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The treatment of gold-plant tailings with ferrous sulphate to remove the cyanide is currently in use, on several gold plants. In some cases there is scope for optimization the process. The present work provides a detailed study of the reaction between cyanide and ferrous sulphate. Optimal conditions for the removal of total cyande required a ph of 5,.5 to 6,5 and an Fe:CN molar ratio of 0,5. Ferrocyanide ion is shown to be unstable In aqueous acidic solution, with rapid oxidation to ferricyanide, (Fe(CN) 6 ), and formation .of Fe(CN)5H2O3- at pH values below 4, The precipitate from the reaction between cyanide and ferrous sulphate consists mainly 01 Insoluble Prussian blue, Fe4[Fe(CNI&!.3,and IS shown to be unstable in the presence of alkaline solution, since it decomposes rapidly at pH values above 7 to form ferrocyanide, (Fe(CN)6 ), in solution and various insoluble iron oxides,

Jan 1, 1992

By Linda J. Dahl

The U.S. Department of the Interior, Bureau of Mines is developing a process to selectively extract manganese from oxide ores as part of its in situ leach mining research program. The Bureau is conducting site characterization studies of two manganiferous iron-formation deposits which include: drill core, regional stratigraphic relationships from the existing geologic database, ore body geometry, geologic structure, hydrologic conditions, proximity of ore minerals to the leach fluid paths, surface subsidence potential, and data collected from laboratory leaching experiments. This information is being used to evaluate the technical, environmental, and economic feasibility of in situ leach mining of manganese for these two deposits. This paper will focus on the stratigraphy, mineralogy, ore textures, fractures, permeability, and porosity as they relate to in situ leach mining.

Jan 1, 1992

By Strickland R. E J

Heap leaching is establishing itself as an efficient method for the extraction of gold from low grade ore. It has the advantage of low capital costs, low operating costs and rapid startup. However, not all ores are amenable to heap leaching. It is only applicable to well oxidized ores that have reasonable permeability characteristics. Ore with excess fines or clay often display low permeability and are unsuitable for heap leaching.In this study, an attempt has been made to increase the rate of cyanide leach solution percolation by flocculating clay particles or reducing the surface tension of the leach solution. A wetting agent was found to decrease the rate of gold dissolution, possibly by presenting a hydrophobic surface to the gold particle. Flocculation of the clay increased the solution flow rate. The flocculation agent had no affect on the total gold leached but decreased the leaching rate.

Jan 1, 1992

By Cotton R. E, Cox R

Digger Rocks is one of several nickel-bearing sulphide deposits localised within komaLiitic volcanics of the Forrestania Greenstone Bell within the Archaean YiIgam Block of Western Australia. Exploration and evaluation to April 1990 have delineated a resource, at a nominal cut-off grade of 0.5 per cent Ni, of 1.9 Mt at 1.1 per cent Ni within a lensoid sulphide body which strikes NW, dips 50°SW, and occurs at a depth of 30 - 110 m below surface. There has been no production from any of the Forrestania nickel deposits to-date. The deposit, comprising both disseminated and massive sulphides, has maximum dimensions of 400 m strike, 115 m vertically and 90 m true width. Generally the massive sulphides occur at the base of the disseminated sulphides, on or close to the base of the Digger Rocks dunite. The two main massive sulphide lenses have maximum dimensions of 120 m strike, 75 m vertically and 16 m true width (northern lens) and 60 m strike, 25 m vertically and 4 m true width (southern lens). The average grades of the massive and disseminated sulphides are 5.9 per cent i and 1.2 per cent i respectively. The massive sulphides generally have sharp hangingwall and fOOlwall contacts and display strong internal grade anisolropy.The massive sulphides are mainly within the supergene zone and consist of violarite, pyrite and marcasite. The disseminated sulphides are mainly within the primary zone and consist of pentlandite, pyrrholite, pyrite and minor chalcopyrite. Alteration zones, up to six in number, are complex in detail. The sulphides are capped by an average of 30 m of sub-economic, leached, siliceous, oxidised material.A genetic model for the deposit is described which places Digger Rocks in Category 2 (sulphides in large layered dunite bodies) of the latest classification of komatiitic nickel sulphide deposits in the Yilgam Block of Western Australia by Hill and Gole (1990).

Jan 1, 1992

By Kapoor M. L

EMF measurements were performed in the temperature range of 933-1095 K to determine the thermodynamic properties of oxygen dissolution in liquid lead and lead-tin alloys with tin in the dilute concentration range of 0 to 6 atom per cent. The oxygen in the Pb-O system was varied by equilibrating with (PbO) slag, and that in the Pb-O-Sn system was varied with the addition of lead oxide. Wagner's interaction parameter approach was used to evaluate the self interaction parameter and ternary interaction parameters at different temperatures, to yield: E8(pb) = 97.35 - 113.27 x 103/t Eo(pb) = 139 - 20.616 x104/1' Quasichemical formulation was employed to yield Inf to reveal the effect of tin on oxygen in lead. Results have been predicted on the basis of classical models and those obtained using the QCT approach of Alcock and Richardson at Z=2 have been found to agree with the experimental Data.

Jan 1, 1992

A number of factors have resulted in the widespread use of computer simulation as a day to day tool in the mineral processing industry, as is the case in most engineering disciplines. A number of simulation packages, both steady-state and dynamic are now available commercially. The developers of such software face an enormous challenge in maintaining and improving the packages due to the complexity inherent in such systems. This problem known as the software crisis faces all developers of complex software. Object-oriented (OOP) and design is a methodology which has been developed to try and minimise this problem. The use of the OOP paradigm in the devlopment of simulation software for mineral processing systems is explored in this paper and it is found that OOP techniques have major benefits for the design and development of such software.

Jan 1, 1992

The State of Washington has a federal program that gives the Office of Surface Mining responsibility for assuring the reclamation of lands affected by coal mining. Most of Washington's coal-bearing regions lie west of the Cascade Mountains. The state's coal reserves are estimated at 1.4 billion tons, about 0.3 percent of the nation's total coal reserve. Steeply dipping. minable seams range from 2.5 to 25 feet in thickness. The occurrence of coal in Washington has been documented since the early days of its settlement; at one time, coal production played a significant role in the state's economy. During the late 1800s and early 1900s, coal was second only to lumber in Washington's industrial production. Coal production declined as other sources of energy were developed. By 1959, production was at 200,000 tons. Regulation of the coal mine operations in Washington is conducted by the Office of Surface Mining's Casper, Wyoming, Field Office and its local office in Olympia, Washington. All permit applications and abandoned mine land reclamation are completed by the OSM Western Support Center in Denver, Colorado. Inspections of mine and reclamation sites are conducted by OSM reclamation specialists located in Olympia.

Jan 1, 1992

By Gary P. Sames

This report discusses some practical applications of a geotechnical investigation conducted by the U.S. Bureau of Mines that can help mine operators meet revised Federal regulations in their roof control plans. The investigation, designed to characterize roof conditions near the coalbed outcrop in drift coal mines in eastern Kentucky, revealed that weathered stress-relief joints near outcrop are crucial ground control factors in the region. The joints' origin and character were determined through underground mapping of many joints in coal mine roof and detailed observations and measurement of joint trends and physical characteristics in widely separated strip mine highwalls and roadcuts. This resulted in an understanding of stress-relief-joint patterns and the effect of various rock types on the intensity of weathering in the joints. That information is used in this report to show how stress-relief joints contribute to roof failure and how, through improved roof support and mine planning, safer roof support plans can be developed.

Jan 1, 1992

By Amusin BZ

The concept of rigid or yielding bolts is discussed based upon support requirements for excavations of equivalent geomechanical behaviour. The concept of equivalent geomechanical behaviour is introduced for comparison purpose where the rock mass properties are varied for a given depth (stress) so that the deformation of the roof without any support remains constant = 300mm. A simple experimental theoretical analysis for a uniform stress field acting on an axi-symmetric excavation is conducted to establish roof bolt requirements under different conditions such as width of a given excavation, time of setting of support etc. Results are presented in graphical forms.

Jan 1, 1992

By Carolita U. Kallaur

In contrast with the United Kingdom, the Netherlands, and Japan, the marine mining industry in the United States exists at a very rudimentary level. Depletion of onshore resources has undoubtedly been an important factor in the development of marine mining industries abroad. However, the institutional framework presented by government can advance or present obstacles to the development of a marine minerals industry. The role of government involves questions of the degree of risk sharing between government and industry, as well as questions of the strategic and economic importance of developing the technology and the infrastructure to recover minerals. In 1984, the Minerals Management Service (MMS) created a program office to handle these questions and to respond to a potential increase in commercial opportunities that might result from the Presidential Proclamation establishing a U.S. Exclusive Economic Zone. A critical component to the success of the program has been the formation of partnerships with coastal States to pursue projects in areas of mutual interest. Such projects involve commodities showing commercial promise and strong public need. Such a cooperative approach lessens the risk of Federal, State, or private interests working at cross purposes.

Jan 1, 1992

By S. K. Sharma

The present study attempts to critically review the pillar-design as required by Coal Mines Regulations of India vis-a-vis latest rockmechanics formulae, Equivalent material modelling was the approach adopted for testing the safety and stability of the pillar sizes predicted by various formulae. Two parameters, considered here for calculating pillar sizes was the stresses acting over the pillars and the strength of the pillars. Stresses acting on the pillars were calculated by the tributary area method. Based on the studies of Coates and Hustrulid, the stress obtained was reduced by 40 percent. For calculating the strength of the pillars, three formulae, namely Holland and Gaddy, Salamon and Munro and Central Mining Research Station, India, were used. The pillar widths were then determined by equating the product of recommended factor of safety and pillar stress with the pillar strength.

Jan 1, 1992

By W. K. Connor, O&apos

The Bureau of Mines has conducted beneficiation, carbothermic reduction, and leaching tests of Mn oxide ores as part of its evaluation of the Mn and Co resources of the West- Central Arkansas District. The major Mn oxides in the ore include cryptomelane, psilomelane, pyrolusite, and lithiophorite. Cobalt is contained within the Mn oxides. Nonbeneficiated ore was reduced at 800' C with coal and leached in ammonium sulfate and ammonium carbonate leach liquors. Ore concentrates were calcined at 600" C prior to reduction under the same conditions as the raw ore. Head analyses reported up to 21 ptt Mn and 0.11 pct Co. Extractions of 70 to 90 pct Mn and 40 to 60 pct Co were achieved.

Jan 1, 1992

By W. E. Threlkeld, J. A. Treacy, L. J. Stewart, J. C. Ruckmick

The Mustang Draw sulfur deposit is developed in a dolomite reef complex in the Permian San Andres Formation on the eastern margin of the Midland basin in Glasscock County, Texas. Interpretation of the genesis is dependent upon coincidence of a NE-trending fault system with the NW- trending reef complex. The reefs, reef talus, and oolites contained up to 30% interstitial anhydrite. It is indicated that artesian ground waters, hydrocarbons, and bacteria circulated into the reef complex along the fault zone. Bacterial consumption of hydrocarbons and anhydrite created extensive porosity, permeability, and deposition of sulfur in vugs and cavities, and along fractures in the dolomite.

Jan 1, 1992

By Roger N. Kust

Removal of heavy metals from industrial process streams is becoming increasingly important for _the recovery and reuse of values in process tails. Technology has been available for several years which removes heavy metals, from dilute (0.1-3.0 g/L) streams, as hydroxide or hydrated oxide sludges, allowing discharge of washed cakes with up to 60% solids. This paper reports on improvements to this technology which now allows treatment of streams with metal concentrations in excess of 60 g/L while eliminating the need for thickeners. Streams containing copper, iron, aluminum, chromium, nickel, zinc, cobalt and lead have been successfully treated.

Jan 1, 1992

By J. Lizak

Calcium carbonate is one of the highest volume industrial mineral products in North America. It is used in filler and extender applications, roofing products, floor tile, glass manufacture, etc. Calcium carbonate has over a dozen major filler and extender applications plus a host of minor uses. North American consumption of calcium carbonate fillers and extenders in 1991 is estimated at over 5,000,000 tons valued in excess of $400,000,000. There were five major suppliers of calcium carbonate fillers in the Middle Atlantic region in 1988 :?Bestone, Genstar, National Gypsum, Thomasville Stone and Lime, and White Pigment. With the exception of Genstar's Maryland operation, all of these operations are within a few miles of York, Pennsylvania. The Millington Group (TMG) purchased the assets of Bestone Corporation in February of 1989. TMG then seized the opportunity to strengthen its business position by acquiring National Gypsum's and White Pigment's Pennsylvania filler businesses in December, 1989 and July, 1990, respectively. By July of 1990 TMG's filler business acquisitions included six quarries and one underground mine, totaling over 1,200 acres and three processing facilities. The assets were restructured into two new companies - Delta Carbonate, Inc. and Penroc, Inc. (hereafter collectively referred to as Delta). Delta identified the assets of the three predecessor companies as undervalued from the outset. The initial phase of Delta's turnaround strategy was to reassess the combined mineral. mining, processing, transportation and marketing assets. The second phase was to effectively integrate these resources in order to exploit their inherent synergy.

Jan 1, 1992

By D. Piper, J. Noble, M. Richardson, J. Wojcik, L. W. Cope

L. Cope Welcome. I am pleased to see so many people interested enough to stay until this last session of the last afternoon of the convention. Of the people on the panel here, everyone has done everything in placer mining, but we have tried to sectionalize it with each one of us taking a particular portion. Any one of us could probably answer any question. I am very pleased to see some well experienced people in the audience. To start the discussion, Joe, can you give us a brief comparison of pit and drill sampling? J. Wojcik They both have their place. If you expect your deposit is something that is going to have widespread fairly uniform grades, then the pits may be the way to go. If you are going to have something you have to trace for several miles down the river valley, you can't do it with pits and do a proper sampling job. C. McLain Joe, the end result of all of this is to go ahead and mine it if it is a deposit. Do you try to relate your drilling results to something in mining itself against the recovery, because the drilling in different types of ground will give you different kinds of recoveries, and mining in the end is what you are going to do? Do you try to relate this to your mining method?

Jan 1, 1992

By J. C. Yingling

An approximate analytic- model is developed for minerals liberation when comminution processes are applied to multi-component ores, i.e., ores that include grains of multiple mineral species. The model employs a one-dimensional representation of ore texture similar to that employed by King (1979) and Klimpel and Austin (1983). The spatial texture representation is viewed as being generated by a stationary semi-Markov process. Associated semi-regenerative processes are defined that can be used to establish, approximately, the joint distribution of particle size and composition, where composition refers to the identities and relative proportions of mineral species included within the particle. Numerical predictions made by the model are compared to size and composition distributions observed in previous experimental studies.

Jan 1, 1992

By R. W. Smith

A microorganism will function as a mineral flocculant if it is to some degree hydrophobic and can attach itself in some manner, such as through electrostatic interaction, to the fine mineral particles to be flocculated. The present paper concerns the use of a hydrophobic bacterium, Mycobacterium phlei, as flocculating agent for phosphate slimes. Experimental work on the flocculation of phosphate slimes and of dolomite and clay mineral suspensions was performed. It was found that M. phlei functions as an excellent flocculant for a dolomitic slime but does not function as well for mineral suspensions where large quantities of the solids are finer in size than the approximately 1 µm size of the bacterium.

Jan 1, 1992

Against a background of deeper pits, the introduction of prestripping fleets and the need for closer control of operating costs (especially the waste removal component), Australian coal operations utilising draglines have in recent years become increasingly focused on:1. assessment of more efficient excavation methods; and2. application of explosive products and initiation systems which offer more flexibility than ever before.Additionally, developments in blast performance assessment techniques and equipment, and computer modelling and excavation monitoring systems have provided an improved opportunity to design a blast to achieve a desired profile suited to the excavation equipment and Sequence.

Jan 1, 1992

By Doug Hoy

The scope of the Cliff Avenue Reconstruction Project in Sioux Falls, South Dakota was to widen a two lane highway to five lanes, along with removing and reconstructing both above and below ground utilities located along the project limits. The objective of this paper is to present the blasting techniques used in the rock excavation phase of the Cliff Avenue Reconstruction Project.

Jan 1, 1992