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By Ryokichi Shimpo

Much amount of sludge is produced from the wastewater treatments in surface finishing industry. There are many problems for the abandonment of the sludge because of the high water content and heavy metals included. It is often observed that hexavalent chromium, which is toxic, is generated in the course of heat treatments of the sludge for reducing its amount by dispersing water. In this study, conditions of the sludge calcinations for reducing water contents have been examined. Maximum hexavalent chromium generation was observed in the temperature range around 773 K, at which most of the crystallization water decomposed from the sludge. When the heating temperature became higher than 1173 K, the amount of the hexavalent chromium extracted from the calcined sludge became as low as 10 mg/kg sludge. When the sludge was heated with iron oxides, FeO or Fe203, iron ferrite has been synthesized which may be used as a magnetic material. The amounts of hexavalent chromium generated in the heat treatment with iron oxides were not much different from those without iron oxides.

Jan 1, 2003

By Louis W. Cope

Since its discovery, Cuba has been called the “Pearl of the Antilles.” The country remains that, albeit a little tarnished these days. In Havana, many of the buildings are being refurbished, while some new ones are under construction. Since 1991, the laws have been relaxed so that Cuba is developing a mixed economy of central control with free market. Joint venture agreements have been signed with businesses from many countries. This does not include the United States due to its embargo. But even these regulations have been relaxed some.

Jan 1, 2003

By Doug Smith, Gary Taylor, Paul Ogryzlo

"Uranium mining and processing typically requires large quantities of high-grade reactive quicklime for the neutralization and clean-up of contaminated mine water and mill process waste streams. Currently the Saskatchewan uranium industry’s lime requirements are being supplied from deposits located in Manitoba and Alberta, resulting in transportation costs, which equal or exceed the market value of the product. During the summer of 2001, the northern village of Pinehouse located 220 kilometers south of the Key Lake uranium mill, staked two previously discovered limestone deposits. The relatively shallow deposits, known as Missi Island and Sleeping Giant are located in close proximity to one another, approximately 35 km south of Pinehouse adjacent to highway 914. This paper describes the results of a scoping study carried out by AMEC for the development of the two deposits based on a seasonal limestone mine and a continuous 40,000 to 60,000 tpy wood fired calcining plant designed to supply all of the quicklime needs of the Saskatchewan based uranium industry. Also described are the results of calcining and customer acceptance testwork on samples of lime prepared from recent Pinehouse limestone drill core. The potential benefits of the project include a significant new source of revenue for the community of Pinehouse, lower lime costs for the Saskatchewan uranium industry and employment for northerners in the mining, processing and wood harvesting operations.IntroductionInterest in the Pinehouse/Massinahigan River area for limestone was precipitated by the results of a 1977 industrial minerals drill hole program by the Saskatchewan Department of Mineral Resources. These results led to the acquisition of land in the area by Missi Island Mines Ltd who carried out extensive exploration during the period 1978-1982. They discovered a deposit on the southwest side of the Massinihigan River thought to contain approximately seven million tonnes of limestone with an average grade of 94.5% CaCO3. Missi Island carried out preliminary feasibility studies and prepared an Environmental Overview Statement. However, in spite of positive recommendations, the project was dropped in the mid 1980’s."

Jan 1, 2003

By G. H. Lind

Research into the safe and economic extraction of underground coal pillars in the Witbank and Highveld coalfields of South Africa highlighted that future practices will have to consider pertinent risks associated with this least safe of all underground coal mining methods conducted in South Africa. To this end, a computer-based program called A-PEP (Analysis for Pillar Extraction Potential) was developed to assess three aspects of this mining practice, viz. risks associated with the physical attributes, operational risk attributes and economic attributes. This intelligent tool can thus be used when planning to conduct underground pillar extraction to ensure that all pertinent risk elements and legislative requirements are considered to conduct this mining method safely before a submission is made to the Department of Minerals and Energy. Keywords: operational risk management, mine planning, underground coal mining, pillar extraction.

Jan 1, 2003

By Makiko Takahashi

A tool is being developed to predict and visualize the microstructural evolution of steels during quenching. This tool utilizes experimental data and reference data that are stored in a database to predict the microstructural development. The visualization tool animates qualitative representation of two- dimensional microstructure drawings as well as the quantitative volume fractions of phases present as a function of time. This is achieved by superimposing the Jominy End-Quench test results over the Continuous Cooling Transformation diagram of the alloy. The predicted microstructure is presented through the web browser to maximize the ease of use. In addition, a parallel coordinate system is used to aid in identifying similarities within the data set by presenting the large number of data at a glance. The results for 4140 steel that was quenched in a wide variety of quenchants will be presented to illustrate the prediction and visualization tools. Keywords: Quenching, Microstructure Prediction, Simulation, Data Visualization, Database, Applet, Animation

Jan 1, 2003

By H. Copur

Experimental studies for quantification of force and brittleness indices relevant to rock cutting performance are presented. A simple interpretation method is developed, which quantifies the force-penetration response obtained from indentation tests. Basic parameters of the quantification are force increment and decrementrates, force increment and decrement periods, and number of increment and decrement data points. Blocks of eleven different rock samples were collected from different operating mines in Turkey and subjected to indentation tests to calculate the indices. The samples included harzburgite, serpentinite, trona, limestone, claystone, two different sandstone samples, siltstone and three different chromite ore samples. The concept was validated by a set of full-scale linear cutting tests using a conical cutter for measuring the cutting performance in relieved and unrelieved conditions, i.e. cutter forces, specific energy, size distribution of rock cuttings. The rock cuttings were sieved to determine coarseness index, indicates coarse chip generation characteristics, and size distribution. The force index is moderately correlated with the cutting performance and mechanical properties of the rocks, and poorly correlated with the coarseness index and size distribution of cuttings. A general and moderate trend is observed between the brittleness index and the coarseness index, cutting performance for unrelieved cutting conditions and mechanical properties of the rocks. However, additional data is required to fill the data gaps and to potentially establish relationship between the brittleness index and all other parameters.

Jan 1, 2003

By C. Pelley, S. Kelebek, S. Gregersen, P. Katsabanis

A series of small scale tests have been conducted to evaluate the effect of micro-fracture development, imposed by blasting, on the physical properties of the rock as well as its resistance to crushing and grinding. The uniaxial compressive strength, tensile strength, Young’s modulus, Poisson’s ratio, P-wave, S-wave velocity, point load strength index and grinding work index were evaluated for samples without any blasting load and for samples which had received a variety of blast loads, such as a simple side impact from a detonating cord, or combined impacts without any delays and with very short delays. The investigation covered two types of rock, granodiorite and limestone. The effect of blasting load on the physical and rock mechanics parameters of the rock was clearly shown and damage was quantified and related to loading. However the work index did not show significant differences between blasted and not blasted samples, probably due to the relatively low level of impact. Numerical modelling using the AutodynTM code was used to demonstrate damage development in the various configurations tested.

Jan 1, 2003

Pyrometallmurgical reactors constitute a key processing component in the total primary and secondary resource cycle, being involved both in primary smelting, converting and extraction, as well as the reprocessing of scrap, from aluminum cans to end-of-life automobiles. To effectively control the overall resource cycle, one needs to take a systems modeling approach of the whole cycle, seeking to also understand the dynamic process behavior of the individual components of the cycle, and then especially the part that contributes most to the chemical conversion, namely the pyrometallurgical reactor. This paper highlights the role of pyrometallurgical thermodynamics, in the whole resource cycle and specifically places equilibrium thermochemistry in the context of process dynamics where large variable inventories are recycled or maintained within the system. This paper will therefore review the semi-empirical dynamic modeling tools, which are used to model complex systems with the specific goal of developing dynamic predictive models, which also include slag-alloy chemistry, towards controlling the recycling in a feed forward manner. To illustrate the primary processing side, high carbon ferrochrome will be presented as a brief case study. It also will show how the distributed nature of the chemistry of melts in the case of primary extraction, and secondary materials such as recycled end-of-life vehicles, have a significant impact on the process outcomes and model predictions. It is therefore argued that the fundamental thermodynamics and kinetics in metallurgical reactors playa final crucial role in modeling the closed material cycle, but only when it is used in conjunction with process systems theory based on reconciled data for parameter estimation and model calibration.

Jan 1, 2003

By Edward Rosenberg

The synthesis and characterization of silica polyamine composites modified with a variety of sulfur containing ligands is described. The two most successful ligands in terms of sulfur in-corporation and mercury capture are ethylene sulfide and carbon disulfide. The ethylene sulfide forms either an amino mercaptane or a polysulfide upon reaction with amino groups on the composite. The carbon disulfide undoubtedly forms a dithiocarbamate functional group upon reaction of the amino group under basic conditions. Both materials posses excellent capture kinetics and capacities for mercury, Once captured, the mercury is extremely difficult to remove from the composite materials, even with concentrated acids, and they easily pass the TCLP test. The materials are compared with related thioether modified silica polyamine composites and appropriate potential applications are discussed.

Jan 1, 2003

By M Scoble, R A. Hall

The mining industry has aggressively sought competitiveness through increased productivity and return on investment. A primary strategy has been the pursuit of economies of scale. This has also been dependent upon the implementation of new technology and systems integration. System integration has been accomplished through the implementation of mine dispatch, global positioning and mine wide communication technologies. These technologies have tended to advance at different rates of development and implementation. The result has been that across the industry, and even within companies, mines are at various stages of operational system re-engineering in these areas, driven by improvements in productivity and operational efficiency. Although this strategy has been successful, little effort has been made to analyse change in operational performance in order to understand and model the effects of scale in a quantitative manner. This paper considers the particular impact of equipment scale, together with potential future trends. It then presents and demonstrates a preliminary method to quantify through simulation the anticipated benefits of economies of scale.

Jan 1, 2003

By N. Barton, E. Quadros

This paper addresses the prediction of groutable joint apertures, grout penetration limitations, and possible grout take volumes per cubic metre of rock, as a result of 5 to 10 MPa pre-injection pressures ahead of tunnels. Joints are obviously opened more than in the preceding Lugeon tests, and many rock mass properties can apparently be improved if stable micro-cement based materials are used. Cet article concerne la prédiction des ouvertures des fractures injectables, les limites de pénétration du coulis et les volumes injectés par mètre cube, d’après les résultats des injections à l’avant tête des tunnels sous pressions de 5 à 10 MPa. Evidemment les joints s’ouvrent plus que dans les essais Lugeon précédents. Maintes propriétés du massif peuvent apparemment être améliorés si l’on emploi des coulis a base de micro-ciment stable. Die Publikation widmet sich der Prognose injizierbarer Kluftöffnungen, Grenzwerte für Injektionsreichweiten und erreichbarer Injektionsvolumen pro Kubikmeter injizierter Fels, durch die Anwendung von 5 bis 10 MPa Vorinjektionsdrücken vor der Tunnelfront.Die Klüfte werden offensichtlich weiter geöffnet als in den vorhergegangenen Lugeon Versuchen und mehrere Felsparameter können durch die Verwendung von stabilisierten Micro-Zement basierten Injektionsmaterialien verbessert werden.

Jan 1, 2003

By Bora Derin

The partial pressure ratios of sulfur and oxygen for several copper flash smelting plants were derived using the Reddy-Blander (RB) model and predicted dissolved sulfur contents available in the literature. The sulfide capacities (Cs) of six different flash smelting plants (FeO-CuO0.5- CaO-MgO-FeOwAIOl.s?SiO2) slags were calculated. The log (Po2/PS2) versus matte grades of various industrial processes was determined. The PoiPS2 ratio increased with an increase of copper grade. The calculated partial pressure ratios for the copper flash smelting are in good agreement with those of the experimental data.

Jan 1, 2003

By Gordon King

The City of Atlanta Water Department required the construction of a two sludge tanks and a wet well at the existing Chattahoochee Water Treatment Plant. Western Summit won a design build contract to build the project and proceeded to evaluate the wet well size options, and construction procedures. The final design required the construction of a 1 million gallon tank. The proximity of the underground tank to adjacent roads and existing plant structures ruled out laying back the excavation. As a result a tied back sheet pile retaining wall was initially proposed.

Jan 1, 2003

By Z. Jin, Q. Yun, C. Lu

This paper presents a quantitative assessment model for the assessment of environmental load in gold production, which is based on environmental ecology, Life-Cycle Assessment and technical conditions of gold production in China. This model can make environmental assessment in terms of a set of indexes and quantitative approach by means of artificial neural network, which also improves the theory of Life-Cycle Assessment. Keywords: Artificial neural networks, Environmental load, Assessment, Utility function, Gold production

Jan 1, 2003

By Lyman File

This paper discusses the overall challenges to construct a two-lane highway tunnel located in southwestern Colorado on U.S. Highway 160 for the Colorado Department of Transportation by the Kiewit Western Company. The purpose of this project is to provide the excavation and temporary support for a highway tunnel 280 m (916 feet) long. The tunnel cross section is 14.3 m (47 feet) wide by 8.5 m (28 feet) high, 105 m2 (1,130 SF).Construction methods include conventional drill and blast excavation with rockbolt and shotcrete ground support. This unique tunnel is being constructed under alpine tunnelling conditions and in the immediate vicinity of active highway traffic.

Jan 1, 2003

By N. Kornelius

In recent years there has been an increased focus on corporate governance matters worldwide. The duties and responsibilities of directors of companies have come under close scrutiny, with shareholders increasing their demands for greater responsibility and accountability. Media attention and pressure groups have also had their effect. Governmental actions have supported these demands and directors have witnessed sweeping legislative changes imposing more onerous duties and liabilities than formerly imposed upon them at common law and in terms of the Companies Act. At the same time, the power of regulatory bodies has been increased to enforce this legislation and make someone pay to remedy an alleged infringement. Breach of such duties may incur personal or criminal liability, or both. Environmental protection legislation has become a particularly prevalent feature in this regard, and the number and complexity of statutes concerning the environment have increased over the past few years. Directors of South African companies will be familiar with relevant acts such as the National Environmental Management Act 107 of 1998; Conservation of Agricultural Resources Act 43 of 1983;Hazardous Substances Act 15 of 1973, as well as the National Water Act 36 of 1998. Now the directors of mining companies are faced with the Mineral and Petroleum Resources Development Act 28 of 2002.

Jan 1, 2003

By Jonkion M. Font

An expression for the distribution ratio of arsenic between slag and copper matte or liquid copper was developed by both, an extension of the Reddy-Blander moderl for deriving a priori the arsenic capacity, and by a relationship between the arsenic capacity and the arsenic distribution ratio. In this study, the a priori arsenic capacities in the FeO-SiO2, CaO-SiO2,MgO-SiO2, FeO-CaO-SiO2, FeO1.5-CuO0.5-MgO-SiO2, FeO-FeO1.5-CuO0.5-CaO-Mgo and FeO-FeO1.5-CuO0.5-CaO-Mgo-SiO2, slags were calculated at 1573 K. The a priori arsenic distribution ratio between the FeO-FeO1.5-CuO0.5-CaO-MgO-SiO2 slag and copper matte mn (Lx, )' and between the FeO-FeO1.5-SiO2 or FeO-FeO1.5-CuO0.5*-CaO-Mgo slag and liquid copper (Ls/cua) were calculated. The model calculated data are found to be in good agreement with the reported experimental data. The availability of reliable thermodynamic data for slag components and impurities in the slag-matte- metal system is essential for the accurate prediction of impurity capacities and distribution ratio data. The arsenic distribution ratio model developed here, can be extended for predication in multi-componet slags and mattes or liquid metal, and thereby may lead to the development of new slag systems for the efficient removal of arsenic in the copper smelting, converting and refining processes,

Jan 1, 2003

By M E. Pierce

Recent advances in comminution and heap leach technology have resulted in the development of many large-scale, low-grade open pit mines that coincide with areas of historical underground workings. Twoand three-dimensional numerical modelling has been conducted to assess the interaction between open pit slope stability and remnant underground voids. Most design analyses for open pit slopes assume a two-dimensional problem geometry. This is not the condition encountered in practice ù particularly when remnant underground voids interact with a large-scale open pit slope. Three-dimensional numerical models have been shown to provide a more realistic representation of the interaction between overall open pit slope stability and remnant underground voids.

Jan 1, 2003

By F. Yang, T. Pan, T. Zhao, Z. Shao, D. Zuo

In this paper, the development and applications of robot technique is summarized, and the status and developing direction of China coal mine robotics. A description of the research meaning, frame and key technology of underground salvage robot is given. Keywords: coal mine, robot, special robot, salvage robot.

Jan 1, 2003

By N J. Arunakumaren

A coal mine is proposed for an area where a major river traverses the project area. There were initial concerns that inflow of groundwater from exposures of high permeability alluvium associated with the river system could pose mine dewatering problems together with adverse impacts on surface water resources in the river. The project included collation and analysis of geological and hydrogeological data collected historically over a long period of project investigation and evaluation. The project also included establishment of additional groundwater monitoring points to provide a reliable groundwater contours. The groundwater level contours were produced to allow numerical models to be calibrated to support estimation of groundwater inflow. River bed cross sections were also prepared to assist study of the effect of river flow on the inflow. Two separate MODFLOW groundwater models were produced to simulate long-term groundwater inflow to the mine with an upper model consisting of the Quaternary and Tertiary alluvium lumped together and a lower, separate model consisting of Mesozoic coal measures. Analytical solutions were used to predict initial inflow from the alluvium and from the coal measures.

Jan 1, 2003