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By Michael D. Balen

During the years 1987 through 1989, the Bureau of Mines Alaska Field Operations Center (Bureau) in cooperation with the Western Field Operations Center and the Alaska Division of Geological and Geophysical Surveys (ADGGS), conducted mining, geological, and geochemical investigations in the 5.7 million-acre Valdez Creek Mining District (VCMD). This investigation was conducted as part of the Bureau's continuing Mineral Land Assessment (MLA) mining district studies program. The Bureau's MLA program is designed to provide reliable and comprehensive mineral resource information that supports mineral resource policy and land use decisions made by Congress and Federal land management agencies. The information also provides the basis for decisions that would expand the domestic supply of important mineral resources, primarily strategic and critical minerals. Much of the MLA work is done jointly with cooperating State or U.S. geological surveys.

Jan 1, 1992

By M. H. Moys, J. Engelbrecht, N. Terblanche

Interface levels in flotation columns are generally measured with the aid of a pressure-sensitive Instrument, e.g. a differential-pressure cell. This paper criticizes the use of this type of measurement, and discusses other methods that are claimed to give more accurate measures of interface levels. The paper focuses on the development of methods based on the measurement of conductivity across the froth-slurry interface. These are often sabotaged by variations in the conductivity of the feed slurry, particularly when the pH of the slurry IS being controlled, e.g. In sulphide flotation. Methods of improving the accuracy and reliability of this technique are described. The result IS a robust, easy-to maintain level-control scheme that successfully rejects large disturbances in plant operation (including a 5:1 change in slurry conductivity) while controlling levels to an accuracy of I 4 cm.

Jan 1, 1992

By D. McCarthy

This paper discusses the process involved in developing an optimum method of treating and removing heavy metals from water that have leached out from the native rock -prior to discharge back into the environment. Also designed into the system is a manner to stabilize the metals removed as a precipitate, so that they can be disposed of as a non-hazardous waste.

Jan 1, 1992

By W. P. Barnett

In 1988, the U.S. Department of Energy's Pittsburgh Energy Technology Center identified three coal cleaning options for achieving flexible environmental control strategies aimed at reducing energy-related SO2 emissions. These are selective agglomeration, advanced froth flotation, and advanced cycloning. Each technology relies on maximum liberation of pyrite and other mineral matter through feed coal comminution to fine and ultrafine sizes. Research projects designed to expeditiously develop each of these technologies to the point of commercial viability were initiated. This paper will present the status of these projects and the application potential of each technology to coal beneficiation.

Jan 1, 1992

By W. R. Dengler

Dynatec Mining Limited contracted to sink a lS00 metre (4960 ft.) concrete lined shaft for Falconbridge Nickel Mines in Sudbury, Ontario, Canada. The shaft is 6.3 metres (20.S ft.) in diameter inside the concrete lining and is equipped with steel furnishings. Dynatec used the owner supplied 4.6 metre (l5 ft.) diameter double-drum hoist to sink the shaft with 12.S tonne buckets for muck removal and 4 cubic metre concrete buckets for concrete placement. One of the unique features of the shaft sinking operation is the use of a four-boom electric hydraulic drill jumbo permanently mounted in the shaft sinking stage. This paper will describe the performance obtained with the electric hydraulic drilling equipment and the high capacity muck removal and concreting equipment.

Jan 1, 1992

By Bruce J. Barker

"Environmental concerns have recently been growing over the disposal of reactive desulphurizing slag. Consequently, increased pressure has been placed on the foundry industry to reduce the reactivity of this slag.To address this problem, Cyanamid has developed a new product which significantly reduces the calcium carbide content of the desulphurizing slag. Testing equipment and procedures have also been developed to evaluate both the existing levels of carbide in the slag and the decreased levels which are achieved with this new material.The development and use of this engineered carbide desulphurizer has made possible significant environmental and efficiency improvements in the field of calcium carbide desulphurizing. Consequently, the lifespan of calcium carbide in ductile iron desulphurization has been increased, as have the benefits of its use in the foundry industry. IntroductionIn the production of ductile iron, calcium carbide has long been used for hot metal desulphurization external to the cupola. Its cost effectiveness, reliability and ease of use have traditionally made it the desulphurizer of choice for a great majority of ductile operations. Recently however, environmental concerns have been raised regarding the quantity of calcium carbide remaining in the slag after desulphurizing. Analysis has shown that as much as 25070 of the weight of the slag may contain active carbide. This has caused disposal concerns as calcium carbide when in contact with water, produces acetylene via the following reactionr:"

Jan 1, 1992

By Heikki Tuovinen

The total utilization of raw materials and energy is the most important criterion when planning. industrial processes. The main goal is clearly to use the raw materials and energy as effectively as possible in order to make the desired products directly in the primary process itself', or to recycle unused materials and energy either as such, or after cleaning back into the process. However, few industrial processes are so straightforward. Most processes generate by-streams of materials and energy, which cannot be recycled directly and it is namely these by-streams which tend to remain as wastes. These by-streams are slags, dusts, vaporized metals, liquids, slurries, sludges, gases etc. Most base metal processes produce all these by-products. Waste water and gas emission controls and regulations are tightening all the time, so new processes must be developed to keep pace with these requirements. These processes generate more solid wastes, which must be utilized or at least processed into a harmless form landfilling. Municipal and hazardous wastes also contain valuable materials and energy, which must be used to minimize landfilling. The development of processes for these purposes places even greater demands on research and development. The same principles and methods developed for mining, ore dressing and metal refining processes can also be adapted for research and development work on processes for waste minimization. However, the problems encountered are much more complicated and less familiar, demanding more versatile and accurate tools and equipment. This paper presents principles, examples and some references of R & D work on processes for waste minimization.

Jan 1, 1992

By Duran A, Eggers M. J

It is standard practice in geotechnical studies for mine design to drill a series of inclined oriented boreholes into the proposed pit walls. However, this investigation tool is often used without an adequate understanding of the inherent shortcomings in the method and the many potential sources of error. Of the more commonly used orientation methods in Australia the clay imprint technique is probably the most reliable. Contoured stereographic plots of oriented core data are frequently characterised by diverse pole distributions and low concentration maximums compared with line mapping data. Common sources of error producing these poor results are misinterpretation of orientation marks or imprints, inaccurate marking of the reference line, errors in the structural measurement of the defects, lack of continuity information and blind zones sub-parallel to the borehole direction which correction methods frequently do not fix. Line mapping is the preferred method of structural data collection due to the lower overall cost, availability of continuity information and higher accuracy. The projectability of field mapping data to final wall positions can be assessed with a good understanding of the regional geology and local structural patterns. Where field mapping is not possible due to a thick regolith cover, core orientation should be carried out by experienced personnel to minimise the many potential errors.A series of case studies are presented which compare oriented core with mapping and highlight the inherent problems with the technique.

Jan 1, 1992

Rehabilitation has been very effective in the short to medium term in providing a cost effective and reliable means of containing the side effects of land disturbance. However, there is still insufficient data to critically evaluate the sucess of rehabilitation in the long term. There is an urgent need to develop objective criteria to monitor the sucess of rehabilitation. The aim of rehabilitation in Australia has traditionally been to return disturbed land to natural vegetation compatible with the surrounding area. This objective has often been accepted instinctively without adequately addressing alternatives.

Jan 1, 1992

By Art Johnston

Gas handling at Magma Copper Company's, San Manuel smelter receives process gas from a flash smelting furnace and four copper converters. The major gas handling equipment consists of four electrostatic precipitators and a sulfuric acid plant. Process vessels in gas handling are typically confined spaces. Lethal gases., mechanical and chemical hazards, and the difficulty of rescue, should an accident occur, makes this area a must in the safety plan. The presence of hazardous chemicals and explosive gases in process vessels and piping are of major concern when repairs are required. Proper job procedures are critical to prevent injury during repairs. This includes plant employees and contractors who are likely to be unfamiliar with the hazards involved. The safe operation of a gas handling operation must include the functions of operations employees on a daily basis. This includes a safe working environment and involvement. of all employees in the safety program. If an injury does occur quick medical response is critical to prevent serious injury. Medical responders must be adeqliately trained and prepared to treat the injured person without becoming victims themselves.. The methods used at Magma copper Company to deal with these safety problems are the focus of this presentation.

Jan 1, 1992

By Yukio Ishikawa

Sumitomo Metal Mining Co,. Ltd. (SMM) has been producing 22,000 t/y of electrolytic nickel at Niihama by nickel matte electrorefining process since 1970. Although the matte electrorefining is an established process and the productivity has been greatly improved in the last 20 years, SMM has intensively developed the chloride process for the nickel production since 1970's. The nickel and cobalt refining process involving solvent extraction and electrowinning from the chloride solution has been successfully developed for the treatment of the mixed sulphide in 1975. The first application of chlorine leach to the anode slime has been succeeded since 1986. Based on those technology, the matte chlorine leach electrowinning process (MCLE) has been developed as an alternation to the relatively old technology of matte electrorefining. The new process offers significant cost down and excellent quality of the product. In 1986, the feasibility of MCLE was confirmed by the test work using the integlated pilot plant. The innovation of the chlorine leach process has been undertaken by this work. The new refining process can be divided into three stages including chlorine leach stage, purification stage and electrowinning stage. More than 99 % of nickel was extracted in atmospheric chlorine leach. Although copper ion was used for electron carrier in the chlorine leach, the excess copper from the feed matte is bled off from the leach circuit by de copperizing electrolysis. The copper ion of the pregnant solution is fixed on nickel matte by the cementation reaction. The nickel matte containing copper is processed in the chlorine leach. In the purification circuit, cobalt, iron and other impurities were removed from the nickel chloride solution. The nickel chloride solution is then fed into the electrowinning cell. Based on the process established, the new plant with a capacity of 330 t/M electrolytic nickel was commissioned in order to obtain the engineering data for design of the full scale plant in 1989. The performance of the plant was fully satisfied and the new process demonstrated the potential application of modern process control.

Jan 1, 1992

By Bhattacharyya AK

With increasing demand for more efficient production from the underground coal mines in the Southern Coalfields- of New South Wales, their design and operational aspects are constantly being reviewed and improved. One key area in such pursuits is the reliable design of stable and yielding pillars. The current designs of pillars based mostly on experience leads to unnecessary sterilisation of coal or strata control problems. To explore such mine design problems, computer based modelling is increasingly being applied. In the study described in this paper, the object was to determine the particular width of pillars separating three roadways in a panel at which the pillars yielded completely and their loads largely transferred to the unmined coal at the flanks of the panel. This was approached through a computer simulation of the behaviour of the strata around a panel, in which the three roadways were separated by pillars of progressively decreasing width. A computer program called FLAC based on the finite difference method was used to simulate the relevant strata behaviour in vertical sections. The appropriate in situ values of the deformability parameters relating to the coal seam, roof and floor were determined from the back analysis of some displacement measurements in such a panel. The process involved successive modelling of a vertical section through such a panel,starting with realistic values of the parameters and varying them until the measured and the modelled displacements agreed closely. Based on the results of the numerical modelling, the width of a yielding pillar for the given conditions is Suggested.

Jan 1, 1992

By N. T. Cowper

Slurry viscosity ultimately affects the majority of mineral extraction processes. However, to date its role has been disguised because mineral processing equipment has been conservatively designed to operate at minimal slurry viscosity. With most ores this still meant acceptable solids concentration was achieved. However, with the advent of treatment of weathered ores the resulting higher slurry viscosity (rheology) has meant solids concentration has had to be reduced, often to unacceptable levels. To permit operation at higher solids concentration chemical dispersants are employed. These dispersants are expensive and their addition should be controlled. Slurry Systems Pty Limited (SSPL) has developed an On-Line Viscometer to monitor and control slurry viscosity, whether by controlling water addition or by controlling dispersant addition. Using this instrument the slurry rheology can be controlled at the optimum level, maximizing solids throughput, and minimizing water, reagent, and dispersant addition. This paper discusses rheology of typical mineral slurries, the relationship between slurry rheology and percent solids in a slurry, and the need for rheological control in mineral processing. The effects of rheology on various process steps, and the use of dispersants are reviewed. The paper concludes with summarizing actual case histories and cost impact of Theological control.

Jan 1, 1992

By W. Drummond

The cooling of smelter gases by air dilution, adiabatic evaporative cooling and indirect heat exchange is discussed with reference to the process, to the subsequent cleaning of the gas. and to the use of the heat extracted from the gas. The method of reducing the effect of acidic sulphide formation on the corrosive properties of the gas and the dust and the development of surface cleaning mechanisms?are discussed. The development of indirect recuperators using air, water or steam cooling, made possible by the control of surface fouling is traced. The application of the modern Waste Heat Boiler to the new sulphide smelting processes is discussed with respect to the natural and forced circulation concepts. Case histories are presented to illustrate mistakes made with respect to designs produced without recourse to sensitivity analysis and without an appreciation of "worst process? conditions".

Jan 1, 1992

By Osamu Taki

The development of new auger bits for soil cement column drilling equipment has made it possible to create a homogeneous mixture of soil and cement-reagent slurry. As a result, soil-cement columns are used for foundations of houses and buildings, with reliable results, as demonstrated by many field projects and laboratory tests. This paper presents and discusses construction techniques for soil-cement columns, characteristics of the soil-cement solid, quality control, bearing test results, and soil-cement foundation design procedures.

Jan 1, 1992

By Lumley G. I, Hayes H

Non-intrusive methods for the reliable determination of dragline bucket and rigging performance have been achieved using physical modelling. Modelling offers a logical first step towards developing mathematical simulation models. The process of physical modelling has been applied successfully to predict dragline bucket performance and capacity as well as to demonstrate the effect of varying dump rope length on performance. ACIRL's Surface Miming Group has used physical modelling to carry out dragline bucket sizing for a new high productivity bucket and compared performance with Throng Coal's existing dragline bucket. The predicted bucket performance has since been confirmed in the field using dragline monitoring techniques.

Jan 1, 1992

By James R. Myers

A source of clean gas containing sulfur dioxide and sufficient oxygen for convers.ion to sulfur trioxide ?is essential to the production of sulfuric acid. S02 containing gases obtained from roasting sulfide ores are heavily contaminated with inorganic dust and volatile impurities. If not removed, these contaminants will reduce product acid quality, foul the catalyst beds and mist eliminators, and accelerate equipment corrosion. This paper reviews conventional gas cleaning systems for metallurgical acid plants, followed by a discussion of modern systems utilizing DynaWave Scrubber technology. This technology is based on a unique approach to? gas scrubbing that can concurrently accomplish several gas cleaning/processing tasks scrubbing liquid is injected into the gas stream to create. a "Froth Zone". This is a region of extreme turbulence, with a very high rate of liquid .surface renewal. It efficiently removes both particulate matter and gas contaminants, and is also a cost effective quenching device for gases as hot as 1250º C. Smelter

Jan 1, 1992

By Sarkis G. Ampian

Crystalline silica (quartz, cristobalite, and tridyrnite) is regulated by the Mine Safety and Health Administration (MSHA) and Occupational Safety and Health Administration (OSHA) because of its potential for causing debilitating but nonmalignant lung diseases. In 1987, the International Agency for Research Against Cancer (IARC) conducted a review of the health literature and concluded that crystalline silica was a probable human carcinogen. As a result of this finding, OSHA was required to regulate crystalline silica under its Hazard Communication Standard (HCS). The standard requires that all materials handled by OSHA-regulated facilities be labeled according to the requirements of RCS and that workers receive proper training on the handling of the material if the crystalline silica content equals or exceeds 0.1 weight percent (0.1 %). MSHA currently is considering enacting its own RCS. This will be similar to OSHA's RCS. If the standard is enacted, most mineral producers will have to determine the respirable monitor filter and bulk crystalline silica contents of their ores and products so that workers and/or customers will know whether they are in compliance with the 0.1% HCS and/or the OSHA permissible exposure level (PEL) of 50 µg for an 8-hour workday for respirable crystalline silica as determined from monitor samples. Two major concerns with the RCS are the widespread occurrence of crystalline silica in nature and the suitability of current technology for routinely determining crystalline silica concentrations at the 0.1 % RCS level. Most ores are extracted from silica-bearing deposits and it is a common constituent of rocks and soils. OSHA's RCS will have the greatest impact on the producers of crushed stone, diatomite, dimension stone, gravel, industrial sand, perlite, pumice, pyrophyllite, sand, and talc because these materials frequently are shipped directly from the mill to the customer. MSHA's RCS would affect nearly all mineral producers. Those producers that have crystalline silica present in concentrations near the 0.1 % cutoff point will have the most difficulty with the analysis. Crystalline silica can be quantified at the 0.1 % level by X-ray diffractometry in simple systems containing one, two, and possibly three minerals if (1) none of the accessory minerals has X-ray diffraction reflections that coincide or overlap with those of crystalline silica and (2) the standard has a particle size distribution and crystallinity similar to those of the sample. In some instances, it may not be possible to determine the crystalline silica content of a sample with any degree of certainty using the recommended regulatory protocol. In all cases, it is recommended that a qualified mineralogist identify the minerals in a sample prior to any regulatory analysis. Additionally, the uncertainty as to whether some silica polymorphs should be classified as crystalline or noncrystalline and the suitability of metastable high-temperature standards, such as cristobalite and tridyrnite, for regulatory analysis at ambient temperatures should be addressed further. This overview is written both to highlight these problems and to serve as a guide for analysts, regulators, and industry personnel who are involved in the crystalline silica issue. It also covers some of the difficulties and/or shortcomings in quantifying crystalline silica, such as the ubiquitous mineral quartz, in the workplace.

Jan 1, 1992

By J. D. Miller

On the basis of nonequilibrium zeta potential measurements by laser-Doppler electrophoresis, the sign of the surface charge of alkali halides in their saturated brines has been established. The results are generally as expected from simplified lattice ion hydration theory. This recent electrokinetic information coupled with the stability and prevalence of collector colloids in such soluble-salt flotation systems suggests that the selective flotation of alkali halides is due to the adsorption of oppositely charged collector colloids by heterocoagulation. Experimental flotation results confirm this surface-charge/collector-colloid adsorption model and are presented herein.

Jan 1, 1992

By M. A. Boucher

The purpose of my presentation is threefold: a) to make you aware of what is available in Canada in terms of refractory minerals. b) indicate the mineral deposits that have potential for development. c) show the advantages of Canada as a supplier of electrical energy necessary for the production of electrofused minerals. Canada is a producer of natural refractory minerals, electrofused minerals, and synthetic refractory minerals. Several deposits also have good potential for development. The natural refractory minerals produced in Canada are shown in Table 1. The major minerals by decreasing order of importance in terms of tonnage and values are: dolomite, graphite and magnesite.

Jan 1, 1992