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By Ihor A. Kunasz

Lithium minerals occur predominantly in pegmatites that contain mineral assemblages derived from the crystallization of post- magmatic fluids or from the metasomatic action of residual peg- matitic fluids. They have been the traditional sources of raw material for ceramic and chemical industries. With the discovery of the Searles Lake deposits, brines became new sources of lithium, and, today, two brine deposits satisfy nearly one-half of the free world demand for lithium chemicals. Indeed, lithium production from pegmatites has been superseded by brines sources. In the United States, the brines of Clayton Valley, NV, have been exploited since 1964 by Cyprus Foote Mineral Company, a subsidiary of Cyprus Minerals Company. In Chile, Sociedad Chilena de Litio Ltda., an affiliate of Cyprus Minerals Company, is now producing lithium carbonate from the brines of the Salar de Atacama. Recently identified brine deposits suggest that these may well become the prime sources of lithium chemicals. In Bolivia, the government is negotiating the rights to exploit the brines of the Salar de Uyuni. The Salar del Hombre Muerto in Argentina is being evaluated as a future center of chemical production. The brines of the Great Salt Lake of Utah, the Smackover Formation, and the Imperial Valley geothermal field have been defined as important resources of lithium. In Tibet, high concentrations of lithium have been reported in several saline lakes. In the People's Republic of China, lithium may be produced from the brines of the Dabusan playa in the Qinghai Basin. The 1950s saw a great number of lithium companies develop. However, following the termination of the Atomic Energy Commission purchase program in 1959, several companies, such as Maywood Chemical Co., American Lithium Chemicals, and Quebec Lithium Corp., were forced to close their operations. Nevertheless, with the development of new applications in glass ceramics, air conditioning systems, synthetic rubber, and metallurgy (aluminumpotlines), the lithium industry grew steadily. With the potential application of lithium metal in batteries, nuclear reactors, and fuel cells, a steady growth can be foreseen. New products and new applications are likely to stimulate exploration for expanded reserves as well as the search for new sources from which lithium could be extracted economically. Presently identified reserves and production capacity are sufficient to satisfy the conventional market growth of lithium.

Jan 1, 1994

By T. P. Mucho

Mine roof failure due to excessive horizontal stress has been recognized as a major cause of hazardous roof conditions in some mines. Stress measurements gathered by the U.S. Bureau of Mines (USBM) at 24 different eastern mines show horizontal stress to be typically 2 to 3 times as great as vertical stress. The focus of current Bureau work is to develop detailed design parameters to assess and control the effects of horizontal stress. To facilitate the recognition of horizontal stress effects and to easily determine principal stress direction without resorting to cumbersome, expensive, and time consuming field measurements, the Bureau has developed a stress mapping methodology. Stress recognition and direction determination are required to successfully employ a number of control strategies such as mine layout, mining sequences, and support optimization to control the effects of horizontal stress, thereby increasing the safety of U.S. coal mines. This approach has been used in other major coal producing countries, most notably Australia and the UK, and has greatly enhanced the safety of their mines (1). This paper discusses horizontal stress, directional based control techniques, and provides guidelines for the use of the stress mapping technique. A case study of a mine where the technique has been used is also presented.

Jan 1, 1994

By Connie Postupack

The purpose of the workshop is to show the effect of various blasting factors on the overall results.

Jan 1, 1994

By Louis M. Schlesinger

KMG Minerals, Inc., a mica-feldspar-quartz producer in Kings Mountain, N.C., uses about 50% of its plant's -200 mesh slimes to manufacture brick. However, the company is unable to market the remaining 50% of this fine mineral mixture. The NCSU Minerals Research Laboratory operated a pilot plant to process these slimes to produce an additional product. The process, consisting of blunging and hydraulic sizing, was designed to separate a kaolin-enriched -270 mesh product from the bulk of the coarser +270 mesh "grit" minerals. Size analysis showed that this product was 80% finer than 20 microns and 50% finer than 6 microns (in equivalent spherical diameter). An evaluation indicated that it is a hydrous aluminum silicate that might be suitable in the filler and extender markets for traffic paint, some types of plastics, joint cements, and dusting compounds. Because of its high viscosity, it will be difficult to use more than a small percentage in cast ceramic bodies. However, it might be possible to use up to 10% in extruded ceramic bodies (i.e., electrical porcelain). The 15.2 cm (6 in,) diameter Linatex Hydrosizer was tested using a range of teeter water flowrates, so that the net rise velocity was varied from 0.10 cm/s to 0.40 cm/s. The solid feed rate to the sizer was maintained at approximately 1.1 t/hr/m2 (0.12 ton/hr/ft2). Tests were run using both "shallow" (i.e., 6 in.) and "deep" (i.e., 15 in. teetered beds. The best overall result was obtained when the sizer was operated with the "deep" teeter bed and a net rise velocity of 0.10 cm/s. About 97% of the +270 mesh material was rejected and approximately 79% of the -270 mesh material was recovered in a 14% solids slurry.

Jan 1, 1994

By D. J. Senor

Closed chamber incineration (CCI) is a novel technique by which irradiated nuclear graphite may be destroyed without the risk of radioactive cation release into the environment. The process utilizes an enclosed combustion chamber coupled with molten carbonate fuel cells (MCFCs). The transport of cations is intrinsically suppressed by the MCFCs, such that only the combustion gases are conducted through for release to the environment. An example CCI design was developed which had as its goal the destruction of graphite fuel elements from the Fort St. Vrain reactor (FSVR). By employing CCI, the volume of high level waste from the FSVR will be reduced by approximately 87 percent. Additionally, the incineration process will convert the Sic coating on the FSVR fuel particles to SiO2, thus creating a form potentially suitable for direct incorporation in a vitrification process stream. The design is compact, efficient, and makes use of currently available technology.

Jan 1, 1994

By David G. Dixon

A mathematical model is derived in dimensionless form which simulates the effluent concentration response of reagents from spent heaps under both fresh and recycled water rinsing. The model is based on dispersion from isochoric pathways distributed in length and cross-section, oriented normal to convection channels in ideal plug flow. The effects of heap height, rinsate flow, and initial reagent concentration are examined. It is shown that the rinsing cycle undergoes a distinct shift between fast and slow rinsing at a certain time depending on the amount of stagnant solution in the heap, and the distribution of dispersion pathways. Results of preliminary column rinsing tests on both agglomerated and unagglomerated ores are presented which partially validate the model.

Jan 1, 1994

By Adrian J. Moore, Alan B. Richards, Rob Evans

Air and ground vibration from blasting is influenced by the delay pattern that is used. Wavefronts from blastholes fired in a blasting pattern can combine in certain circumstances to give increased blast vibration levels. A simple computer model has been developed which shows the combined effect of wavefronts from a multi-hole blast and identifies if wavefront reinforcement occurs, and permits delay patterns to be designed which will avoid or reduce wavefront reinforcement.

Jan 1, 1994

By P. Muduli, Y. Xi, T. M. Yegulalp, A. J. Arias

A short review of current practices and recent developments is followed by a description of a newly developed approach for solution of the optimum, ultimate pit limit problem. The new approach utilizes network modeling of the problem for solution by maximum flow algorithm. The latest developments in the implementation of maximum flow algorithm present significant time and memory savings as compared to initial development due to Ford and Fulkerson (1956). Results of a series of computational tests are presented to demonstrate how this approach performs as compared to the well-known Lerchs Grossman algorithm. It is also shown that the solution by the new method automatically includes several optimal solutions based on a predetermined number of benches to be included in the analysis.

Jan 1, 1994

By Mike McGill, Stephen Chung, Dale S. Preece

Cast blasting can be designed to utilize explosive energy effectively and economically for coal mining operations to remove overburden material. The more overburden removed by explosives, the less blasted material there is left to be transported with mechanical equipment, such as draglines and trucks. In order to optimize the percentage of rock that is cast, a higher powder factor than normal is required plus an initiation technique designed to produce a much greater degree of horizontal muck movement. This is a significant change from normal blasting practice where fine fragmentation and sufficient muck movement were the prime requirements to permit efficient excavation.

Jan 1, 1994

Determine the effectiveness of remining operations in reducing contaminant load (acidity, iron, and sulfate) of discharges emanating from abandoned surface and underground coal mines. Background Until the implementation of remining initiatives, most States had regulations that held the operator remining an abandoned site responsible for preexisting acid mine drainage (AMD) discharges. For example, if a mining. company wanted to remine an area hydrologically connected to an existing AMD discharge, the company became responsible, as soon as the site was activated, for treating that discharge to meet effluent standards. If the mining operation improved the quality of the discharge, but the discharge failed to meet effluent standards, the company was held accountable for perpetual treatment. Because of this regulation, most mine operators avoided abandoned sites with minable coal reserves and AMD discharges. However, changes in remining legislation allow coal companies to be released from treatment liability as long as the post-remining pollution load does not exceed the pre-remining level. If remining can improve water quality through improved mining and abatement techniques, abandoned mine land (AML) areas that previously were liabilities could become

Jan 1, 1994

Improve the reliability and accuracy of subsurface images using constrained tomography with enhanced ray-tracing capabilities. Background Geophysical tomography is a technique for imaging the structure of a rock mass using seismic or radio waves, in the same way that medical CAT scans image human tissue using X-rays. Tomography has found numerous practical applications related to mining, including lithologic and structural characterization, fracture detection and fluid monitoring, void detection, and evaluation of stress state and integrity of mine structures. Problems Two fundamental problems have largely prevented geophysical tomography from enjoying the tremendous success achieved by medical tomography. The first is a consequence of practical limitations on the placement of sources and receivers of wave energy: ideal resolution can be attained only when the region being imaged is entirely surrounded by sources and receivers, so that it is crossed by rays traveling in all possible directions. When such coverage is impossible or impractical, the inversion becomes underdetermined: there id not enough information in the measured data to provide a mathematically unique solution. The second major problem in geophysical tomography is the necessity for detailed ray tracing. Commercial software, as well as previous U.S. Bureau of Mines (USBM) software, employs a ray-shooting algorithm that may be unable to model some ray paths when velocity contrasts are larger than about 100%. These ?shadow zones" result in loss of data and degradation of reconstructed images.

Jan 1, 1994

By Ronald S. Conti

This U.S. Bureau of Mines (USBM) report describes various fire-fighting resources available to the mining industry and examines the fire preparedness of four western coal mines. Information regarding fire-fighting equipment indicates that an inadequate maintenance program may cause component failure of fire extinguishers, damage to waterhoses is usually a result of improper care, and foam may be a convenient means of conveying water to the fire. Performance data relative to water nozzles (throw distance) and specific practices to improve the state of preparedness in many of these areas are discussed. Studies also indicated that a high-expansion foam plug, will travel down an entry, with a 1% rise in elevation, 207 m (680 ft) before a plywood stopping separating the generator and plug failed. The advance rate of the foam plug decreased when the entry is dry, requiring more foam concentrate and as the foam spread further down the entry. An examination of the mines showed state-of-the-art monitoring systems were common at the minesites. Fire safety was also stressed, including early detection and rapid response of the miners to evacuate the mine. However, the mines placed little emphasis on performance of water nozzles, or personal protective clothing for the underground firefighters.

Jan 1, 1994

By Leonard A. Duval

This concept employs a viable energy saving method that uses a solvent to separate oil from particle matter; it can be used in metal forming industries to deoil sludges, oxides, and particle matter that is presently committed to landfill. If oily particles are used in their oily state, severe consequences to environmental control systems such as explosions or filter blinding, occur in the air handling equipment. This is due to the presence of hydrocarbons in the stack gases resulting from the oily particles. After deoiling, the particles can be recycled and the separated oil can be used as a fuel. The process does not produce a waste of it's own and does not harm air or water. It demonstrates the dual benefits of being commercially viable and in the national interest of conserving resources.

Jan 1, 1994

By M. E. Smith

Chile is the world's largest copper producer and as such sets the standard of practice in copper SX/EW design. The authors summarize the liner systems used at many of Chile's major copper producers both operating and planned. The evolution in the state of the art is also discussed, considering both economic factors and Chile's burgeoning environmentalism.

Jan 1, 1994

By J L. Maule, S J. Mathews, K A. Rodgers

Gold and Silver bearing epithermal veins of the Golden Cross deposit are hosted in Miocene and Pliocene calc-alkaline volcanics occurring 8 km northwest of Waihi at the southern extent of the Coromandel Peninsula, North Island, New Zealand. Veining occurred during a period of hydrothermal activity that began early to late Pliocene, and possibly continued into the Pleistocene.   Field relations and petrographic relationships reveal that multiple generations of FeS2 occur in the Golden Cross region, with FeS2 occurring in all nine rock types recognised at Golden Cross. The variability of FeS2 morphology was investigated by preparation of high purity FeS2 separates, and grain counting. Marcasite is the dominant FeS2 phase at Golden Cross, and along with pyrite is shown to have a systematic habit variation. Pyrite shows a sequence from cubes through octahedra to pyritohedra to dendritic growth. This pyrite sequence conforms to an experimentally determined sequence. The parallel sequence for marcasite at Golden Cross is from tabular through bladed aggregates to euhedral miscellaneous marcasite morphologies. The FeS2 sequences observed are believed to be due to increasing temperature, and perhaps also increasing FeS2-oversaturation and fluid flow.

Jan 1, 1994

By S. N. Ojha, Gouthama, R. K. Mandal

"Spray deposition processing of liquid immiscible alloys, based on AI-Pb and Cu-Pb systems have been investigated. Process variables have been optimized to generate uniform dispersion of ultrafine second phase particles in· the matrix of the primary phase. Mechanisms governing the microstructural evolution in this synthesis methodology are discussed. Results of the present investigation are used to demonstrate that rapid solidification of atomized droplets initially provides a high nucleation rate of the second phase during the liquid phase separation. The solid matrix phase nucleates at a later stage and grows with a high velocity enabling trapping of the dispersed phase. Subsequent alteration in the size and size distribution of the second phase is suggested to arise further during deposition of high velocity droplets. Possible reasons for this effect are brought out. Microstructural features of atomized powders and spray-deposits of these alloys are presented to support the present approach of synthesizing composites. IntroductionIn recent years, synthesis of advanced materials with metastable microstructures and ultra fine dispersion of second phase particles has led to the development of novel techniques of materials processing. The other requirement of such a processing methodology is to achieve near-net shape geometries in less number of processing steps. The solidification processing method via spray deposition route qualifies these criteria. This process primarily involves atomization of a melt by high energy gas jets into spray of droplets which are subsequently propelled by the kinetic energy of the gas towards a deposition substrate to build-up a thick high density preform. Although the concept of spray deposition was pioneered by Singer [1] in the early seventies, the fundamentals of the deposition process has been understood only recently [2-4]. Several benefits of spray deposition processing are by now well established [5,6]. Rapid solidification effects are inherent in spray deposition processing due to high heat exchange rate at the droplet-gas interface and also on the deposition surface by force convection. Since considerable heat extraction occurs from the atomized spray prior to droplet consolidation, a relatively low processing temperature is ensured in this process. As a result deleterious coarsening phenomenon can be minimized. In addition, controlled maneuvering of the substrate provides the capability of the process in producing disc, sheet or tube shape preforms of difficult to work materials in a single operation. A significant improvement in properties, resulting from microstructural homogeneity and refinement in grain size induced by spray deposition has been reported for several alloy systems [7,8]."

Jan 1, 1994

An integrated approach to risk management to complement insurance is the sustainable way forward for the modem organisation. For risk management to work, its various aspects need to operate interactively, not in isolation from insurance. This is the approach recommended in this paper. The risk management process is a strategic method for reducing an organisation's total cost of risk. Well established and basic risk management techniques will help identify and achieve risk management Objectives.

Jan 1, 1994

By R. K. Rajamani

The theoretical model based on fluid mechanics, in conjunction with the laser-Doppler velocimetry (LDV) measurements, elucidate the size-classification mechanisms in an industrial hydrocyclone. The model has no adjustable parameters and involves solving the Navier-Stokes equations to predict the liquid-phase velocities. The spatial-concentration gradients were determined considering the particle phase in the Lagrangian frame and the classification curve was determined by balancing the forces acting on the particle. The force balance requires liquid velocities, which in turn depend on the local volumetric concentration of the particles. Hence, complete modeling work involves coupling both the concentration and liquid-phase velocity calculations until convergence is reached. Finally, the experimental and predicted classification curves were presented for 250-mm hydrocyclone operating at high-percent solids.

Jan 1, 1994

By J. G. Groppo

Lowering of filter cake moisture of ultra-fine coal to a 20 percent level using conventional vacuum filtration could be achieved using a combination of metal ion and surfactants. Pretreating coal slurry with about 0.2 Kg/ton of a surfactant and 50 ppm of copper or 10 ppm of aluminum ions provided filter cake containing 22.8 percent moisture. The lowering of moisture is explained due to formation of hydrophobic micro-agglomerates which facilitates dewatering.

Jan 1, 1994

By G. D. Hood, C. E. Jordan

The US Bureau of Mines investigated rapid froth flotation through more efficient bubble-particle collisions that improved the overall flotation kinetics. An in-line static mixer efficiently mixed the bubbles, water and ore, selectively attaching these bubbles to the hydrophobic mineral's surface. As the mixture entered the flotation chamber, the hydrophobic mineral was already attached to the bubbles and was quickly floated away from the remaining ore pulp. The rapid flotation system was evaluated for beneficiation with a western porphyry copper ore containing 0.67% copper and with a phosphate-bearing amine flotation tailings sample containing 9.5% P2O5 in a quartz matrix. Over 88% of the copper was recovered from the ore in a rougher concentrate containing 5.9% copper at a rate seven times, faster than conventional flotation. Sixty percent of the quartz in the phosphate-bearing sample was floated at a rate four times faster than conventional flotation. The unfloated product retained 80% of the phosphate in a 16.9% P2O5 concentrate.

Jan 1, 1994