionally in terms of known and assumed lithospheric fault zones inferred to control mineralisation (eg. Corbett 1994; Kendrick et al 1995; Hill et al 1996) to determine reactivation of these zones. When combined with the new kinematic plate models for the evolution of New Guinea (Hall 1997) there is the potential to predict likely zones of mineralisation. The low-medium grade? Palaeozoic rocks of the Bena Bena terrane yielded a zircon fission track age of 17 Ma, indicating the time of cooling below 200¦C. The age is consistent with `the shift, at about 16-18 Ma, from volcanolithic sediments to mixed provenance sediments rich in quartz and metasedimentary lithic fragments in the southern Finisterre Ranges (Abbott et al. 1994). This shift was recorded in the Sukurum Formation, which ranges in age from Middle Miocene to Pliocene with quartzose and metasedimentary grains in all samples. Although recording rocks at temperatures of 200¦C and hence depths of ---5km, the 17 Ma age suggests the Bena Dena terrane was rapidly cooling at that time due to uplift and erosion, supplying metasediments to the southern flank of the Finisterre Range, currently 100 km to the east. Significantly, the Middle Miocene Akuna Intrusive Complex, dated 14-17 Ma by Page (1976), lies almost entirely within or adjacent to the Bena Bena terrane. Potentially the uplift, erosion and cooling of the terrane at 17 Ma may have been caused by the rising plutons. If so the 800 sq km exposure Akuna Intrusive Complex at the SE end of the Bena Bena terrane may have been the focus of uplift and supplied the metasedimentary detritus to the Finisterre Range. This suggests that the Finisterre Range was not far removed from the Bena Bena terrane, perhaps less than the 200 - 400 km indicated by Abbott et al (1984). The Akuna Intrusive Complex probably resulted from subduction of the Solomon Sea Plate beneath the PNG margin. In order for the subducted slab to reach depths of -100km below the area to facilitate partial melting and plutonism (Hamilton 1994), subduction probably commenced 3-5 Ma Ma before plutonism, ie at or prior to 20 Ma suggesting a significant change in the tectonic regime at -20 Ma, perhaps related to collision of the Solomons - Ontong Java Plateau collision (eg. Hall 1997). The main result to emerge from the 28 apatite fission track analyses is that the whole of the study area underwent rapid cooling due to uplift and denudation in the Late Miocene, mainly between 7-10 Ma. Results from several samples indicate that they were not totally overprinted prior to uplift indicating maximum burial of -3 km in the Middle Miocene, assuming normal temperature gradients. The burial is less if higher gradients are assumed, allowing for Middle Miocene plutonism. The Late Miocene cooling in the Mobile Belt agrees well with the Pliocene to Recent cooling in the Fold Belt to the SW, interpreted to be due to uplift and erosion associated with fold and thrust deformation of the Miocene Limestones (Hill & Gleadow 1989). This timing relationship suggests, that compressional deformation in the Mobile Belt occurred in the Late Miocene, at 105 Ma, and that the deformation migrated towards the undeformed foreland in the southwest in the Pliocene, at 5-2 Ma. The regional Late Miocene uplift and denudation in the Mobile Belt is also consistent with that postulated by Crowhurst et al (1996; 1997) for northwest PNG, although they considered the event to have occurred mainly from 8-5 Ma. If so, then the uplift and denudation may have been migrating from east to west as well as to the south into the Fold Belt. These timing relationships place significant constraints on tectonic models for the area, indicating that the major compressional pulse in PNG commenced in the northeast at -10 Ma and migrated to the southwest and west in the latest Miocene to Pliocene. This suggests that the initial arc-continent collision and associated shortening occurred in the Late Miocene around -10-12 Ma. This immediately followed intrusion and cooling of the Akuna Intrusive Complex at -17-14 Ma and the Bismarck Intrusive Complex at -12.5 Ma (Page 1976), indicating a linkage between the end of plutonism and the start of compressional deformation. The timing is consistent with the observation of Hamilton (1994) that in areas of subduction `the common regime in overriding plates is extensional and leading edges are crumpled only in collisions. This suggests that the Middle Miocene magmatism in northern New Guinea occurred during extension above a subducting slab and was terminated by Late Miocene arc collision and resultant compression commencing at -10-12 Ma. In general, these data indicate that the acme of denudation and cooling in the Mobile Belt was in the Late Miocene, with relatively little denudation there since. In contrast, Hill & Gleadow (1989) found that the peak of denudation in basement outcrops in the Fold Belt was in the Pliocene at -4 Ma. However, in this study some samples from the Mobile Belt yielded Pliocene ages or high

Jan 1, 1997

By W. H. McDonald, D. D. Carr

The use of stone in building construction predates written history. From the time that stone was first used, builders have constructed stone buildings predominately from local or regional materials. However, since World War II, the stone business has become increasingly global. For example, French limestone is now sold to builders in the United States, and American granite is shipped to Japan. The internationalization of architectural and construction firms has encouraged this trend. Differences among nations in trade practices, environmental demands and the level of knowledge of dimension-stone characteristics make international trading in stone a risky and potentially disastrous business for unwary participants.

Jan 1, 1997

By D. M. Walters, C. M. van der Vyver, L. J. deVulliers

The occurrence of underground fires in narrow tabular ore- bodies where high density timber support is used is a dangerous and disruptive occurrence. The containment and extinguishing of the fire remains a very important consideration in reducing not only the loss in production time but also in limiting the extent of the area damaged by the fire. Mindful of this, Gold Fields have adopted and developed the inert gas generator system from its origins in Poland for use in Group precious metal mines. The system generates an oxygen- deficient atmosphere which is introduced in the fire area after this has been sealed. A number of problems had to be overcome to operate this system successfully within the infrastructure of these mines. Of particular significance is the operation of a jet engine, the prime component of the system, at air pressures encountered below sea level. The modifications have been found to be satisfactory to the point where, since 1992, ten underground fires have been extinguished using this system. Invariably, the areas affected by these fires were extensive (over 1 000 000 m3) and required continuous operation of these units over extended periods of time (in some cases in excess of 400 hours).

Jan 1, 1997