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By Aliye Arabaci

In the present investigation, an attempt has been made to study the reduction behavior of composite pellets consisting two different types of iron oxide fines (high and low grade) and coke or lignite fines as reducing agents. The reduction experiments were carried out under isothermal conditions and constant flow of nitrogen gas in the temperature range of 900 ? 1100 oC. The variables investigated are the reduction temperature, Cfix/Fe3O4 ratio, reduction time and reductant type. In the experiments carried out with Sivas Divrigi A head magnetite ores (high grade) at a temperature of 1100 oC, for 40 minutes and on the condition that Cfix/Fe3O4 ratio is 0.2, in which lignite and coke fines were used as reductant, degree of reduction was obtained as 91 % and 86 %, respectively. Whereas, in the experiments realized with Malatya-Hekimhan-Hasançelebi magnetite ores (low grade) on the same conditions by using lignite as the reductant, around 60 % degree of reduction was found.

Jan 1, 2008

By Magdelinka Padenkova-Yaneva, Emilia Christova Kostakeva

"Environmental protection is becoming over the years an increasingly significant problem of mankind. Up to the last decade the only way to make the domestic waste harmless in Bulgaria was deposition on uncontrolled landfills without undertaking actions for protection of the soils. This also caused pollution to spread into the surface and underground waters and that is why actions are now undertaken for remediation of contaminated soils. This is achieved by developing projects for the closing down of polluted sites. In the present paper some projects for closing down of polluted areas are discussed. The actual conditions are examined and project decisions for preventing the surface waters from penetrating into the waste are presented. In this way the pollution of the soil is stopped and the soils are gradually remediate.IntroductionSoil is the topmost layer of the earth crust. It consists of mineral particles, organic substances, water, air and living organisms and is an extremely complex and changing living environment. Soil is a non-renewable natural resource which is of considerable importance in a number of crucial processes (production of foods, storing, filtrating and turnover of many substances, including water, carbon and nitrogen). It also serves as a basis for human activities, shaping the landscape, ground on which cultural heritage is built, and source of raw materials. These functions of soil must be protected both because of their social and economic significance and from the point of view of environmental protection.The processes of erosion, loss of organic substances, compaction, salination and contamination contribute to the degrading of soils accompanied by a negative impact on human health, natural ecosystems and changes in climate, as well as on the economy. All these make it necessary to protect soils from contamination. Over the last years intensive work started in Bulgaria for the construction of controlled sanitary landfills for rendering municipal solid waste harmless. Pursuant to Bulgarian legislation, in these controlled sanitary landfills measures are undertaken for protecting the soils from contamination through appropriate project decisions – the filtration of the products from the biological decomposition of waste into the adjacent sites (soils) and, therefore, the contamination of the surface and underground waters is prevented. At the same time the purity of air is maintained, human health is protected and conditions are created for including the controlled sanitary landfills into the surrounding landscape."

Jan 1, 2008

By S Arthur, J Mills, A R. Penney

A key aspect of seismic management for narrow vein stoping of the west zone at the Beaconsfield Gold Mine has been the development of a fully remote extraction method that does not require personnel access to sill drives within the orebody once stoping commences. Initially, sill driving within the reef is undertaken in a conventional fashion under geological control. Sill drives are developed at a vertical backs-to-floor height ranging from 7 - 12 m. This mining stage includes all activities prior to the commencement of stoping, after which no personnel enter the unstoped section of the sill drive at any time for any purpose. The key aspect of the remote mining cycle is the use of footwall drill drives paralleling the ore drive at a minimum separation of 6 m under survey control. These drives provide the platform for fan drilling of the orebody. Up to 20 m strike panels are blasted in a single shot using electronic blasting techniques. Ore is mucked from the extraction level sill drive using tele-remote loaders. Aerials for tele-remote operation are installed through boreholes from the footwall drive, negating the need for personnel access to the sill drive. Once mucking of a stoping panel is complete, a laser scanning survey instrument is used to survey the final void for subsequent design and production reconciliation purposes. The survey instrument is mounted in the bucket of the tele-remote loader, and is also operated remotely. Finally, tele-remote loaders are used to dump waste rock fill from the upper sill drive. A system of flags and cameras installed in boreholes from the footwall drive assists the operator in locating the live stope edge during the filling cycle, again negating the need for personnel access.

Jan 1, 2008

By Brendan Henry

The Canada Line is a 19km long automated light rapid transit system with 16 stations in Vancouver, BC, Canada. The Concession was awarded to InTransitBC to design, build, partially finance, operate, and maintain the system for 35 years. The project must be complete by November 2009 to be ready for the 2010 Winter Olympics to be held in Vancouver and Whistler, BC. The bored tunnel section consists of 2.45 km of twin bored tunnel and 3 stations. The station work is limited to the excavations and temporary support necessary to facilitate the bored tunnel works. A joint venture between SNC-Lavalin Constructors Pacific and SELI (SSJV) has recently completed the design and construction of this section. Work for the bored tunnel commenced in November 2005 with shoring and excavation works for the tunnelling operations pit that will become Olympic Village Station and will be completed in the spring of 2008. The tunnels were driven with a 6m diameter Earth Pressure Balance Tunnel Boring Machine (EPBM) and lined with 250mm thick, 5.3m diameter precast concrete segments. Seven hundred and fifty meters of each tunnel were driven through glacial and interglacial deposits of sand, silt, and clay with granitic boulders. The paper discusses the challenges faced in negotiating these soils which contained unforeseen geological conditions. These conditions were overcome by developing a systematic approach to Risk Management that included thorough risk assessments, regular risk management meetings with the participation of two of the world?s leading EPBM experts, Professor Eisenstein and Professor Kovári, and by the ability of the construction team to effectively analyze and mitigate problems.

Jan 1, 2008

By M. L. Harris

In underground mines, coal dust explosions are prevented by the addition of rock dust sufficient to render the coal dust inert. The National Institute for Occupational Safety and Health (NIOSH) has developed a hand-held instrument that uses optical reflectance to measure the explosibility of a rock dust and coal dust mixture. This instrument is called the Coal Dust Explosibility Meter (CDEM). In this study, NIOSH personnel accompanied Mine Safety and Health Administration (MSHA) inspectors on their routine band surveys in five and three underground coal mines in MSHA District 2 (PA) and District 11 (AL), respectively. While underground, NIOSH personnel and MSHA inspectors used the CDEM to assess the explosibilities of the dust samples. The values of percent incombustible content (% IC) determined by the CDEM agreed well with those obtained later by low temperature ashing (LTA) in both MSHA and NIOSH laboratories. Further, the meter identified some samples as potentially explosible that LTA analysis had found to possess sufficient rock dust for inerting. The CDEM provides more information on the hazards in the mine. Rapid identification of areas with explosible dust mixtures using the CDEM allows for immediate intervention rather than a wait of several weeks for laboratory analysis.

Jan 1, 2008

By Oliver Finn

Gold dredging has made such rapid strides of late and there is such a widespread interest in this branch of mining that I venture to contribute a detailed account of the way in which a Keystone driller was used by me in California to loosen, by blasting, a very tight gravel deposit, preparatory to dredging. There is a great difference between “cemented gravel” and “tight gravel.” A truly cemented gravel is not a dredging proposition, while the tightest possible gravel, where there is no cement, can be made easy working by the following method of blasting:

Jan 1, 2008

By George Burnhart

"Sonic drilling is a relatively new technology even though it has been in development since the late 1940s. It was initially funded by the U.S. petroleum industry and then, in the late 40s, Russian scientists worked on developing sonic drilling, their interest based on drilling rates 3 to 20 times that of conventional methods. In the early 1960s, the Shell Oil Company backed research that resulted in a down-hole device with a series of eccentric weights driven by drilling fluid to generate vibration. Hawker Sidley, in the early 1980s, developed the first modern prototype sonic drills in Vancouver B.C. and the North Star Drilling Company in Minnesota became the first contractor in the U.S. to operate sonic equipment in 1985. In 1994, North Star became a division of Boart Longyear, headquartered in Salt Lake City, Utah.What’s Unique about a Sonic DrillA sonic drill rig appears and operates very much like any conventional top-drive rotary rig. The key difference is that a sonic drill has a specially designed hydraulically powered drill head, containing oscillators, that generates adjustable high-frequency vibratory forces. The sonic head is attached directly to the drill pipe or outer casing, sending the high frequency vibrations down through the drill steel to the face of the drill bit. This creates displacement, fracturing or shearing action depending on the material being drilled. The oscillator uses two eccentric, counter-rotating balance weights or rollers that are timed to direct 100% of the vibration at 0 degrees and 180 degrees. An air spring houses the oscillators and separates the vibration from the drill rig itself. The vibratory frequency is controlled to suit operating conditions and to achieve optimum drilling rates.When the vibrations coincide with the natural resonant frequency of the steel drill rod or casing, a natural phenomenon called “resonance” occurs. It allows the rig to transfer timed vibratory energy into the top of the drill string, utilizing the natural stored energy of the steel. This causes the drill string to use inertia and act like a flywheel delivering tremendous amounts of energy directly to the bit face. In friendly overburden formations, a sonic drill rig can achieve penetration rates of one ft per second."

Jan 1, 2008

In the last eight years inclined conveyor haulage systems have established themselves in the mainstream for hard rock underground mine haulage. This leaves the question; what else might be on the horizon for mine haulage and how do we address the process of selecting haulage systems for new mines? This paper considers the identification of viable haulage technologies for underground mines and explores an approach for assessing existing and potential technologies. The example of a large deep mine is considered here. The evaluation of existing haulage systems relies on precedence and the assessment of the system capacity to meet the haulage requirements envisaged for a particular mining project. The assessment of potential technologies for mine haulage relies on the capacity to deliver a viable production-scale system within the timeline envisaged for developing a mining project. The haulage technologies addressed in this paper include: shaft hoisting,conveyor haulage,truck haulage,vertical conveyors, andhydraulic hoisting. This paper does not consider rail haulage out of a mine. This is simply because Australian topography typically has insufficient relief to bring them into consideration. However, rail haulage is a widely used and effective haulage solution in situations where significant topographical relief is present. The assessment of haulage system capability focuses on the following fundamental questions: How reliable are they? What is the degree of technical risk in a business context?What levels of flexibility do they offer?How capital effective are they? What returns are indicated by the balance of capital and operating cost estimates?

Jan 1, 2008

By Russel Delmar

Construction of Ontario Power Generation?s 12.8-m diameter, 10.4-km long water diversion tunnel in Niagara Falls, Ontario, is underway. The tunnel is being excavated by means of a 14.44-m diameter open gripper Tunnel Boring Machine. The tunnel lining is constructed as a two-pass system with the initial lining consisting of rock bolts, mesh, steel channels or ribs, and shotcrete, and the final lining consisting of pre-stressed cast-in-place concrete with a waterproof membrane. This paper describes salient design and construction aspects as follows: ? Regional and Site Geology ? Tunnel Layout and Design ? TBM Tunnelling and Cast-in-place Concrete Lining Construction

Jan 1, 2008

By D Lau

Traditionally X-ray diffraction (XRD) has not been significantly used by the cultural heritage sector, as the most commonly used technique, X-ray powder diffraction (XRPD), requires sample removal from the artwork or artefact, followed by grinding of the sample to a fine powder. With the development of micro-X-ray diffraction (micro-XRD) and other associated advances, non-destructive, in situ analysis of crystalline pigments on micro-areas of paintings and artefacts has become possible. This is illustrated with the application of this technique to the in situ analysis of propriety paints, paint cross-sections and small paintings. However, workers have noted that XRD can be insufficiently sensitive with pigment mixtures, due to matrix effects. This study obtained X-ray diffractograms of 17 single pigment preparations and determined relative amounts of crystalline content. The purity of single pigments was compared with Joint Committee on Powder Diffraction Standards (JCPDS) database diffractograms. The impact of pigments with high X-ray absorption coefficients on the detection limits of pigments with low X-ray absorption coefficients was further investigated by building on work done with the chromium oxide-zinc oxide series with the preparation of a second series of binary mixtures of zinc oxide (which has a high absorption coefficient and is almost fully crystalline) and ultramarine blue, which has a lower absorption coefficient but which is more crystalline. Semi-quantitative analysis, where baseline and absorption factor corrections are made, confirm detection limits as low as five per cent for chromium oxide and ultramarine blue when in a binary matrix with zinc oxide. However, this type of analysis is very time consuming. So in order to theoretically simulate issues that will be encountered with binary pigment mixtures, the single phase diffractograms were used to theoretically investigate the matrix effects of the three white pigments with the various coloured pigments. This illustrated that detection limits can be as low as five per cent or in non-ideal conditions, such as with partial peak clashes or where there are large differences in relative peak intensity, as high as 50 per cent. These results have significant implications for the analysis of painted surfaces on artworks or artefacts. It has been demonstrated that ideally this method is more suited to the investigation of surfaces where there is minimal mixing of pigments or where there is not a significant difference between the absorption coefficients of the mixed pigments.

Jan 1, 2008

By M. Rîsteiu

The authors aim to analyze the behavior of smart sensors using Transmission Control Protocol/Internet Protocol (TCP/IP) infrastructure in hazardous applications, because of their advantages regarding safety, expansion and Quality of Service (QoS). Initially, some constraints are discussed for these applications. Then, the possibility is analyzed of using 2.4 GHz TCP/IP based transmission for sending data out of an industrial area. In this setup the authors evaluated the round-trip implementation (which requires a database of packet lengths), related to the delay introduced by the radio transmission algorithms from 802.15.4, and 802.11d/g protocols. Tuning results of different varying time-delays were compared to the constant delay cases from the literature (Deák, 2003; Lincoln, 2003). Both the hardware and software setups are implemented. Based on TinyOS specific software for hardware checking/ initiating communication/ starting/ closing measurements the authors have developed separate/combined procedures for testing the integrated devices. Measured time delay is presented and analyzed, for both beaconed and non-beaconed 802.15.4 transmission, with power optimization criteria. By testing two different implementations (Zhang et al., 2001), (ATmega256 RZAV - 256KB flash memory, the CC2420 IEEE 802.15.4 and ZigBee-compliant RF transceiver core - 128KB flash memory) the authors have found some time delay variations as a result of local processing by the ZigBee controller with an amount of flash memory. The work is also focused on adapting industrial measuring standard systems to the smart sensors, but not only through the 4-20 mA standard.

Jan 1, 2008

By Norbert Hort, Karl Ulrich Kainer, Carsten Blawert, Daniel Fechner

"With the development of new heat resistant magnesium alloys, the automotive industry has introduced several parts to the drive train. The rising number of large magnesium components will result in a higher quantity of automotive post consumer scrap and the changing legislation will force car manufacturers to take magnesium recycling into consideration. So far post consumer scrap has not been used for magnesium alloy production. Quite a reasonable amount of automotive scrap is likely to end up in a mixed light metal shredder fraction. The separation of mixed magnesium scrap according to several alloys is complex. Therefore secondary magnesium alloys made from blended post consumer scrap would be useful. For this work a matrix of potential recycling alloys was prepared by chill casting and high pressure die casting. The materials were investigated for their microstructure, mechanical properties, heat resistance and corrosion properties. The results will be presented in this paper.IntroductionWithin the last ten to fifteen years several heavy magnesium parts have been assembled in passenger cars, such as gear box housings and crank cases [1, 2]. Reasons are the lately developed new heat resistant alloys and the increasing responsibility of automotive manufacturers to reduce the vehicles weight and thereby CO2 emissions. The latter is pushed by international legislation [3, 4]. The rising quantity of magnesium in automobiles will result in an increasing amount of so called post consumer scrap at the end of the vehicles life.So far magnesium recycling was done only for clean scrap that is free from impurities, contaminations and sorted according to a chemical composition or a single alloy respectively [5- 15]. The latter is also called class 1 scrap and mainly consists of sprues and runners from magnesium die casters [15, 16]. For the upcoming automotive post consumer scrap the materials quality strongly depends on the way end of life vehicles are treated. By proper dismantling of old cars, the bigger magnesium components could be collected and possibly treated similar to class 1 scrap [15]. Up to date automotive manufacturers have no uniform recycling system for end of live vehicles. Most probably a considerable quantity of old cars will be shredded. The resulting light metal shredder fraction will contain aluminium and magnesium scrap, both from several alloys. A separation of mixed magnesium and aluminium scrap is feasible according to [17]. Other authors claimed that the grade of separation of magnesium from aluminium is still not sufficient for a proper industrial recycling process of magnesium post consumer scrap [15, 16]. If an automatic sorting is possible it will probably be very expensive [18]. Therefore, so far the main use of post consumer scrap has been the steel desulphurisation and aluminium production [15]. The use of post consumer scrap for magnesium alloy production has been considered already by [15] and [16] but some problems have to be approached."

Jan 1, 2008

By N. D. L. Burger

An effective prototype face support system to minimize rockfalls in rockfall-prone mines was developed and patented during a project sponsored by the Mine Health and Safety Council (MHSC). An experimental development model (XDM) roof support unit was developed and evaluated. Mines with rockfall problems in the face areas can use the roof support system to reduce fatalities and injuries in the face area of stopes. The roof support system consists of two similar support units connected to each other via two crank mechanisms. Each unit consists of a headboard supported by a ?wishbone? structure (top and bottom leg). In the first design a threaded bar with struts similar to a scissors jack keeps the legs apart. (In the final version that was field trialed, the threaded bar mechanism was replaced with a hydraulic cylinder). All the components are manufactured from steel. To move the system forward the first support unit is collapsed, the second remaining in the loaded position. The first unit then hangs from the second unit to which it is connected. The first collapsed unit is then manually cranked forward and prestressed. If the required position is still not achieved, the other unit is released and moved forward. The specification for the system was determined and presented at a workshop with industry participants. Different concepts were developed and evaluated against the system specifications. A technology demonstrator was then developed and tested on surface. The technology demonstrator development process included detail design, building and testing of components and subsystems, design reviews and the building and commissioning of the technology demonstrator. The testing of the technology demonstrator was done in a 500-ton hydraulic press, in a mock-up stope and underground. A risk analysis, in which technical, logistical and economic aspects were assessed, was done to determine the critical areas of the system. During the next phase of the project working prototypes were developed for underground tests and evaluation. This process indicated that it was necessary to adjust the system specifications and a redesign was called for. In an iterative process test units were built for purposes of evaluation, specification verification and field trialing. After the successful conclusion of the trials the equipping of a complete production stope started for purposes of integrating the system into the current mining process.

Jan 1, 2008

By Lee Fergusson

"The primary features of ViroMine™ Technology are introduced and applications of ViroMine™ Technology to mine site remediation and the treatment of a variety of intractable waste-streams, including a technical discussion of acid neutralizing capacity, metals binding capacity and longterm stability of results. Outcomes from four applications at high-profile international mine sites are presented: 1) the superfund site at the Gilt Edge Mine, South Dakota, USA (four years of data on the treatment of acidity, TDS and metals such as Al, Co, Fe, Mn and Zn); 2) one of Australia’s most polluted sites at King River Delta in Tasmania (treatment of TAA and TPA, and metal and metalloid contaminants such as As, Cr and Hg); 3) The Aljustrel “Aqua Forte” mine site in Portugal (high acidity, metal and metalloid contaminants such as Al, As, Cu and Zn) and 4) the Ulsan Iron Ore Mine at Ulsan, South Korea (treatment of metal and metalloid contaminants such as As, Cd and Ni).IntroductionThe commercialisation of ViroMine™ Technology has resolved some of the most intractable pollution issues associated with historic mining ventures on a global scale and has facilitated the neutralisation of Acid Rock Drainage (ARD), remediation of acidic and metal contaminated impoundments (including tailings dams) and promoted revegetation on tailings deposits and waste rock dumps. ViroMine™ Technology also enables current mining ventures to manage effluent simply and efficiently to meet increasingly stringent environmental standards and is enabling the mining sector to reconceptualise the management of mine spoil. The abilities of ViroMine™ reagents to neutralise the actual and potential acidity of sulphidic mine spoil coupled with the ability to bind metal and metalloid contaminants into non-bio-available forms are the key features delivering environmental and economic benefits to the mining sector and the broader community. Results from four projects utilising ViroMine™ Technology are presented to highlight the suitability of ViroMine™ Technology to treat all forms sulphidic mining wastes. 37"

Jan 1, 2008

By Christian Maguire

The presence of hydrogen sulphide in sewerage systems leads to severe concrete corrosion. Acid causes breakdown of the concrete matrix, and attacks reinforcement. Older sewer systems under acid attack are often found to be acutely corroded, sometimes after short operational periods. Consequently secondary liners are now almost always used. Polymer concrete is extremely acid resistant and if used in segmental linings can forgo the need for a secondary lining. Combined with fibers and/or GFRP rebar Polymer Concrete can produce a very strong acid resistant lining, saving considerable time in the installation of additional liners. This paper explains the problems and advantages of using Polymer concrete in segmentaly lined wastewater tunnels, addressing areas of design, cost, and programming.

Jan 1, 2008

By Vincent Scovazzo

This paper compares the two most common pillar design equations used worldwide by John T. Boyd Company; the Mark-Bieniawski Equation, an empirical approach, and the Wilson Equation, an analytical approach. The equations are compared in two ways; by their stress profiles and by the Mark-Bieniawski Equation stability factor. Contrasting the two equations based on the visual comparison of their stress profiles is straight forward but evaluating their resulting pillar designs is problematic. Complications arise due to the differences between the use and development of stability factors for empirical equations and safety factors for analytical equations. To work around these differences, comparisons are made between the two equations by first calculating pillar sizes using the Wilson Equation and then determining the Mark-Bieniawski Equation stability factor for these pillars. Pillars designed using the Wilson Equation were based on site-specific data from 23 mines located in the Americas and Australia. Comparing sizes of pillars designed by the Wilson Equation to the Mark-Bieniawski Equation; the Wilson Equation pillar sizes were smaller in 77% of the cases, similar in 3%, and larger in 20% of the cases.

Jan 1, 2008

By E Y. Baafi

Artisanal and small-scale gold mining (ASSM) offers lucrative employment opportunities to the locals of most developing countries. The major drawback of ASSM is its adverse impacts on the environment resulting from improper mining and processing techniques. Papua New Guinea (PNG) has very active ASSM activities. The artisanal and small-scale gold mining in PNG provide employment at local and national levels and the sector is an important source for inflow of foreign exchange into rural communities. However, small-scale mining activities are associated with sensitive health and environmental issues. The process of recovering gold by retorting and heating the amalgam over an open fire is a dangerous health practice. This paper discusses artisanal and small-scale gold mining operations in PNG and their impacts on the local environment.

Jan 1, 2008

By D G. Miljak, J Khachan, B K. Schwitter

The performance of prototype magnetic resonance sensors suited to mineral measurement in conveyor, slurry or portable applications is described. The sensors can be positioned around conveyors and modified slurry pipes, providing deep penetration of the sensing field, relative insensitivity to ore surface conditions and high mineral discrimination. Measurements on slurry, concentrates and ores sourced from mine operations are presented for two applications. Firstly, the quantitative measurement of chalcopyrite in slurry was demonstrated in laboratory measurements. In a calibration test, a standard error of 0.1 wt per cent and detection limit of 0.3 wt per cent was obtained. Secondly, results were obtained for the discrimination of iron ore texture. Signals were readily observed using measurement integration times of seconds to several minutes, depending on ore material. The results demonstrate the feasibility of online quantitative analysis of selected minerals in processing applications using magnetic resonance.

Jan 1, 2008

By L. Becze, B. Pierre, S. Di Carlo, G. P. Demopoulos

From January to June 2007, the autoclave production at the Kidd Metallurgical Site was severely affected as a result of plugged discharge lines and extensive precipitation/crystallization of sulphates that caused massive scaling in different autoclave compartments. Work was performed at McGill University to understand the root causes. The crystallization of zinc and ferrous sulphate salts was investigated in terms of solubility measurements. Scale samples were characterized using chemical and mineralogical-spectroscopic analysis. In this paper, following a description of the Kidd zinc pressure leach operation, highlights from this investigation are presented and solutions used to overcome the problem are outlined.

Jan 1, 2008

By D Bradshaw, J R. R de Villiers

The non-stoichiometric sulfide mineral pyrrhotite (Fe(1-x)S), common to many nickel and platinum group element (PGE) ore deposits, occurs in varying crystallographic forms with the different types exhibiting subtly different physical and chemical properties. These differing properties are likely to influence the flotation performance of pyrrhotite, which in the case of PGE operations is actively recovered, whereas in nickel operations pyrrhotite is depressed. In this study, examination of natural pyrrhotite samples from Southern African and Canadian nickel and PGE ore deposits revealed a variety of pyrrhotite compositions in terms of iron content (Fe7S8, Fe9S10, Fe11S12) and solid solution nickel concentration. Pyrrhotite composition was correlated with its mineral association depending on whether non-magnetic pyrrhotite occurred in conjunction with troilite, non-magnetic pyrrhotite occurred as single phase pyrrhotite, magnetic pyrrhotite occurred as single phase pyrrhotite or whether the two phases; magnetic and non-magnetic pyrrhotite co-exist. Subsequent microflotation tests of selected single phase pyrrhotite samples revealed that the non-magnetic pyrrhotite is slightly more floatable than magnetic pyrrhotite. Microflotation tests also showed that varying flotation responses occur between differing magnetic pyrrhotite samples. These differences in flotation performance are postulated to be a result of the effects of varying pyrrhotite crystallography, trace metal content and mineral association on pyrrhotite oxidation, formation of surface species and subsequent adsorption with xanthate collector.

Jan 1, 2008