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By D. Corrigan, A. Ahmad, R. Sood, J. Bratt, R. Holt

Zinc oxide based electronic ceramics are being used increasingly to protect electric and electronic circuits against transient voltage surges. Varistors are produced by sintering and annealing ZnO based powder compacts through long sintering and annealing cycles. Because of the length of these cycles, a manufacturing plant is saddled with expensive high temperature equipment with low throughput. Ceramics Kingston Inc. has developed a new technology that uses 2.45 GHz microwave energy for sintering and annealing. The new technology has the potential for increasing equipment and labour productivity very considerably. Additionally, the new technology will result in appreciable energy savings and add flexibility to the manufacturing process. Microstructural examination of varistors sintered conventionally and by microwave technology showed considerably smaller grain size in the microwave sintered materials. The electrical properties of the microwave sintered ceramics compare very favorably with those of the ones sintered conventionally.

Jan 1, 1990

LITHOPROBE is a national, collaborative research grogram with the general objective of understanding the teotectonic evolution of the North American continent through multidisciplinary lithospheric studies in carefully selected areas of Canada. Six transect areas are investigating Precambrian evolution, although only in two of these is the research well evolved. The Archean Kapuskasing Structural Zone in Ontario is confirmed as an upthrust slice of upper to mid crust exposed at the surface. The Late Proterozoic Keweenawan mid-continent rift is shown to be the deepest known rift on Earth and the Grenville collisional zone of Ontario and Quebec involves crustal scale imbrication and ramping of deeply buried rocks to the surface. Two transect areas are investigating Phanerozoic evolution. In the Newfoundland Appalachians the geologically defined tectonostratigraphic domains do not coincide with lower crustal blocks defined by seismic reflection data. The Southern Cordillera Transect in western Canada is examining the nature, timing and dynamics of the assembly of the Cordillera, and particularly the role of accreted terranes. Work in the eastern and central segments has extended the known western limit of the North American craton at least IOO km westward and crustal-scale ramps associated with metamorphic core complexes have been identified.

Jan 1, 1990

By D. G. Chedgy

Environmental improvement efforts are focusing with increasing intensity on pollutants resulting from combustion. The high cost of removing these pollutants at the power station is well documented. Physical coal cleaning has always been and should remain the most economic method of reducing sulfur oxide emission from coal combustion. It is critical in the selection of preparation plant circuitry to consider capital and operating costs, as well as the level of sulfur reduction. This paper describes the technical criteria which must be used for efficient process selection and summarizes the cleaning systems available or in development.

Jan 1, 1990

This paper presents a resume of the likely profitable mining areas in New Zealand. It covers the main 'minerals' û gold, coal, oil and gas, ironsands, silica sands, clays, lump silica, perlite, sulphur and limestone. The potential mining projects are depicted on a map of New Zealand together with the associated works involved in hydro-electric and geothermal power development requirement for industries such as aluminium, nickel ferro-silicon or silicon carbide production. The political need for mining development to relieve unemployment and reverse emigration is stressed. A case is made for exploration and development assistance by government in labour re-training, energy supply and transportation, if the tremendous losses through lack of use of human and industrial resources are to be rapidly reduced. These losses are currently estimated at $10 000 000 000 per year. The need for protection of the sanctity of contract and security of tenure of all mining operations is touched on briefly as is the need for a reasonably balanced view on conservation. However, as both of these are more properly covered in papers on the legal and environmental aspects of the mining climate, they are presented here only as they affect the economy of the mining operation. Finally, there is a brief comment on the mining climate in New Zealand relative to Australia and South Pacific mining operations.

Jan 1, 1990

By S. Subramanian, K. A. Natarajan, D. N. Sathyanarayana

FTIR spectroscopy is used to study the ad¬sorption of an oxidized starch on hematite, corundum, and quart: substrates. The difference spectrum of the adsorbed starch on hematite indicates surface reactions involving -CH2OH and -COH groups and shows striking similarities with that of the ferric-starch system, suggesting chemical interaction between the iron of hematite and the starch adsorbate. The IR spectra of starch adsorbed on corundum and quart: show no evidence of chemical interaction, although hydrogen bonding is apparent. The extent of adsorption of starch on hematite. corundum, and quartz decreases along the series. The evidence for chemical interaction of starch with hematite is further obtained by the X-ray photoelectron spectra of starch adsorbed on hematite, showing noticeable decrease in peak positions of O(Is) and C(Is) of free starch. The Mössbauer spectrum of hematite with stanch adsorbed on it complements these findings.

Jan 1, 1990

Large GDP increases in the Pacific Rim countries have been accompanied by similarly large increases in demand for oil products. In the case of residual fuels, this demand has been tempered by the substitution of other energy products such as coal or gas. In the region's developing and newly industrialised nations, it has not been possible to make the very large investments in infrastructure which allow other energy sources to be used for transportation. As a result, GDP growth has been mirrored in the demand growth for automotive fuels. Other non-substitutable products such as lubricants have also benefitted by the region's GDP growth.   The combination of a number of years of sustained growth, coupled with increasing quality requirements is now stretching the upgrading capacity of the region's refineries. IT, as seems likely, the region continues to enjoy a high GDP growth rate, then this will be accompanied by increasing reliance on finished products coming out of the Middle East.   The owners of the most simple form of refinery in which crude is simply distilled and the naphtha reformed into petrol will face major capital investments. If they decide not to bear this cost, they will face increasing problems in selling their surplus residual fuel oil at an economic price. Quality will become an increasingly important issue. Not only in the well publicised areas such as unleaded petrol, but also for products such as lubricants which play a major role in the efficiency of modem equipment. Quality of service such as hours of opening, ease of access, and service station facilities will also become increasingly important as the oil companies use these to attract customers and gain brand differentiation.

Jan 1, 1990

By M. Fiset, D. Belley

"To better understand the wear process of various materials that may be used as blades on snow removal equipment, the first step is to evaluate the influence of the load applied and the moving speed on road wear rates of one type of steel and three types of polymers. While the behavior of steel conforms to Archard's law, wear rates of polymers increase to a power of ex of the load applied according to a model implying that the wear of these materials is due to fatigue. The wear rate of some of the polymers varies considerably in terms of speed, unlike the steel. The wear resistance of some of these polymers outclasses the steel tested as long as the speed is not too great. They, therefore, present interesting alternatives for snow removal on more fragile surfaces such as sidewalks and zone made of inter-block slabs.IntroductionSince the dawn of the Industrial Revolution, the massive use of machines has brought with it a number of different problems regarding wear. Snowplowing roads, parking lots and sidewalks is an activity that generates enormous expense in a country such as Canada. To better understand these wear processes and in the hope of stimulating new approaches designed to reduce the costs related to this sector of activity, this paper presents the behaviour of several materials (steel, polymer and rubber) as they wear on an asphalt-fines matrix surface lubricated with water. Also discussed is the effect of various parameters such as the load applied and speed."

Jan 1, 1990

By N. Birtek, R. P. King

The washability characteristics of fine South African coals were measured and were found to be well characterized by an M-curve having the equation Z = aQb exp(cQ) x dQ, where Z is the ash content per 100 units of total feed and 0 is the mass yield. Parameters a, b, c, and d were determined for 23 different samples of coal from important coal seams in the main South African coalfields in the size range 0,0025 to 1 mm. The relationship between ash content and relative density was determined and correlated by means of two linear relationships. This characteristic behaviour was explained in terms of the liberation of macerals and the different association between the mineral mater and the two major macerals vitrinite and inertinite. The results obtained in this study can be used to calculate the expected performance of an ideal separation process, and can also be used as input for the simulation of real beneficiation plants. An example is worked through in detail to illustrate the method of calculation.

Jan 1, 1990

By N. A. Abdel-Khalek

An experimental study was carried out to compare the results of laboratory column flotation versus conventional flotation for the cleaning of fine coals of different rank and their oxidized samples as well as discrete size fractions. Surface oxidation caused a significant reduction in the flotation yields achieved with both methods. However, the column flotation produced concentrates? of lower ash content. The recovery -size curve achieved with column was similar in shape to that obtained with conventional cell, with superior results in the region of fine fractions. The influence of some column operating parameters was also discussed.

Jan 1, 1990

By J. E. Garlanger

Each year, Florida mines approximately 40 million tons of phosphorite, most of which is ultimately converted to various commercial fertilizers. The phosphorite is mined from within the bottom portion of the 40-to 60-ft. thick surficial aquifer, using open pit mining techniques. The ore zone or "matrix" is generally overlain by relatively permeable fine sand to silty and slightly clayey fine sand. The ore itself is highly variable in nature but, in Central Florida, typically consists of less permeable clayey phosphatic sands and sandy clays with stringers of permeable sand. The ore is much more sandy in the north Florida mining area.

Jan 1, 1990

By Terry Nichols, Karl E: Warkwick Burgher, Charles J. Wideman

The application of Fourier spectral analysis to records of ground vibration generated by over 100 explosions from an open pit mine is used to develop empirical predictor equations that relate the response spectra to the blasting parameters used to generate the excitation motion. Time series representations of ground particle velocity are transformed into the frequency domain where the appropriate modifications are made such that the inverse Fourier transform yields the time series representation of particle displacement and acceleration. Compensations are made for the transform function of the recording system in the frequency domain. Spectral analysis of the three types of ground motion is correlated with the blasting parameters. The results show that the frequency content of ground vibrations generated from a mine blast can be quantified in terms of the predictor equations.

Jan 1, 1990

By Nowell SB, Cottrill DA

Host-rock - wallrock major and trace element geochemistry associated with epithermal gold mineralisation in the Hauraki Goldfield of New Zealand is poorly documented, even though rock geochemistry is a recognised tool in exploration. Such responses assist in recognition of the regional scale imprint of fossil hydrothermal activity, and indicate targets for detailed evaluation within these alteration zones.Recent investigation of gold deposits in the Waihi (Gladstone), Golden Cross (Empire), Thames (Waiotahi) and Coromandel (Tokatea) areas indicate enrichments of Au, As and Sb in the andesitic wallrocks hosting mineralisation. Of the other elements examined, Si, K and Rb are enriched, and Na, Ca, and Sr are depleted at all deposits. These trends are best developed in the vicinity of veining. In deposits with clay alteration dominating (Waiotahi and Tokatea) there is also depletion of Mg, Mn, Zn and Cu. Ba and Cr are variably enriched or depleted within different styles of alteration. Base-metal enrichment in the wallrocks is not a feature of Hauraki deposits.

Jan 1, 1990

By Stuart F. McTavish

Mechanically suitable grinding mills became available to the mining industry in 1908. Since then, mill operators have been searching for the best material and design with which to line the mills. These liner systems had to fulfill several criteria. Most important, they had to last long enough in an operating mill to protect its structure from the abrasive wear of the ore and the grinding media. In addition, they had to be capable of efficiently transferring the energy from the mill to the mill charge in order to facilitate the grinding process. And these liners had to be easy to install and remove. The first liners used were generally made of cast white iron, Hadfield manganese, unalloyed high-carbon steel and composites of steel and concrete or cemented in flint blocks or natural stone. In the early 1920s, pieces of solid rubber truck tires were used as emergency repairs for broken cast metal liners. Thus was rubber first introduced as a mill liner material. The first patent for rubber mill liners was awarded in 1921 to James Denny and Rolla Watson, both of the Coniagas Mine in Cobalt, Ontario, and to Dale Barnum of the Comstock Lode in Virginia City, NV. This original design was covered under US Patent No. 1470597. It had a fabric backed rubber that was bonded to the shell of the mill.

Jan 1, 1990

By B S. Utting, W J. Cowie

The alluvial gold industry of New Zealand is based on the placer deposits in Otago and on the West Coast. Production from these since discovery in the 1850s has been an estimated 480 t (15 Moz) of gold. Annual output has expanded continuously since 1980 and is expected to be over 2 t of gold for 1989. Following a historical review, the characteristics of typical operations, which use hydraulic excavators and mobile trommel units are discussed. Descriptions are then given of alluvial activities in Otago and on the West Coast.

Jan 1, 1990

By M. Leroux, P. Lacombe, S. R. Rao, J. Y. Kim, J. A. Finch, G. Labonté, N. Macminn, M. Ounpuu

"Laboratory investigations on two complex ores, the A1 zone ore from Les Mines Selbaie and the Lyon Lake ore from Mattabi Mines Ltd. (Division of Noranda Minerals), have been carried out to determine some of the main variables in collectorless flotation. In particular, the effect of pulp potential (controlled by gas composition), conditioning time, pH and grinding media have been studied.Chalcopyrite showed the greatest response to collectorless flotation among the four major sulphide minerals present, followed by galena. Flotation of sphalerite was variable from minimal to important depending on the mineralogy and the pre-treatment performed. Appreciable silver recovery was achieved collectorlessly for the Lyon Lake ore while it could not be achieved for the A1 zone ore of Les Mines Selbaie. It appears that the difference between the two ores is related to silver's predominance as tetrahydrite in the Lyon Lake ore while it is as argentite and native silver in the A1 zone ore.The response of the ores to collectorless flotation is strongly dependent on the pulp potential, Ep, and pH. Using different gas compositions and different conditioning times it was found that collectorless flotation occurs when Ep is +195 to +295 mv (vs SHE). The actual on-set potential for collectorless flotation is dependent on the ore. A too high potential or prolonged oxidation leads to a decrease in selectivity. Some other factors were examined, notably the effect of pH and the type of grinding media on the selectivity achieved in the laboratory.Preliminary results from a plant trial at Mattabi Mines Ltd. confirmed that collectorless flotation occurs and that it is preferential for chalcopyrite and to a lesser extent galena. Collectorless flotation was not attempted at Les Mines Selbaie. However, examination of the distribution of collector between the different addition points in the copper circuit suggests that it may be present."

Jan 1, 1990

By S. P. Mathew

The ISASMELT Lead Process is a continuous two stage process for the production of crude lead from concentrate. It is based on the use of a top entry submerged Sirosmelt lance to produce turbulent baths in which high intensity smelting or reduction reactions can occur. The process involves oxidizing the concentrates in the first stage to produce a high lead slag. This slag is tapped continuously and transferred down a launder to a second furnace where it is reduced with coal. Crude lead and discard slag are tapped continuously from this furnace through a single taphole and separated in a conventional forehearth. Process and engineering design work for a commercial scale Lead ISASKELT plant designed to produce 60000 tpa crude lead has been completed. This plant is planned to be operational in 1991.

Jan 1, 1990

By Salley J, Gould WD

The stack-gas scubber effluent from base metal smelters often contain 20-100 ppm of oxidized selenium salts. Due to their toxicity, these must be removed from solution prior to release of the effluent to the environment. Many species of microorganisms including Corynebacterium diotheriae, Neurospora crassa, Candida albicans, Escherichia coli and various species of Salmonella are capable of assimilating oxidized selenium and reducing it intracellularly to red amorphous selenium. CANMET in cooperation with several companies has developed a biological process to recover selenium from dilute solutions. The laboratory, mini-pilot plant and the large industrial pilot- plant studies leading to the development of this process will be described.

Jan 1, 1990

By J. A. Sekhar

Solidification processing/casting is increasingly being adopted as the preferred manufacturing technique for the fabrication of net shaped complex geometry components. Modeling of solidification processes is important both for design purposes as well as for understanding the physics of morphological evolution of the solidification microstructure. A fundamental aspect of such modeling involves the precise understanding? of heat transfer through the two phase solid/liquid region. A scheme to do this will be presented where the nonlinearity of the fraction liquid with change in temperature can be incorporated into the numerical calculations. The importance of properly accounting for the non-linear mushy zone will be discussed. Typical processes like squeeze casting and electromagnetic stirring will be discussed to illustrate how precise modeling of the solid/liquid region can aid in the calculation of accurate heat transfer coefficients for these processes.

Jan 1, 1990

By D. J. Dunn

Grinding balls, simple in shape, are actually sophisticated machine components and essential elements of mineral grinding mills. Their physical properties and quality must be adequate to achieve design life and grinding mission with few failures. Consistent properties and freedom from breakage are essential. Size, mass, hardness profile, chemistry, and microstructure are important variables that should be designed, specified, controlled, and verified to achieve optimal mill performance. Failure to specify ball properties in detail or failure to obtain required ball properties and quality can cause milling productivity losses and excessive costs that could endanger a milling operation's survival in the competitive mineral industry.

Jan 1, 1990

By A. LaPlante, A. Cauchon

This gravity circuit at Les Mines Camchib Inc. consists of two pinched sluices to bleed a feed to one of two 76 cm (30") Knelson concentrator. The Knelson concentrate is upgraded to smeltable grade with a smaller Knelson (18130 cm) and a riffleless table. Their tails are column cyanided and washed prior to recycle to the grinding circuit. This paper details size- by-size circuit performance. The Knelsons recover around 90% of free gold (as determined by Mozley Laboratory Separator), even below 37 pm. The sluices are ineffective, with upgrading ratios around 2, but approaching unity in the fine sizes. Much of the effectiveness of the circuit lies in the high gold circulating loads in the grinding circuit, which partly atone for the poor sluice performance, and the ability of the Knelsons to recover free gold. Secondary upgrading recovers slightly above 99% of the primary concentrate gold, 90% of it in a 65% Au concentrate and the balance in a heavily loaded (10 to 20 oz/st) pregnant solution, generated by intensive column cyanidation.

Jan 1, 1990