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By Sam Kangwa, Thomson Sinkala

In the mining industry, drilling accuracy has a significant effect on the economy of operations. In this paper, results from the Nkana Division of the former Zambia Consolidated Copper Mines are presented. For the stope investigated, it was found that the extra operational costs alone were 462% of the planned costs! Clearly, there is more than good reason to pay attention to drilling of good quality holes.

Jan 1, 2004

By V. I. Zhuchkov, L. A. Smirnov, E. I. Arzamastsev, A. A. Babenko

A brief analysis is given for state-of-the-art of manganese and chromium ferroalloy production in Russia and their consumption by metallurgy plants. The main causes of low output of manganese and chromium ferroalloys, and ways to resolve the issue of ferroalloy production development are considered.

Jan 1, 2004

By S. E. Olsen, K. Tang

The complex heterogeneous equilibria associated with the production of manganese ferroalloys have been simulated by employing recently developed thermochemical databases. The non-ideal Mn-Fe-Si-C alloy and the MnO-SiO2-Al2O3-CaO-MgO-FeO slag system have been modelled separately by the compound energy and cellular model. A large number of experimental thermodynamic and phase-equilibrium data were used to evaluate the model parameters for the liquid and solid Mn-Fe-Si-C phases. In addition to the liquid metal phase, solid mixture phases occurring in the Mn-Fe-Si-C system have also been studied. Over 500 measured equilibrium data have been utilised to verify and calibrate the model calculations. The paper will present typical simulation results, from activities of components to multicomponent heterogeneous equilibria. Good agreements can be obtained for many important technological parameters such as carbon solubility, phase relations and equilibrium diagrams, element distribution as function of temperature and slag composition etc. Application of the present models to the silicomanganese production will be demonstrated in this paper.

Jan 1, 2004

By N. A. Barcza

This publication records the proceedings of the Tenth International Ferroalloys Congress, INFACON X, and the third INFACON hosted in South Africa. The Proceedings of the previous two South African congresses in 1974 and 1992 serve, as this volume does, as a valuable record of the papers presented at these important events. This publication comes at a time in South Africa?s democratic development where the theme ?Transformation Through Technology? is very appropriate. The ferroalloy industry has played an increasingly significant role in transformation and black economic empowerment in South Africa, particularly through the advancement and sharing of technology. INFACON X plays an important role in this process, and the stakeholders and organisers of this Congress are thankful for the opportunity to hold this event at this time of transformation in our country. The world of ferroalloys, as well as that of the steel and stainless steel industries, has continued to change rapidly. Recent innovations, better use of resources, increased awareness of environmental issues and ongoing efforts to improve occupational health and safety are among the topics addressed at INFACON X and in these Proceedings. The theme of ?Transformation Through Technology? has been chosen to reflect the regional and global developments in the ferroalloy industry, and the crucial role that technology plays. The Proceedings of INFACON X, the first Congress in Southern Africa of the new millenium, represent a milestone in the technical developments in this major global industry. It contains almost eighty papers in twenty Sessions, from authors in twenty countries, covering raw materials, reductants, energy, electrodes, refractories, furnace design, post taphole services, modelling, simulation, control, sensors, fundamental issues and the applications of ferroalloys as related topics. The major ferroalloys, namely ferrochromium and ferromanganese, are covered extensively in many interesting papers. This comes as no surprise, since South Africa is the leading producer of ferrochromium and also plays a major role in the supply of manganese ore and alloys. Papers on ferronickel, silicon and ferrosilicon ensure that all the large-volume ferroalloys are addressed. These Proceedings of refereed papers of high quality will serve the ferroalloy industry for many years to come, as has been the case with previous INFACON events. For the first time in the history of INFACON, the Proceedings will be available both in bound and in a searchable electronic CD-ROM format. We appreciate the time and effort that the authors and referees have devoted to making this publication a really valuable document. Their contributions are recorded for posterity and reflect the advancements they and their colleagues have made to benefit the ferroalloy industry. Without these ongoing improvements, the industry would stagnate and not fulfil its role in the advancement of mankind. All papers included in these Proceedings were peer-reviewed by at least two referees. About 130 referees were sourced internationally to fulfill this function, and their valuable technical and editing inputs are gratefully acknowledged. Finally, I would like to thank the Technical Programme and Publication committees, led by Dr. Lloyd Nelson and Dr. Noël Machingawuta respectively. Without the tireless efforts of these individuals and their Committee members, the technical programme and these Proceedings would not have been the success they certainly are.

Jan 1, 2004

By Fred Baldassare, Marcia Harris, Kenneth K. Eltschlager

Surface mine blasting was recently investigated as a potential source of high concentrations of stray gases found in nearby residences of western Pennsylvania. In one incident carbon monoxide was detected in a home and in the other, high concentrations of carbon dioxide were found in a home. Both carbon monoxide and carbon dioxide are by-products of blasting. However, other potential sources of these gases may also exist in a residential setting. In each case, gas chromatography (GC) and carbon isotopic analyses were used to define atmospheric concentrations inside the homes, and to determine the source of a stray gas. Molecular and isotopic analyses provide geochemical evidence as to the origin and source of the stray gas. This paper discusses elements of a stray gas investigation and the analyses necessary to identify the source of a stray gas.

Jan 1, 2004

By Maria I. De Rosa

Table 1 and figure 1 show the number of fires and fire in¬juries that occurred in underground coal mines by state during 1990-1999. Table 1 also shows by state the risk rates, employ¬ees' working hours, lost workdays, and coal production. Over¬all, 87 fires occurred in 12 states. Twenty-seven of those fires caused 34 injuries (the yearly average was 8.7 fires and 3.4 injuries). One fire and one injury involved a contractor. The underground mine fires required 25 mine rescue team interventions and 30 mine/section evacuations followed by 13 mine/section sealing/flooding/CO2/N2, gas injections. The Ewhr value was 1,003 x 106 hr (In = 0.007), the CP value was 4,008 x 106 st (Frr = 0.022), and the LWD value was 208. Virginia had the most fires (15 fires and 7 injuries). Pennsyl¬vania had the most fire injuries (12 fires and 9 injuries), fol¬lowed by Kentucky (12 fires and 6 injuries), and Alabama (12 fires and 4 injuries). Among these states, Alabama had the highest fire risk rate value (Frr = 0.073), whereas Pennsylvania had the highest injury risk rate value (In = 0.016). Table 2, partly illustrated in figure 2, shows by time period the number of fires, fire injuries, risk rates, employees' working hours, lost workdays, and coal production. The number of fires and fire injuries show a decrease followed by an increase during the five time periods (see table 2 and figure 2). This was ac¬companied by a decline in employees' working hours throughout the periods and an overall small decrease in coal production. The In and Frr values follow patterns similar to those shown by the fire and injury values. By comparison, data from Pomroy and Carigiet [1995] show that during 1978-1992 a total of 11 states were involved in 164 underground coal mine fires (yearly average, 10.8) with 43 injuries (yearly average, 2.9) and 27 fatalities (yearly average, 2; however, the 27 deaths occurred during a single fire caused by an overheated air compressor [MSHA 1984]). The CP value was 5,340 x 106 st (yearly average, 356 x 106 st) (Fn = 0.031). Data on employees' working hours and injury risk rates were not available. Tables 3-8 show the number of fires by ignition source, method of detection and suppression, equipment involved, location, and burning material by time period. Figure 3 shows the major variables during 1990-1999. Table 9 shows the number of fire injuries per number of fires causing injuries and total fires by year, ignition source, equipment involved, and location.

Jan 1, 2004

By R. St. C., G. E. Morris, M. Zbik, Smart

Effective flocculation and dewatering of slurry streams containing clays (particularly kaolin and smectites which are often <200nm in lateral dimension) is becoming increasingly urgent. Release of water (often >75 wt%), for recycle and reduced make-up water consumption, from slurries in tailings streams and dam beds is usually slow and incomplete. Changes in settling rates and solids density of tailings containing clays can be achieved in practice by changes in pH, dissolved cations and flocculant additions. To achieve fast separation of clays from water and minimization of retained water, individual particles need to be bound in the initial stages of thickening into large, high-density aggregates, which may sediment more rapidly with lower intra-aggregate water content. Quantitative STIMAN (STructural IMage ANalysis) cryo-SEM imaging, shows that the structure of aggregates formed before flocculant addition has a determinative effect on these outcomes. Without flocculant addition, 4 stages occur in the mechanism of primary dewatering of kaolinite: initially separate particles and aggregates are dispersed (<0.3GP, where GP is the gel point); a partially-gelled chain network then forms linking particles edge-edge (EE) still well below the OP but remains largely suspended; after an induction time, this network structure rearranges from EE to face-face (FF) contacts densifying, compacting and dewatering the aggregates with settling rates well above Stoke&apos;s Law estimates for >20µm particles or aggregates; the GP is rapidly reached during settling producing a network spanning the vessel with compressive strength. This sponge-like structure with EE oriented particles limits slurry dewatering because the steric effect in the resulting partially-gelled structure is much more dominant than the electrostatic effects predicted by DLVO theory. Van der Waal&apos;s forces at very close distances, as particles slide across each other, may be responsible for the EE to FF change in structure. In this way, the previously extended network contracts, and when the solid volume fraction is low, the continuous network breaks apart forming aggregates and aggregate associations as flocs which arc able to freely settle. These densified aggregates settle at increased rate, give lower bed density and retain less water after drainage. With flocculant addition, the internal structure and networking of the pre-aggregates is largely preserved but they are rapidly and effectively bound together by the bridging action of the flocculant(s). The STIMAN analysis shows that there is a inverse correlation of intra-aggregate porosity (and void permeability) with Darcian permeability (and extent of dewatering) whereas there is a strong positive correlation of Darcian inter-aggregate permeability with settling and primary dewatering rate.

Jan 1, 2004

By M. Pawlik

The rheological properties of mineral suspensions affect the design and operation of transport, mixing, size classification, grinding, gravity concentration, flotation and de-watering systems. In many cases, the rheological properties can be modified to improve processing through the addition of chemical additives. These additives may be either organic or inorganic and generally affect the state of particle aggregation or dispersion. Inorganic modifiers act primarily by affecting the surface charge of mineral particles and thus control the magnitude of electrostatic attraction/repulsion between particles. The action of organic additives (polymers and surfactants) is a combination of electrostatic and steric forces – the latter being related to the molecular weight of these reagents. While low molecular weight polymers are dispersants (viscosity reducers), high molecular weight polymers are likely to induce flocculation and increase yield stress.

Jan 1, 2004

By N. Sutcliffe

Refractories and slags play a vital role in the production of stainless steel. They are in intimate contact with the steel at temperature, and chemical reactions between the three can and do occur. These interactions can be beneficial, in the case of active tundish and ladle slags, and negative in the case of refractory erosion and slag entrapment. This paper presents the results of both plant trials and laboratory investigations of steel/refractory and slag/refractory interactions. The interaction mechanisms observed are described leading to selection criteria for new refractory products. Keywords: slags, steels, refractories, reaction mechanisms.

Jan 1, 2004

By A. Patti, S. Reutzel, D. M. Herlach, L. Ratke, I. Egry

Cu-Co shows a metastable miscibility gap in the region of the undercooled melt. Undercooling of the melt below the binodal leads to separation of the melt into a Co-rich LI-phase and a Curich L2-phase. Experimentally, undercooling into the metastable miscibility gap is realised by means of electromagnetic levitation (EML), processing in drop tube (DT) and by melt flux embedding. As undercooling is large in these experiments, the velocity of the solidification front is high and the microstructure is frozen in instantaneously. Samples have been undercooled and solidified in the TEMPUS-facility (container less electromagnetic processing under weightlessness) during parabolic flight under reduced gravity conditions. Microstructures of solidified samples have been analysed and compared to those processed under gravitational conditions. The influence of convection on phase growth is much lower in reduced gravity. The microstructure shows spherical droplets of the minority phase, statistically dispersed in the majority phase.

Jan 1, 2004

By D Craw

The Macraes gold deposit is located in a low angle NE dipping (~15¦) shear zone, the Hyde Macraes Shear Zone (HMSZ) cutting greenschist facies metasediments of the Otago Schist. The shear zone is host to large volumes of mineralised schist and relatively sparse quartz veins. Early in the development of this through going shear the schist experienced an episode of hydro fracturing and fluid redistribution. As a result, presently exposed schists within the Intrashear sequence are pervaded by localised swarms of quartz filled pure extension and extensional shear fractures hosting goldscheelite mineralization. The swarms comprise networks or æstockworksÆ of veins that strike NE, are subvertical and form subperpendicular to the shear zone fabric. Vein frequency across strike is typically ~1 m-1, with most veins five to ten centimetres thick and vertically continuous for up to ~20 m. Many of the veins show delicately banded internal textures that are parallel to the vein margins. These bands/lamina indicate incremental growth and are defined by a variation in grain size or alternatively by thin slivers of wallrock schist, though typically uncommon. The majority of veins are overprinted by a weak plastic deformation, although primary structures are largely preserved. This deformation has produced subgrain structures, migration of grain boundaries with sutured margins and undulose extinction of grains. These microstructural observations possibly indicate that temperatures were around 300¦C during stockwork vein formation. In general, the mode of brittle failure that developed the stockwork veins can be directly related to lithological variation. The geometry of stockwork veins indicate that local vertical shortening and extension occurred in the Intrashear sequence of the HMSZ synkinematically with thrusting. Localised extension was mainly parallel to the structural trend; that is, it took place perpendicular to the direction of inferred thrusting. The development of lateral ramps most likely gave rise to extension in parts of the shear zone during continuous shortening to form swarms of stockwork veins.

Jan 1, 2004

By H. Preßlinger, H. Hiebler, K. Klepp, W. Posch, M. Mayr

It was investigated in which form sulphur is bonded in ladle slags. For this purpose, the mineralogical phases of the ladle slags were qualitatively and quantitatively evaluated by means of a microprobe. This slag characterization allowed reconstructing the bonding of sulphur into the phases of the ladle slag. Moreover, the reaction process with regard to the ionic theory as well as the structural formula for the mechanism of sulphur bonding were discussed. The bonding of sulphur into calcium aluminate slags is determined by the sulphide ion content in the slag as well as by the ratio of (CaO)/(Al2O3). Calcium sulphide separates only if the slag contains a large number of sulphide ions. When Ca12Al14O33is separated, the sulphide ion is successively integrated into the lattice. The crystal lattice of Ca12Al14O33is characterized by an open, three-dimensional anionic network composed of aluminium-oxygen tetrahedrons linking the edges. In this network, large interstitial spaces are formed, which may be filled with calcium ions on the one hand and statistically with a free oxygen or sulphide ion on the other hand. Key Words: ladle slag, structure, phases, calcium sulphide, calcium aluminate, desulphurization

Jan 1, 2004

By B. Samanta

LHD (load haul dumper) is now used as a loading machine for intermediate mechanization in underground coal mining. For survival in the intense competition in the global business environment in recent years it is essential that LHD machine should be reliable and maintained effectively and efficiently. This paper seeks to study the reliability, availability and maintainability (RAM)of an LHD machine with failure and repair data by Markov modelling. The constraints and reasons for machine unavailability are outlined. The reliability and maintainability of an LHD and its subsystems are evaluated. Possible modification or design alternatives are highlighted. Reliability and maintainability of an LHD system are disappointing. There is room to take decisions on optimal maintenance planning and machine improvement from this analysis. Keywords: reliability, availability, maintainability, Markov model, LHD

Jan 1, 2004

By Tracie Zoeller, G. Paul Neitzel, Jr. Sanders

"As-cast aluminum alloy microstructures are highly segregated. Coring occurs when solute is rejected during solidification resulting in a non-uniform solute distribution across the dendrite arms. Furthermore, coarse constituent phases are formed in the interdendritic channels as a result of coring. These constituents are either soluble or insoluble and can form from the major solute elements, or the impurity elements iron and silicon. The dissolution of these constituents, or precipitates, is an important consideration in determining the microstructural evolution of an alloy. The properties of an alloy are significantly affected by the morphology of the precipitates. Precipitates can be either beneficial or detrimental to the properties of the alloy. Regardless of the nature of the precipitates present, it is useful to understand the dissolution process. A diffusion-limited dissolution model for planar precipitates is presented and compared to an analytical solution and to models in the literature. Experimental data for the dissolution of AhCu precipitates in a dilute alloy are compared to the proposed model, and found to have good agreement.IntroductionDuring the processing of precipitation hardening alloys, beginning with the solidification step and ending with the final solution heat treatment step, there are a variety of particles that form. Some of these particles must be dissolved and solute redistributed and re-precipitated in a more homogeneous distribution than as it first appears in the as-cast microstructure. The particles can be classified by size as microstructure develops during processing. Coarse particles that form during solidification can either be soluble, partially soluble or insoluble. These particles can be the result of coring of the major solute elements as well as the limited solubility of elements such as iron and silicon. Iron and silicon can combine with the major solute elements such as copper in 2xxx alloys forming coarse phases often referred to as constituents. Figure l(a) shows the as cast microstructure with the constituent phases, Al2Cu and the insoluble phases containing Al-Fe-Mn-Cu-Si [7]. During preheating the soluble phases such as AhCu that were formed by eutectic decomposition must be taken back into solution, whereas the insoluble phases remain essentially unchanged by most thermal operations. Figure l(b) and (c) show some of these constituents after subsequent preheating steps. In Figure l(b), AhCu platelets are shown and in Figure l(c) the remnants of the AhCu phase are noticeable, along with Mn-bearing dispersoid phases. Reduction in the volume fraction and size of these phases improves the ductility and fracture toughness as well as reducing the inhomogeneities that occur during coring. Also adjacent to the dendrite arm boundaries are smaller AhCu phases that precipitate by a solid-state transformation on cooling to room temperature."

Jan 1, 2004

By A. McKenzie

During the late 1990s Anglo American PLC was evaluating the Gamsberg zinc deposit in the Northern Cape Province. As the primary South African metallurgical technology provider, Mintek became involved in the evaluation of a pyrometallurgical process for the recovery of zinc from the Gamsberg deposit. eloping DC arc furnace technology for the metallurgical industry. This includes the patented Enviroplas® process for the treatment of zinc bearing waste materials. As a consequence Mintek has developed extensive expertise in the pyrometallurgical processing of zinc bearing materials. However, Mintek?s technologies stopped with the production of Prime Western Grade (PWG) zinc. Early on in the evaluation of the Gamsberg project, it became evident that the refining of PWG zinc would play an important part in the economic viability of the project. At the time the only pyrometallurgical technology available for the refining of PWG zinc to Special High Grade (SHG) zinc was the New Jersey process. This process represents 50-year-old technology and has not undergone significant refinement since the technology was developed. In order to provide a complete pyrometallurgical flow sheet for possible implementation at Gamsberg, Mintek assessed the New Jersey process with a view to either improving the technology or developing a new technology appropriate to the 21 century. In 1998 Mintek convened a consortium consisting of Mintek, the University of Cape Town, Eskom Enterprises, Bateman Metals and Anglo American PLC. The consortium successfully applied to the Innovation Fund for funding to develop a new process for the pyrometallurgical refining of PWG zinc to SHG zinc. The main aims of the project were to develop a new technology for pyrometallurgical zinc refining that conformed to the following: ?Decrease the production cost of SHG zinc metal to stimulate the development of the Gamsberg deposit. ?Be compatible with the current Enviroplas® process, preferably as an add-on to that process. ?Should use electrical energy to benefit from local price tariffs. The project commenced at the beginning of 2000 and consisted of three phases: ?an initial technology search and assessment of the fundamental aspects of zinc distillation. ?the design of a pilot plant for zinc refining. ?the manufacture, commissioning and operation of the pilot plant. A new technology based on a DC arc boiler feeding a packed distillation column was developed and during 2003 the project culminated in the successful operation of a 200 kg/h pilot plant. Ultimately, all of the aims of the project were met and the main outcome is that an advanced process for the pyrometallurgical refining of zinc (the Zincref process) has been developed. The main innovation of the technology was the switch from an energy transfer limited process to a mass transfer limited process (for which a patent has been registered).

Jan 1, 2004

The trend for using larger equipment in open pit mining to achieve cost effectiveness raises the question about the optimum economic point of scale in the current world of globalization. The present paper treats this question through the prism of a new methodology of assessing the impact of the size of production equipment on the economic outcomes of coal mining ventures. The methodology incorporates a production scheduling optimization model that implements both principles of mine planning, coal quality optimization and waste deferment. The implementation of the waste deferment principle dealing with the spatial and time aspects of the mine sequence arrangement allows the adequate modeling of the optimality of production equipment scale through the use of mine investment parameters, such as, purchase and ownership costs and discounted cash flows analysis. A case study is provided to illustrate the applicability of the new methodology.

Jan 1, 2004

By H. Saari, M. Pates, P. C. Patnaik, A. Merati

Single crystal nickel-base superalloys such as PWA1484 exhibit superior performance compared to conventional superalloys, and are used extensively in turbine blade applications requiring good high temperature properties. The life of these blades is typically limited by cracks and erosion. Due to the high cost of these blades, welding techniques are being considered to weld/repair worn components, extending their useful lives and delaying the need for expensive replacement components. However, the sensitivities for solidification cracking and post weld heat treatment cracking are relatively high in these alloys. Electron beam (EB) welding can deliver concentrated heat sources and has the potential to address these issues. Numerous welding trials and structural tests must be conducted to identify the optimum method and welding parameters. Weldability is studied over a range of material conditions, welding parameters, and directions. The influence of welding parameters on the fusion zone microstructure and resultant weldability is investigated using combination of microscopic examination and micro-hardness testing. This paper summarizes some of the results of a feasibility study conducted to understand the effects of welding parameters on localized microstructural features, cracking sensitivity, and mechanical properties of autogenously EB welded coupons of single crystal PWA1484.

Jan 1, 2004

By Ashish D. Patel, Ramesh S. Minisandram

"Vacuum Arc Remelting (VAR) is the final and, hence, critical melting step for the production of a sound, segregation-free ingot for the manufacture of alloys used in rotating components in aircraft engines. A mathematical model for this process has been developed by the Specialty Metal Processing Consortium (SMPC). The model predicts temperature distribution in the solidifying ingot, flow in the molten metal pool, and the electromagnetic field in the ingot. These predictions may be used to estimate the effect of melting parameters on the pool profile in the ingot. In this paper, typical pool shapes and flow fields during VAR of Alloy 718 and Ti-6Al-4V are presented. The differences in the pool profile are primarily due to vastly different melting conditions. The model predictions are compared to the observed pool shapes from industrial-size VAR ingots.1. IntroductionVacuum Arc Remelting (VAR) is a process in which an electrode is melted in vacuum by the heat from a DC electric arc. Metal droplets from the electrode fall into the molten metal pool, which solidifies in a water-cooled copper crucible to form the ingot, as shown in Figure I. The ingot obtained from VAR is sound, and has superior cleanliness and chemical homogeneity. Hence, the process is the final melting process for most nickel-base superalloys and titanium alloys used in the manufacture of critical rotating components (discs & blades) of aircraft engines. Modeling of this process provides an insight into the effect of melting parameters on the molten metal pool in the solidifying ingot, which is a key first step in process optimization and defect prevention. In this paper, typical pool shapes, both measured and predicted, for VAR of Alloy 718 and Ti-6Al-4Vare presented. Alloy 718 is the most common VAR-processed nickel-base superalloy; whereas Ti-6Al-4V is the ''workhorse"" alloy for titanium-based alloys."

Jan 1, 2004

By Steven C. Borell

For more than a decade, changes have occurred each year that have improved the regulatory and business climate for mining in Alaska. These changes have taken place during Republican and Democratic governorships as well as when the state House of Representatives and Senate were controlled by either party. During some years, the changes have been relatively minor. In others, including the 2003 legislative session, the changes could only be characterized as massive. These improvements have encouraged exploration. This, in turn, has resulted in some major new discoveries. But Alaska is essentially unexplored and tremendous opportunities remain.

Jan 1, 2004

By John G. Reid

When the paper "Operations at the Greenvale Nickel Project Mine and Refinery" was delivered at the 1st International Laterite Symposium in February 1979, the Yabulu Caron plant had been operating for four years and production had just stabilized. The design had been based closely on the Caron plant at Nicaro, Cuba, built in 1944, also by Freeport. Yabulu had 10 Herreshoff ore roasters and production in 1978 was 18,682 tonne nickel as impure oxide sinter and 763 tonne cobalt in a mixed sulphide with a cobalt to nickel ratio of 1 :2.5. In the 25 years since the 1st Symposium, two more roasters have been added, but dry ore processing rate has remained relatively unchanged at 2.4M Uyr to allow a lower feed rate per roaster with associated higher recovery. The ore source has changed from the domestic Greenvale mine to imports from New Caledonia, Indonesia and the Philippines. Nickel production between 1978 and 2003 has risen by 67%, cobalt has risen by 146% and the products have changed to high purity nickel compacts and "ChemGrade" cobalt salt. The plant changes that have contributed to the increased recovery, production and product value are discussed. Keywords: Caron, Yabulu, nickel, cobalt, ammonia

Jan 1, 2004