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By S. Chander

The effect of pretreatment potential on the response of a gold electrode for Eh measurements in sulfide solutions was examined in terms of measured Eh values and electrode response time. The electrode response time is defined as the time required for the electrode to reach a steady-state value. The relationship between measured Eh values and the hydrosulfide ion concentration is established. The effect of pH, the reversibility of the gold electrode in the sulfide solutions, and the reproducibility of measurements are also investigated. A mixed potential theory is proposed to explain the observations.

Jan 1, 1989

By B. Arjang

ABSTRACT: Ground stresses are one of the significant factors in the context of rockbursts and underground instability at some hard rock mines in Canada. Overcoring strain relief measurements using triaxiaI strain eel is were performed at depths between 60 to 1890 m at several mine sites to provide stress data for stability analysis and optimum mine design. Pre-mining ground stress determinations from 64 stress tensor analyses resulted in the following average stress gradients: Maximum horizontal stress. -Hmax - 8.18 - 0.0122 MPa/m depth Minimum horizontal stress. _-,,min - 3.64 - 0.0276 MPa/m depth Average horizontal stress. -11, 5.91 - 0.03-19 MPs m depth Vertical stress. '-, - 0.0266 - 0.008 MPa/m depth The maximum and minimum horizontal compressive stresses. with an average ratio of 1.75 ,0..45. prevail in east--west and northerly directions. respectively. Horizontal compressive stresses in excess of vertical overburden load were determined. indicating large variations in ratios to a depth of about 1000 m with decreasing trend towards depth. From present data. a particular regional zoning for the magnitude and direction of horizontal stress fields cannot be outlined. A common feature at mines with near vertical orebodies is that the maximum horizontal compressive stress acts perpendicular to strike while the minimum horizontal compressive stress is aligned on-strike. The vertical stress components approach the gravitational overburden load.

Jan 1, 1989

Utilize innovative processing technology to prepare high-purity, ultrafine advanced ceramic powders with little or no contamination occurring during the milling process. Advanced ceramic materials made from these powders could substitute for high-temperature alloys containing critical materials such as chromium, cobalt, and nickel. Approach Modify and evaluate the Bureau's turbomill, developed earlier to grind a variety of ceramic raw materials (clay, mica, and talc), as a milling or size-reduction technique for hard and abrasive advanced ceramic powders, such as silicon carbide. Background Powders for producing ceramic materials, such as silicon carbide. silicon nitride, alumina, and zirconia, which arc being considered for use in severe applications requiring high-temperature and/or corrosion resistance, are very difficult to reduce to fine sizes for processing into finished parts. Traditional techniques of particle size reduction, such as ball milling and jet milling, are very energy intensive and/or slow. These traditional techniques often produce materials that have a nonuniform particle size distribution and are contaminated by the milling media or container.

Jan 1, 1989

Provide minx operators with means for evaluating dust generation and bit wear effects on Production without costly and extensive underground testing. Approach Develop personal-computer-based cutting system models that will simultaneously evaluate machine, Coal seam, and mine-operator-controlled parameters for their interactive effects on dust generation, bit wear, and Production by either a longwall shearer or a continuous miner. How It Works CSM Programs have been developed to analyze relative dust generated by a double-drum, ranging arm, longwall shearer and a continuous miner. These interactive programs Provide relative dust, culling forces, and production values for any given set of mining machine parameters, specific seam conditions, and operator-controllable parameters. Expanded versions of each program provide a dynamic evaluation of the effects of bit wear, over time, on production.

Jan 1, 1989

By A. Ghalambor

The objective of this investigation was to determine the sensitivity of three selected input parameters in the operational control of continuous bottom-fed thickeners used for the treatment of coal refuse slurries. The three variable parameters were "Feed Flow Rate," "Feed pH," and "Feed Solids Concentration." These three input parameters were studied under three polymeric conditions which were cationic polymer, anionic polymer, and a combination of cationic-anionic polymer. For each polymeric condition, two mathematical models were developed: one for overflow response, the other for underflow response. The combination polymers produced the best desired quality of overflow and underflow. For this polymeric condition, changes in the feed solids concentration was the most sensitive factor in the maintenance of the overflow quality, and the feed pH was the most sensitive factor for the maintenance of the underflow quality. The mathematical models generated a set of plots which would allow an operator to control and/or adjust any of the three variables to achieve optimum conditions.

Jan 1, 1989

By Musa Karakus

Ceramic build-ups are synthetic mineral deposits formed in critical locations in or near the throats of inductor units in channel induction furnaces, the preferred melting and holding furnaces used in iron foundries. The build-ups are undesirable because they slow down melt circulation, increase power consumption and cost. and decrease the quality of the metal. This study involved the determination of the mineralogy of build-up samples and the quantitative measurement of phase abundance in those build-ups by cathodoluminescence microscopy. These undesirable deposits usually are hard and dense and contain variable amounts of entrained metallic iron. The non-metallic phases dominantly consist of oxides and silicates of several refractory elements, AI, Mg. Ca, Si, and Fe. Minor amounts of the sulfides of Ca. Mg, Fe and REE elements, especially Ce and La. and the oxides and silicates of Ce and La elements are locally present in the build-ups. The build-up samples were found to be ideally suited for study by cathodoluminescence, which has provided an easy means for rapid re-cognition of the phases present in the build-ups. The phase compositions were determined by electron microprobe analysis. The phases identified and their characteristic cathodoluminescence shown in the ceramic build-up samples were: spinel (bright green, blue-green, and red). forsterite (red and purple), periclase (dark reddish-brown, blue. and orange), corundum (red, blue, orange, and white), anorthite (yellow, yellow-green, blue, and blue-purple), hibonite or calcium hexaluminate (dark green), mullite (dull red-brown), gehlenite (deep blue), silica(dark brown, pink, purple, red. and blue), monticellite (light violet blue and light pale yellow-orange), silicon carbide (orange), oldhamite (bright yellow and orange). Ce-La silicate phases (purple), and glass (orange, dull red, and purple). Non-luminescent phases were: hercynite, Fe-oxides, Ce-La-oxides, Fe-sulfides, and metallic iron.

Jan 1, 1989

By Lawson F

The leaching behaviour of BHAS copper matte in oxygenated acidic sulphate chloride solutions at 85¦C has been studied using samples containing 34% copper, 41% lead and 12% sulphur. Copper sulphide in the matte, essentially Cu2S was found to leach in two distinct stages. Similar to the behaviour of pure chalcocite, copper dissolution in the first stage was affected by the availability of oxygen in solution. The presence of chloride ions in the leachant was essential if there was to be any leaching in the second stage (which usually commenced after about 40% of the copper had been taken into solution). Lead sulphide in the matte was oxidised to lead sulphate and formed a shell around the partially leached matte particles. Electrochemical studies showed that this lead sulphate and/or sulphur produced during leaching can form a passivating layer around the copper sulphide. However, this layer was disrupted when chloride ions were present. A Plackett-Burman analysis was used to determine the species in the recycled leach solution that affect the leaching of copper. Under the experimental conditions used, in the first stage the rate of copper dissolution was influenced by the concentrations of sulphuric acid, Zn(II), Cu(II), Fe(III) and Cd(II). In the second stage, the rate was futher modified by the concentrations of Cl(I) and As(V) ions. In solutions of low acidity and high As(V) concentration, insoluble copper arsenate formed which coated the partially leached matte particles and acted as a barrier to futher reaction.

Jan 1, 1989

By Julie Mitchell

The U.S. Bureau of Mines is conducting research on the application of expert sys tens technology to mining equipment diagnostics and predictive maintenance, to increase mining productivity and efficiency. One of the greatest hindrances to mining productivity is the breakdown of equipment, causing lengthy and costly delays. A diagnostic maintenance expert system (DIMES) is being developed for the hydraulic system of a continuous coal mining machine. Through the use of such a system, the frequency of equipment failures and repair time should be significantly reduced. This paper describes the application domain, the functional requirements, and the problem approach for DIMES, the design and implement at i on of the knowledge- based system, the sensor work involved with the project, and the future plans for the continued development of this and other expert systems.

Jan 1, 1989

By K. Holmberg, D. Herriot

This paper by Mr Mclvor is yet another contribution to the eternal controversy surrounding the benefits, or otherwise, of high circulating loads in closed circuit grinding. Throughout the paper it is difficult to establish whether the author is referring to effects relating to the mill, classifier, or to the overall circuit. Table 1 is put forward as indicating the advantage of operating at high circulating loads. From the two (it would be interesting to see more) product sizing points provided in each case, the conclusions to be drawn are that cases one and two have very similar size analyses. The third case, however, indicates a much flatter curve, that is to say, higher fines production and a very wide spread of size ranges. If the objective of this circuit is to provide a closely sized product with minimum overground slimes to the downstream process, then it would appear to be the less "efficient" by far. No data is given for product pulp densities either. The term "efficiency" should never be used without a careful and clear definition. In this case, "efficiency" is used to express an apparent percentage reduction in operating work index (Bond) from the measured "standard" at 250% circulat¬ing load operation. The Bond calculation is itself based upon

Jan 1, 1989

By Mark S. Stagg, Rolfe E. Otterness, Stephen A. Rholl

The Bureau of Mines fired seven test blasts in a 22-ft bench of limestone, screening the material to investigate the influence of explosive type and between row delays on fragmentation. Four 4-hole, single-row test shots were conducted evaluating dynamite, ANFO, emulsion, and a 60-40 emulsion-ANFO mix. Three 12-hole shots, with three rows of 4-holes, evaluated delays between rows of 24, 36, and 120 ms. Accurate in-hole electronic delays were used, firing within 1.5-ms of the nominal delay. All seven shots had a 6- to 7-ft burden, 10-ft spacing, with a hole diameter of 3-1/2 in fired on a 12-ms delay between holes in the row. The tests were instrumented with strain gauges grouted in the burden region examining stress wave and gas pressure effects. Fiber optic probes were used to confirm timing and to obtain detonation velocities.

Jan 1, 1989

By Jack G. Pippenger

This report focuses on the procedures required to review, prepare specifications, bid, and purchase a fully integrated computer system for utilization by engineering personnel in all phases of mine engineering. The presentation is based on the experiences encountered in 1984 in procuring an engineering computer system at The North American Coal Corporation's Western Divi- sion. A two-phase report detailing the purchasing process and subsequent utilization of the engineering computer system will be given. Special detail is also provided on the final system hardware and software setup.

Jan 1, 1989

By Douglas E. Rawling

The successful genetic manipulation of T. ferrooxidans is partly dependent on an understanding of the molecular biology of the organism. For optimum controlled expression of foreign DNA in T. ferrooxidans it is important that donor DNA is derived from bacteria that are genetically similar to T. ferrooxidans or placed under the control of T. ferrooxidans transcriptional promoters. Several structural genes and their controlling regions from T. ferrooxidans have been isolated and their DNA sequenced. These include the genes that encode the nitrogenase enzyme (nifHDK genes), glutamine synthetase (glnA gene) and the recA gene. These genes and the identical genes from a wide variety of other bacteria have been compared at levels of DNA sequence, protein sequence. Where possible, gene expression as well as transcriptional control and protein function of the cloned genes were tested in the enteric bacterium Escherichia coli. The two genes involved in nitrogen metabolism were either expressed or possessed the necessary elements for expression in other bacteria. In contrast the recA gene was not expressed in E. coli from its own promoter. The two gene products that would be tested (glnA and recA) were fully functional in E. coli. The relevance of these findings to the genetic manipulation of T. ferrooxidans is discussed

Jan 1, 1989

By Billy J. Thorne

The damage model in PRONTO simulates the dynamic fracture behavior of brittle rock. It is based on work started by Kipp and Grady, [lg] continued by Taylor, Chcn and Kuszmaul [I91 [20] and recently.modified by B. J. Thorne (first documented here). The essential feature of this model is the treatment of the dynamic fracture process in rock as a continuous accrual of damage in tension, where the damage mechanism is attributed to microcracking in the rock medium. The fundamental assumption of the damage model is that the material is permeated by an array of randomly distributed microcracks which grow and interact with one another under tensile loading.

Jan 1, 1989

By R. D. Short

Environmental regulations for noise and air pollution are directly affecting the type of equipment and construction techniques being utilized for pile driving construction using diesel hammers in California and elsewhere. Consequently, the cost of construction is increasing and in some cases, the use of diesel pile hammers has been prohibited. Based on the trend in California and elsewhere in the world, environmental constraints are spreading and becoming more restrictive. The City of Tokyo, Japan, for example has banned the use of diesel hammers. Environmental restrictions on diesel hammers can be satisfied by using modern hammers, clean burning fuels, synthetic lubricants and pre-excavation techniques.

Jan 1, 1989

By J. Wennerstrand

Slender steel piles have found an increased use in Sweden in resent years. These piles are often driven throw soft normally consolidated clay to refusal in till or at the rock surface. In contrast to most other piles the bearing capacity with regard to failure of the shaft is in many cases smaller than the bearing capacity with regard to failure of the soil or rock at the lower end of the pile. Imperfections such as deviations from a straight line of the pile centerline and residual stresses in rolled and welded profiles are important for the capacity of the pile shaft. Even thow the second order moment caused by initial deviations in piles is only half of that in a column with the same slenderness, imperfections can and should be accounted for in much the same way as for columns.

Jan 1, 1989

By G. P. Brahmaprakash, K. A. Natarajan, N. Jyothi, K. N. Sudha

Some important electrochemical aspects involved in the bioleaching of mixed sulfides have been discussed with reference to selective sphalerite dissolution from different binary mineral combinations. Combination potentials and galvanic currents were measured in different binary combinations of sphalerite with other minerals such as galena, chalcopyrite and pyrite in order to under- stand the electrochemical dissolution behaviour of sphalerite when coupled with other minerals. The effect of applied DC potential was also studied with reference to selective sphalerite dissolution from a binary mineral mixture. An application of a potential of -500 mV (vs SCE) was found to enhance bacterial growth as well as selective sphalerite dissolution. Factors influencing bioleaching of sphalerite under a negative applied potential are discussed.

Jan 1, 1989

By Beck RW, Booth GW

Differences in the gold contents of sub-sample duplicates, derived from a single bulk sample are a function of analytical and random error, inhomogeneity within the bulk and natural variations in the distribution of particluate gold. By minimising bulk sample inhomogeneity and determining analytical precision, the residual natural variation may be modelled statistically to give an estimate of Bold particle sizes.

Jan 1, 1989

By Jeffrey C. Reid

Computer processing and high resolution graphics display of geochemical data were used to quickly, accurately, and efficiently obtain impor¬tant decision-making information for tin (cassiterite) exploration, Seward Peninsula, Alaska (USA). Primary geochemical dispersion patterns were determined for tin-bearing intrusive granite phases of Late Cretaceous age with exploration bedrock lithogeochemistry at the Kougarok tin prospect. Expensive diamond drilling footage was required to reach exploration objectives. Recogni¬tion of element distribution and dispersion patterns was useful in subsurface interpretation and correla¬tion, and to aid location of other holes. Tin was its own best pathfinder. Arsenic, also a useful pathfinder element, forms a discrete halo peripheral to tin mineralization. The arsenic halo is expressed in hand specimens by asenopyrite and/or scorodite staining.

Jan 1, 1989

By R. R. Rollins

Conventional methods of controlling abandoned mine fires include: loading out, inundation, fire barriers, flushing, and surface sealing. This paper describes a proposed fire-control technique utilizing a new explosive fragmentation method. An impervious barrier is created by using explosive energy and strategic emplacement in boreholes drilled from the surface. Blast round design, average fragment size, and impermeability of the fragmentation barrier are discussed. This barrier, created by the blasted floor rock, could also be used to fill in the open space in abandoned mines for subsidence prevention or control.

Jan 1, 1989

By J. L. Jambor

Sulfide-rich tailings accumulated in a 4l-hectare impoundment at the Waite Amulet minesite near Noranda, Quebec, have undergone partial oxidation and destruction of the principal sulfides (pyrite and pyrrhotite) in the vadose zone. Mineralogical studies and whole-rock chemical analyses of 18 samples from 3 boreholes along a cross-section of the tailings pile indicate that the principal chemical manifestations of the alteration are a pronounced depletion in sulfide-sulfur, and an enrichment in total Fe as Fe203' Other elements such as Al, Mn, Mg, Ca, Na, and K in the solids show erratic or inconsistent variations, but a trend to Si enrichment in the oxidation zone is clear. The trend is interpreted to be a relative enrichment whereby the proportion of the stable silicate minerals has increased as a consequence of the consumption of pyrite and pyrrhotite in the oxide zone.

Jan 1, 1989