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By Shemek Oginski

The 5 km (16,194 lf) of 6.1m (20 ft) diameter TBM driven tunnel built by the J.F.Shea Co. will serve as sewage overflow storage. The TBM tunnel and four connecting tunnels excavated by drill and blast methods in hard granite will remain unlined. Based on the Geotechnical Baseline Report (GBR), the Contract documents provided a design with no required pattern of rock bolts, no probing, no pre-excavation or consolidation grouting, and lastly, no final lining of the tunnels was deemed necessary. This paper will provide a general overview of these topics with the emphasis on the actual ground conditions encountered versus the projected conditions provided in the GBR and how the GBR reflected the design of the project. Proposed modifications to the temporary and permanent ground support will be presented and the necessity of probing and pre-excavation grouting will be evaluated.

Jan 1, 2005

By F. N. Smith

Corrosion was observed on the aluminum pressure plates and dress-caps that hold the glazing in place on a curtain-walled building, The multi-storey building in question is situated in the downtown area of a busy Canadian city, For aesthetic reasons, the original design required the dress-caps (which have L-shaped cross-sections) to be externally clad with thin copper sheet. Since the aluminum was in direct contact with the copper trim, galvanic corrosion developed that resulted in damage to the aluminum components, Soluble corrosion products washing off the copper trim may also have contributed to the accelerated corrosion of the aluminum, The aluminum pressure plates and dress-caps are being systematically replaced with components made of fibre-reinforced plastic. The outsides of these new components will be clad with thin copper sheet in order to preserve the original appearance of the building.

Jan 1, 2005

By K. J. Stanaway

Major world ilmenite and rutile accumulations reveal similar regional geology and Proterozoic age deeper crustal source rocks. During crustal collision titanium crystallizes as ilmenite and rutile at buried sites of high pressure and temperature rock metamorphism. Hydrothermal activity can convert titanium minerals to rutile, but titanium migration and enrichment seem only local. Many melts crystallize rocks with iron-titanium oxides in solid solution, but titanium enrichment at economic scale takes place in basic intrusive melts often associated with anorthosites and charnokite. Sedimentary placer enrichments have formed since the Proterozoic with water-resistant ilmenite, and rutile segregating by gravity from quartz sands deposited from flowing water. Placers have residual, alluvial, strand and shallow marine variants. Time, organic acids, and sand permeability play lead roles in the leaching of iron from ilmenite during weathering and diagenesis.

Jan 1, 2005

For various reasons, the maintenance of shaft structures is becoming an increasingly important factor in the operation of underground mines. Deterioration mechanisms related to operation of the shaft are identified as corrosion, mechanical damage, fatigue damage and wear. Deterioration mechanisms related to rock movements are identified as vertical strain, ride vertical closure and squeezing. Analytical procedures for assessing this deterioration are discussed, and it is shown how acceptance criteria are developed and implemented. In order to track the deterioration of shaft structures, shaft inspections are undertaken, but the information is often not well documented. Formalised procedures for capturing and recording information, and then processing the information are presented. Finally, two case studies are briefly described to illustrate how these procedures have been implemented in practice, and what benefit has accrued to the mines concerned.

Jan 1, 2005

By J Masliyah, Z Xu

The largest oil sand deposit in the world is located in Alberta, Canada, with a total proven reserve of 2.5 trillion barrels of oil. The water based extraction process is currently being used in commercial operations to recover bitumen by flotation from oil sand ores. A recognised challenge in bitumen extraction is the reduced bitumen recovery when processing ores containing high fines content or æweatheredÆ oil sand ores, collectively known as poor processing ores. Inspired by demonstrated success of using kerosene as collectors in coal flotation, an innovative idea of using oily bubbles (air bubbles coated with a thin layer of oil or solvent) was tested to improve bitumen flotation recovery from poor processing ores. In this study, dynamic contact angle of air bubbles or oily bubbles on bitumen and induction time of bitumen-oily bubble attachment in water were measured to justify the use of oily bubbles in bitumen recovery from poor processing ores. The type of oil or solvents, including kerosene, toluene and naphtha, used in generating oily bubbles showed a marginal effect on the contact angle values, similar to the values measured with air bubbles. However, the spreading of an air bubble was found to be much slower than that of oily bubbles on a bitumen surface. The induction time for oily bubble-bitumen attachment was found to be much shorter than that for corresponding air bubble-bitumen attachment in the process water from poor processing ores. The reduced induction time for kerosene-coated air bubble-bitumen attachment correlates well with the improved bitumen recovery from poor processing ores using kerosene-coated oily bubble flotation technology.

Jan 1, 2005

By D C. Curry, M F. Young

Many flotation operations need to improve liberation to increase recovery, yet often plant operators are concerned that finer grinding will produce æslimesÆ with low flotation recovery. Yet simple circuits can be designed to give good liberation and excellent fines recovery. The economics of fine grinding has changed fundamentally with new stirred milling processes like the IsaMill. This has also transformed flotation design due to the clean surfaces produced in the inert grinding environment and the narrow size distribution produced by the IsaMill. Past poor experiences with æovergrindingÆ in flotation circuits was often due to the wide size distribution and the degradation of mineral surfaces produced by conventional devices using steel media, like ball mills and tower mills. The correct practice is to design both grinding and flotation together to suit the liberation characteristics of the ore. This may result in several stages of grinding and flotation, recovering mineral as soon as it is liberated, then applying further grinding energy only to those particles that still need liberation. Flotation then occurs in relatively narrow size bands and with minerals with similar liberation characteristics. Though the circuit may look more complex on paper, in reality it is far simpler to operate since each section performs predicably. Circuit design also needs to address materials handling. Finer particles affect froth handling and dewatering, but can still be easily handled by standard products with careful attention to design of launders, pumps and pumpboxes, and de-aeration before thickening and filtering. Excellent examples of designing circuits to include ultrafine grinding include Mt Isa and McArthur River (MRM). In the last decade these operations have produced over ten million tonnes of concentrate with an average grain size below 10 ¦m and above 80 per cent recovery. At Mt Isa, zinc recovery was increased by ten per cent by applying fine grinding to existing poorly liberated streams. In fact, grinding finer in the IsaMill actually improved the recovery of fine particles by ten per cent, and maximum particle flotation recovery occurs for 10 ¦m particles. A more recent example is the flotation of Platinum Group Metals (PGMs). The use of conventional ball or tower milling to improve liberation is severely limited by the impact of commonly associated chromite on classification, and degradation of flotation performance by the steel grinding environment. The ability of open circuit IsaMills to deliver a narrowly sized ultrafine product with clean mineral surfaces is transforming the design of platinum flotation circuits. The science and practice of fine-grained flotation is now thoroughly proven. The availability of the 2.6 MW IsaMill has made ultra fine grinding a practical tool for flotation plant design. It is expected to become a standard choice for future applications of both fine-grained ores and for minerals with difficult flotation characteristics.

Jan 1, 2005

By A Kamkar-Rouhani

The paper describes a mineral potential mapping of gold and other base metals in Mahneshan area, Iran, using geographical information system (GIS), in which, the method of weights of evidence is used to combine spatial data obtained from different sources to make prediction for mineral potential. This is a quantitative tool for mineral resource mapping that can be used to delineate and predict favorable areas for further exploration by using the characteristics of known and similar mineral deposits. In accord with the descriptive model for gold and other base metal deposits, the spatial distribution of 20 known mineral occurrences was used. In addition, digital evidential maps were used in this study. The maps include maps of lithological units, faults and first derivative of total aeromagnetic data, remotely-sensing data of alteration and also geochemical evidential maps produced on the basis of the results of chemical analyses of samples taken from the stream sediments in the area, and analysed for Cu, Pb, Zn, Sb, As, Ag, Au, Ba and Hg elements. The binary maps were produced and then combined with the model of weights of evidence using 20 known mineral occurrences to obtain a final map of the favourable areas for further exploration of gold and other base metals in the study area. The final map is a predictive GIS model of the mineral deposits in the area. An interesting matter about the final predictive GIS model is that the faults are mainly located in favorable areas which possesses the most probability of mineralisation. Therefore, the faults in these areas have priority for further exploration of gold and others base metals.

Jan 1, 2005

By Pengfu Tan

A thermodynamic model has been developed to predict the distribution behaviors of Cu, Fe, S, O, Pb, Zn, As, and heat balance in a lead blast furnace. The modeling results have been validated by the plant data of a lead smelter in Asia. The model can be used to predict for any set of controllable process parameters such as feed composition, smelting temperature, degree of oxygen enrichment and volume of oxygen-enriched air. The effects of the blast air, industrial oxygen, and coke charge on the distributions of Cu, Fe, S, O, Pb, Zn, As, and heat balance, and on the lead loss in slag have been presented and discussed.

Jan 1, 2005

By S A. Ravishankar

An overview of flotation reagents used in sulfide and non-sulfide separations, from an industrial perspective, is given in this presentation to highlight the current applications knowledge. The historical and theoretical aspects, which are well documented in numerous books and reviews, will only be highlighted, when necessary, to support the theme of this paper, viz critical analysis of reagent research, design, selection and optimisation with an emphasis on relevance to plant needs and practice. The three types of flotation reagents; viz collectors, frothers and modifiers, used currently in the industry are briefly reviewed; pitfalls and gaps, arising from somewhat arbitrary and reductionistic practice in reagent applications, are identified; and the impact of environmental regulations on current and future reagent development is discussed. The importance of frothers and modifiers, which have received less overall attention than collectors, is highlighted. The need for a rational, holistic (or ætotal systemÆ, ætop-downÆ) approach for reagent design, selection and optimisation is discussed with a view to provide remedies for pitfalls and a platform for filling gaps in reagent chemistry and applications, and to develop reagent technology that can deliver robust solutions to plant needs. Flotation Matrix 100TM, a comprehensive package designed at Cytec to incorporate all the elements of the holistic approach û viz definition of mineralogy and plant needs, rule-based expert system rational reagent selection, and laboratory and plant best practices û will also be described.No paper available for this abstract

Jan 1, 2005

By Michael S. Kucker, Stuart Warren, Robert A. Robinson, Michael J. Lehnen, David McAllister

Geotechnical conditions exposed by the phased exploration programs have had a major impact on the selection of excavation and support methods, dewatering requirements, size of openings, vertical alignment, and estimated cost of construction for the Beacon Hill Tunnel and Station section of the “Link” Light Rail. Beacon Hill is comprised of a very complex glacial geology, including numerous slickensided fractures, injected sand dikes, and multiple perched groundwater levels as revealed by a phased boring program and exposed in a test shaft. The Geotechnical Baseline Report (GBR) presents this complex geology along with a “tool box” of alternative additional support systems to accommodate the varying ground conditions during construction of the station excavation. Additional explorations will also be accomplished during construction to further refine the geotechnical interpretations and provide an opportunity to use pro-active ground improvement techniques to optimize the station excavation and support requirements.

Jan 1, 2005

By K. N. Santini, J. M. Barker

The perlite industry in the United States continued to undergo rapid change and increased competition last year as it did in 2002. U.S. production in 2004 was 510 kt (562,000 st),an increase following five consecutive years of decline (Table 1). Perlite is exported to Canada and to the Pacific Rim. These partially offset imports. Perlite imports from Greece to the eastern and Gulf Coasts of the United States declined by about 22 percent after reaching a record 240 kt (264,000 st) in 2003.But their market remains protected by high rail rates from western U.S. plants. Minor imports of perlite persist by Termolita from Mexico.

Jan 1, 2005

By T J. Sheer

The removal of airborne pollutants from underground ventilating air is discussed. The work concentrates on the removal of CO, CO2, NOx, SO2, radon gas and respirable carbon particles. The investigation combines techniques for multiple contaminant removal using forced chemical absorption and oxidation. Both dry and wet scrubbing techniques are employed. Mixed success has been achieved in the tests carried out and this paper is seen as a progress report on the work done to date. The interference and interaction of the gases on the individual removal efficiencies is a very important factor in the finalisation of a macro air conditioner (MAC) design for treating underground ventilating air. This necessitates a specific sequence of contaminant removal. Efficiencies are discussed and recommendations made. Wet forced chemical absorption and oxidation processes, though efficient in terms of removal efficiencies, cannot be employed in the confined underground environment due to safety and health risks. Impacts on the internal water reticulation systems of the mine have been analysed to determine the effect of future large-scale macro air conditioning practices, including blow-off liquids discharged into the water circuits. To engineer the safety and health risks out of such designs can be costly and it is for these reasons the research now concentrates on dry scrubbing of the contaminants from the underground ventilating air. The paper concludes with statements on the benefits of macro air conditioning in deep hot mines, in both recirculating and series air ventilation distribution strategies. These benefits include reduced re-entry times after blasting and increased production rate opportunities.

Jan 1, 2005

By Jim Nickerson, James McCleish, Tom Abkemeier, Nicholas Willig

The purpose of this project is to convey sanitary sewage from an existing pump station to a new waste water treatment plant. This paper will discuss the design and construction aspects of the project. The scope includes construction of three main shafts ranging from 34 to 100 feet in diameter at depths of 200 to 230 feet and 21,000feet of tunnel. Shaft construction consisted of slurry wall excavations keyed into claystone and limestone at depths ranging from 114 to 130 feet, followed by rock excavation utilizing drill and blast methods. The tunnel is being excavated in the Warsaw and Salem shale and limestone formations utilizing a 12'-6" diameter Wirth hard rock TBM.

Jan 1, 2005

By Terra Dinamica, Frank Lucca

This paper discusses blast design for vibration control in tight construction blasting. Topics include blast pattern geometry, blast design formulas, loading, explosives & initiation selection, and utilizing borehole deviation equipment and lasers, and rules of thumb. The paper will also explore vibration prediction, neighbor relations, and related topics, such as blast plan submittal. Various projects from metropolitan construction blasting operations will be used as examples. Examples include blasting in the inner city, next to pipelines, and in housing developments.

Jan 1, 2005

By S G. Hagemann, M E. Barley

The Mt Tom Price deposit is a world-class high-grade hematite deposit in the Hamersley Province of Western Australia with an original resource of 900 Mt of almost pure hematite, averaging 63.9 wt per cent Fe. Petrological and geochemical studies at both the Southern Ridge and the North deposit at Mt Tom Price have identified three hypogene alteration zones between unmineralised BIF and high-grade iron ore: distal magnetite-siderite-stilpnomelane; intermediate hematite-magnetite-ankerite-talc-chlorite; and proximal martite-microplaty hematite-magnetite-apatite alteration zones.Fluid inclusions trapped in siderite within the distal magnetite-siderite- stilpnomelane alteration zone at the North deposit revealed primary high salinity (25.5 eq wt per cent NaCl-CaCl2) inclusions that homogenised between 107¦ and 142¦C into liquid. Fluid inclusions trapped in ankerite within ankerite-microplaty hematite veins in the intermediate hematite-ankerite-magnetite-talc-chlorite alteration zone at the North deposit revealed mostly H2O-CaCl2 pseudosecondary and secondary inclusions with salinities of 22.4 - 25.4 eq wt per cent and 22.9 - 25.9 eq wt per cent CaCl2, respectively. Pseudosecondary inclusions homogenised between 153¦ and 449¦C and secondary inclusions homogenised between 103¦ and 157¦C. Fluid inclusions trapped in apatite within talc-microplaty hematite veins in the intermediate hematite-magnetite-talc-chlorite-apatite alteration zone at Southern Ridge revealed that primary, medium salinity (7.0 - 9.0 eq wt per cent NaCl) inclusions homogenised between 181¦ and 257¦C and primary high salinity (22.8 - 25.9 eq wt per cent CaCl2) fluid inclusions homogenised between 118¦ and 257¦C into liquid. Microthermometric analysis of quartz from quartz-hematite veins from the Southern Batter Fault, Southern Ridge show a complex fluid inclusion history. Primary fluid inclusions consist of: low- and high-salinity H2O-NaCI inclusions trapped at temperatures of approximately 140¦ to 230¦C; vapour-rich inclusions of unknown compositions; and æcomplexÆ salt-rich (Ca, Mg, K and Na inclusions).Secondary inclusions consist of medium-salinity fluid inclusions trapped at temperatures of about 140¦ to 280¦C.A two-stage hydrothermal model is proposed for the formation of both the Southern Ridge and North deposits. Early 1a hypogene alteration involved the release of hydrothermal NaCl-CaCl2-rich (25.5 eq wt per cent) basinal brines (110¦ - 150¦C) from the underlying Wittenoom Formation and directed upward along normal faults and focused within the silica-rich rocks of the Dales Gorge Member, by the shales of the underlying Mt McRae Shale Member and overlying Whaleback Formation. Within the Dales Gorge Member hydrothermal basinal brines migrated laterally within large-scale folds with permeability controlled by shale bands and the NW trending dolerite dyke sets. Fluid rock reactions transformed unmineralised BIF to magnetite-siderite-iron silicate BIF, with subsequent desilification of the chert bands. Stage 1b hypogene involved an increase in temperature of the hydrothermal, CaCl2-rich saline (24 eq wt per cent) basinal brines (250¦ - 300¦C) resulting in formation of hematite-ankerite-magnetite-talc-chlorite alteration and the crystallisation of microplaty hematite. Late stage 1c hypogene alteration involved the interaction of low-temperature (~120¦C) basinal brines with the hematite-ankerite-magnetite mineral assemblage. At the Southern Ridge deposit this process was very intense (ie high fluid flux), therefore resulting in the almost total removal of ankerite and resulting in the increased porosity of the ore. Stage 2 supergene enrichment in the Tertiary resulted in the removal of residual ankerite and apatite and the weathering of the shale bands to clay.

Jan 1, 2005

By C Yates, S Jobling, Z Y. Yang

The current trend in the UK towards the adoption of retreat longwall mining methods and the associated rapid development of the access drivages have exacerbated the environmental conditions experienced within these workings. There is a recognised need to improve the efficiency of the design and operation of mine ventilation systems in order to maintain an adequate environment and climate within these workings. Any improvement achieved in the quality, quantity and control of the delivered ventilation will assist in the provision of improved gas and dust dilution and climatic control. The paper presents an analysis of the psychrometric data recorded during the execution of a series of comprehensive climatic surveys conducted within two representative deep underground UK coal workings. The surveys were performed across two high production retreat longwall districts within UK Coal Ltd collieries. The surveys employed intrinsically safe psychrometric transducers and digital data-loggers to collect a continuous record of the mine climate over designated weekday production and weekend non-production periods. The transducers and data-logging units are capable of simultaneously measuring and digitally recording changes in the dry bulb temperature and the relative humidity at regular time intervals for extended periods of time.

Jan 1, 2005

By G. van den Berg

Anglo Platinum has initiated a project to investigate hydraulic hoisting technology for platinum mines. Hydraulic hoisting systems are categorized as pumping, fluidizing feeder or displacement feeder systems. Positive displacement piston diaphragm pumps are most suitable for pumping systems but they require that the ore be milled prior to pumping. Fluidizing feeders are unsuitable for platinum ore applications due to the large percentage of fines in the ore. The three-chamber pipe displacement feeder has been most widely used for hydraulic hoisting and is the most suitable technology for platinum mines. Eight hydraulic hoisting applications covering pumping and displacement feeder technologies are reviewed. The key factors to be assessed in selecting a hydraulic hoisting system for a platinum mine are discussed. A typical platinum mine configuration will comprise an ore preparation plant (to produce -15mm material through screening or crushing), motive water pump on surface, high pressure water pipeline from surface to underground, ore slurrification plant, three-chamber displacement feeder, and a high pressure slurry pipeline to surface. The water and slurry pipelines are housed in a purpose drilled borehole. A hydraulic hoisting system selection chart is presented. A 150mm diameter system with a 25 MPa pressure rating is required to hoist 60 000 t/m from a depth of 1 200 m. Generic capital and operating costs are presented. A major potential advantage of hydraulic hoisting is that the fines, which contain a high percentage of PGMs, are captured underground and transported directly to the concentrator. Hydraulic hoisting technology is ideally suited to providing supplementary hoisting capacity to existing shafts that have reached the skip hoisting capacity limit. The main advantage for new shafts is the potential to significantly simplify underground rock handling and transportation. All hydraulic hoisting system components are proven. The only risk area is the wear rates of the valves and piping. Current estimates are based on gold ore. The business cases investigated show that the financial viability of the installations are not sensitive to wear rate. Hydraulic hoisting is technically feasible and financially attractive for platinum mines. Keywords: hydraulic hoisting, slurry

Jan 1, 2005

By C. A. Young, H-H. Huang, L. G. Twidwell

Equilibrium calculational software programs can be effectively utilized to model important parameters in aqueous and aqueous/solid systems, e.g., activity or concentration, solubility, temperature, solution pH, solution potential, and ligand complexation. In this regard, the calculational program ST ABCAL will be demonstrated. Illustrative examples for the creation of diagrams such as potential-pH, and activity or concentration-pH will be presented to demonstrate the fundamentals in real hydrometallurgical systems. Speciation, titration and mixing will be used to simulate or predict operational processes. Berkeley Pit water from a flooded abandoned copper open-pit mine will be used to illustrate the modeling process. According to analytical results the water contains about 20 important constituents. In addition to measured potential and dissolved oxygen, there are two distinctive oxidation/reduction couples. Concentration and other experimental parameters are seldom matched to each other and 12 different conditions have been identified. Water for each condition must be speciated in order to find the best-fit model. The STABCAL program will be used for the modeling calculations and the implication of the water chemistry to defining treatment opportunities will be discussed.

Jan 1, 2005

SOFCs with thin electrolyte of two types: SDC (15um) single-layer and YSZ (5um) + SDC (15um) bi-layer were fabricated by screen printing and co-firing on Ni¬YSZ cermet substrates. Using in-situ sintered Sm0.5Sr0.5CoO3 cathode the SDC-cell shows high performance at low temperature, 1180mW/cm2 peak power density around 650°C, while the YSZ+SDC bi-layer cell generates about 340mW/cm2 at 650°C, and good performance at 700-800°C with almost theoretical OCV value. Many Zr-content micro-islands were found on the SDC electrolyte surface. The influence of co-firing temperature and thin film preparation methods on the Zr-islands' appearance was investigated.

Jan 1, 2005

By J. C. Escobedo, J. M. Almanza, A. Flores, Cortés. D. A.

Secondary aluminum dross, which has been exposed for several years to atmospheric conditions, was characterized using chemical analysis, X-ray diffraction, optical and scanning electronic microscopy, and energy-dispersive spectroscopy. Based on the characterization, a method to purify the solids is presented. This method starts with the washing of the dross in boiling water to eliminate the soluble compounds like Na and K, followed by the physical separation of the metallic aluminum by milling and screening. Finally, an acid lixiviation process is applied using three different acid solutions, HCl, HNO3, and H2SO4. The best results were obtained using HCl. The main insoluble components of the dross after lixiviation were Al, SiO2, and Al2O3. MgAl2O4, AlN, Si, and Na2Al22O3·2H20 species were also found. Based on the alumina content, the solid product could be suitable as a raw material in the manufacture of castable refractories or metal matrix composites.

Jan 1, 2005