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By M. Leroux, S. R. Rao, J. A. Finch

"Poor Pb/Zn selectivity during Pb flotation in laboratory tests on a Mississippi Valley-type Pb/Zn ore was traced to a pH effect. In the pH range 9.5-11 sphalerite floated readily without copper activation. Compared to sphalerite flotation with copper activation this procedure gave equivalent selectivity but reduced flotation rate.Possible mechanisms of this sphalerite flotation without copper activation are discussed. Activation by Fe(OH) 2 is suggested, the Fe++ions being derived from superficial oxidation of pyrite in the ore.INTRODUCTIONGalena and sphalerite commonly occur together. The usual practice is to float galena first followed by the flotation of sphalerite after activation with copper (II) sulphate. If ores contain pyrite it is depressed by maintaining an alkaline pH (9- 10) and using NaCN as depressant.In flotation tests with a Pb/Zn ore from Polaris selective flotation of galena could not be achieved consistently as a considerable amount of sphalerite, even though unactivated, floated. A systematic study was carried out to determine the cause of this problem. This led to the unexpected finding that sphalerite floated in the alkaline pH range 9.5-11.0 without preactivation with Cuso 4 . This paper describes the results of this study and discusses a possible mechanism of the flotation of sphalerite."

Jan 1, 1987

By Robert Martinez

A proven high grade reserve of gold mineralization located in Mexico is evaluated to determine which gold recovery process is best suited for this deposit. The processes evaluated are; Heap leaching, Vat leaching and a CIP circuit. All qualify as viable options, however each one presents a different economic picture which is impacted substantially by the financial constraints of the project. Taking this into consideration the most economic process was selected.

Jan 1, 1987

By Leonard B. Rothfeld

For many years, pulverized coal (PC) boilers in utility power plants have been the dominant market for domestic coal. Today, two new coal utilization technologies challenge the PC boiler's dominance. Atmospheric fluidized bed combustion (AFBC) and "coal gasification/combined cycle" (GCC) stand on the verge of commercial demonstration in the utility environment at a scale of 100 MW. Developed over the past decade, these technologies respond to the demands for cleaner ways to burn coal and for more flexibility in fuel supply. In the near term, these are the "clean coal" technologies most likely to have a significant impact, because they are ready for commercial application. As for environmental acceptability, consider that just a few years ago one of the environmental slogans was "no coal in California." Indeed, the only large quantities of coal above ground in California at that time were in transit on the way to Asia. Today, thanks to new technology, we can point to two operational coal-burning plants in California and one in the works: * Cool Water GCC demonstration plant (100 MW) * California Portland Cement AFBC commercial cogeneration, near Riverside (190 000 lb/hr steam) * Energy Factors AFBC commercial cogeneration at Stockton, to be operational 1988 (44 MW)

Jan 1, 1987

Nippon Telegraph and Telephone Corporation (NTT) developed a new construction method (the M-2 method) that could drive a long, curved small-diameter tunnel (4>1.2 m) without human labor. This method employs the cast-in-place lining system, using quick-hardening resin mortar, so that it can greatly increase the driving distance and execute both long distance driving (longer than 500 m) and curved driving with a radius of curvature of 200 m. Furthermore, the central control system with a mini-computer in a vertical shaft enables all work in a small-diameter tunnel, i.e., excavation, lining, and transportation of excavated soil and materials, without human labor. NTT conducted several field tests and a Practical Application Test (P.A.T.) under a public road bearing great traffic. Good results were obtained and the practicability of this method was demonstrated. Therefore, from now on, NTT will apply this ii-2 method to drive telecommunication cable tunnels in urban areas. This method will also be applicable to constructing public tunnel facilities, such as for water, sewage, electricity and gas.

Jan 1, 1987

By Sudharto RT

Sulphides of Cu, Pb, and Zn occur in quartz veins associated with a quartz monzodiorite stock at Gunung Limbung, West Java. The mineralization was polyphase and occurred at depths of less than lkm. Wall- rock alteration is extensive and typically consists of an outer zone of propylitization and an inner zone of potassic (K-feldspar- rich) alteration. Sporadic argillic altera- tion is probably of supergene origin. A variety of elements were mobilised during hydrothermal alteration and Ba in particular shows mared enrichments in the potassic zone. Fluid inclusions in the vein quartz indicate that temperatures of mineralization were within the range 250-3900C and that two fluids with differing chemistry were involved. One fluid had high Ca/Na ratios and a low overall salinity, the other had low Ca/Na ratios and a moderate salinity. The former is probably of meteoric derivation, whilst the latter had a magmatic origin. Precipitation of the sulphides was probably brought about by mixing of these fluids.

Jan 1, 1987

By Thomas S. Bubanovich

This paper will discuss the installation and operation of the Mundix Monitoring System at the Freeman United Coal Mining Company's Orient No. 4 Mine. Detailed explanations of the objectives set by Management, description of the mine, description of the system, installation procedures, and material used, operating procedures, maintenance procedures, and personnel requirements as well as experiences with carbon monoxide monitoring.

Jan 1, 1987

Detailed characteristics of gold from Pliocene auriferous quartz gravels from Waimumu (Southland) have been studied using a combination of optical microscopy, energy dispersive microprobe analysis and scanning electron microscopy techniques. The gold at Waimumu is classified as either: 1. detrital gold, or 2. irregular gold. A number of different morphologies a recognisable within each 'gold type'. Evidence is given for an predominently authigenic origin for some of the gold at Waimumu.

Jan 1, 1987

By Mark R. Bowie

Air-fall tuffs have been altered to zeolite via reaction of volcanic glass with local pore solutions at the six localities discussed in this paper. These are in the southern Basin and Range Province of Arizona and New Mexico, and in the Trans-Pecos and Coastal Plain regions of Texas. Zeolitization occurred in either closed- hydrologic, open-hydrologic, or hydrothermal groundwater systems. The tripping Spring Valley (DSV) chabazite in Arizona and the Buckhorn clinoptilolite in New Mexico originated in a late Cenozoic network of closed-hydrologic, lacustrine basins extending from southeast Arizona into southwest New Mexico. At DSV, two potentially commercial chabazite-rich tuffs are interbedded with lacustine mudstone. The main zeolite tuft contains up to 90 percent chabazite. The upper zeolite tuff averages approximately 67 precent chabazite. At the Buckhorn deposit, two clinoptilolite-rich tuffs are interbedded with lacustrine m udstone in the upper part of the Gila Conglomerate. The lower zeolite tuff contains up to 90 percent clinoptilolite. The upper zeolite tuff contains over 60 percent clinoptilolite. The Casa Piedra clinoptilolite is in the Trans-Pecos region of Texas. It formed during the Tertiary in a closed basin containing a playa lake. The Casa Piedra tuff averages about 60 percent clinoptilolite. Air-fall tuffs of the Cuchillo Negro, New Mexico and Tilden, Texas clinoptilolite deposits were zeolitically altered by either percolating ground waters in open-hydrologic systems or locally by ponded, saline, alkaline solutions. Cuchillo Negro tuffs are Tertiary and average approximately 50 percent clinoptilolite. Clinoptilolite-rich tuffs of Ebcene age have been mined from four quarries at the Tilden deposits. Tufts from the Kuykendall and Buck Martin quarries contain approximately 50 to 60 percent clinoptilolite. Low temperature, SiO2 - rich, hydrothermal solutions altered air-fall tuff to clinoptilolite and chabazite in the Foster Canyon area of the Tertiary Cedar Hills and Seldon Hills volcanic-vent zone in southcentral New Mexico. Poster Canyon tuffs contain up to 60 percent zeolite and average 40 to 50 percent clinoptilolite. The dominant mineral in the zeolite tufts at the six deposits studied is generally microcrystalline and either chabazite or clinoptilolite. Lithic fragments, unaltered volcanic glass, other zeolites, quartz, calcite, opal-CT, cristobalite, feldspar, evaporites, clays, and mafic minerals are also constituents of the tufts.

Jan 1, 1987

By Richard Louis Viner, William D. Leech, Walter A. Mergelsberg

With the construction management team established and a full funding agreement secured the Washington Metropolitan Area Transit Authority (WMATA) now has the manpower and the financial resources to continue Metrorail construction into the 1990's. This paper describes WMATA's new role as construction manager after the transition from Bechtel Associates and gaining the full funding agreement with the Urban Mass Transit Administration (UMTA) and regional governments to complete 84.7 Metrorail miles (136km). The authors review the most recent station and line tunneling projects. WMATA's contractors have employed the state of the art soft ground and hard rock tunneling equipment and methods - an earth pressure balance TBM, a closed face TBM, and the New Austrian Tunneling Method (NATM). In final, the paper previews future underground work to be let under the funding agreement.

Jan 1, 1987

By Dominic F. Howarth

Cuttability and borability assessment methods in rock and coal are reviewed. TBM, roadheader and coal cutting machine boring rates can be predicted from a knowledge of machine, intact rock property and rock mass parameters. Results that were obtained from a detailed analysis of two TBM borability prediction methods and comparison with data from twenty case histories, show that a simple, low-cost method that uses one machine parameter and one rock parameter compares very favourably with a sophisticated, high-cost method that also includes details of rock mass characteristics (discontinuity, type frequency and orientation).

Jan 1, 1987

By Zhansen P

This paper describes the test re- sults which give a complete proccess of failure of concrete lining embedded in sand medium under load, including the order of appearance of crack along the lining up to failure. nor each crack appearance corresponding calculation being made to assess the redistribution of moment and thrust force in critical section including crown section, section making 45¦ with the vertical etc. De- flection at the above stated critical sections are also measured at each stage of loading. The pressure along the top hori- zontal surface of embedded lining and the vertical sides are measured by pres -sure gauges embedded in sand medium. fhe test results show a complete figure of rupture characteristics of concrete lining embedded in soft ground which approximates alluvial deposite often occur in metro construction at cities near the river side. These test results have been taken as a reference in assessing the action behavior of concrete lining in certain cities in China.

Jan 1, 1987

Recent and on-going studies on the leaching of gold, the properties and activity of carbon, developments in the elution of gold from carbon, and methods of recovering gold from solution are reviewed. Emphasis is placed on Australian contributions, and their impact on gold metallurgy. Consideration is given to the future development of selective solvent extractants, ion exchange resins or alternative reagents for cyanide.

Jan 1, 1987

By Gennaro Marino

Documented case histories are studied where data were found on the initial collapse of the overburden above the longwall panels. Under this scenario, the most controlled conditions exist for assessing the span capacity of the overburden (i.e., before failure the roof spans to fin coal abutments on two to all four sides). In an attempt to correlate theory to field observations, data are used on the overburden lithology, and the depth, width, and face advance of the panel, as well as, the subsidence conditions noted on the surface. The subsidence measured on the surface is used to determine when complete failure in the over- burden rock has occurred.

Jan 1, 1987

By C. F. Gleeson, D. G. Sheehan

"The results of humus and overburden geochemical surveys over the Doyon, Bousquet and Page-Williams gold ore deposits are presented.These studies show that humus sampling for gold gives negative results over the Doyon deposit. The lack of response is probably caused by the presence of 1 m of relatively impermeable glaciolacustrine clay and silt that overlies 1 m to 2 m of till over the surface expression of the ore zone. By contrast, positive responses for gold occur in humus samples over the Page Williams A and C gold deposits. The ""A"" ore zone is covered by several metres of exotic calcareous till over 0.5 m to 1 m of older, locally derived till. Anomalous values for gold in humus range from 10 to 35 ppb over the orebody. Overburden over the ""C"" ore zones is much thinner, generally it consists of less than 2 m of sandy till. Trenching humus anomalies that range from 10 to 1360ppb Au uncovered the gold mineralization. The geochemical dispersal trains in till from the Doyon orebody and the Page-Williams ""A"" zone are relatively short (i.e. less than 200 m) because both deposits occur in the lee of bedrock highs that shielded them from extensive glacial quarrying. Dispersal trains from all three pyritic gold deposits can be defined using either the fine fraction or heavy mineral fraction of the till.The intensity of the gold in till anomalies over the ore zones is variable. Therefore, it would be misleading to attach rigid significant threshold gold values to overburden drilling results. Each case must be evaluated based on bedrock topography, sample density, overburden type, thickness of till, as well as size, type and orientation of the target exposed to glacial erosion."

Jan 1, 1987

By J. H. Bulloch

The paper gives an assessment of the available data on the linear elastic fracture mechanics involved in stress corrosion cracking and in the behaviour of reactor pressure-vessel materials exposed to a simulated pressurized water-reactor environment. As a result of the different experimental techniques used in the various studies mentioned, only a few detailed conclusions can be drawn. The data from constant-displacement wedge-opening loading (WOL) tests, with the exception of one study, exhibited very limited or no crack extension during exposure periods of up to 14000 hours. The data from constant-load tests indicated evidence of crack extension, but the nature and extent of the crack extension are still unclear. When crack extension did occur, it was exclusively transgranular in nature. Certain differences in the available test data are tentatively explained in terms of the experimental procedures used, and the need for a consistent code of experimental techniques is highlighted.

Jan 1, 1987

By Boyce WH

Earthquakes are the most frightening and devastating natural phenomena known to mankind. They strike without warning and their consequences can be disastrous in terms of the toll of human life, financial crises related to the damage or destruction of man-made structures and the social and economic effects on a wide spectrum of the affected communities in the aftermath of the event. Such situations can be widely attested to by most areas around the Pacific Rim. Indeed, the threat of earthquakes is always imminent because of the geological-tectonic nature of the region as manifested by past experiences. It is patently obvious that earthquake occurrences are not only a geological hazard but also pose a serious social danger. When one considers the 19 September 1985 Mexico (Michoacan) earthquake (Mitchell at al., 1986), the necessity of continuing research is of paramount importance. An estimation . of earthquake risk encompasses both qualitative and quantitative aspects and demands a multidisciplinary research effort integrating seismology, tectonics, geology, enginering, sociology, economics, insurance and governmental policies (Bolt, 1978; Booth, 1984). These roles in mitigating such a hazard have been aptly discussed by Press (1985). A series of discussion papers based on an intergovernmental conference covering the whole scenario were published by UNESCO (1978). A comprehensive case history was provided through a workshop on the 1886

Jan 1, 1987

By R. H. King

The Deserado Mine of Western Fuels- Utah Inc. installed a micro-computer based mine wide monitoring and control system for mine environment, beltway fire protection, belt operating parameters, and equipment power utilization. The Colorado School of Mines was funded by the U.S. Bureau of Mines to document, evaluate, and report on the system design, procurement, installation, tests, and operation. This paper results from that project. The paper compares planned activities such as installation and start up, procurement contract specifications and system layout with actual performance to develop recommendations for future installations by mine operators.

Jan 1, 1987

By Y. C. Lo

This paper attempts to answer whether or not the mill performance at Bougainville could have, in fact, been predicted by the population balance approach, or whether other special considerations are required to explain their behavior. In recent studies, the plant tests were performed at Bougainville and batch tests were carried out at the Utah Comninution Center. In all tests power measurements were made and several levels of energy input to grinding were evaluated. Also, tracer tests were performed for mill residence time determination. The performance of Bougainville's 5.5 x 6.4 m mill has been very successfully predicted by population balance methods. The prediction errors are only about 1% on product size distribution and 4% on power with a mill volume scale-up of 3790 to 1. It is significant that this approach will reduce the risk of failure in large mill design that has been recognized in traditional methods.

Jan 1, 1987

By I. Anazia

Selective fatty acid flotation of carbonate gangue from sedimentary apatites was achieved under acidic pH's without a specific apatite depressant and without conditioning the pulp with the collector. Concentrates (35-38% P205, 0.8-1% MgO) with high recoveries (80-85%) were produced from Indian and Chinese dolomitic ores. The calcareous and/or dolomitic-siliceous phosphate ores of South Florida and Utah required two flotation stages: one for carbonate removal, as mentioned above, and the other for phosphate recovery from siliceous gangue. Preliminary tests on the South Florida ore gave concentrates analyzing 29% P205 and 0.8% MgO with a P205 recovery of 76%. Data are also included showing the applicability of the process to the dolomitic-calcareous-siliceous Western U.S. phosphate ore from Utah. A concentrate obtained from this ore assayed 30% P205 and about 1% MaO.

Jan 1, 1987

By I. J. Jansen

Successful soil construction involves preparation of an adequate base, selection of high quality soil materials, and placement of those materials by means which will establish a continuous macropore network and modest to low soil strength. Where such has been accomplished, experiments reveal row crop productivity on reclaimed land which is very competitive with that on undisturbed land. Inferior productivity and sensitivity to drought stress are experienced where the soils are excessively compacted during construction. Some deep tillage practices have been quite successful in improving the compacted soils, but it is preferable to avoid compaction as the soil materials are handled.

Jan 1, 1987