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By N. S. Dalal, V. Castranova, K. Van Dyke, V. Vallyathan

"IntroductionInhalation of crystalline silica is often associated with the development of pulmonary disease (Ziskind et al., 1976). Recently, it has been proposed that freshly sheared silica .may have surface properties that make it more reactive with lung tissue than aged silica, and that this unique reactivity ·of freshly crushed silica enhances its pathogenicity. A recent study in our laboratory strongly supports this theory (Vallyathan, et al., 1988a; 1988b). We found that grinding of silica cleaves bonds in a silica tetrahedral lattice generating reactive free radicals sites on the surface of the silica particles. The presence of surface radicals on freshly ground silica was monitored by electron spin resonance (ESR) spectroscopy. The ESR signal generated from fresh silica in air is characteristic of Si-0 and Si radicals. Evidence, i.e., the ESR signal after the addition of a spin trap (DMPO) and its sensitivity to ethanol, indicates that these silicon-based surface radicals can react with water to form hydroxyl radicals (OH). Results also indicate that these surface radicals make fresh silica more cytotoxic than aged silica; i.e., fresh silica causes more membrane damage as evidenced by hemolysis and lipid peroxidation. Therefore, the presence of reactive sites on the surface of freshly cleaved silica may play a significant role in its pathogenicity.If surface· free radicals are related to cytotoxicity, then screening dusts for the existence of such radicals may predict their relative pathogenicity. Since an ESR spectrometer is not available to many laboratories, the objective of this study was to develop a quick and simple technique to monitor the existence of reactive surface sites on dust. The technique chosen was the measurement of chemiluminescence using a liquid scintillation counter; i.e., an instrument which·would be accessible to most investigators."

Jan 1, 1989

By Ahmed I. A. Salama

This paper describes the development of computer density control for heavy media cyclone circuit at the Coal Research Laboratories of CANMET. The control objective is to reach and maintain the medium density set point in minimum time. A description of the mechanical components and instrumentation are presented. The control strategy and computer software are discussed. Testing and evaluation of the installed system are presented.

Jan 1, 1989

By Peter A. Anderson

Innovative solution management is being used at Coeur-Rochester Inc. to increase bullion production and decrease overall costs. New operating programs call for reduced solution application rates to the heap that increase pregnant stream values at a lower and less costly plant flow rate. Silver and gold extractions are equal regardless of leach solution application rate. Solar heating is used in the summer months to increase the core temperature of the heap for use in the winter months to enhance the silver extraction rate. The Coeur-Rochester silver and gold mine, located in central Nevada, is an open pit, heap leach operation that has been in production since late summer of 1986. The facility produces about 15.4 kt/d (17,000 stpd) of -13 mm (-0.5 in.) ore to a leach area consisting of more than 37 hm2 (4 million sq ft) of 80 ml HDPE liner. Crushing is accomplished with a 1220x 1520-mm (48- x 60-in.) jaw crusher. This is followed by a single 2.1-m (7-ft) standard cone crusher and is completed with four 2.1 m (7 ft) short-head cone crushers. Agglomeration is not required for the crushed ore, which contains less than 10% -75. µm (-200 mesh) material. The ore contains 53 g/t (1. 55 oz per st) silver and 0.377 g/t (0.011 oz per st) gold. It is end dumped over previously leached material, leveled, and then ripped with a bulldozer. Drip emitters at 810 mm (32 in.) spacings on 910 mm (36 in.) centers are used to apply barren solution to the heap. A portion of the emitter lines are buried I m (3 ft) deep during the winter months and are placed on the surface the remainder of the year. The leach solution contains 0.75 g/L (750 ppm) sodium cyanide solution at a pH of 10.5 - 11. Dissolved oxygen averages 8 ppm in the pregnant solution. Cyanide consumption for the ore to date is just under 0.2 kg/t (0.4 lb per st). The pH control is accomplished by adding I kg/t (2.0 lb per st) 0-10 mm (-0.4 in.) pebble lime to the ore at the tertiary crusher. The pregnant solution is processed by a conventional closed circuit Merrill-Crowe system. The pregnant solution is clarified through three 158 L/sec (2500 gpm) US Filter Auto-jet clarifiers. This is followed by deareation through a

Jan 1, 1989

By A. L. Mular

"IntroductionThe mining industry has made slow but steady progress toward the automation of mineral processing plants over the last 35 years. The stimulus to automate is associated with important economic and hidden benefits, so that today, the latest in instrumentation and technology is being employed.This chapter assesses the status of instrumentation justified economically, defines levels of control and certain fundamentals of feedback control loops, describes typical sensors employed in concentrator circuits, summarizes control strategies employed therein, and briefly highlights trends in integrated plant control.Current Status of AutomationAs early as 1948, the mining industry began to show interest in automation, probably because of its close association with the petroleum industry. By 1958, some regulatory control had been achieved in various sections of a concentrator, particularly in crushing circuits. Successes were attributed primarily to the reliability of sensors employed in the corresponding control scheme. By 1961, computers had appeared on the scene, initially, for data logging purposes.From 1958 to 1965, very few new control strategies had been implemented. Guidelines in vogue at this time appeared to be:- Install proven automation, unless a good instrumentation department exists at the concentrator.- Do not bite off too much instrumentation at one time.- Do not purchase on price alone; instrumentation must function in the concentrator environment.- Do not purchase automatic control equipment to be fashionable.Such guidelines were employed1 because of a lack of: (a) quantitative process knowledge, (b) reliable primary sensors, (c) initiative to try something new, (d) trained personnel, and (e) understanding that older concentrators could justify automation in many situations."

Jan 1, 1989

By Douglas A. Anderson

The simplest method used to predict ground vibration from blasting is scaled distance -the distance from a blast divided by the square root of the Pounds per delay. Pounds per delay is defined as the number of pounds of explosive detonated within an 8 millisecond (ms) interval. Based upon this definition, regression plots of peak particle velocity vs. scaled distance have been used to determine likely values of peak particle velocity.

Jan 1, 1989

By H. Knorre, A. Griffiths, J. Loroesch

Introduction Hydrogen peroxide is known to the mining industry as a powerful oxidant, able to attack and to destroy cyanide, the most important leaching reagent (Knorre and Griffiths, 1984; Griffiths, 1988; Griffiths, 1988). CN- + H202 => OCN- + H2O The most recent development, however, is the use of H202 as an oxidant in the cyanidation of precious metals. This application may appear to be a contradiction to the above mentioned detoxification process. This can, indeed, be the case if certain conditions are not considered carefully. Degussa has developed a new process to enable the application of H2O2, in this field without having any detrimental effect on the cyanide. The incentive to seek an oxygen supplier like H2O2 instead of air was the fact that one of the most important conditions for the fast dissolution of gold is the presence of physically dissolved oxygen in the pulp (Kydryk and Kellog, 1954; Warstell, 1987). 2 Au + 4CN- + 1 /2 O2 + H2O => 2 [Au(CN)2]- + 2 OH Complete gold recovery within a reasonable leaching time may only be achieved if the pulp is saturated with dissolved oxygen. Gold losses in leach operations mainly occur due to the following reasons: • In some cases, the saturation of oxygen in the pulp cannot be achieved by aeration due to the difficulty to transfer oxygen from the gaseous into the liquid phase. This happens, for example, in pulps with a high viscosity. In such cases, even violent aeration only results in a low concentration of dissolved oxygen in the pulp. • In any case, the starting phase of leaching requires the highest amount of oxygen. Therefore, it is especially important to raise the dissolved oxygen level to saturation in the starting phase. Peroxide assisted leach process (PAL) The intention of the process is to introduce oxygen in a liquid form. As a result of intensive research work, it could be shown that hydrogen peroxide can be used as a source of oxygen in the leaching of gold ores. To avoid side reactions, the following conditions must be applied: • Hydrogen peroxide must be diluted before it is added to the pulp. • The dosage of H2O2, must be properly regulated based on the oxygen level of the pulp. • An important part of the continuous 02-control is a special oxygen electrode, which resists the extremely abrasive action of the pulp.

Jan 1, 1989

By Mengxiong Guo, Xuxin Shao

The recent depressant research is summarized, and a new kind of depressant (SCO) has been put forward in this article. Using Na-oleate as a collector and SCO as a depressant, separation of dolomite and phosphate was studied. When SCO was added in the concentration range of 80 g/t to 2kg/t at pH 9.5 ± 0.2, dolomite was absolutely depressed, and apatite kept its floatability. Interestingly, in the mixture of phosphate and dolomite, the dolomite floated. The reasons for such a behavior are investigated through flotation and electrokinetic studies. It was found that the adsorption of dissolved species on dolomite and phosphate resulted in reverse flotation. A concentration of 31.59% P205 and 83.87% recovery of P205 was obtained from the mixture of phosphate and dolomite (2:1) with 26.6% P205 using 210 g/t SCO and Na-oleate 4.93*10-5 M at pH 9.

Jan 1, 1989

By A Lance McAnuff, Robert T. Booren

Construction of a dock facility for the Lake Erie Development Project of Stelco Steel involved underwater blasting in commercial fishing waters near Port Dover, Ontario. The most stringent environmental constraints were imposed and a monitoring program involving water overpressure recordings, using equipment developed specifically for this assignment, correlated with observation of caged fish specimens at various distances from the blast source, was undertaken to determine the effects on fish life and to establish whether a protective air-bubble curtain system should be installed around each blast area.

Jan 1, 1989

By T. Malvik

Norway is a big producer of ferrosilicon and silicon metal. The raw material is quartz and quartzite and large quantities from both Norwegian and foreign sources are used. The demands maade on both the chemical purity and the thermomechanical qualities of the quartz/quartzite have increased in recent years in an attempt to reduce energy consumption and to improve utilization. Control of the chemical quality of the raw material is relatively easy by means of routine analysis, but it is more difficult to find a suitable method for testing the thermomechanical properties. A rapid test method to define high quality quartzite deposits for use in the metallurgical industry has been developed. The method is based on a combination of chemical analysis, dilatometry, thermosonimetry and cathodoluminiscence.

Jan 1, 1989

By John D. Janak

Thank you for inviting me to come here and be your keynote speaker. Texas also thanks you for being included as part of the Rocky Mountain Coal Mining Institute. We'll kind of think of Texas as Baja Rocky Mountains. I've always wondered why coal miners were the only people to go to the mountains in the summer time-and now I know why. The program committee should be given a big hand for selecting this RESORT. And the golf course is stimulating to say the least. This is a very beautiful location. I was asked to talk about CHALLENGES, OPPORTUNITIES and INNOVATIONS as they affect the coal industry. I am going to do that from a Texas perspective. But first, since Texas is the newest state to belong to the Institute, I would like to give you a little background on how our coal industry got started and where we are at today. The vast majority of our coal is called lignite-it has a little lower heating value than most other coals and ranks somewhere between buffalo chips and sub- bituminous. Lignite is found In three geological formations running Northeast to Southwest through South and East Texas. In-place reserves lying within 200 ft. of the surface total 14 billion tons. This slide shows the lignite formations with cur- rent mine operations colored in RED. Mines that are planned to be built in the next 10 years are shown in BLUE. Lignite was used mostly by settlers in Texas during the 1800s. It was used as a fuel to fire locomotives during the Civil War. Between 1900-1930, about 100 mines, mostly underground, were operating in Texas producing lignite for home heating and as a boiler fuel. Here are some slides showing underground access, [lie tipple used to process the lignite, and the underground workings. This is the "BIG LUMP COAL COMPANY" as shown here. The typical underground mine was 100-150 ft. deep and each miner produced 7-10 tons per day-all by hand. In 1926, the Texas Power & Light Company built the Trinidad Power Plant and began using lignite as a boiler fuel. The lignite was mined by the McAlester Fuel Company at the nearby Malakoff Mine. Here are some slides showing a stripping shovel at Malakoff uncovering lignite. The lignite was loaded into railcars in the pit for transport to the power plant. This is a picture of the Trinidad Plant which had two 20 MW units and one 32 MW unit. At the time, Trinidad was the largest power plant in the United States using lignite exclusively as a fuel. Trinidad operated until 1942 when it was converted to natural gas that was sold to the plant for 3 ½ ¢ per MMBT'U. The mine closed after having produced 7 million tons. Lignite was mostly forgotten about until 1953 when Alcoa started an aluminum smelter. Our Company formed a subsidiary called Industrial Generating Company to operate the power plant that furnished electricity to the smelter. We also operated the nearby Sandow Mine that supplied lignite as a fuel to the power plant

Jan 1, 1989

By Kalle Hakalehto

Automation and mechanization in mining has no value of its own. It has to be measured in economic terms or in Increased safety or in the utilization of deposits which otherwise were unavailable. The mechanization and automation of workphases in the mining and rock construction process has led to the decrease of manual work. This has had a very essential importance in the countries where the labor is expensive or where there has been difficulties in the availability of labor. The work has become much more efficient. We would like to argue that the need of mechanization has been initiated mostly from the above mentioned reasons. The origin has seldom been the "process" approach or the real need or will to change the way mining is done. Through mechanization bigger unit sizes of machines and operations have become possible and better efficiency is achieved. This has led to new problems as well, but in most cases they have been solved so that better and more economic outcome than before has been the end result. The changes have thus been justified. It is perhaps feasible to state already at this stage that we see that the mechanization andautomation steps in the difficult conditions of mining have been remarkable. There is not a slightest underestimation of the achievements and importance of this development in our mind. Where we are to- day is the result of the experience, know-how and technological excellency of all the parties involved. The natural approach to automation has been through mechanization and automation of individual unit operations and machines. This has been the way as well in manufacturing industry as in mining. There may not have been any other way. The other presentations in this session tell us very clearly of the approach .which the machine manufacturers have taken. They have not done it alone but 'most of the initiatives have come from them. A good use of their present achievements gives many possibilities to increase the, efficiency in mining. We would, however, like to extend the view one step further to the future:

Jan 1, 1989

By D. R. Nagaraj

The chemistry and structure-activity relationships for four new classes of sulfide mineral and precious metals collectors developed recently are discussed in this paper. These collector classes are alkoxycarbonyl alkyl thionocarbamates and thioureas, dialkyl (or diaryl) monothiophosphates and dialkyl monothiophosphinates. The main emphasis will be to highlight the differences between collectors and their affinities for various minerals on the basis of data on kinetics of adsorption on pure minerals, natural ore flotation and microscopy of flotation concentrates. The mechanism of interaction of these collectors with sulfide minerals is also discussed with the available data on the FTIR and solution chemistry studies.

Jan 1, 1989

By G. P. Demopoulos

"The recovery and separation of platinum-group metals (PGM) from primary and secondary materials currently attracts a lot of interest due to the high value of the metals and their increasing demand for high-tech applications. Thus, the traditional refining processes are gradually replaced by newer more efficient separation techniques such as solvent extraction and ion exchange. In this paper the classical and modern refining techniques are reviewed and the pertinent solution chemistry dictating proper processing strategies in each case is discussed. The technological advantages of the modern separation methods are emphasized and reference to the recovery of PGM from primary as well as secondary materials is given. INTRODUCTIONDue to their outstanding physicochemical properties, such as catalytic activity, conductivity and corrosion/oxidation resistance, precious metals now find extensive usage outside of the traditional jewellery and investment industries. The increasing use of precious metals in such areas as electronics and catalysis, as well as their increasing high value, has led to a growing interest in their recovery and separation from primary and secondary materials.Quantitatively the demand of platinum metals in the western world by area of application is described in Table I. Platinum and palladium represent 90% of the total demand, Rh and Ru 8% and the remaining is taken by Ir and Os. In terms of value the following were the average prices (US$/oz) of the metals in the second half of 1986: 500 Pt, 125 Pd, 1200 Rh, 650 Os, 400 Ir and 80 Ru. Due to these prices, exploration, mining, reclamation and refining activity were very high in South Africa, the biggest producer of Pt metals in the world, as well as in other areas: United States (Stilwater deposit), Canada (Sudbury, Marathon and Lac des Isles, Ontario; Kenly Lake, Quebec, etc.), Australia, Europe and elsewhere"

Jan 1, 1989

By Song Xiaotian

In this paper the enviroment in which Tong Kuang Yu mine, China is developed is described. Geological and geomechanical environments which pose difficulties in the design and optimization of Block Caving are discussed. According to mine conditions, caving process simulation was carried out using Displacement Discontinuty Method and relationships between stress distribution .and undercut parameters were established in accordance with different undercut sequence. Based on simulation the influences of caving parameters on caving probability, drift instability and ore-draw control were analysed in order to optimize Block Caving Mining. On the basis of simulation and mathematical programming, the optimal sequence is proposed essential to satisfy the safety, production and other restrictions.

Jan 1, 1989

By O. M. G. Newman

The Electrolytic Zinc Company of Australasia Ltd., generates a jarosite waste at its Risdon smelter. Since 1974 this waste has been disposed of at sea off south-east Tasmania. As part of a monitoring programme prescribed by the Australian Government, bottom sediments from the disposal zone are monitored regularly. QEM*SEM image analysis complements conventional chemical analysis, having the ability to partition the occurrence of an element between sediment particles of metallurgical and natural origin. The adaptation of QEM*SEM techniques to the evaluation of bottom sediments provides insight into the fate of the particles of jarosite waste.

Jan 1, 1989

By R. H. Wright

This paper describes the design philosophy and methods employed in constructing the foundation elements for the Little Britain Project in the City of London. The Contract is a design and construct package for the foundations of a 3-storey basement which will be built using "top-down" construction techniques and is to be carried out by Fairclough Piling and Marine on behalf of Wimgrove Nominees. The Project includes 8000 sq.m. of diaphragm wall and barrettes 139 No. large diameter piles ranging from 900mm to 3000mm in diameter and up to 45m deep, and 9 No. cruciform barrettes for the heaviest column loads. Major factors influencing the design of these foundations include differential settlement, heave analysis and a fast track construction approach. Little Britain will provide 43000 sq.m. of space in two linked buildings which will bridge a new road joining London Wall to Newgate Street. The foundation contract is well advanced and the building is due for completion in the Summer of 1990.

Jan 1, 1989

By Pierre Mousset-Jones

I wish to submit this discussion item on an article published in the August issue of MINING ENGINEERING by Wala and Altman on the use of canonical diagrams for mine ventilation networks. The advent of computer graphics and plotting has enabled complex underground mine layouts to be displayed and plotted in a variety of three-dimensional formats that very closely represent the actual mine layout. This enables the ventilation engineer, who is familiar with the mine, to display the network pressures, quantities, resistances, and fan locations in a way that can be understood by everyone working at the mine. This is important if the ventilation engineer needs to discuss changes in ventilation with production personnel, or escapeway procedures with union personnel. While I can see some of the potential advantages in the canonical ventilation network diagram described by Dr. Wala, it appears to me that the fact that the diagram has no visual equivalence with the actual mine layout means that most mine personnel will find such a diagram almost incomprehensible. The authors have alluded to certain advantages with the canonical diagram. However, I find it difficult to see that these outweigh the fact that almost everything listed can be duplicated in isometric diagrams, and in a manner that is easily understandable to everyone in the mine from the miner to the mine manager. Perhaps the authors could show a clear example comparing an isometric with a canonical portrayal of a mine network showing the information that is immediately available from the canonical network that is not obvious in the isometric diagram. There is in this country a severe problem with the need for ventilation engineering and expertise to be used and accepted by mine management as a necessary part of mine planning. It seems to me that to introduce the requirement for further explanation so that management can understand a canonical network display will hinder more than help the recognition that ventilation engineering needs at so many mines in this country. However, I can see that the canonical approach does have its place in assisting the practicing mine ventilation engineer, wherever he or she exists in the organization chart for a typical mine. In this case, could the authors please indicate the availability of the computer program to compute and plot the canonical diagram for a mine ventilation network.

Jan 1, 1989

By J Mensah, G C. Sen

Often large boulders of rock have to be fragmented in civil or mining engineering operations. These oversize boulders are encountered after primary blasts in both surface and underground excavations of minerals. Various methods are employed to break large boulders into a manageable size for loading and crushing. These methods range from mechanical breaking (such as drop-ball and hydraulic impactor) to the use of explosives. Apart from these, static agents (such as expanding chemicals) are used in special circumstances.

Jan 1, 1989

By A. T. Iannacchione

Numerical simulation of coal pi1lar loading has traditionally been a difficult task due to the unique and highly variable properties of coal and the inability of numerical procedures to duplicate these properties. This simulation was based upon material properties developed from laboratory tests of coal cubes and examined against coal pillar strength data developed from actual underground measurements. The coal cube measurements indicated the coal followed a nonlinear Mohr- Coulomb failure criterion. The in situ measurements showed that a pillar yield zone developed similar to Wilson's hypothesis and, at high confinements, the pillar core seemed to followed a pseudo-ductile behavior. The strain-softening material model, based on a 1inear Mohr- Coulomb failure criterion, simulated coal cube and pillar behavior at moderate load conditions. However, at high loads the models were inaccurate, due to an inadequate failure mechanism and/or to changes in the pillar constraints at the coalbed interface.

Jan 1, 1989

By w. w. Milde

"Since its startup in 1975, the Rabbit Lake mill has been modified (0 process both increased tonnage and higher grade ore. Ore initially came from the Rabbit Lake pit . In 1985, a major mill expansion was commissioned to allow treatment of B-zone pit ore, which is mineralogically and metallurgically different fromRabbit Lake pit ore.Mill modifications, and the changing ore characteristics and processing targets which made them necessary, are described. Mill LocationThe mill complex, shown in Figure I, comprised of milling facilities, acid plant, power generation , warehouse and administration offices, is located approximately 1.5 Ian south of the Rabbit Lake pit, and about 8 Ian southwest of the B-zone open pit mine.Original Milling CircuitOre feed to the mill commenced June 10, 1975. The mill was designed to process 1500 tonnes per day , 483 000 tonnes per year with an average grade of O.44OJo Ups and an annual production of 2000 tonnes UPs' Run-of-mine ore was dumped directly onto a 60 em square opening grizzly. Oversize was broken with an Ingersoll-Rand hydrauli c rock breaker. Minus 60 cm ore was fed to a 6 m diameter by 1.8 m long Hardinge semi-autogenous (SAG) grate discharge mill. Mill discharge was screened over a Tyler double-deck vibrating screen, with screen oversize returned to the SAG mill feed chute via conveyor belt. Screen undersize (minus 2.4 mm) was pumped to 51 cm diameter Krebs cyclones in closed circuit with the SAG mill. Cyclone overflow (about 50% minus 74 micron) was thickened to 55% solids in a 30 m diameter neutral thickener .Thickened pulp was stored in two mechanically-agitated wood stave tanks (5.5 m diameter by 6 m high), to which sulphuric acid was added to obtain a pH range of 1.5 to 2.0. The fmalleaching was carried out in five more identical tanks. Sulphuric acid and sodium chlorate were used to maintain a pH of 1.5 and a terminal emf of -450 to -500 mV. Steam sparge was utilized to obtain a temperature of 45°C."

Jan 1, 1989